[by] J.M. Luttinger and L. Tisza. / "Reprinted from the Physical review, vol. 70, nos. 11 and 12, 954-964, Dec. 1 and 15, 1946." / Includes bibliographical references. / Contract OEMsr-262.

The use of geophysical techniques to image the interiors of active volcanoes can provide a better understanding of their structure and plumbing. The need for such information is especially critical for undersea volcanoes, whose environment makes them difficult to investigate. Because undersea volcanoes are made up of highly magnetic basaltic rock, it is possible to use variations in the magnetic field to explore the internal structure of such edifices. This study combines magnetic survey data from 12 research cruises to make a magnetic anomaly map of volcanically active Loihi, located in the Hawaiian Island chain. NRM intensities and susceptibility measurements were measured from recovered rock samples and suggest that magnetic properties of Loihi are widely varied (NRM intensities range from 1-157 A/m and susceptibilities from 1.26 x 10-3 to 3.62 x 10-2 S.I.). The average NRM intensity is 26 A/m. The size and strength of magnetic source bodies were determined by using various modeling techniques. A strongly magnetized shield can explain most of the anomaly with a large nonmagnetic zone inside, beneath the summit. Prominent magnetic highs are located along Loihi's north and south rift zone dikes and modeling solutions suggest strongly magnetized source bodies in these areas as well as a thin, magnetic layer atop the nonmagnetic zone. The strong magnetic anomalies found along the volcano's rift zones cannot be readily attributed to recent lava flows at the surface. Instead, the source bodies must continue several kilometers in depth to give reasonable magnetization values and are interpreted as dike intrusions. Nonmagnetic anomalies at the summit and south of the summit suggest the presence of a magma system. The model solution suggests Loihi is an inhomogeneously magnetized seamount with highly magnetic dike intrusions along the rift zones with a nonmagnetic body at its center overlain with a magnetic layer.

The EEC (Electron Energy Corporation) in conjunction with the National Aeronautics and Space Administration is researching the magnetic bearings for an alternative to conventional journal or ball bearings. The purpose of this research was to design and develop a high-temperature (1000ºF) hybrid Magnetic Bearing using High Temperature Permanent Magnets (HTPM), developed by the EEC for high performance jet engines at high speeds that supply loads of 500 lbf. Another objective is to design and build a test rig fixture to measure the load capacity of the designed bearing. The permanent magnet bias of the Homopolar radial magnetic bearing reduces the amount of current required for magnetic bearing operation. This reduces the power loss due to the coil current resistance and improves the system efficiency because the magnetic field of the HTPM can suspend the major portion of the static load on bearing. A high temperature radial magnetic bearing was designed via an iterative search employing 3D finite element based electromagnetic field simulations. The bearing was designed to produce 500 lbf of force at 1000ºF and the design weight is 48 lbs. The bias flux of the Homopolar radial bearing is produced by EEC HTPM to reduce the related ohmic losses of an electromagnetic circuit significantly. An experimental procedure was developed to measure actual load capacity of the designed bearing at the test rig. All the results obtained from the experiment were compiled and analyzed to determine the relation between bearing force, applied current and temperature.

For decades, Metallic Glass, with its isotropic featureless structure while exhibiting outstanding mechanical properties was possible only at a high rate of quenching and with at least one dimension in the submicron regime.  This limitation was overcome with the discovery of Bulk Metallic glasses, BMGs, containing three or more elements following the additional two empirical rules of optimum geometric size differences and negative energy of mixing among the constituent elements. Since then thousands of Fe-, Ni-, Al-, Mg-, Ti- based BMGs have been discovered and comprehensively investigated mainly by groups in Japan and USA. Yet the discovery of new combinations of elements for BMGs is alchemy. We do not know with certainty which element when added will make possible a transition from being a ribbon to a bulk rod.    In this thesis we report a discovery of castable BMGs rods on substitution of Fe by nickel in an alloy of FeBNb which could otherwise have been only melt-spun into ribbons.  For example, we find that substitution of just 6 at.% of Fe raises the glass forming range, GFA, to as much as ∆Tx =40K while the other parameters for GFA like Trg, γ, and δ reach enhanced values 0.57, 0.38, and 1.40 respectively.  Furthermore, the electrical conductivity is found to increase by almost a factor of two.  Magnetically it becomes softer with coercivity 260mOe which further reduces to much lower values on stress relaxation.  Ni does not seem to carry a magnetic moment while it enhances the magnetic transition temperature linearly with Ni concentration. We have investigated the role of Ni in another more stable BMGs based FeBNbY system in which case ∆Tx becomes as large as 94K with comparable enhancement in the other GFA parameters. Due to the exceptional soft magnetic properties, Fe-based bulk metallic glasses are considered potential candidate for their use in energy transferring devices. Thus the effect of Ni substitution on bulk forming ability, magnetic and electrical transport properties have been studied for FeBNb and FeBNbY alloy systems. The role of Ni in these systems is densification of the atomic structure and its consequence. We have exploited the superior mechanical properties of BMGs by fabricating structures that are thin and sustainable.  We have therefore investigated studies on the thin films of these materials retaining their excellent mechanical properties. Magnetic properties of FeBNb alloy were investigated in thin films form (~200-400nm) in the temperature range of 5-300K. These Pulsed Laser deposited amorphous films exhibit soft magnetism at room temperature, a characteristic of amorphous metals, while they reveal a shift in hysteresis loop (exchange anisotropy, HEB=18-25Oe), at liquid helium temperature. When thickness of films is reduced to few nanometers (~8-11nm), they exhibit high transparency (&gt;60%) in optical spectrum and show appreciably high saturation Faraday rotation (12o/μm, λ= 611nm). Thin films (~200-400nm) of Ni substituted alloy (FeNiBNb) reveal spontaneous perpendicular magnetization at room temperature. Spin-reorientation transition was observed as a function of film thickness (25-400nm) and temperature (200-300K), and correlated to the order/disorder of ferromagnetic amorphous matrix as a function of temperature. These two phase films exhibits increased value of coercivity, magnetic hardening, below 25K and attributed to the spin glass state of the system.    Using the bulk and thin films we have developed prototypes of sensors, current meters and such simple devices although not discussed in this Thesis.                                         Ti-based bulk metallic glasses have been attracting significant attention due to their lower density and high specific strength from structural application point of view. High mechanical strength, lower values of young’s modulus, high yield strength along with excellent chemical behaviors of toxic free (Ni, Al, Be) Ti-based glassy metals make them attractive for biomedical applications. In the present work, toxic free Ti-Zr-Cu-Pd-Sn alloys were studied to optimize their bulk forming ability and we successfully developed glassy rods of at least 14mm diameter by Cu-mold casting. Along with high glass forming ability, as-casted BMGs exhibit excellent plasticity. One of the studied alloy (Ti41.5Zr10Cu35Pd11Sn2.5) exhibits distinct plasticity under uniaxial compression tests (12.63%) with strain hardening before failure which is not commonly seen in monolithic bulk metallic glasses. / <p>QC 20120906</p> / Hero-m

This thesis presents the study of organofunctional alkoxysilane coatings to prevent high temperature oxidation of Sm-Co powders. Sm-Co are important permanent magnetic alloys, owing to their high Curie temperature and large values of magnetocrystalline anisotropy. They possess stable magnetic properties in the temperature range -40 to 120 °C which makes them very attractive candidates for automobile’s electric motors. However, the environmental conditions for such applications are a sum of high temperatures, humidity, fuels and salts which provide perfect breeding ground for corrosion. In this study we report the high temperature oxidation resistance of Sm2Co17 powders coated with four common commercially available organofunctional silanes; (3-aminopropyl)trimethoxysilane (APTMS), (3-aminopropyl)triethoxysilane (APTES), methyltrimethoxysilane (MTMS) and (3-glycidyloxypropyl)trimethoxysilane (GPTMS). The as received powder was a multimodal mixture of many sizes and shapes which represented a typical ball milling product. The thermal analyses of the powders suggested that the powders without surface coatings had profound affinity towards oxidation. The thermal properties of sieved uncoated powders revealed that the small powders were more susceptible to oxidation than the large powders due to their large specific surface area. The isothermal properties of coated powders revealed that the powders coated with silanes had at least 10 times higher resistance to oxidation as compared to uncoated powders heated at 400 °C for 10 h. The non-isothermal tests conducted from room temperature to 500 °C also revealed that the uncoated powders gained 6 times more mass as compared to the powders coated with an ideal (MTMS) silane. The microstructural analysis of the uncoated powders heated from 400 °C to 550 °C revealed diffusion of oxygen, instable intermetallic phases which resulted in a redistribution of alloying elements, precipitation of alloying elements and formation of a featureless shell (approximately 20 µm in thickness) that surrounded the unreacted core. The coated powders on the other hand showed homogenous distribution of alloying elements, stable intermetallic phases and limited the shell thickness (1 µm). The thermo-magnetic properties of Sm-Co powders showed that the thermal instability also affected the magnetic properties adversely. It was found that the magnetic properties were deteriorated with a decrease in powder size. The energy dispersive spectroscopic (EDS) analyses showed that the small powders contained higher oxygen content than the large powders. Moreover XRD analysis also revealed that the small powders contain higher residual strains and smaller crystallite size which can play their role in deteriorating magnetic properties. It was found that surface modification by silanization improve the thermo-magnetic properties by effectively shielding the powder surfaces from surface oxidation. The rheological properties Sm-Co/PA12 composites revealed that the viscosity of the composites was increased with decreasing powder size due to the presence of rough surfaces and sharp corners in small powders. The rheological properties of the melts containing coated powders revealed that the silane layer acted as a lubricant and decreased the melt viscosity. It was found that coating the powders with silanes not only improve the rheological properties but also improve the other physical properties such as glass transition temperature the loss modulus by modifying the interfacial layer between the polymer matrix (PA12) and the powder. It results in a decrease in viscosity, a broadening of the glass transition temperature and a change in the damping properties of the composites. The dynamic mechanical properties of Sm-Co/PA12 composites showed that the storage modulus was increased with decreasing powder size. The results were expected as the rough surfaces act as local welding points between the powder and the polymer matrix. It was found that the surface modification improve the storage modulus. It is assumed that the silanes modify the interfacial properties which not only resulted in increasing the storage modulus but also broadened the glass transition temperature, Tg and damping, tanδ peaks. From the thermogravimetric, microstructural, rheological and magnetic analyses it can be concluded that the silanes are the effective coatings in preventing high temperature oxidation, stabilizing microstructure, enhancing mechanical properties, and improving rheological and magnetic properties. / <p>QC 20121205</p>

Detailed information on past oceanographic and climatic changes is crucial for our understanding of natural climate variability and for the assessment of future climate variations. Sediments strongly influenced by the North Atlantic Current accumulate at high rates in the northeastern Skagerrak, forming a potential highresolution archive for information on past climatic and oceanographic processes and events. Through a highresolution, multi-proxy study of the 32 meter long core MD99-2286 from the north-eastern Skagerrak, and interpretation of chirp sonar profiles from the coring area, this thesis provides new and detailed insights about the paleoceanographic development of the eastern North Sea region since the deglaciation. The chronostratigraphic control of core MD99-2286 relies on 27 radiocarbon dates. Ages are presented in calibrated thousand years before present (abbreviated “kyr”). Core MD99-2286 was correlated to chirp sonar profiles using measured physical properties. This correlation demonstrates that a strong regional acoustic reflector, previously assumed to represent the Pleistocene/Holocene boundary, was formed as a result of rapid ice retreat during the latest Pleistocene. Based on the distribution of ice rafted debris in the core, ice berg calving in the Skagerrak ended at 10.7 kyr. Detailed grain-size analyses of the core were interpreted using a novel 3D-visualization technique. Between 11.3 and 10.3 kyr, clay-rich distal glacial marine sediments were deposited in the northeastern Skagerrak, derived from Baltic melt-water outflow across south-central Sweden through the Otteid-Stenselva strait. As a result of differential isostatic uplift, the route of the major outflow and the associated sediment deposition moved southwards along the Swedish west coast. After 10.3 kyr, sediment deposition in the north-eastern Skagerrak gradually adopted to a fully interglacial normal marine sedimentation dominated by Atlantic inflow and the North Jutland Current. The establishment of the modern circulation system in the eastern North Sea is marked by abrupt coarsening of the sediments in core MD99-2286 at 8.5 kyr. This was a result of increased Atlantic inflow, opening of the English Channel and the Danish straits, and formation of the South Jutland Current. Mineral magnetic properties of the core show a distinct relationship reflecting general sediment source variability. After 8.5 kyr, sediments in the northeastern Skagerrak were derived predominantly from the Atlantic Ocean and the North Sea, with varying contributions from the South Jutland Current, the Baltic Current, and the currents along the coasts of western Sweden and southern Norway. Between 6.3 and 3.8 kyr, the eastern North Sea was further developed towards the modern situation by an increase of the South Jutland Current flow. The Skagerrak bottom currents were probably forced by strong Atlantic water inflow between 0.9 and 0.5 kyr, and after that by increased wind stress. The influence of regional climate on the eastern North Sea circulation has increased since the middle of the Holocene.

This thesis describes a research of suppression of superconducting gap in a superconducting island of a Ferromagnetic-Superconducting-Ferromagnetic Single-Electron-Transistor due to the fringing magnetic fields produced by the ferromagnetic leads. The devices are working below the critical temperature of the superconducting gap. A model is proposed to explain how the fringing magnetic field produced by the leads is strong enough to suppress the superconducting gap. The peak of the fringing magnetic field produced by one lead reaches 5000 oe. It is observed an inverse tunneling magneto resistance during the suppression of the superconducting gap, obtaining a maximum absolute value 500 times greater than the TMR in the normal state where the efficiency of the spin injection is low. It is concluded that the suppression of the superconducting gap is due to fringing magnetic field and not to the spin accumulation because the low efficiency of the spin injection. It is suggested a new geometry to reduce the effect of the fringing magnetic field so it can be obtained a suppression of the superconductivity due to the spin accumulation. It is described the qualitatively behavior of the IV characteristic when the suppression of the superconductivity is due to spin accumulation.

A unique approach for lightweight multifunctional composites was developed using Fe3O4 nanoparticles and polypyrrole-coated Fe3O4 particles as fillers. Fe3O4 particles are a good candidate for filler in a multifunctional composite system because they can reinforce mechanical properties of a polymer matrix and impart magnetic properties into a composite. Polypyrrole coating on Fe3O4 particles was utilized to incorporate electrical conductivity to the properties of composites. The effects of filler size and filler content were studied on both the mechanical and electromagnetic properties. Fe3O4 nanoparticles improved fracture toughness, but they compromised strength and modulus. Polypyrrole-coated Fe3O4 has potential for multifunctional material applications because the coating allows for concurrent increase in magnetic permeability and electrical conductivity in a composite. The polypyrrole coating also improved the strength of the composite. Fe3O4 nanoparticles were a major part of this work from their synthesis to their application in composites. The surface effect on magnetic properties was analyzed for Fe3O4 nanoparticles, resulting in a more accurate calculation of the magnetically dead layer thickness than previously reported. The results from this work contributed to further understanding of synthesis and characterization of magnetic nanoparticles, fabrication and characterization of nanocomposites, and design and development of lightweight multifunctional materials. Although the properties of the fabricated composites require further improvement, the methodology and approach provide a basis for future work in development of lightweight multifunctional composites.

Magnetic properties of cobalt clusters (20 N 200) were studied in molecular beams. The magnetization of cobalt clusters is studied at a broad range of temperatures, magnetic fields and clusters sizes. It is shown that the agnetization of ferromagnetic clusters in a cluster beam can be understood as an adiabatic process using the avoided crossing theory. Besides the ground state that bears magnetic moment of about 2 Bohr magneton per atom, an excited state that has 1 Bohr magneton per atom was discovered for every cobalt cluster observed. The energy separations between the two states was investigated by photo-ionization experiments. The ionization threshold shows that the energy gap between the two states is on the order of 0.1 eV for small clusters (N 100) and vanishes for larger clusters. Experiments also show that the polarizability of the excited state is lower than that of the ground state, which indicates a significant electronic tructure difference between the two states. Two states are also found for iron clusters (20 N 200) for which the magnetic moments per atom are about 3 Bohr magneton for the ground state and 1 Bohr magneton for the excited states. This explains the fractional magnetic moments as well as the local magnetic order observed above the Curie temperatures for iron group ferromagnets. Further experiments show two states for manganese clusters for which the ground state has magnetic moment of 1 Bohr magneton per atom in about the same size range. This suggests that the two states are a universal phenomenon of 3d transition metal clusters, which originate from the interaction between 3d and 4s electrons.

In this study, prealloyed austenitic stainless steel and premixed soft magnetic Ni-Fe permalloy compacts were consolidated through microwave and conventional sintering routes at combinations of various sintering temperatures and compaction pressures. Sintered alloys were characterized in terms of their densification, microstructural evolution as well as mechanical and magnetic properties. The effect of sintering method in terms of the applied sintering parameters on the final properties of the compacts were investigated in a comparative manner. It was determined that microwave sintered permalloys are superior compared to their conventionally sintered counterparts in densification response, microstructural characteristics such as pore shape and distribution as well as mechanical properties for both austenitic stainless steel and permalloy compacts. However, permeability of the microwave sintered permalloys was inferior to their conventionally sintered counterparts in some cases due to microstructural refinement associated with microwave sintering route.