Salinity is one of the fundamental ocean state variables. Variations of ocean salinity can be used to infer changes in the global water cycle and air-sea freshwater exchange. Many institutions have developed gridded Argo products of global coverage. However, the existing gridded salinity products have not yet been dedicatedly intercompare and assessed. In this study, the mean state, annual and interannual variabilities, and decadal changes of ocean salinity from five Argo-based gridded salinity products, available from UK Met Office, JAMSTEC, Scripps Institution of Oceanography, China Second Institute of Oceanography, and International Pacific Research Center, are examined and compared for their overlapping period of 2005-2015 within two depth intervals (0-700 m and 700-2000 m), as well as the sea surface. Though some global and regional features are relatively reproducible, obvious discrepancies are found particularly for the deeper layer. These discrepancies are not apparent on the 11-year climatological mean or the trend patterns, but are readily evident on temporal variations. For instance, the potentially undersampled current systems in the North Atlantic and Southern Ocean are one of the main reasons for the observed discrepancies. The gridded products from Scripps, JAMSTEC and Met Office show large deviation from the ensemble mean, particularly in regions like the Atlantic Ocean and the tropical Pacific. Large disagreements are found in the first and final years, which can lead to different estimates on decadal trends. This study can serve as a useful reference on how to utilize and improve the existing gridded salinity products.

Increasing population and extensive urbanization have strained resources around the world, promoting water scarcity and solid waste accumulation. Addressing the issues of access to safe drinking water and basic sanitation in developing countries is challenging due to limited technological and financial resources. Therefore, it is imperative that durable, low-cost, and sustainable technologies are developed to help alleviate these problems. At the same time, the production of solid waste has increased and includes waste tires, which pose a health and environmental hazard. Although efforts have been made to develop new markets for recycled scrap tires, a vast majority are still being stockpiled or landfiled. This study aims to evaluate a water treatment system that addresses the problem of access to safe drinking water and sanitation, while providing a new market for recycled scrap tires. The system, termed ECOL-Mem, utilizes commercially available porous rubber tubing (PRT), which is marketed for drip irrigation purposes. To our knowledge, this is the first time this product has been used in a water treatment system. The PRT is manufactured through a hot extrusion process and contains 65% recycled crumb rubber and a binder (e.g. polyethylene). The proposed configuration simulates a hollow fiber membrane filtration system driven by a vacuum that operates inside-out. The system was first tested using clean water to obtain intrinsic characteristics. It was then tested using bentonite and sludge solutions that simulated impaired source water. For the case of a bentonite solution containing 700 mg/L, 20L of permeate could be obtained in one hour while the total solids removal remained around 20%. In order to improve the water quality, a flocculation-enhanced filtration phase was explored. The flocculant is chitin, a biopolymer that can be derived from waste shellfish. Upon addition of the chitin, between 60% and 70% of total solids removal could be obtained for different feed waters. Although optimization is needed, the PRT system has shown promising results, while providing a technology that targets the needs of developing countries in the areas of safe drinking water, basic sanitation, and solid waste recycling.

This thesis is about Global Water Governance (GWG) – an overarching normative framework by which water management practices across all scales may be guided. More specifically, it seeks to develop an understanding of how Corporate Water Stewardship (CWS), and its facilitation of the inclusion of companies’ perspectives to address water issues, affects GWG. Understood as a form of market environmentalism – a doctrine premised on mutual synergies between environmental conservation and economic growth – CWS provides a channel for companies to participate in, as well as spearhead, a quest for more sustainable water management within and beyond their own operations. Despite a proliferation of activities undertaken by companies, CWS has attracted limited scholarly attention, and an overarching analysis of the effects that mounting corporate involvement has had on the global water discourse has so far been absent from scholarly debates. This research draws on over 500 documents published by companies, NGOs, and other organisations, alongside 50 interviews with key practitioners. It specifically questions: (i) the empirical context through which CWS emerged; (ii) the manner in which companies from various sectors conceptualise water and its management; (iii) the way CWS endeavours are legitimised and; (iv) the mechanisms through which companies exert influence. Chapters 4 to 8 comprise an analysis of the main research findings. Chapter 4 investigates why companies are interested in water issues, how companies frame them, and how CWS could materialise. Chapters 5 and 6 address how companies from different sectors engage in CWS in the contexts of water resources management, and Water, Sanitation, and Hygiene (WASH). Chapter 7 turns attention to how companies draw on non-conventional sources of authority to legitimise their activities, and Chapter 8 analyses how CWS influences GWG. When taken holistically, the thesis attests to the key point that the inclusion of companies in solving water issues matters; their presence changes the status quo of water governance. More importantly, the thesis goes beyond such assertions by pointing towards how it matters. It finds that, as a result of corporate involvement, water is being reconceptualised from an environmental and social risk to society, to an economic risk for businesses. Moreover, although companies may not be doing this in an ill-intentioned way, the research suggests that when they participate in water interventions, they alter GWG by promoting the commercialisation of water management, the valuation of water risk, and the liberalisation of water governance. Thus, although the involvement of companies may contribute to improving the management and governance of water across all scales, their involvement has to be matched with proper ‘checks and balances’ to ensure that CWS serves the public good, rather than simply contributing to private profit.

The purpose of this study was to use the Global Water Stormwater Sampler SS201 to characterize the urban runoff in Pecan Creek. Location of the samplers was influenced by land use and ease of installation. Determination of the constituents for analysis was modeled after those used in the NPDES permit for seven cities within the Dallas/Ft.Worth metroplex. Some metals, notably cadmium and arsenic, exceeded the U.S. EPA's MCL's. Statistical analysis revealed first flush samples to be significantly more concentrated than composite samples. Minimum discharge loadings were found to be significantly lower than maximum discharge loadings. Additionally there were significant differences of specific constituents between station locations and storm events.

Today billions of people live without access to basic sanitation facilities, and thousands die every week due to diseases caused by fecal contamination associated with improper sanitation. It has thus become crucial for decision makers to have access to relevant and sufficient data to implement appropriate solutions to these problems. The Global Water Pathogen Project http://www.waterpathogens.org/ is dedicated to providing an up-to-date source of data on pathogen reduction associated with different sanitation technologies that are important if the world is to achieve the Sustainable Development Goals (SDGs) related to health and sanitation provision. In this research, a subset of the Global Water Pathogen Project (GWPP) data is used to access the reduction of bacteria and viruses across different mechanical and natural sanitation technologies. The order of expected removal for bacteria during wastewater treatment was reported as highest for a membrane bioreactor (4.4 log10), waste stabilization pond (2.3 log10), conventional activated sludge (1.43 log10), anaerobic anoxic oxic activated sludge (1.9 log10), trickling filter (1.16 log10), and upflow anaerobic sludge blanket reactor (1.2 log10). Furthermore, the order of expected removal for viruses was reported as highest for a membrane bioreactor (3.3 log10), conventional activated sludge (1.84 log10), anaerobic anoxic oxic activated sludge (1.67 log10), waste stabilization pond (1 log10), upflow anaerobic sludge blanket reactor (0.3 log10) and trickling filter (0.29 log10). It was found that hydraulic retention time (HRT) had a statistically significant relation to the reduction of bacteria in an anaerobic, anoxic oxic treatment system. Similarly, a significant relation was found between the number of waste stabilization ponds in series and the expected reduction of bacteria. HRT was also found to be a significant factor in virus reduction in waste stabilization ponds. Additionally, it was observed that waste stabilization ponds, trickling filters, and UASB reactors could obtain a greater reduction in bacteria (5-7 log10) when combined with additional treatment (e.g., chemical disinfection or use of maturation ponds). Also, mechanized systems, such as activated sludge systems and membrane bioreactors, obtained a greater reduction (2-3 log10) of viruses when compared to a natural system. It was concluded that the selection of the best suitable technology for pathogen reduction depends on environmental, design, and operational factors as well as considering the performance of specific wastewater treatment systems individually as well as when combined with other treatment technologies that may provide added removal of microbial constituents.

Since the start-up of the GRACE (Gravity Recovery And Climate Experiment) mission in 2002 time dependent global maps of the Earth's gravity field are available to study geophysical and climatologically-driven mass redistributions on the Earth's surface. In particular, GRACE observations of total water storage changes (TWSV) provide a comprehensive data set for analysing the water cycle on large scales. Therefore they are invaluable for validation and calibration of large-scale hydrological models as the WaterGAP Global Hydrology Model (WGHM) which simulates the continental water cycle including its most important components, such as soil, snow, canopy, surface- and groundwater. Hitherto, WGHM exhibits significant differences to GRACE, especially for the seasonal amplitude of TWSV. The need for a validation of hydrological models is further highlighted by large differences between several global models, e.g. WGHM, the Global Land Data Assimilation System (GLDAS) and the Land Dynamics model (LaD). For this purpose, GRACE links geodetic and hydrological research aspects. This link demands the development of adequate data integration methods on both sides, forming the main objectives of this work. They include the derivation of accurate GRACE-based water storage changes, the development of strategies to integrate GRACE data into a global hydrological model as well as a calibration method, followed by the re-calibration of WGHM in order to analyse process and model responses. To achieve these aims, GRACE filter tools for the derivation of regionally averaged TWSV were evaluated for specific river basins. Here, a decorrelation filter using GRACE orbits for its design is most efficient among the tested methods. Consistency in data and equal spatial resolution between observed and simulated TWSV were realised by the inclusion of all most important hydrological processes and an equal filtering of both data sets. Appropriate calibration parameters were derived by a WGHM sensitivity analysis against TWSV. Finally, a multi-objective calibration framework was developed to constrain model predictions by both river discharge and GRACE TWSV, realised with a respective evolutionary method, the ε-Non-dominated-Sorting-Genetic-Algorithm-II (ε-NSGAII). Model calibration was done for the 28 largest river basins worldwide and for most of them improved simulation results were achieved with regard to both objectives. From the multi-objective approach more reliable and consistent simulations of TWSV within the continental water cycle were gained and possible model structure errors or mis-modelled processes for specific river basins detected. For tropical regions as such, the seasonal amplitude of water mass variations has increased. The findings lead to an improved understanding of hydrological processes and their representation in the global model. Finally, the robustness of the results is analysed with respect to GRACE and runoff measurement errors. As a main conclusion obtained from the results, not only soil water and snow storage but also groundwater and surface water storage have to be included in the comparison of the modelled and GRACE-derived total water budged data. Regarding model calibration, the regional varying distribution of parameter sensitivity suggests to tune only parameter of important processes within each region. Furthermore, observations of single storage components beside runoff are necessary to improve signal amplitudes and timing of simulated TWSV as well as to evaluate them with higher accuracy. The results of this work highlight the valuable nature of GRACE data when merged into large-scale hydrological modelling and depict methods to improve large-scale hydrological models. / Das Schwerefeld der Erde spiegelt die Verteilung von Massen auf und unter der Erdoberfläche wieder. Umverteilungen von Erd-, Luft- oder Wassermassen auf unserem Planeten sind damit über eine kontinuierliche Vermessung des Erdschwerefeldes beobachtbar. Besonders Satellitenmissionen sind hierfür geeignet, da deren Umlaufbahn durch zeitliche und räumliche Veränderung der Schwerkraft beeinflusst wird. Seit dem Start der Satellitenmission GRACE (Gravity Recovery And Climate Experiment) im Jahr 2002 stellt die Geodäsie daher globale Daten von zeitlichen Veränderungen des Erdschwerefeldes mit hoher Genauigkeit zur Verfügung. Mit diesen Daten lassen sich geophysikalische und klimatologische Massenumverteilungen auf der Erdoberfläche studieren. GRACE liefert damit erstmals Beobachtungen von Variationen des gesamten kontinentalen Wasserspeichers, welche außerordentlich wertvoll für die Analyse des Wasserkreislaufes über große Regionen sind. Die Daten ermöglichen die Überprüfung von großräumigen mathematischen Modellen der Hydrologie, welche den natürlichen Kreislauf des Wassers auf den Kontinenten, vom Zeitpunkt des Niederschlags bis zum Abfluss in die Ozeane, nachvollziehbar machen. Das verbesserte Verständnis über Transport- und Speicherprozesse von Süßwasser ist für genauere Vorhersagen über zukünftige Wasserverfügbarkeit oder potentielle Naturkatastrophen, wie z.B. Überschwemmungen, von enormer Bedeutung. Ein globales Modell, welches die wichtigsten Komponenten des Wasserkreislaufes (Boden, Schnee, Interzeption, Oberflächen- und Grundwasser) berechnet, ist das "WaterGAP Global Hydrology Model" (WGHM). Vergleiche von berechneten und beobachteten Wassermassenvariationen weisen bisher insbesondere in der jährlichen Amplitude deutliche Differenzen auf. Sehr große Unterschiede zwischen verschiedenen hydrologischen Modellen betonen die Notwendigkeit, deren Berechnungen zu verbessern. Zu diesem Zweck verbindet GRACE die Wissenschaftsbereiche der Geodäsie und der Hydrologie. Diese Verknüpfung verlangt von beiden Seiten die Entwicklung geeigneter Methoden zur Datenintegration, welche die Hauptaufgaben dieser Arbeit darstellten. Dabei handelt es sich insbesondere um die Auswertung der GRACE-Daten mit möglichst hoher Genauigkeit sowie um die Entwicklung einer Strategie zur Integration von GRACE Daten in das hydrologische Modell. Mit Hilfe von GRACE wurde das Modell neu kalbriert, d.h. Parameter im Modell so verändert, dass die hydrologischen Berechnungen besser mit den GRACE Beobachtungen übereinstimmen. Dabei kam ein multikriterieller Kalibrieralgorithmus zur Anwendung mit dem neben GRACE-Daten auch Abflussmessungen einbezogen werden konnten. Die Modellkalibierung wurde weltweit für die 28 größten Flusseinzugsgebiete durchgeführt. In den meisten Fällen konnte eine verbesserte Berechnung von Wassermassenvariationen und Abflüssen erreicht werden. Hieraus ergeben sich, z.B. für tropische Regionen, größere saisonale Variationen. Die Ergebnisse führen zu einem verbesserten Verständnis hydrologischer Prozesse. Zum Schluss konnte die Robustheit der Ergebnisse gegenüber Fehlern in GRACE- und Abflussmessungen erfolgreich getestet werden. Nach den wichtigsten Schlussfolgerungen, die aus den Ergebnissen abgeleitet werden konnten, sind nicht nur Bodenfeuchte- und Schneespeicher, sondern auch Grundwasser- und Oberflächenwasserspeicher in Vergleiche von berechneten und GRACE-beobachteten Wassermassenvariationen einzubeziehen. Weiterhin sind neben Abflussmessungen zusätzlich Beobachtungen von weiteren hydrologischen Prozessen notwendig, um die Ergebnisse mit größerer Genauigkeit überprüfen zu können. Die Ergebnisse dieser Arbeit heben hervor, wie wertvoll GRACE-Daten für die großräumige Hydrologie sind und eröffnen eine Methode zur Verbesserung unseres Verständnisses des globalen Wasserkreislaufes.

学位プログラム名: 京都大学大学院思修館 / 京都大学 / 0048 / 新制・課程博士 / 博士(総合学術) / 甲第21233号 / 総総博第5号 / 新制||総総||1(附属図書館) / 京都大学大学院総合生存学館総合生存学専攻 / (主査)特定教授 林 信夫, 教授 濵本 正太郎, 教授 山敷 庸亮 / 学位規則第4条第1項該当 / Doctor of Philosophy / Kyoto University / DGAM

<p>Relevant information is essential for finding solutions in Integrated Water Management (IWM). Complex water systems and a need for increasing integration of sectors, actors and scales in IWM require new methods for developing and managing such information. This thesis investigates the role of information within the IWM process, as well as the main challenges for development of representative, accessibleand harmonized information. Results show how information needs and the information production process for IWM may be systematized, and indicate a large potential for information system development for IWM. However, in order to reach the full potential, today’s limited and heterogeneous water information needs to become more comprehensive, transparent, interoperable, dynamic, scalable and openly accessible. Large pressures on water systems are found in coastal catchment areas that are unmonitored across the local to the global scale, indicating a large importance of these areas for nutrient and pollutant loading. The globally accessible runoff data from catchment areas that are rich in pressures from population, agriculture and general economic activity further exhibit a rapidly declining trend during recent years. Major water system changes may therefore pass unnoticed if analyzed on the basis of openly accessible runoff global data. Furthermore, large discrepancies are found between land cover databases, which may result in major uncertainties in quantification of water and evapotranspiration flows. Identified information challenges may be relatively easily overcome by making better use of available information, while other challenges such as development of consistent baselines of core data and a possible re-prioritization of water-environmental monitoring programs may be both difficult and costly.</p>

Relevant information is essential for finding solutions in Integrated Water Management (IWM). Complex water systems and a need for increasing integration of sectors, actors and scales in IWM require new methods for developing and managing such information. This thesis investigates the role of information within the IWM process, as well as the main challenges for development of representative, accessibleand harmonized information. Results show how information needs and the information production process for IWM may be systematized, and indicate a large potential for information system development for IWM. However, in order to reach the full potential, today’s limited and heterogeneous water information needs to become more comprehensive, transparent, interoperable, dynamic, scalable and openly accessible. Large pressures on water systems are found in coastal catchment areas that are unmonitored across the local to the global scale, indicating a large importance of these areas for nutrient and pollutant loading. The globally accessible runoff data from catchment areas that are rich in pressures from population, agriculture and general economic activity further exhibit a rapidly declining trend during recent years. Major water system changes may therefore pass unnoticed if analyzed on the basis of openly accessible runoff global data. Furthermore, large discrepancies are found between land cover databases, which may result in major uncertainties in quantification of water and evapotranspiration flows. Identified information challenges may be relatively easily overcome by making better use of available information, while other challenges such as development of consistent baselines of core data and a possible re-prioritization of water-environmental monitoring programs may be both difficult and costly.