Thesis (M. App. Sc.) - Department of Chemical Engineering, University of Adelaide, 1979. / Typescript (photocopy).

Thesis (Ph. D.)--Columbia University, 1930. / Vita. Bibliography: p. 41-47.

No description available.

Thesis (M.S.)--University of Wisconsin--Madison, 1967. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

Målet med denna undersökning är att minska energiförbrukningen vid framställning av gjutna detaljer i austenitiskt manganstål. Detta görs genom att undersöka om det är materialmässigt möjligt att göra förändringar som förkortar framställningsprocessen av de gjutna detaljerna medan snarlika materialegenskaper bibehålls. Den processförändring som undersöks är att slopa upplösningsbehandlingen under framställningsprocessen genom att istället släcka den gjutna detaljen direkt efter uppslag från gjutform. Konkret innebär detta att detaljen slås upp och släcks vid ett tidigare och tidsbestämt skede. Detta tillvägagångssätt kallas inom metallindustrin för direkt släckning och appliceras idag på andra legeringar och tillverkningsprocesser.För att undersöka om det är materialtekniskt möjligt att genomföra denna förändring i framställningsprocessen tas provkroppar fram. Dessa provkroppar är av en förbestämd geometri och tas fram under kontrollerade förutsättningar. Av totalt nio provkroppar släcks sex provkroppar direkt medan tre genomgår upplösningsbehandling där de senast nämnda används som referenser. Provkropparna undersöks med metoder så som mikroskopi och hårdhetsmätning för att bestämma de relevanta materialegenskaperna i provkropparna. Undersökningen visar antydningar på att det är möjligt att införa direkt släckning. Detta eftersom kornstorlek och karbidandelar inte skiljer sig nämnvärt mellan direkt släckta och värmebehandlade prover som har undersökts i denna studie. Men för ett mer definitivt fastställande behövs fortsatta studier. / The aim of this study is to reduce the energy consumed during manufacturing of parts in manganese steel. This is done by determining the possibility to make changes that shortens the production process of the castings while keeping the material properties similar. The process change that is studied is to see if it is possible to skip the heat treatment process by quenching directly after shake out of the casting. This means that the casted product needs to be shaken out and quenched at an earlier and more specific time. This process is known in the metal industry as direct quenching and is by the time of writing applied on different alloys and manufacturing processes.To determine the possibility to make the aforementioned changes to the casting process, taking the material properties into account, sample bodies are created. These sample bodies are of a predetermined geometry and are manufactured under controlled circumstances. From a total of nine sample bodies six are directly quenched and three are put through a heat treatment process, the later mentioned bodies are used as references. The sample bodies are studied with methods such as microscopy and hardness testing. In this study there are indications that it is possible to introduce direct quencing in the production of details made of austenitic manganese steel. This is because the difference in grain size and fraction of carbides is small between the direct quenched and the heat treated samples in this study. Nevertheless, further studies needs to be made to make a more definitive conclusion.

Medium-manganese steels (5-12 wt%) are candidates for third-generation advanced high strength steel (AHSS). Potential applications for these steels are centered around the automotive industry due to their combination of high tensile strength, high tensile ductility, and low alloying cost. Previous studies at VT have been primarily focused on the effect of chemistry on mechanical properties with only a minor emphasis on microstructure. This led to a detailed investigation into the effect of carbon content on the microstructure of Fe8Mn2AlSiC alloys. Six different chemistries with carbon contents of 0.30, 0.34, 0.39, 0.44, 0.49 and 0.52 wt% were produced at the Kroehling Advanced Materials Foundry. After a variety of heat treatments, the samples were characterized using x-ray diffraction (XRD), electron backscatter diffraction (EBSD), electron probe microanalysis (EPMA), optical microscopy, and hardness testing. This thesis will discuss how the microstructure and hardness of these medium manganese steels is influenced by the carbon content. / Master of Science / This research will be used to help design steel alloys that might one day be used in automotive applications. These steels need to be tough and ductile so they can absorb impact without fracturing. This is especially important in the event of a car crash, in which the steel needs to deform without breaking and causing injury to the driver or passenger. In order to achieve such qualities today, expensive elements are often added to the steel which increases cost. Medium manganese steels hope to alleviate this issue by providing a less expensive alternative with similar deformation properties. The properties of steel can be correlated with its microstructure, and more specifically, the different phases that make up the microstructure. These phases give rise to the macroscopic properties that make steel so useful. Microstructure can be controlled through chemistry and through thermomechanical processes. This research focuses on the effects of carbon and on heat treatments. This research is unique in that it keeps the chemistry consistent between all of the samples, making the effect of carbon or of the heat treatment identifiable. A total of six different carbon contents were tested over eight different heat treatment conditions. After creating the samples, the hardness was measured. The samples were then characterized to understand the microstructure. The results of this research showed there is a direct connection between heat treatment and chemistry to the microstructure.

Presence of inclusions in high manganese steel are a major concern in the steel making industry, since these particles affect the processing and properties of the steel. During the refining of high manganese steel in the ladle furnace, the types of inclusions present and their growth in the liquid steel, or during solidification of the steel, caused by the addition of manganese and other alloying elements are to be examined. This research developed a kinetic model for the presence and growth of inclusions in the liquid high manganese steel for the ladle metallurgy process. The diffusion of dissolved elements, and the seed of inclusions for the growth and consumption of inclusions, were both addressed in the model. The present model for inclusions was coupled to the updated kinetic model for slag-steel reactions in the ladle furnace for high manganese steel. The coupled model allows for verifying the process analysis plant data for the highest manganese concentration presently available in the steel industry. Finally, an analysis of the coupled kinetic model was performed to compare the effect of the different processing conditions, and the presence and growth of inclusions in the high manganese steel from the ladle metallurgy process. / Thesis / Master of Applied Science (MASc)

The automotive industry, has been innovating in the field of materials development in order to meet the demand for lower emissions, improved passenger safety and performance. Despite various attempts of introducing other lightweight materials (Al, Mg or polymers) in car manufacturing, steel has remained as the material of choice till date due to its excellent adaptability to systematic upgradation and optimization in its design and processing. One of the outcomes is the development of second generation high Mn TWin Induced Plasticity (TWIP) steels with excellent strength-ductility balance suitable for automotive applications. Cost effective high performance TWIP steel design is mostly based on its alloy design and advanced up and down stream processing methods (thermomechanical controlled processing (TMCP)) which can help achieve suitable microstructure to meet the property requirements. It has been observed that grain boundary migration (GBM) in austenite during high temperature TMCP stage dictates grain growth to control the final microstructure. This research work initially investigates the grain growth in Fe-30%Mn steel within a temperature regime of 1000-1200°C. Compared to conventional low Mn steel, austenite boundary mobility in Fe-30%Mn was found to be 1-2 orders of magnitude smaller. Atom probe tomography results showed no Mn segregation at austenite high angle grain boundaries (γ-HAGB) which rules out the effect of Mn solute drag on growth kinetics in Fe-30%Mn steels. Grain boundary character distribution (GBCD) study showed that the sample consists of two different population of grain boundaries. 50% of the grain boundaries are random HAGBs with high mobility. Remaining 50% are special in nature which introduce low mobility boundary/boundary segments in the global boundary network. The special boundaries are mostly in the form of Σ3 CSL boundaries or its variants like Σ9, Σ 27. These boundary/ boundary segments were introduced by the formation of annealing twins and their interactions with the random HAGBs. An attempt to investigate the effect of Mn on growth kinetics at 1200°C showed that Mn slows down growth kinetics up to 15 wt% predominantly by the formation of annealing twins. A qualitative study of the microstructures showed that as Mn concentration is increased from 1% to 15%, the annealing twin density increases resulting in Σ3 frequency to be 30%. The increased twinning frequency is attributed to the effect of Mn on lowering the stacking fault energy (SFE). Annealing twins, belonging to Σ3 CSL family, intersect the HAGBs resulting into twin induced boundary segments which possess very low mobility. In the light of this idea, slow grain growth in high Mn steel was attributed to the population of low mobility boundaries. The proposed ‘twin inhibited grain growth’ model clearly points to the low mobility boundary/boundary segments to be the rate controlling factor during grain growth in high Mn steels. The effect of carbon on grain growth in Fe-30%Mn steel showed that the presence of carbon makes the growth kinetics faster by a factor of 4 and 6 at 1200°C and 1100°C respectively. Although, atom probe tomography results indicated that in presence of carbon, Mn segregation takes place at γ-HAGBs in Fe-30%Mn steel, solute drag does not appear to play a role as it was seen that with increase in Mn content beyond 1%, the solute effect of Mn in slowing down HAGB migration becomes weak. Also, abovementioned higher mobility values are obtained from the growth kinetics of Fe-30Mn-0.5C. This once again highlights the fact that effect of Mn in slowing down grain growth is due to the low mobility of twin/twin related boundaries or boundary segments. Controlling grain growth has been commonly proposed to be accomplished through small addition (<0.1%) of microalloying elements (Nb, V and Ti) which can slow down GBM at high temperature by solute drag and at low temperature by precipitate pinning (Zener drag). This research work has also experimentally quantified the solute drag of Nb in a series of Fe- 30%Mn steels. Grain boundary mobility was estimated for various temperatures and niobium contents. An attempt was made to calculate the grain boundary mobility in presence of niobium using Cahn’s solute drag model. This calculated mobility, when used in the proposed ‘twin inhibited grain growth’ model, the predicted growth kinetics which showed very good fit with the experimentally obtained growth kinetics in case of Fe-30Mn-0.03Nb and Fe-30Mn-0.05Nb steels at 1100°C. The effect of Nb solute drag, thus captured using Cahn’s model, was shown to be slowing down only the HAGB migration in the microstructure, whilst the special boundary mobility was not affected by solute Nb. Another attempt was made through grain boundary engineering (GBE) to control grain growth in Fe-30Mn-0.5C steel. Using different TMCP schemes, GBCD was modified to produce maximum frequency of special boundary. Preliminary studies on grain growth of single step-grain boundary engineered samples did show a significant lowering of grain size compared to a no-GBE sample after grain growth. However, the effect of iterative GBE didn’t show any significant effect in controlling grain growth in spite of the fact that it increased Σ3 frequency to 64%. This probably indicates that the effect of GBE on grain growth by the formation of annealing twins/special low mobility boundaries is a complicated process which might involve twin/special boundary morphology, annihilation kinetics and formation of grain clusters in the microstructure other than the formation of immobile special triple junctions through the intersection of twins/special boundaries with the random HAGBs. / Thesis / Doctor of Philosophy (PhD)

Yes / Abstract Höganäs Astaloy CrM powder was used to prepare mixtures with 0.3-1.6 % carbon contents, both with and without 1 wt.% manganese additions. The carbon was added in three ways: as a graphite powder, as a solid CnHm hydrocarbon powder, and as a mixture of both. Green compacts were pressed at 300 - 800 MPa and sintered isothermally at temperatures in the range 1170 - 1295°C under flowing high purity nitrogen or nitrogen/hydrogen (9:1) atmosphere. Compressibility of the powder mixtures was investigated. Carbon loss occurring during sintering was carefully monitored. Sintering behaviour of numerous combinations of carbon content was investigated by dilatometry. For high carbon contents and high sintering temperatures, densification resulted from controlled generation of a liquid phase. Advantages of using solid hydrocarbon as a carbon donor and of Mn addition in powder metallurgy processing of steels are indicated.

Advanced High Strength Steel (AHSS) has become a popular steel grade among automakers to produce vehicle bodies. With improvements in strength and elongation, AHSS has evolved to its 2nd generation, including high manganese steel. Even though it has outstanding strength, the 2nd generation of AHSS faces some production problems due to its high alloying elements. With continual improvement, the 3rd generation of AHSS is currently in production. In this generation, the steel types still have a competitive strength and elongation like the 2nd generation of AHSS while having lower alloying element contents and production costs. One of the types of 3rd generation AHSS is medium manganese steel. Research related to the 2nd and 3rd generation of AHSS mainly focuses on their mechanical properties and microstructures. As there is a strong correlation between mechanical properties and inclusion characteristics, further investigation of the evolution of inclusions is still required. In this study, high-temperature experiments were conducted to investigate the effects of metal chemistry on the inclusion evolution in liquid steel. The concentrations of manganese, aluminum, and nitrogen were varied systematically. Two and three-dimensional analysis techniques were applied to study the number, composition, and size distribution of inclusions. Electrolysis extraction was used to identify the oxide, sulfide, and nitride inclusions, whereas an automated SEM with an ASPEX feature was used to detect a larger number of inclusions for better representation of the steel matrix. This work has established inclusion classification rules to distinguish nitride inclusions from oxide inclusions. To the best of the authors’ knowledge, this is the first discussion of this type of inclusion classification in the open literature. Based on the automated SEM (ASPEX Feature) analysis, the type of detected inclusions in medium and high manganese steels were Al2O3(pure), Al2O3-MnS, AlN(pure), AlN-MnS, AlON, AlON-MnS, and MnS inclusions. As the manganese content in the steel increased from 2% to 20%, the total amount of inclusions, especially AlN-contained inclusions, was raised. This phenomenon occurred due to the increase in nitrogen solubility with increased manganese content in the steel. The thermodynamic calculation also predicted that AlN inclusions would form when the steel was cooled or during the solidification. Moreover, AlN and MnS inclusions were observed to co-precipitate together. Similar to manganese, the increase in the aluminum content (Al = 0.5-6%) increased the total amount of inclusions in the steel, and the dominant inclusion type is AlN. AlN and Al2O3 inclusions can be heterogenous nucleation sites for MnS inclusions. Furthermore, Al2O3 inclusions also became heterogeneous nucleation sites for AlN inclusions. The experimental set-up was further modified to investigate the effect of nitrogen on the formation of inclusions in the medium manganese steels. The nitrogen was introduced by purging or injecting N2 gas into the steel system. Similar to the effect of manganese and aluminum, the increase in the nitrogen content also increased the total amount of inclusions. Once the nitrogen content in the steel exceeded the critical limit for the formation of AlN inclusions, AlN inclusions can be stable in the liquid steel. Moreover, regardless of the nitrogen content in the steel, AlN-MnS inclusions were formed in the slow-cooled steels. In terms of morphology, AlN inclusions can be formed of plate-like, needle, angular, agglomerate, or irregular shapes. Furthermore, a brief investigation on the addition of calcium and nitrogen to the medium manganese steels found that calcium led to the formation of other complex inclusions, such as CAx and CAS-Other inclusions. In the medium manganese steel composition in the present study, the number of CAS-Other inclusions was dominated by (Ca,Mn)S-Oxide inclusions after the addition of Ca. However, with time and after introducing N2 gas into the steel, the number of (Ca,Mn)S-Nitride inclusions also increased. The formation of (Ca,Mn)S-Nitride inclusions resulted from the co-precipitation of CaS, MnS, and AlN. The current work provides a better understanding of the formation mechanism of inclusions in medium manganese steels and high manganese steels. It presents complete information on the characteristics of inclusions, such as the number density, type, and morphology of inclusions. This knowledge can help steelmakers improve the steelmaking process to control the formation of inclusions, which can be problematic for the manufacture and performance of medium manganese steels and high manganese steels. / Dissertation / Doctor of Philosophy (PhD)