The aim of this literature study is to compare and discuss different fields of paleolimnology, with a focus on three main research areas – eutrophication, acidification, and climate change. Pioneering work and the development of paleolimnological methods around these three areas were reviewed and synthesized. Paleolimnology started out as limnology and paleoecology, but has evolved tremendously over the past decades. Early paleolimnological studies focused on lake ontogeny and mechanics in the catchment such as weathering. The focus eventually shifted to nutrient loadings during the 1960s – 1970s as the debate on human induced eutrophication emerged. The important question to answer was which nutrient was the limiting factor in eutrophication. Acidification was the next topic of investigation during the 1980s – 1990s, and paleolimnology developed methods to infer past pH change based on chironomids and diatom fossils preserved in lake sediment. This research resulted in calibration sets and proxies which can be used to reconstruct past conditions. The paleolimnological community eventually shifted focus in the late 1990s to climate change and began to use lake sediment to reconstruct past climatic trends using multiproxy studies such as diatoms, chironomids and geochemistry. Varved lake sediment offered a much needed terrestrial high resolution option to the ice core records. History plays a fundamental role in all environmental issues and paleolimnology has the ability to provide historical records of past environmental conditions. Paleolimnology will most likely play a key role in management and restoration in the future. As technology and training sets develop, fast and cheap ways to interpret sediment proxies will emerge and maybe even fully automated identification of proxies.

This thesis summarizes the efforts of two years of field investigation and water quality data analysis. With a focus on construction sites, background monitoring was carried out at two sites and data from a third, active site was also included for analysis. The water quality data was used to estimate event-based sediment yield from each location, and continuously-collected rainfall, water level and turbidity data was used to calibrate an event-based hydrologic model (SEDCAD). Based on the results of this research and the outputs of the calibrated model, an event-based sediment yield equation calibrated for Southern Ontario conditions is presented in conjunction with an IDF design tool. The IDF design tool can be used to effectively size and site construction-phase erosion and sediment controls before shovels break ground. The regulatory framework by which such controls are assessed is also discussed, and improvements to existing stormwater management guidelines are proposed.

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High Arctic meromictic lakes are frequently used to generate detailed records of past environmental variability within their sedimentary profiles. However, without detailed analyses of sedimentation influences over time, their paleoclimate records cannot be accurately interpreted. This thesis presents a comprehensive examination of the sedimentology and paleoenvironmental records of meromictic Lake A, Ellesmere Island (83°00’N, 75°30’W), including detailed analysis of the sedimentary history, development and evaluation of several paleoclimate records. The sedimentary record was primarily composed of clastic material but varying inputs of authigenic components from biological and chemical processes in the water column resulted in a complex history of lake sedimentation. Under chemically stratified conditions during the past millennium, annual laminae (varves) formed and were used to develop a sedimentary chronology. Sedimentary pellets were most likely formed by ice-rafting processes and were deposited during high melt years in this perennially ice-covered lake. The pellet frequency record indicated that the twentieth century contained the most frequent reduced ice cover summers during the past millennium, although the 1500s and 1600s were also inferred warm periods. Comparison with instrumental climate data indicated that varve thickness was primarily related to late summer and autumn snowfall in the previous year, which highlighted the importance of snow availability in spring rather than melt energy in sediment transfer to the lake in this non-glacial catchment. The varve thickness and grain size records suggested increased flow competency and autumn snowfall particularly during the late-1000s to early-1100s and first half of the 1900s. Paleoenvironmental records from Lake A corresponded well with many regional proxy records and provided a long-term framework within which to examine observed environmental change along the northern Ellesmere Island coast during the past century. Finally, these analyses would not have been possible without obtaining high quality sediment cores. This research also investigated the effectiveness of a gel seal method for preserving the fragile sediment-water interface during transport and its results could be useful for other sediment core studies. / Thesis (Ph.D, Geography) -- Queen's University, 2008-05-08 13:34:14.044

Freshwater systems in Canada are affected by a multitude of environmental stressors, including cultural eutrophication, introduction of non‐native species, and climate change. Multiple stressors can interact in unpredictable ways and generate novel ecological scenarios, thus creating challenges for lake management. Lake Simcoe is an example of an aquatic system impacted by multiple stressors, facing management challenges of deteriorating water quality and coldwater fisheries. In order to better understand stressor interactions and pre‐disturbance lake conditions, a long‐term perspective is necessary. Therefore, this study used paleolimnological techniques to assess changes in the water quality of Lake Simcoe over the past ca. 200 years. Sedimentary diatom assemblages were analyzed in 210Pb‐dated cores from five sites across the lake. Diatom assemblages recorded several pronounced and synchronous shifts over the last ca. 200 years. Modest lake‐wide shifts in diatom community composition occurred in the late‐1800’s and early‐1900’s, suggesting that early cultural disturbances, such as land clearance and canal construction, had relatively minor impacts on Lake Simcoe. However, starting in the 1930’s, agricultural and urban development intensified, as indicated by substantial increases in eutrophic taxa. The most pronounced lake‐wide shift in diatom assemblages occurred in the mid‐to‐late 1900’s, the taxonomic nature and timing of which strongly suggest a response to regional climate warming. Moreover, diatom compositional trends at all sites were significantly correlated with instrumental records of regional temperature and lake ice the last ca. 100 years. An additional and marked lake‐wide shift in diatom assemblages occurred in the mid-1990’s, coinciding with the invasion of dreissenid mussels. The combination of stressors acting concurrently on Lake Simcoe, as well as the lake’s distinct water chemistry and size, make it challenging to reconstruct single limnological variables (such as, total phosphorus) in this system. Nevertheless, overall patterns of diatom compositional changes from the five sites revealed the largest shifts occurred in the post‐1950 sediments and that change in lake‐water total phosphorus concentrations played a minor role. Our results imply that substantial changes in climate have amplified the effects of multiple stressors in this complex system. / Thesis (Master, Biology) -- Queen's University, 2010-08-04 12:03:42.267

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The availability of phosphorus from the anoxic hypolimnia of lakes to epilimnetic plankton was investigated by experimental studies on eight lakes in Ontario and Quebec. Availability was determined with a short-term bioassay based on the standardized retardation of planktonic uptake of phosphorus tracer in the presence of orthophosphate; availability was also estimated by SRP (soluble reactive phosphorus) analysis, since approximately 90% of SRP was available in anoxic waters. / Iron concentrations were high in some hypolimnia, but should become diluted after mixing with surface water. When iron concentrations after mixing exceeded 0.20 mg/L, aeration lowered availability and SRP. Therefore, samples from anoxic hypolimnia were kept anoxic. The fate of hypolimnetic phosphorus at turnover was studied by construction of a budget for SRP, total phosphorus, particulate iron containing phosphorus and particulate biological phosphorus at fall turnover in Lake Magog. Despite high concentrations of hypolimnetic iron, only 30% of the upwelling hypolimnetic phosphorus combined with iron after complete mixing, 30% was incorporated into biomass and 38% stayed potentially available as SRP. / In two lakes, hypolimnetic iron was undetectable hydrogen sulfide concentrations were high. H(,2)S interfered with the SRP analysis and poisoned plankton. After degassing, routine SRP analysis was possible, and availability was close to 100%. Iron and H(,2)S interference in the SRP analysis were circumvented by degassing or by maintaining anoxia. A simpler method, the analysis of TRP (total reactive phosphorus) after aeration, was developed which analyses SRP quantitatively in anoxic waters.

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