The Gulf of Mexico hypoxic zone is created by strong persistent water stratification and nutrient loading from the Mississippi River which fuels primary production and bacterial decomposition. The Texas-Louisiana shelf becomes seasonally oxygen depleted and hypoxia (O2 less than or equal to 1.4 ml l-1) occurs. Low oxygen environments are conducive for the microbial production of nitrous oxide (N2O), a powerful greenhouse gas found in the atmosphere in trace amounts (319 ppbv). Highly productive coastal areas contribute 61% of the total oceanic N2O production and currently global sources exceed sinks. This study is the first characterization of N2O produced in the Gulf of Mexico hypoxic zone. Because of enhanced microbial activity and oxygen deficiency, it is hypothesized that the Gulf of Mexico hypoxic zone is a source of N2O to the atmosphere. Seasonal measurements of N2O were made during three research cruises in the Northern Gulf of Mexico (Sept. 2007, April 2008, and July 2008). Water column N2O profiles were constructed from stations sampled over time, and bottom and surface samples were collected from several sites in the hypoxic zone. These measurements were used to calculate atmospheric flux of N2O. The Gulf of Mexico hypoxic zone was a source of N2O to the atmosphere, and N2O production was highest during times of seasonal hypoxia. N2O was positively correlated with temperature and salinity, and negatively correlated with oxygen concentration. Atmospheric fluxes ranged from -11.27 to 153.22 umol m-2 d-1. High accumulations of N2O in the water column (up to 2878 % saturated) were associated with remineralization of organic matter at the base of the pycnocline and oxycline. Seasonal hypoxia created a source of N2O to the atmosphere (up to 2.66 x 10-3 Tg N2O for the month of September 2007), but there was a slight sink during April 2008 when hypoxia did not occur. Large fluxes of N2O during the 3 to 5 month hypoxic period may not be counterbalanced by a 7 to 9 month sink period indicating the Gulf of Mexico hypoxic zone may be a net source of N2O to the atmosphere.

Recent hurricanes in the Gulf of Mexico (e.g., Ivan, Dennis, Katrina, Rita and Ike) were observed to develop wave conditions that were near or exceeded the predicted 100-year conditions. As a result, many offshore facilities, as well as coastal infrastructure, which were designed to withstand the 100-year condition, were damaged. New estimates of extreme conditions, which incorporate recently observed maxima, are needed to provide better guidelines for design of coastal and offshore structures. Berek et al. (2007) have used modeled data to develop new criteria, but these estimates can be very sensitive to the data and to the statistical methods used in the development. Berek's estimates also do not cover the entire Gulf of Mexico. We have developed updated estimates of the 100-year extreme wave conditions for the entire Gulf of Mexico using a more comprehensive approach. First, the applicability of standard parametric wind models was examined and appropriate adjustments to the Rankine vortex model were developed to reduce the wind field errors during hurricane conditions. The adjusted winds reduced the error by up to 25 percent compared to the original Rankine vortex model. To obtain reliable wave data, merged wind fields were generated using the NCEP/NCAR Reanalysis 1 project modeled wind data for background wind and the parametric wind model for hurricane conditions. Next, the SWAN wave model was used for the 51-year period from 1958 to 2008 along with multiple statistical methods (Gumbel, Weibull and GEV-Generalized Extreme Value distribution). The effect of the recent hurricane season (2004-2008) shows that maximum 100-year wave height values and their distribution changes. A resampling technique (bootstrap) is used to evaluate and select the optimum statistical method to estimate more appropriate extreme wave conditions.

In the northern Gulf of Mexico, seafloor hydrocarbon fluid and gas seepage is an ubiquitous process on the continental margin. Although seafloor seepage and seep-related features (mud volcanoes, carbonate formation) have been studied for many years, little is known about their mechanisms of formation and the relationship of sub-surface structure to current seep activity. In this study, we examined three seafloor seeps in the Garden Banks and Mississippi Canyon areas using exploration and reprocessed 3D multi-channel seismic (MCS) data augmented with side-scan sonar (Garden Banks site) to characterize hydrocarbon seep activity and develop an understanding of the processes that led to their formation. Side-scan sonar data provided high resolution coverage of the seafloor while the exploration seismic data were used to image near and deep sub-surface features. Additionally, the 3D amplitude extraction maps were useful in delineating amplitude anomalies often associated with seep related activity. The reprocessed 3D seismic data were used to map in greater detail near seafloor features and amplitude anomalies. Using remote sensing geophysical data, we were effectively able to map sub-surface features such as salt topography, seep-related faults and geophysical indicators of hydrocarbons and correlate them with seafloor amplitude anomalies and fault traces in order to characterize seep activity level. The southern mud volcano in the Garden Banks site is characterized as an established high flux seep vent owing to signs of active seepage and sediment flows as well as the build-up of hard grounds. The northern mud volcano in the area, with greater hard ground build-up and fewer signs of active seepage represents an established low flux seep vent. In the Mississippi Canyon area, the data suggest that the seep mound can be characterized as a mature high flux vent due to the extensive build-up of hard ground, evidence of gas hydrates and signs of active seepage and sediment flows. The mechanisms of formation are similar between the two study sites. Upwelling salt appears to have fractured the sub-surface leading to the formation of fault induced depressions. Mapping of geophysical indicators of hydrocarbons implies that hydrocarbon migration is occurring along bedding planes to the fault systems underlying the depressions. Here they appear to migrate vertically to the seafloor creating the topographic features and seafloor amplitude anomalies that characterize the seeps

Total mercury (Hg) levels were determined in the tissues of ten taxa of pelagic fishes, with a special emphasis on apex predators (large vertebrates). Highest Hg levels were observed in blue marlin (Makaira nigricans), carcharhinid sharks (Genus Carcharhinus) and little tunny (Euthynnus alletteratus), ranging from 1.08 to 10.52 ppm. Moderate to low concentrations (<1.0 ppm) were observed in blackfin tuna (Thunnus atlanticus), cobia (Rachycentron canadum), dolphinfish (Coryphaena hippurus), greater amberjack (Seriola dumerili), king mackerel (Scomberomorus cavalla), wahoo (Acanthocybium solandri) and yellowfin tuna (Thunnus albacares). For the majority of species examined, Hg level did not vary significantly between locations (Texas and Louisiana) and years (2002 and 2003). The relationship between Hg level and fish size/weight was also explored and six taxa (blackfin tuna, carcharhinid sharks, dolphinfish, king mackerel, wahoo, yellowfin tuna) showed significant positive relationships between Hg level and body size and/or weight. Natural dietary tracers, stable isotopes (15N, 13C) and fatty acids were used to evaluate the relationship between Hg and trophic position and the relationship between Hg and dietary history. Stable nitrogen isotope analysis showed that Hg levels in fish tissues were positively associated with trophic position. Based on the 13C and 15N values of pelagic consumers examined in this study, three natural groups were identified with cluster analysis, and the same groupings were detected based on fatty acid profiles. This not only confirmed the existence of these natural groupings, but also indicated that the distinguishing factors for the grouping was likely connected with the dietary history of these fishes. The classification tree based on the fatty acid profiles of pelagic fishes readily separated fishes from different regions, suggesting that diets of pelagic taxa within the same region are similar or these consumers share a common source of organic matter in their food web. Findings from this study complement other Hg investigations conducted in the Gulf and also furthered our understanding of the link between feeding ecology and Hg accumulation. Moreover, the combined use of stable isotope and fatty acid techniques provided new insights on the dietary history of pelagic fishes in the Gulf of Mexico.

The Perdido fold belt is the compressional toe of the complex system of detached structures in the western Gulf of Mexico. Located in the Alaminos Canyon protraction area in ultra deep-water, this extensive fold belt has the potential to accommodate large amounts of hydrocarbons. These folds detach upon Jurassic-age Louann salt, and are northeast-southwest trending and symmetrical to asymmetrical. The lower units in these folds are comprised of mostly carbonates and limy carbonate mud, whereas the upper portion consist of fine grained and muddy siliciclastics which are typical of turbidite and other typical deep water deposits. 2-D, prestacked, depth-migrated seismic data (TGS Phase 45) was interpreted in conjunction with Hess Corporation to determine the geometry and timing of the folds outboard of the allochthonous Sigsbee salt nappe. The interpretation of the seismic data consisted of evaluating the folds by mapping age-dated reflections and kink-band boundaries (fold axial surfaces), along with creating isochores and dip maps. Through the development of new geometric model building of excess areas, which identifies material being added to the cores of the anticlines, along with the extensive seismic interpretation, the Perdido fold belt is identified to have originated in the west as early as the early Paleocene, with some continual fold growth to near present day. The folds in the Perdido fold belt continue to form eastward into the basin, up to the basinward limit of the autochthonous Louann salt. Also, it has been determined that the geometries and structural styles of the folds are partially dependent on the type of sediment or rock type in place. The lower portions consisting of the carbonates give shallower dipping fold axial surfaces, whereas the upper portions (siliciclastics) provide more steeply dipping fold axial surfaces.

Hydrocarbon exploration involves drilling into or near salt deposits in the Gulf of Mexico, Brazil, Egypt, and the Middle East. Drilling these systems has proven to be quite dangerous, challenging, and expensive due to the pressure and stress perturbations that exist around the salt. My study focuses on characterizing the pressure and stress distribution at the Mad Dog field, which is a large oil field below an allochthonous salt body in the deepwater Gulf of Mexico. The Mad Dog field lies beneath the Sigsbee Escarpment, which represents the surface and seaward-most indicator of a mobile salt in Green Canyon blocks 781, 782, 825, and 826, 190 miles southwest of New Orleans in 4,500-6,500 feet of water. I characterize the pressure distribution within the Lower Miocene sandstone reservoir which has produced over 100 million barrels to date. I map the reservoir horizon using 3D seismic data and that the reservoir is a complex regional anticlinal structure that is separated by numerous normal faults that cause it to be segmented into compartments. The in-situ pore pressures show that the compartments are not in pressure communication across the field and that multiple aquifer phase pressures are present. The in-situ pore pressure measurements are used to characterize the pressure distribution in the Miocene sediments below the salt body and in front of the mobile salt body. These measurements show that between the upper Miocene to middle Miocene there is an absolute pressure decrease and between the middle to lower Miocene there is a large pressure increase. This pressure distribution is seen both within the Miocene sediments below salt and in front of salt. A porosity and effective stress relationship from shallow Pleistocene sediments was developed to predict the pressure behavior observed within the Miocene and compare the predicted pressure with in-situ pore pressure measurements. The mudstone pressure prediction overestimates the in-situ sand pore pressure. The mudstones bounding regional sandstone have a constant porosity throughout the field, suggesting that the vertical effective stress is constant. These observations can be used to estimate the mudstone pore pressure in a new well location. If the vertical effective stress in an offset well is known and given knowledge of the total vertical stress in the new well location, the mudstone pore pressure can be estimated. / text

Deepwater Gulf of Mexico well construction operations are some of the most challenging and expensive operations in the E&P industry; not only does the outer continental shelf of the Gulf of Mexico present the distinct environmental challenges of hurricanes and loop currents, its geologic profiles can include such challenges as salt, tar or pressurized zones. To overcome these challenges technology is being pushed to its operational and mechanical limits but technology advances can only accomplish so much without the presence of capable personnel. In the E&P industry, human resources are becoming more limited due to the “Big Crew Change”; a disproportionate relief of the retiring Baby Boomers by Generation X workforce that now requires Generation Y assistance. Regardless of the aforementioned, operators venture out into deepwater with hopes to capitalize on the recently discovered attractive development and exploratory opportunities, but to do so they must organize and properly develop their internal well construction organization in a manner that all members are capable to address the challenges as they come. Therefore, team organization is an operator’s priority, a challenge that should be addressed through common project management practices. This paper parallels the project management practices to establish the appropriate organizational structure for an operator’s deepwater well construction group, manage the human resources to properly delineate responsibilities and to structure their staff management processes to acquire, develop and manage personnel in a manner scalable with the operator’s expansion agenda. / text

No description available.

Density, species diversity, species richness, and evenness of bivalve mollusks were measured in the deep (0.2km to 3.7km) northern Gulf of Mexico to describe the community structure of benthic bivalve mollusks. Density decreased gradually from shallow continental slope depths, with remarkably high values in the Mississippi canyon, to the deepest sites. Diversity of bivalve mollusks increased from shallow continental slope depths, with low values in the Mississippi canyon, to a maximum at intermediate depths (1-2km), followed by a decrease down to the deepest locations (3.7km). Nine distinct groups were formed on the basis of the similarity in species composition. The pattern varied more abruptly on the slope compared to the deeper depths, possibly due to steeper gradients in physical variables. ANOVA indicated that the density of bivalve mollusks was not significantly different at different depths, was not significantly different on different transects, was not significantly different between basin and non-basin, but was significantly different in canyon and non-canyon locations. Similar distinctions were observed in diversity, except that basins were lower than non-basins. The patterns observed reflect the intense elevated input of terrigenous sediments accompanied by high surface-water plankton production from the Mississippi River to the north central gulf.

In the past ten years, there have been 194 hurricane-damaged platforms in the Gulf of Mexico (GOM), each with many wells that have not been permanently abandonment. This could lead to disastrous environmental consequence. The wells where their platforms were destroyed by hurricanes cannot be abandoned by conventional methods. Our research showed that barite-weighted epoxy material could be potentially used for well abandonment for those wells in GOM. Shear bond strength tests showed that between two candidates epoxy systems - the bisphenol A system and the bisphenol F system, the latter was less sensitive to barite weighting material. The shear bond strength of besphenol A system was deteriorated as barite increased, while bisphenol F system showed slightly increasing trend when barite was added. The minimum bond strength given by bisphenol A system appears around 68 wt% of barite, which is around 1290 psi. The maximum value of 2200 psi comes at 0 wt% of barite. And the bisphenol F system can stand a minimum of 1010 psi bond strength at 0 wt% of barite, and a maximum of 1160 psi of bond strength with 70 wt% of barite. Moreover, mixing with seawater did influence the shear bond strength between epoxy system and low-carbon steel. The influence that seawater has on the F system is less than that of the A system. The time that the epoxy system needs to fully develop the bond is far longer than curing time determined in our parallel research. Bond strength is lower in both seawater environment and at high temperature.