The experiments discussed in this thesis exploit parity violation in elastic electron proton scattering in order to measure properties of the nucleon. Both experiments make use of the high quality, highly polarized electron beam available at Thomas Jefferson National Accelerator Facility. Q_weak will measure the weak mixing angle, sin²θ_W, via a measurement of the weak charge of the proton, at a four-momentum transfer, Q² ~ 0.026 GeV²/c². The precision of this measurement gives Q_weak access to new physics at the scale of 2.3 TeV, making it a test of the standard model. The G⁰ experimental program provides the fully separated contributions of the strange quark to the charge and magnetization distributions of the nucleon at two different values of four-momentum transfer, Q² ~ 0.22 and 0.63 GeV²/c². The measurement of the strange quark content of the proton in the G⁰ experimental program and other parity-violating electron scattering experiments provides a measurement of the hadronic contribution to the asymmetry in Q_weak. In addition, G⁰ was able to measure the parity-conserving beam normal single spin asymmetries that provide a measurement of the imaginary part of two photon exchange. The measurement of this asymmetry is necessary to understand the systematic contribution to measurements of parity-violating asymmetries, but it is also an important physics result. Recent theoretical work has shown that higher order radiative effects, such as two photon exchange, may be able to explain discrepancies between experiments which measure the ratio of the electric and magnetic form factors of the proton. The measurement of the transverse or beam normal single spin asymmetries provides a benchmark for theories that estimate the size of radiative corrections that are important for precision electroweak scattering experiments such as those described in this thesis. The results of the measurement of the transverse asymmetries at backward angles in G⁰ are presented at the two values of Q² ~ 0.22 and 0.63 GeV²/c² for hydrogen. Results for deuterium, which can provide the first measurements of the beam normal single spin asymmetries on the neutron, are also presented. / Ph. D.

A dual approach integrating structural tailoring and adaptive materials technology and designed to control the dynamic response of cantilever beams subjected to external excitations is addressed. The cantilevered structure is modeled as a thin-walled beam of arbitrary cross-section and incorporates a number of non-classical effects such as transverse shear, warping restraint, anisotropy of constituent materials and heterogeneity of the construction. Whereas structural tailoring uses the anisotropy properties of advanced composite materials, adaptive materials technology exploits the actuating/sensing capabilities of piezoelectric materials bonded or embedded into the host structure. Various control laws relating the piezoelectrically-induced bending moment with combined kinematical variables characterizing the response at given points of the structure are implemented and their effects on the closed-loop frequencies and dynamic response to external excitations are investigated. The combination of structural tailoring and control by means of adaptive materials proves very effective in damping out vibration. In addition, the influence of a number of non-classical effects characterizing the structural model on the open and closed-loop dynamic responses have been considered and their roles assessed. / Ph. D.

Based on a refined analytical anisotropic thin-walled beam model, aeroelastic instability, dynamic aeroelastic response, active/passive aeroelastic control of advanced aircraft wings modeled as thin-walled beams are systematically addressed. The refined thin-walled beam model is based on an existing framework of the thin-walled beam model and a couple of non-classical effects that are usually also important are incorporated and the model herein developed is validated against the available experimental, Finite Element Anaylsis (FEA), Dynamic Finite Element (DFE), and other analytical predictions. The concept of indicial functions is used to develop unsteady aerodynamic model, which broadly encompasses the cases of incompressible, compressible subsonic, compressible supersonic and hypersonic flows. State-space conversion of the indicial function based unsteady aerodynamic model is also developed. Based on the piezoelectric material technology, a worst case control strategy based on the minimax theory towards the control of aeroelastic systems is further developed. Shunt damping within the aeroelastic tailoring environment is also investigated. The major part of this dissertation is organized in the form of self-contained chapters, each of which corresponds to a paper that has been or will be submitted to a journal for publication. In order to fullfil the requirement of having a continuous presentation of the topics, each chapter starts with the purely structural models and is gradually integrated with the involved interactive field disciplines. / Ph. D.

Understanding mechanisms at the molecular level is essential for interpreting and predicting the outcome of processes in all fields of chemistry. Insight into gas-surface reaction dynamics can be gained through molecular beam scattering experiments combined with classical trajectory simulations. In particular, energy exchange and thermal accommodation in the initial collision, the first step in most chemical reactions, can be probed with these experimental and computational tools. There are many questions regarding the dynamic details that occur during the interaction time between gas molecules and organic surfaces. For example, how does interfacial structure and density affect energy transfer? What roles do intramonolayer forces and chemical identity play in the dynamics? We have approached these questions by scattering high-energy, rare gas atoms from functionalized self-assembled monolayers. We used classical trajectory simulations to investigate the atomic-level details of the scattering dynamics. We find that approximately six to ten carbon atoms are involved in impulsive collision events, which is dependent on the packing density of the alkyl chains. Moreover, the higher the packing density of the alkyl chains, the less energy is transferred to the surface on average and the less often the incident atoms come into thermal equilibrium with the surface. In addition to the purely hydrocarbon monolayers, organic surfaces with lateral hydrogen-bonding networks create more rigid collision partners than surfaces with smaller inter-chain forces, such as van der Waals forces. Finally, we find some interesting properties for organic surfaces that possess fluorinated groups. For argon scattering, energy transfer decreases with an increasing amount of surface fluorination, whereas krypton and xenon scattering transfer most energy to monolayers terminated in CF₃ groups, followed by purely hydrocarbon surfaces, and then perfluorinated surfaces. / Ph. D.

In the present investigation, a comprehensive photonic characterization and analysis of low energy Ar⁺ ion beam processed GaAs surfaces is presented. The purpose of this investigation was to evaluate the damage and amorphization introduced at the surface and sub-surface regions by ion bombardment. Ar⁺ ion beam etching was selected in order to rule out the possibility of producing any additional effects at the interface due to chemical reactions in the case of reactive ion etching. After a brief review of the concepts and underlying physics, several photonic structures are introduced. The basic theory governing the photovoltaic devices and photoconductive samples is discussed. The preparation and characterization techniques of ion beam processed GaAs samples are described. An automated photovoltaic materials and devices (PVMD) system was developed. Asyst, a Forth based scientific software was selected to write the source codes for data acquisition and reduction. The inherent fast execution times of the software allows data acquisition in real time, ensuring the quasi-steady state condition. The electrical and optical evaluation procedures developed and employed for the present investigation are discussed. One of the striking features of the ion beam bombardment on semi-insulating (SI) GaAs samples was the observation of persistent photoconductivity. A phenomenological model for optically generated ion beam induced metastable defect state formation was proposed to explain the persistent photoconductivity. Presence of two or more exponential curves in the relaxation mode indicates the distributed nature of the traps within the band gap. A conjectural flat-band energy diagram was introduced to elucidate the proposed model. The observed dark and photoconductivity response model was based on the distributed lumped electrical components analysis. Fundamental transport equations were employed in the analysis of the lumped electrical components model. Metal-Insulator-Semiconductor (MIS) type Schottky barrier diodes and photodiodes were fabricated employing both thermal and anodic oxides. Diode parameters were evaluated as a function of ion-beam energy. An increase in reverse saturation current density accompanied by an increase in the ideality factor was observed, indicating the presence of trap-assisted tunneling and a region of high recombination. The effective barrier height was generally lowered; however, no monotonic correlation with the ion energy was observed. It is proposed that the mechanisms described in previous studies (e.g. tunneling, stoichiometry effects, ion penetration depth) were dominated by the effect of Fermi level pinning at the electronic states of process-induced defects. Deep level transient spectroscopy (DLTS) indicated the presence of at least two distinct deep trap levels, at 0.32 eV and at 0.52 eV below the conduction band edge, as a consequence of ion beam etching. The EL2 peak was evident in the virgin sample and vanished in the ion beam etched samples and such observation is in agreement with our proposed model. The photovoltaic response was characterized using illuminated current-voltage (I-V) and spectral response measurements. The ratio of external quantum efficiencies of IBE devices to unetched device indicates the regions and relative extent of the damage. Since the damage has a impact on the band-bending due to excess carrier generation, the sub-bandgap photon absorption response reveals the degree of disorder. XPS results indicated an increased surface sensitivity and change in Ga/As ratio as a function of ion beam energy. The modelling of ion-beam-processed samples was considered and several computer programs which simulate their operation are described. The depth of amorphization was calculated using the Lindhard-Scharff-SchiΦtt (LSS) theory and the standard projected range and straggle parameters, and experimental parameters. A large difference was observed in the values calculated using LSS theory and experimentally measured values, using optical probes. The difference was explained in light of the Collision-Cascade model. / Ph. D.

A common problem encountered in phased array signal processing is how to remove sources of interference from a desired signal. Two existing methods to accomplish this are the Linearly Constrained Minimum Variance (LCMV) beamformer and the Side-Lobe Canceller (SLC). LCMV provides better performance than SLC, but comes with much higher computational costs. The Steered Auxiliary Beam Canceller (SABC) presented in this thesis is a new algorithm developed to improve the performance of SLC without the computational costs of LCMV. SABC performs better than SLC because it uses high-gain auxiliary channels for cancellation. This new technique is now possible because digital arrays allow for direction finding algorithms such as Estimation of Signal Parameters via Rotational Invariance Techniques (ESPRIT) to estimate the directions of the interference sources. With this added knowledge, high gain beams similar to the main beam may be used as auxiliaries instead of low-gain antenna elements. Another contribution is a method introduced to calculate the computational complexity of LCMV, SLC, and SABC much more accurately than existing methods which only provide order-of-magnitude estimates. The final contribution is a derivation of the signal loss experienced by SLC and SABC and simulations that verify the performance of LCMV, SLC, and SABC. / Master of Science

A numerical model of the temperature field during pulsed laser cutting of thin sheets (approximately 2.5 x l0⁻⁵ m) was developed. Cutting was simulated through removal of nodes from a finite difference scheme based on sensible heating to the phase change temperature and a single value of latent heat (melting or vaporization). The pulsed laser model predicts a heat-affected zone of less than 0.02 mm for pulsed laser cutting. For comparable cutting with a continuous power laser, a heat-affected zone between 0.05 and 0.10 mm is predicted. Thermal stress levels were predicted to be an order of magnitude lower for pulsed laser cutting than for continuous power cutting. The stress levels predicted by the model also increased with cut speed. Experimentally, pulsed laser cutting yielded better cut quality, based on less cracking, than continuous power cutting. In addition, the cut quality deteriorated as the cutting speed was increased for the continuous power laser. Presently, application of pulsed laser cutting is limited by its low cutting speed, which is restricted by the energy density of the laser. The model predicts that increasing energy density will decrease the size of the heat-affected zone and increase the maximum cutting speed. Therefore, pulsed laser cutting at high speeds should be attainable without deterioration in cut quality. / Master of Science

A test program for the Hybrid-Composite Beam (HCB) was conducted prior to its use for the replacement of a skewed, simply-supported bridge (Tide Mill Bridge). The HCB is an innovative combination of conventional materials and ideas in a structural beam. The beam consists of a concrete arch tied with prestressing strand that is placed within a Fiber-Reinforced Polymer (FRP) box. Behavior in individual HCB's and a three HCB-system was examined to determine the appropriateness of the current design methodology developed by John Hillman and the simplifying assumptions made within it. Such assumptions include strain compatibility and linear-elastic behavior. Three HCB's were tested at the structures laboratory at Virginia Tech. During individual beam tests, the predicted behavior of the FRP box and prestressing strand agreed with experimental results. The tests revealed the arch was susceptible to local bending and behaved far differently from predicted. Overall, the beams were shown to behave linearly. A final test was performed to apply the design live load to the system. Slight non-linear behavior was observed in the beams. Distribution factors for the system were also investigated and compared to AASHTO and Hillman's model. AASHTO factors were conservative for exterior girders but unconservative for interior girders. Hillman's factors were often conservative but were in agreement for the shear in the exterior girder. The current design procedure appeared to predict FRP and strand behavior well, but the behavior of the arch appeared to differ greatly from the other components of the HCB. / Master of Science

Over the past decade there has been an explosion in the demand for wireless mobile personal communications systems (PCS), a trend that shows no signs of slowing down in the foreseeable future. This demand has created a greater need for low-cost, low-power, compact system solutions. As a result, "single-chip" implementations of wireless functions have received a significant amount of attention. A significant roadblock to complete integration of these functions is the requirement for high-Q resonators in RF filter and tank circuits. Current on-chip techniques being used to realize monolithic RF resonators based on planar inductors, capacitors and active circuits are accompanied by problems such as high loss, large chip area and high power consumption. An alternative to these on-chip solutions is the use of monolithically integrated electromechanical devices. This thesis describes the modeling, fabrication and characterization of nanoelectromechanical (NEM) single crystal silicon resonators. The potential advantages associated with these devices are high-Q, small die area and low power consumption. The development of such devices compatible with modern integrated circuit fabrication techniques offers the possibility for integration of high performance RF filters and resonators onto a single RFIC chip. The advantageous characteristics of these resonators could lead to mobile PCS devices with lower cost and increased battery life. The NEM resonator designs investigated in this work are fabricated using an electron-beam lithography based surface machining process in silicon-on-insulator technology. Various design, fabrication and testing issues are discussed. The feasibility of lateral capacitive actuation and detection in such structures is examined. / Master of Science

Adjacent box beam bridges are economical bridge systems for accelerated bridge construction. The box beams are constructed at precast plants and are traditionally connected by a shear key filled with grout. This system is ideal for short spans with low clearance restrictions. However, due to the grout deteriorating and debonding from the precast concrete in the shear key, reflective cracking propogates through the deck allowing water and chemicals to leak down into the joints. This can lead to the prestressing steel inside the precast member and the transverse tie steel corroding. This necessitates the bridge being rehabilitated or replaced which shortens the life-span of the bridge system and negates the economical value it had to begin with. This research project aimed to design a rehabilitation plan for an adjacent box beam bridge with deteriorated joints using Very High Performance Concrete (VHPC). VHPC was chosen as an economical alternative to the proprietary Ultra High Performance Concrete (UHPC) and extensive material tests were performed. The results of the material testing of VHPC and grout revealed that VHPC had higher compressive and tensile strengths, a higher modulus of elasticity, gained strength faster, bonded better to precast concrete, was more durable over time, and shrank less than conventional grout. The results of this research project were applied to rehabilitate the Buffalo Branch Bridge and further testing will be completed to determine the effectiveness of the rehabilitation. / Master of Science