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Ultrafast photophysical and photochemical dynamics of polyhalogenated alkanes, cycloalkanes, and transition metal complexesBudkina, Darya S. 23 April 2019 (has links)
No description available.
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Crystal structures of 2-[3,5-bis(bromomethyl)-2,4,6-triethylbenzyl]isoindoline-1,3-dione and 2-{5-(bromomethyl)-3-[(1,3-dioxoisoindolin-2-yl)methyl]-2,4,6-triethylbenzyl}isoindoline-1,3-dioneStapf, Manuel, Leibiger, Betty, Schwarzer, Anke, Mazik, Monika 12 July 2024 (has links)
The title compounds, C23H25Br2NO2 (1) and C31H29BrN2O4 (2), crystallize in the space group P21/n with two (1-A and 1-B) and one molecules, respectively, in the asymmetric unit of the cell. The molecular conformation of these compounds is stabilized by intramolecular C—H⋯O hydrogen bonds and C—H⋯N or C—H⋯π interactions. The crystal structure of 1 features a relatively strong Br⋯O=C halogen bond, which is not observed in the case of 2. Both crystal structures are characterized by the presence of C—H⋯Br hydrogen bonds and numerous intermolecular C—H⋯O hydrogen-bonding interactions.
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