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Determination of Molecular Descriptors for Illegal Drugs by Gc-fid Using Abraham Solvation ModelAkhter, Syeda Sabrina 12 1900 (has links)
The Abraham solvation parameter model is a good approach for analyzing and predicting biological activities and partitioning coefficients. The general solvation equation has been used to predict the solute property (SP) behavior of drug compounds between biological barriers. Gas chromatography (GC) retention time can be used to predict molecular descriptors, such as E, S, A, B & L for existing and newly developed drug compounds. In this research, six columns of different stationary phases were used to predict the Abraham molecular descriptors more accurately. The six stationary phases used were 5% phenylmethyl polysiloxane, 6% cyanopropylphenyl 94% dimethylpolysiloxane, 5% diphenyl 95% dimethylpolysiloxane, 100% dimethylpolysiloxane, polyethylene glycol and 35% diphenyl 65% dimethylpolysiloxane. Retention times (RT) of 75 compounds have been measured and logarithm of experimental average retention time Ln(RTexp) are calculated. The Abraham solvation model is then applied to predict the process coefficients of these compounds using the literature values of the molecular descriptors (Acree Compilation descriptors). Six correlation equations are built up as a training set for each of the six columns. The six equations are then used to predict the molecular descriptors of the illegal drugs as a test set. This work shows the ability to extract molecular information from a new compound by utilizing commonly used GC columns available with the desired stationary phases. One can simply run the new compound in GC using these columns to get the retention time. Plugging in the retention time into the developed equations for each of the column will predict the molecular descriptors for the test compound and will give some information about the properties of the compound.
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Estimating Penalties for Violating the Minimum Wage and Hiring Illegal Immigrants: The Case of the U.S. Apparel Manufacturing IndustryRangel, Marie-Teresa 16 November 2006 (has links)
The U.S. apparel manufacturing industry includes many reputable firms, but is also believed to include many sweatshop operations. Sweatshop workers often work under sub-minimum wages, excessively long hours, and abusive management. Sweatshop establishments in the United States typically violate several U.S. labor laws. Two they commonly violate are the minimum wage under the Fair Labor Standards Act of 1938 and the ban on hiring illegal immigrants under the Immigration Reform and Control Act of 1986. The purpose of the present research was to estimate minimum penalties that would provide no monetary incentive for the average U.S. apparel manufacturing firm to violate the minimum wage and the ban on hiring illegal immigrants.
The minimum per-violation penalties that were estimated to deter violation of the minimum wage are 8 to 28 times the current maximum penalty of $1,000 per violation, and those estimated to deter the hiring of illegal immigrants are 3 to 10 times the current maximum penalty of $10,000 per violation. The estimated penalties are associated with annual probabilities of prosecution ranging from 5% to 15%. The estimated penalties primarily depend on the difference between legal and illegal wage rates. A sensitivity analysis indicated that the estimated penalties are insensitive to the value of the own-price elasticity of production labor demand, which is one of the variables used to calculate the penalties. The results suggest that current federal penalties for violating the minimum wage or the ban on hiring illegal immigrants do not deter infraction of these laws by U.S. apparel manufacturers. / Master of Science
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Gender, Migration Regimes and Frames of Deservingness: The Gendered Management of Women's Care Migration from Armenia to TurkeyTeke Lloyd, Fatma Armagan 02 February 2016 (has links)
This thesis investigates the ways in which women’s international migration from Armenia to Turkey is governed by the production and re-production of appropriate feminities and masculinities by macro-level state policies, legal texts and by everyday cultural discourses. Through an analysis of policy documents, legal texts and data collected through interviews with policy makers both in Armenia and Turkey, this thesis shows that gendered norms and rituals are implicated in how states regulate, intervene or simply ignore who are allowed or denied entry. Border regulations are affected and in return discipline the ideas and norms revolving around how the deserving feminine subjects of society should act and think.This thesis demonstrates that in focusing on a South-South migration from the perspective of gender challenges the dominant analysis of International Relations (IR) on migration, which has framed international migration mostly as a question of international security. In contrast, this thesis brings the rich political histories, social contexts and economic concerns – framed by gender, class and racial hierarchies – to bear on the flows of migrant women from Armenia to Turkey. This framework developed here has two important implications for how migration is studied in IR: one, it paints a much more complex picture of state-migrant interactions that goes beyond simplistic security/exclusion claims; and secondly, it allows for a multi-faceted conception of women’s agency.
This thesis argues that migrant women develop several methods of managing their identities in order receive acceptance and legitimacy in the context of the gendered regulation of migration by Armenia and Turkey. They actively participate sometimes to challenge their characterization as “illegals”, as immoral mothers and women, and as useless workers. Their relationships with their families, employers, police officers and compatriots are carefully described and analyzed. The findings suggest that migrant women’s experiences are multifaceted and cannot be subsumed under a category of “irregular” migrant. / Dissertation / Doctor of Philosophy (PhD)
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PROTECTING THE SOUTHERN BORDER: FRAMING MEXICANS IN A POST-9/11 MEDIAWagstaff, Audrey E. 24 April 2007 (has links)
No description available.
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US Labor Demand: a Discourse Analysis on the "Hidden Force" behind Illegal ImmigrationCooper, Jeffrey T. 26 February 2008 (has links)
The dominant ideology within the illegal immigration discourse in the US primarily faults illegal workers for the problem by highlighting the act of illegally entering the US as the origin of the problem. As the dominant ideology goes, illegal immigrants evade law enforcement at the border; they deceive employers to secure work. They disrupt labor markets by lowering wages which displaces lower class US workers. The illegal immigrants and their families abuse social services that they do not pay into at the US taxpayers expense. They form ethnic enclaves, and those who remain in the US resist assimilation into US culture. So the story goes. This thesis challenges this dominant ideology, a subset of the illegal immigration discourse, by documenting decades of immigration law in the US created to serve US employers' demand for labor, and alternately, closing the immigrant worker pipeline when it suited the government's political objectives or the special interests of employers. Loopholes in the immigration laws have tended to insulate employers from prosecution. Meanwhile, undocumented workers have faced lower wages and increased risk. This thesis examines what constitutes the dominant ideology of the illegal immigration discourse. It also includes a discourse analysis of illegal immigration by reviewing national, regional, and local media coverage of the simultaneous raids in December 2006 of six Midwest meat processing plants operated by Swift & Company. The discourse analysis explores media coverage of the raids conducted by the Department of Homeland Security's Bureau of Immigration and Customs Enforcement (ICE). The raids led to the arrest of 1,282 suspected illegal immigrants, and the analysis will attempt to understand to what extent media coverage supports or challenges the dominant ideology of the illegal immigration discourse. / Master of Arts
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An analysis of the taxability of illegal activities in South Africa / Orlando Christian StreicherStreicher, Orlando Christian January 2015 (has links)
The South African Income Tax Act (58 of 1962) does not specifically deal with the tax treatment of receipts resulting from illegal activities. Expenditure resulting from illegal activities is also only partly dealt with in terms of Section 23(o) of the Income Tax Act. This has resulted in uncertainty pertaining to the normal income tax treatment of illegal activities within a South African context. In response to this, the South African Revenue Service has issued a draft interpretation note dealing with the tax consequences of embezzlement and theft of money for both the victim as well as the offender during 2013. This draft interpretation note also deals with the normal tax consequences of illegal receipt in the hands of the thief. In an attempt to evaluate this draft interpretation note to clarify the tax consequences of illegal activities in South Africa, the meaning of illegal receipts is firstly determined. Subsequently the concept of „illegal receipts‟ is measured against the definition of „gross income‟ contained in Section 1 of the Income Tax Act. Expenditure relating to illegal activities is also analysed and measured against the general deduction formula contained in Section 11(a) of the Income Tax Act. Relevant principles established from general case law applicable to the definition of gross income as well as the general deduction formula is analysed to determine its applicability within the context of illegal receipts and expenditure. Also, principles established through case law, both nationally and internationally, specifically applicable to the taxation of illegal activities were analysed to establish guidelines that could be applied to clarify the taxability of illegal activities within a South African context. / MCom (South African and International Tax), North-West University, Potchefstroom Campus, 2015
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An analysis of the taxability of illegal activities in South Africa / Orlando Christian StreicherStreicher, Orlando Christian January 2015 (has links)
The South African Income Tax Act (58 of 1962) does not specifically deal with the tax treatment of receipts resulting from illegal activities. Expenditure resulting from illegal activities is also only partly dealt with in terms of Section 23(o) of the Income Tax Act. This has resulted in uncertainty pertaining to the normal income tax treatment of illegal activities within a South African context. In response to this, the South African Revenue Service has issued a draft interpretation note dealing with the tax consequences of embezzlement and theft of money for both the victim as well as the offender during 2013. This draft interpretation note also deals with the normal tax consequences of illegal receipt in the hands of the thief. In an attempt to evaluate this draft interpretation note to clarify the tax consequences of illegal activities in South Africa, the meaning of illegal receipts is firstly determined. Subsequently the concept of „illegal receipts‟ is measured against the definition of „gross income‟ contained in Section 1 of the Income Tax Act. Expenditure relating to illegal activities is also analysed and measured against the general deduction formula contained in Section 11(a) of the Income Tax Act. Relevant principles established from general case law applicable to the definition of gross income as well as the general deduction formula is analysed to determine its applicability within the context of illegal receipts and expenditure. Also, principles established through case law, both nationally and internationally, specifically applicable to the taxation of illegal activities were analysed to establish guidelines that could be applied to clarify the taxability of illegal activities within a South African context. / MCom (South African and International Tax), North-West University, Potchefstroom Campus, 2015
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Democracy and Discrimination: Analyzing Diverging Local Responses to ImmigrationSteil, Justin Peter January 2015 (has links)
Over the past decade, cities have passed an unprecedented number of laws seeking to drive undocumented immigrants from their jurisdictions. At the same time, however, large numbers of cities have passed policies seeking to incorporate recent immigrants into local civic and social life, regardless of immigration status. What explains why similar cities have responded so differently?
Quantitative analysis tests the explanatory power of theories of political opportunity structure, labor market competition, demographic changes represented as threats, and the exclusionary tendencies of homeowners in predicting the passage of exclusionary and inclusionary ordinances in cities nationwide. The predictors of the passage of exclusionary ordinances are consistent with the salience of political opportunity structure, demographic changes represented as threats, and the exclusionary tendencies of homeowners. The predictors of the passage of inclusionary ordinances are most consistent with theories of political opportunity structure and the relative absence of the exclusionary tendencies of homeowners in cities with lower levels of owner-occupied housing.
Case studies in two sets of paired cities that passed diverging ordinances examine the social and political processes on the ground. This qualitative research finds that residents in exclusionary cities expressed anxieties over the effects of demographic change on home values and neighborhood character. Diverging processes of framing and mobilization emerge as central to the development of local collective identities that include or exclude new immigrant residents.
Network analysis of the connections between local civil society organizations in each of the four case study cities identifies the architecture of local civil society networks as a significant factor correlated with the divergent responses to demographic change. The networks in exclusionary cities score highly on measures of density, clustering, and closure, suggest that the network is broken into cliques and that local elites are isolated both from recent immigrants and from non-elite, native-born residents. The high levels of network closure facilitate the creation of rigid group boundaries, the high levels of clustering reinforce pre-existing beliefs within those groups, and the network density aids in the enforcement of sanctions against those who deviate from group norms. By contrast, the networks in inclusionary cities are characterized by multiple organizational bridges between immigrant and native-born communities that facilitate the creation of relationships necessary to craft inclusive policies and a sense that local resources can grow with the population.
The research suggests that the local laws seeking to drive out undocumented immigrants are an example of a broader category of exclusionary property laws. The linked social and spatial processes involved in the enactment and enforcement of these laws are one way in which categorical inequalities, such as socio-economic disparities by race, ethnicity, immigration status, or gender become embedded in place.
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”The life of an American hero was stolen by someone who had no right to be in our country” En kvalitativ innehållsanalys av hur Donald Trump framställer det amerikanska folket och de illegala immigranternaEdvinsson, Josefin January 2019 (has links)
During recent years, America’s attitude toward immigrants has become increasingly excluding. Previous research shows that it is common for illegal immigration and crime to be related to one another, although research shows that there is no relationship between them. The president of the United States, Donald Trump, is known for dividing the American people from the illegal immigrants. Therefore, this study analyses how Trump portraits the American people and the illegal immigrants. Further, the study analyses how he divides these groups from each other. The study is based on a qualitative content analysis where six speeches made by Trump is analysed. The results of the study show that Trump positively portrays the American people by saying they possess unique values. Unlike this, he portrays the illegal immigrants as people that commit crimes such as murder and sexual crimes. Trump also portraits the two groups by dividing them from each other. He does this by giving a positive picture of the American people at the same time as he gives a negative picture of the illegal immigrants. Further, he divides the groups by creating a feeling of unity between the American people through talking about shared culture, values, and an unique history. / Under de senaste åren har USA:s inställning blivit alltmer exkluderande gentemot immigranter. Tidigare forskning visar att det är vanligt att illegal immigration och brottslighet ställs i relation till varandra trots att forskning visar att det inte finns ett samband däremellan. Amerikas president Donald Trump omtalad för att skapa en uppdelning mellan det amerikanska folket och de illegala immigranterna. I relation till detta analyserar denna studie hur Trump framställer det amerikanska folket och de illegala immigranterna samt hur han separerar grupperna från varandra. Studien är baserad på en kvalitativ innehållsanalys där sex av Trumps tal analyseras. Studiens resultat har visat på att Trump ofta framställer det amerikanska folket på ett positivt sätt genom att säga att deras värderingar är unika. Till skillnad från detta framställs ofta de illegala immigranterna som mördare och sexualförbrytare. Han framställer grupperna även genom att separera dem från varandra genom att ge en positiv bild av det amerikanska folket samtidigt som han ger en negativ bild av de illegala immigranterna. Vidare separerar han grupperna genom att framkalla känslor av gemenskap hos det amerikanska folket genom att tala om att de delar en gemensam kultur, värderingar och historia som är unik.
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The Net Fiscal Effects of Illegal Immigrants: Evidence from the Urban Counties of GeorgiaGlover, Victoria Anne 26 November 2007 (has links)
This thesis engages in a review of the existing literature and empirical analysis, which addresses the impact of immigrants, specifically illegal, on urban counties in Georgia. It is increasingly accepted that immigration plays a significant role in many aspects of government services, and that immigrants in some form, do provide income, but the debate wages between how much transfers an immigrant takes and the taxes an immigrant pays. However, little attention has been focused on illegal immigrants and their local fiscal effects on government taxes and transfers. This area has not been the focus of systematic inquiry or substantive critical consideration because most studies center around legal immigrants and their federal impacts.
The results from this thesis call for a mobilization of a heightened enthusiasm for addressing research challenges in this field and for current immigration policy to strive to maximize the well-being of the native population.
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