Moisture induced damage of hot mix asphalt pavements has a significant economic impact in terms of excessive maintenance and rehabilitation costs. The moisture sensitivity of an asphalt mix depends on the combined effects of material properties, mixture design parameters, loading conditions and environmental factors. Traditional methods to assess moisture sensitivity of asphalt mixes rely on mechanical tests that evaluate the mix as a whole. These methods do not measure material properties and their role in moisture sensitivity of the mix independently. This information is very important to select materials resistant to moisture induced damage, or to modify locally available materials to improve their resistance to moisture damage for economic reasons. The objective of this research is to develop experimental and analytical tools to characterize important material properties that influence the moisture sensitivity of asphalt mixes. Quality of adhesion between the aggregate and bitumen binder in wet and dry conditions plays an important role on the moisture sensitivity of the asphalt mix. A part of this research work was to develop the Wilhelmy plate method and the Universal Sorption Device to measure the surface free energy components of the bitumen and aggregate with adequate precision and accuracy, respectively. Surface energy of these materials was used to identify parameters based on thermodynamics that can quantify their interfacial adhesion and propensity to debond in the presence of water. The thermodynamic parameters were shown to correlate well with the moisture sensitivity of asphalt mixes determined from laboratory tests. Specific surface areas of the aggregates were also used to account for the influence of mechanical interlocking at the micro scale. In some mixes, chemical bonding also contributes to the adhesion between bitumen and aggregate. The use of a micro calorimeter was introduced in this research as a versatile and fast tool to quantify the combined effects of physical and chemical adhesion between these materials.

The performance characteristics of pure hydrogen PEMFC (called HFC) stacks made with heterogeneous carbon fiber bipolar plates are studied in this thesis. In addition, the problem that the heterogeneous carbon fiber bipolar plate leaks in the high gas pressure is also solved in this studies so that the new plate can be used to the high current power sources. Because of the gas leakage of the first generation stack at high inlet gas pressure, the fuel supply is insufficient in the high current density. A 4-cell PEMFC stack made with this new bipolar plate is built with weight 370 g and volume 385 cm3 without a fan. The total power out of the 4-cell stack is about 30 W at room temperature. The specific power and volumetric power densities are 81 mW/g and 78 mW/cm3, respectively. The average power density is about 160 mW/cm2, but the power density of a single-cell can reach a value about 220 mW/cm2. The insufficient fuel supply cause that the power density of 4-cell PEMFC stack is lower than single cell, so it is necessary to solve the gas leakage at high pressure. Our experiment found that gas leakage occurs in heterogeneous bipolar plates can be relate to the insufficient or improper hot-pressing temperature, time and pressure while we are making the carbon fiber bunches. So the processes in making new carbon fiber bunches include water expansion, uniform glue adding, high hot-pressing pressure, and using proper temperature and enough solidification time. The airtight of the second generation of heterogeneous carbon fiber bipolar plates improves obviously with the new processes. No leakage occurs for gas pressure under 1atm. We expect that this design can be used to high inlet pressure. It is also quite suitable for various high-power electrical sources.

Many applications in microelectromechanical systems such as smart living space sensing system, microchannel system on chip and biomedical sensing system usually require instantaneously compensating or controlling the temperature of chip to acquire more linear and accurate output signal. So it is necessary to develop a micro temperature sensor or micro-hot-plate which has highly thermal isolation and low power characteristics. This thesis aims to design and fabricate a low power micro-hot-plate and a high-sensitivity temperature sensor for portable applications. This dissertation utilized a high power E-beam evaporator to deposit the platinum thin film as the material of temperature sensing and heating. The Pt layer is patterned using the lift-off technique. In addition, the micro-hot-plate can be released from the silicon substrate as a floating thin-plate using TMAH-based anisotropic etching technology. The floating structure can improve the thermal isolation and reduce the power loss through the silicon substrate. In this study, the higher temperature sensitivity (1914 ppm/¢J) and optimized sensing linearity ( > 99.9 %) of the platinum-based temperature sensor is demonstrated. On the other hand, the heating power of the floating micro-hot-plate developed in this research is only 14 mW when it be heated to 300 ¢J and the power efficiency is very high (18.3 ¢J/mW).

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Thesis (Ph. D.)--University of Missouri-Columbia, 1996. / Typescript. Vita. Includes bibliographical references (leaves 201-208). Also available on the Internet.

In the steel industry, laser triangulation based measurement systems can be utilizedfor evaluating the flatness of the steel products. Shapeline is a company in Linköpingthat manufactures such measurement systems. This thesis work will present a series ofexperiments on a Shapeline measurement system in a relatively untested environment, thehot rolling mill at SSAB in Borlänge.The purpose of this work is to evaluate how the conditions at a hot rolling mill affectsthe measurement performance. It has been anticipated that measuring in high temperatureenvironment would introduce difficulties that do not exist when measuring in cold environments.A number of different experiments were conducted, where equipment such as laserand camera bandpass filter were alternated. Via the experiments, information about noisedue to the environment in the hot rolling mill was gained. The most significant noise wascaused by heat shimmering. Using the presented methods, the magnitude and frequencyspectrum of the heat shimmering noise could be determined. The results also indicates thatheat shimmering cause large errors and is quite troublesome to counter. In addition to this,the quality of the line detections under the hot rolling mill circumstances was examined. Itcould be observed that the line detections did not introduce any significant errors despitethe harmful conditions.

A series of experiments have been performed to understand fast electron generation from ultra intense laser-solid interaction, and their transports through a cold material. Using Micro-Electro-Mechanical Systems (MEMS), we contrived various shape of cone and wedge targets. The first set of experiment was for investigating hot electron generations by measuring x-ray production in different energy ranges. K[alpha] and hard x-ray yields were compared when the laser was focused into pyramidal shaped cone targets and wedge shaped targets. Hot electron production is highest in the wedge targets irradiated with transverse polarization, though K[alpha] is maximized with wedge targets and parallel polarization. These results are explained with particle-in-cell (PIC) simulations utilizing PICLS and OOPIC codes. We also investigate hot electron transport in foil, wedge, and cone targets by observing the transition radiation emitted from the targets rear side along with bremsstrahlung x-ray measurement. Twodimensional images and spectra of 800 nm coherent transition radiation (CTR) along with ballistic electron transport analysis have revealed the spatial, temporal, and temperature characteristics of hot electron micro-pulses. Various patterns from different target-laser configurations suggest that hot electrons were guided by the strong static electromagnetic fields at the target boundary. Evidence about fast electron guiding in the cone is also observed. CTR at 400 nm showed that two distinct beams of MeV electrons are emitted from the target rear side at the same time. This measurement indicates that two different mechanisms, namely resonance absorption and j x B heating, create two populations of electrons at the targets front side and drive them to different directions, with distinct temperatures and temporal characteristics. This interpretation is consistent with the results from 3D-PIC code Virtual Laser Plasma Laboratory (VLPL). / text

Dynamics between organic molecules and surface enhanced Raman scattering (SERS) hot spots are extracted from far-field optical images by two experimental methods presented in this thesis: orientational imaging and super-resolution optical imaging. We introduce SERS orientational imaging as an all-optical technique able to determine the three-dimensional orientations of SERS-active Ag nanoparticle dimers. This is accomplished by observing lobe positions in SERS emission patterns formed by the directional polarization of SERS emission along the longitudinal axis of the dimer. We further extend this technique to discriminate nanoparticle dimers from higher order aggregates by observing the wavelength-dependence of SERS emission patterns, which are unchanged in nanoparticle dimers, but show differences in higher order aggregates involving two or more nanoparticle junctions. Dynamic fluctuations in the SERS emission pattern lobes are observed in aggregates labeled with low dye concentrations, as molecules diffuse into regions of higher electromagnetic enhancement in multiple nanoparticle junctions. In order to investigate these dynamic interactions between single organic molecules and nanoparticle hot spots we present the first super-resolution optical images of single-molecule SERS (SM-SERS), introducing super-resolution imaging as a powerful new tool for SM-SERS studies. Mapping the dynamic movement of SM-SERS centroid positions with +/- 5 nm resolution reveals the position-dependent SERS intensity as the centroid samples different positions in space. We have proposed that the diffusion of the SERS centroid is due to diffusion of a single molecule on the surface of the nanoparticle, which leads to changes in coupling between the scattering dipole and the optical near field of the nanoparticle. Finally, we combine an isotope-edited bi-analyte SERS spectral approach with super-resolution optical imaging and atomic force microscopy (AFM) structural analysis for a more complete picture of molecular dynamics in SERS hot spots. We demonstrate the ability to observe multiple molecule dynamics in a single hot spot and show that in addition to the single-molecule regime, a "few" molecule regime is able to report on position-dependent SERS intensities in a hot spot. Furthermore, we are able to identify multiple local hot spots in single nanoparticle aggregates. / text

Heat losses are an important problem in domestic hot water circulation systems. Therefore, to reduce these losses becomes an issue of utmost importance both economically and environmentally. Nevertheless, it has not been until recent years when these losses have been studied further. Commonly studies have focused on the heat space system operation or radiator system. This study focuses on heat losses in the domestic hot water circulation through the piping system in a building at a school located in Gävle (Sweden) using non-destructive flow and temperature reading devices. The heat used by the school is provided by the district heating network that feeds several heat exchangers. The heat losses, at the same time, will be compared with simulation and theoretical procedures to corroborate them. The domestic hot water piping system of this study consists on more than 1200 meters of insulated copper pipes with different diameters and different insulation thickness. The system was measured for one week (April 26, 2015 to May 3, 2015) when there are working days and nonworking days. A 5% of the annual district heating consumption in the school was calculated as heat losses in the domestic hot water circulation system in the building studied. Finally, improvements in insulation system and changes in the domestic hot water temperature have been simulated and they demonstrate that savings of up to 35% of the heat losses can be achieved and produce significant energy savings.