Context. Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. The time-dependence of deuterium fractionation and the relative abundances of different nuclear spin modifications are supposed to provide a means of determining the evolutionary stages of these objects. Aims. We aim to test the current understanding of spin-state chemistry of deuterated species by determining the abundances and spin ratios of NH2D, NHD2 and ND3 in a quiescent, dense cloud. Methods. Spectral lines of NH3, NH2D, NHD2, ND3 and N2D+ were observed towards a dense, starless core in Ophiuchus with the APEX, GBT and IRAM 30-m telescopes. The observations were interpreted using a gas-grain chemistry model combined with radiative transfer calculations. The chemistry model distinguishes between the different nuclear spin states of light hydrogen molecules, ammonia and their deuterated forms. Different desorption schemes can be considered. Results. High deuterium fractionation ratios with NH2D = NH3 similar to 0 : 4, NHD2 = NH2D similar to 0 : 2 and ND3 = NHD2 similar to 0 : 06 are found in the core. The observed ortho/para ratios of NH2D and NHD2 are close to the corresponding nuclear spin statistical weights. The chemistry model can approximately reproduce the observed abundances, but consistently predicts too low ortho/para-NH2D, and too large ortho/para-NHD2 ratios. The longevity of N2H+ and NH3 in dense gas, which is prerequisite to their strong deuteration, can be attributed to the chemical inertia of N-2 on grain surfaces. Conclusions. The discrepancies between the chemistry model and the observations are likely to be caused by the fact that the model assumes complete scrambling in principal gas-phase deuteration reactions of ammonia, which means that all the nuclei are mixed in reactive collisions. If, instead, these reactions occur through proton hop/hydrogen abstraction processes, statistical spin ratios are to be expected. The present results suggest that while the deuteration of ammonia changes with physical conditions and time, the nuclear spin ratios of ammonia isotopologues do not probe the evolutionary stage of a cloud.

We sort 4683 molecular clouds between 10 degrees < l < 65 degrees from the Bolocam Galactic Plane Survey based on observational diagnostics of star formation activity: compact 70 mu m sources, mid-IR color-selected YSOs, H2O and CH3OH masers, and UCH II. regions. We also present a combined NH3-derived gas kinetic temperature and H2O maser catalog for 1788 clumps from our own GBT 100 m observations and from the literature. We identify a subsample of 2223 (47.5%) starless clump candidates (SCCs), the largest and most robust sample identified from a blind survey to date. Distributions of flux density, flux concentration, solid angle, kinetic temperature, column density, radius, and mass show strong (>1 dex) progressions when sorted by star formation indicator. The median SCC is marginally subvirial (alpha similar to 0.7) with >75% of clumps with known distance being gravitationally bound (alpha < 2). These samples show a statistically significant increase in the median clump mass of Delta M similar to 170-370 M-circle dot from the starless candidates to clumps associated with protostars. This trend could be due to (i) mass growth of the clumps at (M) over dot similar to 200-440 M-circle dot Myr(-1) for an average freefall 0.8 Myr timescale, (ii) a systematic factor of two increase in dust opacity from starless to protostellar phases, and/or (iii). a variation in the ratio of starless to protostellar clump lifetime that scales as similar to M-0.4. By comparing to the observed number of CH3OH maser containing clumps, we estimate the phase. lifetime of massive (M > 10(3) M-circle dot) starless clumps to be 0.37 +/- 0.08 Myr (M/10(3) M-circle dot)(-1); the majority (M < 450 M-circle dot) have phase. lifetimes longer than their average freefall time.

We present deep NH₃ and CCS maps of L1495-B218 filaments and the dense cores embedded within the filaments in Taurus. The L1495-B218 filaments form an interconnected, nearby, large complex extending over 8 pc. We observed the filaments in NH₃ (1,1)&(2,2), CCS Nⱼ = 1₂-0₁, and HC₇N J = 21-20 with spectral resolution of 0.038 km/s and spatial resolution of 31". The CSAR algorithm, which is a hybrid of seeded-watershed and binary dendrogram algorithm, identifies 39 leaves and 16 branches in NH₃ (1,1). Applying a virial analysis for the 39 NH₃ leaves, we find only 9 out of 39 leaves are gravitationally bound, and 12 out of 30 gravitationally unbound leaves are pressure-confined. Our analysis suggests that a dense core may form as a pressure-confined structure, evolve to a gravitationally bound core, and then undergo collapse to form a protostar. We find that the L1495A, B213E, and B216 regions have strong CCS emission and the B211 and B218 regions have weak CCS emission. Analysis of CCS emission with NH₃ (1,1) and dust continuum emission shows that CCS is not a good tracer for starless core evolution. On the other hand, CCS appears to trace recently accreted gas in L1495A and L1521D. We also present more realistic dynamic stability conditions for dense cores and filaments. In a new analysis of stability conditions we account for converging motions which have been modeled toward starless cores and take the effect of radiation fields. We find that the critical size of a dense core having a homologous converging motion with its peak speed being the sound speed is roughly half of the critical size of the Bonnor-Ebert sphere. We also find the critical mass/line density of a dense core/filament irradiated by radiation to be considerably smaller than that of the Bonnor-Ebert sphere/isothermal cylinder when the radiation pressure is stronger than the central gas pressure of dense core/isothermal cylinder. For regions in the inner Galaxy and near OB associations, the critical mass/line density of a dense structure may be less than 20% of the critical mass/line density of Bonnor-Ebert sphere/isothermal cylinder.

We present an update to the ultraviolet-to-radio database of global broadband photometry for the 79 nearby galaxies that comprise the union of the KINGFISH (Key Insights on Nearby Galaxies: A Far-Infrared Survey with Herschel) and SINGS (Spitzer Infrared Nearby Galaxies Survey) samples. The 34-band data set presented here includes contributions from observational work carried out with a variety of facilities including GALEX, SDSS, Pan-STARRS1, NOAO, 2MASS, Wide-Field Infrared Survey Explorer, Spitzer, Herschel, Planck, JCMT, and the VLA. Improvements of note include recalibrations of previously published SINGS BVRCIC and KINGFISH farinfrared/submillimeter photometry. Similar to previous results in the literature, an excess of submillimeter emission above model predictions is seen primarily for low-metallicity dwarf or irregular galaxies. This 33-band photometric data set for the combined KINGFISH+SINGS sample serves as an important multiwavelength reference for the variety of galaxies observed at low redshift. A thorough analysis of the observed spectral energy distributions is carried out in a companion paper.

We present a catalog of all CO (J = 4-3 through J = 13-12), [ C I], and [ N II] lines available from extragalactic spectra from the Herschel SPIRE Fourier Transform Spectrometer (FTS) archive combined with observations of the low-J CO lines from the literature and from the Arizona Radio Observatory. This work examines the relationships between L-FIR, L'(CO), and L-CO/L-CO,L-1-0. We also present a new method for estimating probability distribution functions from marginal signal-to-noise ratio Herschel FTS spectra, which takes into account the instrumental "ringing" and the resulting highly correlated nature of the spectra. The slopes of log(L-FIR) versus log (L'(CO)) are linear for all mid- to high-J CO lines and slightly sublinear if restricted to (ultra) luminous infrared galaxies ((U) LIRGs). The mid-to high-J CO luminosity relative to CO J - 1-0 increases with increasing L-FIR, indicating higher excitement of the molecular gas, although these ratios do not exceed similar to 180. For a given bin in L-FIR, the luminosities relative to CO J = 1-0 remain relatively flat from J = 6-5 through J = 13-12, across three orders of magnitude of L-FIR. A single component theoretical photodissociation region (PDR) model cannot match these flat SLED shapes, although combinations of PDR models with mechanical heating added qualitatively match the shapes, indicating the need for further comprehensive modeling of the excitation processes of warm molecular gas in nearby galaxies.

Stars form when filaments and dense cores in molecular clouds fragment and collapse due to self-gravity. In the most basic analyses of gravitational stability, the competition between self-gravity and thermal pressure sets the critical (i.e. maximum stable) mass of spheres and the critical line density of cylinders. Previous work has considered additional support from magnetic fields and turbulence. Here, we consider the effects of non-ionizing radiation, specifically the inward radiation pressure force that acts on dense structures embedded in an isotropic radiation field. Using hydrostatic, isothermal models, we find that irradiation lowers the critical mass and line density for gravitational collapse, and can thus act as a trigger for star formation. For structures with moderate central densities, similar to 10(3) cm(-3), the interstellar radiation field in the Solar vicinity has an order unity effect on stability thresholds. For more evolved objects with higher central densities, a significant lowering of stability thresholds requires stronger irradiation, as can be found closer to the Galactic centre or near stellar associations. Even when strong sources of ionizing radiation are absent or extincted, our study shows that interstellar irradiation can significantly influence the star formation process.

Compact substructure is expected to arise in a starless core as mass becomes concentrated in the central region likely to form a protostar. Additionally, multiple peaks may form if fragmentation occurs. We present Atacama Large Millimeter/submillimeter Array (ALMA) Cycle 2 observations of 60 starless and protostellar cores in the Ophiuchus molecular cloud. We detect eight compact substructures which are >15 '' from the nearest Spitzer young stellar object. Only one of these has strong evidence for being truly starless after considering ancillary data, e.g., from Herschel and X-ray telescopes. An additional extended emission structure has tentative evidence for starlessness. The number of our detections is consistent with estimates from a combination of synthetic observations of numerical simulations and analytical arguments. This result suggests that a similar ALMA study in the Chamaeleon. I cloud, which detected no compact substructure in starless cores, may be due to the peculiar evolutionary state of cores in that cloud.

We report a discovery of shocked gas from the supernova remnant (SNR) G357.7+0.3. Our millimeter and submillimeter observations reveal broad molecular lines of CO(2-1), CO(3-2), CO(4-3), (CO)-C-13 (2-1), and (CO)-C-13 (3-2), HCO+, and HCN using the Heinrich Hertz Submillimeter Telescope, the Arizona 12 m Telescope, APEX, and the MOPRA Telescope. The widths of the broad lines are 15-30 km s(-1), and the detection of such broad lines is unambiguous, dynamic evidence showing that the SNR G357.7+0.3 is interacting with molecular clouds. The broad lines appear in extended regions (>4'.5 x 5'). We also present the detection of shocked H-2 emission in the mid-infrared but lacking ionic lines using Spitzer/IRS observations to map a few-arcminute area. The H2 excitation diagram shows a best fit with a two-temperature local thermal equilibrium model with the temperatures of similar to 200 and 660 K. We observed [C II] at 158 mu m and high-J CO(11-10) with the German Receiver for Astronomy at Terahertz Frequencies (GREAT) on the Stratospheric Observatory for Infrared Astronomy. The GREAT spectrum of [C II], a 3 sigma detection, shows a broad line profile with a width of 15.7 km(-1) that is similar to those of broad CO molecular lines. The line width of [C II] implies that ionic lines can come from a low-velocity C-shock. Comparison of H2 emission with shock models shows that a combination of two C-shock models is favored over a combination of C- and J-shocks or a single shock. We estimate the CO density, column density, and temperature using a RADEX model. The best-fit model with n(H-2) = 1.7 x 10(4) cm(-3), N(CO) = 5.6 x 10(16) cm(-2), and T = 75 K can reproduce the observed millimeter CO brightnesses.

We present a multiwavelength investigation of a region of a nearby giant molecular cloud that is distinguished by a minimal level of star formation activity. With our new (CO)-C-12(J = 2-1) and (CO)-C-13(J = 2-1) observations of a remote region within the middle of the California molecular cloud, we aim to investigate the relationship between filaments, cores, and a molecular outflow in a relatively pristine environment. An extinction map of the region from Herschel Space Observatory observations reveals the presence of two 2 pc long filaments radiating from a highextinction clump. Using the (CO)-C-13 observations, we show that the filaments have coherent velocity gradients and that their mass-per-unit-lengths may exceed the critical value above which filaments are gravitationally unstable. The region exhibits structure with eight cores, at least one of which is a starless, prestellar core. We identify a low-velocity, low-mass molecular outflow that may be driven by a flat spectrum protostar. The outflow does not appear to be responsible for driving the turbulence in the core with which it is associated, nor does it provide significant support against gravitational collapse.

This Projects goal was to develop a manual, which was to be used as help for a fishing company in the making of an SMS (Safety Management System). The manual was going to follow the guidelines presented by the IMO (International Maritime Organisation) and the Swedish Transport Agency.   The projects client was a smaller fishing company that was about to build a fishing vessel. The work has been carried out as a project, it was finished within the schedule and the client was most satisfied with the result. The client has used the manual in the making of the Safety Booklet (SMS) and they are now certified according to the rules of the Swedish Transport Agency.