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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
51

STUDY OF ELECTROLYTE ADDITIVES IN LI-ION BATTERIES USING ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ON SYMMETRIC CELLS

Petibon, Remi 22 August 2013 (has links)
Electrolyte additives are generally used in commercial Li-ion cells to improve capacity retention and calendar life. Although it is apparent that electrolyte additives play an important role, the details of how they work are poorly understood. In order to be able to distinguish the effect of an additive on the positive or negative electrodes, an experimental method has been developed based on electrochemical impedance spectroscopy of symmetric cells constructed from electrodes of disassembled full cells similar to the method described by previous workers. This technique proved to be useful and showed that the effects of additives on both electrodes depend strongly on their concentration. It also showed that in some cases, when two additives are introduced in the same cell, both additives contribute to the formation of the surface layer of both electrodes. In other cases, each additive controls the formation of the surface layer of only one electrode.
52

Consolidated Nanomaterials Synthesized using Nickel micro-wires and Carbon Nanotubes.

Davids, Wafeeq. January 2007 (has links)
<p>The current work focuses on the synthesis and characterization of nano-devices with potential application in alkaline electrolysis and secondary polymer lithium ion batteries.</p>
53

A Study on Nano-Si/Polyaniline/Reduced Graphene Oxide Composite Anode for Lithium-Ion Batteries

Li, Kai January 2013 (has links)
Because of its high theoretical specific capacity (4200mAh/g) and natural abundance (2nd most abundant element on earth), silicon is considered a promising anode candidate for high energy density lithium-ion batteries. However, the dramatic volume changes (up to 400%) that occur during lithiation/delithiation and the relative low electrical conductivity of silicon prevent the implementation of this material. In this work, a nano-silicon/polyaniline/reduced graphene oxide composite was synthesized via a two-step process: in-situ polymerization of polyaniline (PANi) in the presence of nano-silicon followed by combination of the prepared n-Si/PANi binary composite with reduced graphene oxide (RGO), to form a n-Si/PANi/RGO composite. Electron microscopy reveals the unique nano-architecture of the n-Si/PANi/RGO composite: silicon nanoparticles are well dispersed within a PANi matrix, which in turn is anchored to the surface of RGO sheets. The n-Si/PANi/RGO ternary composite delivered an initial capacity of 3259 mAh/g and 83.5% Coulombic efficiency. The new composite displayed better rate performance and capacity recovery than either nano-Si or n-Si/PANi. Structural and morphological studies combined with AC impedance analysis suggest that the n-Si/PANi/RGO composite has higher electrical conductivity than the other two component materials, yielding better performance at high current densities or C rates. The good rate performance, high initial specific capacity and stable Coulombic efficiency of n-Si/PANi/RGO make it a promising anode material for high energy density lithium-ion batteries.
54

A Study on Nano-Si/Polyaniline/Reduced Graphene Oxide Composite Anode for Lithium-Ion Batteries

Li, Kai January 2013 (has links)
Because of its high theoretical specific capacity (4200mAh/g) and natural abundance (2nd most abundant element on earth), silicon is considered a promising anode candidate for high energy density lithium-ion batteries. However, the dramatic volume changes (up to 400%) that occur during lithiation/delithiation and the relative low electrical conductivity of silicon prevent the implementation of this material. In this work, a nano-silicon/polyaniline/reduced graphene oxide composite was synthesized via a two-step process: in-situ polymerization of polyaniline (PANi) in the presence of nano-silicon followed by combination of the prepared n-Si/PANi binary composite with reduced graphene oxide (RGO), to form a n-Si/PANi/RGO composite. Electron microscopy reveals the unique nano-architecture of the n-Si/PANi/RGO composite: silicon nanoparticles are well dispersed within a PANi matrix, which in turn is anchored to the surface of RGO sheets. The n-Si/PANi/RGO ternary composite delivered an initial capacity of 3259 mAh/g and 83.5% Coulombic efficiency. The new composite displayed better rate performance and capacity recovery than either nano-Si or n-Si/PANi. Structural and morphological studies combined with AC impedance analysis suggest that the n-Si/PANi/RGO composite has higher electrical conductivity than the other two component materials, yielding better performance at high current densities or C rates. The good rate performance, high initial specific capacity and stable Coulombic efficiency of n-Si/PANi/RGO make it a promising anode material for high energy density lithium-ion batteries.
55

Diagnosis and prognosis of degradation in lithium-ion batteries

Birkl, Christoph January 2017 (has links)
Lithium-ion (Li-ion) batteries are the most popular energy storage technology in consumer electronics and electric vehicles and are increasingly applied in stationary storage systems. Yet, concerns about safety and reliability remain major obstacles, which must be addressed in order to improve the acceptance of this technology. The gradual degradation of Li-ion cells over time lies at the heart of this problem. Time, usage and environmental conditions lead to performance deterioration and cell failures, which, in rare cases, can be catastrophic due to res or explosions. The physical and chemical mechanisms responsible for degradation are numerous, complex and interdependent. Our understanding of degradation and failure of Li-ion cells is still very limited and more limited yet are reliable and practical methods for the detection and prediction of these phenomena. This thesis presents a comprehensive approach for the diagnosis and prognosis of degradation in Li-ion cells. The key to this approach is the extraction of information on electrode-speci c degradation through open circuit voltage (OCV) measurements. This is achieved in three stages. Firstly, a parametric OCV model is created, which computes the OCV of each electrode. Secondly, a diagnostic algorithm is devised, through which the OCV model is tted to OCV measurements recorded on Li-ion cells at various stages throughout their cycle life. The algorithm identi es the nature and quanti es the extent of degradation experienced by the cells. Lastly, the outputs of the algorithm are used to identify the likely failure modes of the cells and predict their end-of-life. The presented methods improve safe operation and predictions of remaining useful cycle life for commercial Li-ion cells. Greater certainty about the reliability, safety, required maintenance and depreciation of Li-ion battery systems can signi cantly enhance the competitiveness of battery electric storage in both automotive and stationary applications. The ndings presented in this work are therefore not only of technological but also of commercial interest.
56

Crystalline polymer and 3D ceramic-polymer electrolytes for Li-ion batteries

Hekselman, Aleksandra K. January 2014 (has links)
The research work presented in this thesis comprises a detailed investigation of conductivity mechanism in crystalline polymer electrolytes and development of a new class of ceramic-polymer composite electrolytes for Li-ion batteries. Firstly, a robust methodology for the synthesis of monodispersed poly(ethylene oxides) has been established and a series of dimethyl-protected homologues with 13, 15, 17, 28, 29, 30 ethylene oxide repeat units was prepared. The approach is based on reiterative cycles of chain extension and deprotection, followed by end-capping of the oligomeric chain ends with methyl groups. The poly(ethylene oxide) homologues show a superior level of monodispersity to previous work and were subsequently used to prepare crystalline PEO6:LiPF6 polymer electrolytes. A correlation between the number of ether oxygens in the polymer chain and the ionic conductivity of crystalline polymer electrolytes has been established. The structure and dynamics of the monodispersed complexes were studied using solid-state NMR spectroscopy for the first time. The results are in agreement with the proposed mechanism of ionic conductivity in crystalline polymer electrolytes. A new class of composite solid electrolytes for all-solid-state batteries with a lithium metal anode is reported. The composite material consists of a 3D interpenetrating network of a ceramic electrolyte, Li₁.₄Al₀.₄Ge₁.₆(PO₄)₃, and an inert polymer (polypropylene), providing continuous pathways for the ionic transport and excellent mechanical properties. 3D connectivity of this novel composite was confirmed using X-ray microtomography and AC impedance spectroscopy.
57

Nanoparticles-infused lithium manganese phosphate coated with magnesium-gold composite thin film - a possible novel material for lithium ion battery olivine cathode.

Hlongwa, Ntuthuko Wonderboy January 2014 (has links)
>Magister Scientiae - MSc / Architecturally enhanced electrode materials for lithium ion batteries (LIB) with permeable morphologies have received broad research interests over the past years for their promising properties. However, literature based on modified porous nanoparticles of lithium manganese phosphate (LiMnPO₄) is meagre. The goal of this project is to explore lithium manganese phosphate (LiMnPO₄) nanoparticles and enhance its energy and power density through surface treatment with transition metal nanoparticles. Nanostructured materials offer advantages of a large surface to volume ratio, efficient electron conducting pathways and facile strain relaxation. The material can store lithium ions but have large structure change and volume expansion during charge/discharge processes, which can cause mechanical failure. LiMnPO₄ is a promising, low cost and high energy density (700 Wh/kg) cathode material with high theoretical capacity and high operating voltage of 4.1 V vs. Ag/AgCl which falls within the electrochemical stability window of conventional electrolyte solutions. LiMnPO₄ has safety features due to the presence of a strong P–O covalent bond. The LiMnPO₄ nanoparticles were synthesized via a sol-gel method followed by coating with gold nanoparticles to enhance conductivity. A magnesium oxide (MgO) nanowire was then coated onto the LiMnPO₄/Au, in order to form a support for gold nanoparticles which will then form a thin film on top of LiMnPO₄ nanoparticles crystals. The formed products will be LiMnPO₄/Mg-Au composite. MgO has good electrical and thermal conductivity with improved corrosion resistance. Thus the electronic and optical properties of MgO nanowires were sufficient for the increase in the lithium ion diffusion. The pristine LiMnPO₄ and LiMnPO₄/Mg-Au composite were examined using a combination of spectroscopic and microscopic techniques along with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Microscopic results revealed that the LiMnPO₄/Mg-Au composite contains well crystallized particles and regular morphological structures with narrow size distributions. The composite cathode exhibits better reversibility and kinetics than the pristine LiMnPO₄ due to the presence of the conductive additives in the LiMnPO₄/Mg-Au composite. This is demonstrated in the values of the diffusion coefficient (D) and the values of charge and discharge capacities determined through cyclic voltammetry. For the composite cathode, D= 2.0 x 10⁻⁹ cm²/s while for pristine LiMnPO₄ D = 4.81 x 10⁻¹⁰ cm2/s. The charge capacity and the discharge capacity for LiMnPO₄/Mg-Au composite were 259.9 mAh/g and 157.6 mAh/g, respectively, at 10 mV/s. The corresponding values for pristine LiMnPO₄ were 115 mAh/g and 44.75 mAh/g, respectively. A similar trend was observed in the results obtained from EIS measurements. These results indicate that LiMnPO₄/Mg-Au composite has better conductivity and will facilitate faster electron transfer and therefore better electrochemical performance than pristine LiMnPO₄. The composite cathode material (LiMnPO₄/Mg-Au) with improved electronic conductivity holds great promise for enhancing electrochemical performances, discharge capacity, cycle performance and the suppression of the reductive decomposition of the electrolyte solution on the LiMnPO₄ surface. This study proposes an easy to scale-up and cost-effective technique for producing novel high-performance nanostructured LiMnPO₄ nanopowder cathode material.
58

Investigation of Lithium Ion Battery Electrodes: Using Mathematical Models Augmented with Data Science to Understand Surface Layer Formation, Mass Transport, Electrochemical Kinetics, and Chemical Phase Change

Brady, Nicholas William January 2019 (has links)
This thesis first uses physical scale models to investigate solid-state phenomena - surface layer formation, solid-state diffusion of lithium, electrochemical reactions at the solid-electrolyte interface, as well as homogeneous chemical phase change reactions. Evidence is provided that surface layer formation on the magnetite, Fe3O4, electrode can accurately be described mathematically as a nucleation and growth process. To emulate the electrochemical results of the LiV3O8 electrode, a novel method is developed to capture the phase change process; this method describes phase change as a nucleation and growth process. The physical parameters of the LiV3O8 electrode: the solid-state diffusion coefficient, phase change saturation concentration, phase reaction rate constant, and exchange current density, are all quantified and the agreement with experimental results is compelling. Electrochemical evidence, corroborated by results from density functional theory, indicate that delithiation is a more facile process than lithiation in the LiV3O8 electrode. Further investigation of the LiV3O8 electrode is undertaken by coupling the crystal scale model to electrode scale phenomena. Characterization of the LiV3O8 electrode by operando EDXRD experiments provides a unique and independent set of observations that validate the previously estimated physical constants for the phase change saturation concentration and phase change reaction rate constant; they are both found to be consistent with their previous estimates. Finally, it is observed that anodic physical phenomena are important during delithiation of the cathode because the kinetics at the anode become mass-transfer limited. Finally, it is illustrated that coupling physical models to data science and algorithmic computing is an effective method to accelerate model development and quantitatively guide the design of experiments.
59

Fluorine-free electrolytes for Li-ion batteries

Wahlfort, Filippa January 2021 (has links)
Lithium-ion batteries are of great importance for today's society. The state-of-the-art batteries that are used today use a fluorinated electrolyte that contains the salt LiPF6 and acts as both a safety hazard and an environmental issue due to its ability to form the toxic gas hydrogen fluoride (HF). This project aims to find a fluorine-free electrolyte that can be used in silicon-based lithium-ion batteries to make them more environmentally friendly without detriment to the electrochemical performance. To do so, an additive that may form a solid electrolyte interphase (SEI) stable enough to allow a fluorine-free electrolyte to replace the ones used today is sought for. The salt of interest is lithium  bis(oxalato)borate (LiBOB). Based on previous research electrolytes using LiBOB in either the solvent γ-Butyrolactone (GBL) or a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) are examined. The additives used are vinylene carbonate (VC) and 1,3,2-dioxathiolane 2,2-dioxide (DTD). Techniques used are cyclic voltammetry, linear sweep voltammetry, galvanostatic charge and discharge, X-ray photoelectron spectroscopy and scanning electron microscopy.  The cells using GBL as solvent have cycled very poorly during this project while LiBOB in EC:EMC + VC shows the most promising results, with highest capacity retention and less amount of degraded LiBOB during the first charge. It is also to be noted that both EC:EMC based electrolytes provide the formation of a passivating solid electrolyte interface (SEI) and are of interest for further investigation based on the results obtained during this project.
60

Application and Challenges of Neutron Depth Profiling to In-Situ Battery Measurements

Lyons, Daniel J. 29 September 2021 (has links)
No description available.

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