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Obtenção e caracterização de compósitos preparados com poliestireno expandido reciclado e pó de madeiraPoletto, Matheus 18 December 2009 (has links)
O presente trabalho tem como objetivo analisar as propriedades mecânicas, térmicas, termo dinâmico-mecânicas e morfológicas de compósitos preparados com poliestireno expandido reciclado e pó de madeira. Compósitos com diferentes teores de agente compatibilizante e diferentes teores de pó de madeira foram desenvolvidos em extrusora dupla rosca co-rotante e moldados por injeção. Os resultados obtidos demonstram que o compatibilizante com maior quantidade de anidrido maleico, menor massa molar ponderal média e utilizado em quantidade igual a 2% em massa gerou compósitos com melhores propriedades mecânicas. A melhora na adesão interfacial também foi observada através da análise termo dinâmico-mecânica. Verificou-se aumento no módulo de armazenamento, redução na altura do pico de tan δ e também menor valor do fator de adesão, associado com a maior adesão na região da interface. Para os compósitos desenvolvidos com diferentes teores de pó de madeira a densidade obtida foi semelhante a densidade teórica indicando estar de acordo com a regra das misturas. A utilização de compatibilizante reduziu o teor de vazios dos compósitos. Os resultados obtidos nos ensaios de flexão demonstraram que o módulo de flexão aumenta com a quantidade de carga e também se aproxima do comportamento previsto pela regra das misturas, entretanto os compósitos sem compatibilizante apresentaram redução na resistência a flexão com o aumento do teor de pó de madeira. No ensaio de impacto observou-se redução da resistência ao impacto com a adição de carga, porém os compósitos com compatibilizante apresentaram resultados superiores aos compósitos sem compatibilizante para todos os teores de pó de madeira. Observou-se aumento no módulo de armazenamento, no módulo de perda e também na efetividade do reforço com a adição de pó de madeira. Ocorreu redução na largura e também na altura do pico de tan δ conforme a adição das partículas de madeira, contudo os compósitos com compatibilizante apresentaram redução mais acentuada devido à melhora na adesão interfacial. O modelo teórico para predizer o comportamento do módulo de armazenamento demonstrou proximidade com os valores experimentais para baixos teores de carga. Para tan δ o modelo teórico se mostrou inadequado. As micrografias dos compósitos sem compatibilizante indicaram arrancamento e a presença de vazios entre o pó de madeira e a matriz, entretanto os compósitos com compatibilizante demonstraram maior recobrimento das partículas de madeira pela matriz. A estabilidade térmica dos compósitos com compatibilizante foi reduzida para todos os teores de pó de madeira quando comparada aos compósitos sem compatibilizante. / The present work aims to analyze the mechanical, thermal, dynamicalmechanical thermal properties and morphology of composites based on recycled polystyrene and wood flour. Composites with different types and levels of coupling agent and also with different levels of wood flour were developed in a co-rotating twin-screw extruder and injection molded. The results show that the coupling agent with higher amount of maleic anhydride, lower weight average molecular weight and used in to 2% by weight produced composites with better mechanical properties. The improvement in interfacial adhesion was also observed by dynamical-mechanical thermal analysis. An increase in the storage modulus, decrease in peak height and also lower value of adhesion factor, was observed due to the improved on interfacial adhesion. For the composites developed with different levels of wood flour density obtained was similar to theoretical density indicating that in accordance with the rule of mixtures. The use of coupling agent reduced the concentration of voids in the composites. The flexural modulus increases with the amount of wood flour and also approaches the behavior predicted by the rule of mixtures, however the composites without coupling agent showed reduction in flexural strength. The impact strength decreases with the addition of wood flour, but the composites with coupling agent showed better results than the composite without coupling agent for all levels of wood flour. There was an increase in the storage modulus, loss modulus and also the efficiency of filler with the addition of wood flour. There was a reduction in width and also in peak height of tan δ as the addition of wood particles, composite with coupling agent demonstrated greater reduction due to improved on interfacial adhesion. The theoretical model to predict the behavior of the storage modulus showed proximity with the experimental values for low levels of filler. Theoretical model for tan δ proved inadequate. The micrographs of composites without coupling agent indicated the presence of pulled-out traces and gaps between the wood flour and matrix, however the composites with coupling agent show the strong bonding and good wetting of the fillers by the matrix. The thermal stability of composites with coupling agent was reduced for all levels of wood flour when compared to composites without coupling agent.
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Ensaios de carregamento dinâmico em estacas no complexo de SuapeSilva, Thiago de Moraes 01 April 2011 (has links)
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Previous issue date: 2011-04-01 / This presented work analysis of the load capacity of the dynamic load test carried through in the props used in the construction of the Atlântico Sul Shipyard and Internal Wharf IV (Port of Suape - PE). The assayed piles are of the type continuos fly anger and pre cast concrete. Also the location of the piles and soundings are presented, characteristics, executive proceeding and instrumentation of the studied piles, as well as the compilation of the results found through the registers of monitoring of the piles. With the results of load capacity of cuttings obtained through and dynamic loading test surveys SPT (Stand penetration test), comparisons were made with the methods: Aoki and Velloso (1975) and Décourt (1996).
From the curves load x settlement generated for method CAPWAP of the props had been carried through attempts of verification of load capacity, through the intersection of the curve with the extrapolation of the straight line proposal for NBR 6122/1996, Method of Davisson
(1972), rupture load corresponds stresses to it for the method of Terzaghi (1942) and Method of De Beer (1967). Discussed in this work the influence of damping coefficient (J), the efficiency of the system of crimping and proposed an expression for the calculation of tension
in pile driving pre-shaped, from the back analysis of the expression of Broms and e analysis of the lateral attrition by means of the comparison between methods half-empiricists and established hypotheses. One concludes that the presented results of the load capacity in the
methods Aoki and Velloso (1975) and Décourt (1996) based in the soundings of reference of the assay in general does not demonstrate compatibility with the load capacity of the assay of the ECD; with regard to the curves load x it stresses, the methods and adopted hypotheses
indicate that the reached maximum shipment level in the assay, was not enough to mobilize the total load capacity of the props / Este trabalho apresenta a análise da capacidade de carga dos ensaios de carregamento dinâmico realizados nas estacas utilizadas na construção do Estaleiro Atlântico Sul e Cais
Interno IV (Porto de Suape PE). As estacas ensaiadas são do tipo hélice contínua e prémoldadas. Estão também apresentadas as locações das estacas, sondagens, características, processo executivo e instrumentação das estacas estudadas, bem como a compilação dos
resultados encontrados através dos registros de monitoração das estacas. Com os resultados de capacidade de carga das estacas obtidos através dos ensaios de carregamento dinâmico e sondagens SPT (Stand Penetration Test), foram realizadas comparações com os métodos: Aoki e Velloso (1975) e Décourt (1996). A partir das curvas carga x recalque das estacas, gerados pelos métodos CAPWAP e DLTWAVE foram realiza das tentativas de verificação de
capacidade de carga, através da interseção da curva com a extrapolação da reta proposta pela NBR 6122/2010, método de Davisson (1972), carga de ruptura corresponde ao recalque pelo método de Terzaghi (1942) e método de De Beer (1967). Discutiu-se também neste trabalho a
influência do coeficiente de amortecimento (J), a eficiência do sistema de cravação e se propôs uma expressão para o cálculo da tensão na cravação de estacas pré-moldadas, a partir da retro análise da expressão de Broms e análise do atrito lateral mediante a comparação entre métodos semi-empíricos e hipóteses estabelecidas. Conclui-se que os resultados apresentados da capacidade de carga nos métodos Aoki e Velloso (1975) e Décourt (1996) baseados nas
sondagens de referência do ensaio não demonstram em geral compatibilidade com a capacidade de carga do ensaio do ECD; com relação às curvas carga x recalque, os métodos e
hipóteses adotados indicam que o nível de carregamento máximo atingido no ensaio, não foi suficiente para mobilizar a capacidade de carga total das estacas
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Konstrukce 3D tiskárny pro tisk materiálu s příměsí karbonových vláken / Desigm of the 3D printer for print material with carbon fibersChaloupka, Matyáš January 2017 (has links)
The presented thesis deals with FDM 3D printing method with emphasis on printing carbon fiber reinforced plastic (CFRP). The aim of this thesis is to engineer the FDM 3D printer designed for printing CFRP and to execute the experiment targeted on comparison of CFRP material properties against commonly used 3D printing plastics such as PLA, ABS, PET etc. The device designed in this work has printing area of 200 x 200 mm with maximum height of the object of 200 mm. The printing bed is heated and the whole device is enclosed. There are two kinds of experiments carried out within the thesis. The first one is focused on tensile strength and Young's modulus of selected materials, while the second experiment compares Charpy's impact strength of specimen with different infill percentage on two selected materials, PET and PET filled with chopped carbon fiber.
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Biocompatibilidade e potencial bioativo de cimentos endodônticos com silicato de cálcio /Hoshino, Roberto Almela. January 2020 (has links)
Orientador: Paulo Sérgio Cerri / Resumo: OBJETIVO: Avaliar a reação tecidual e bioatividade provocada por NeoMTA Plus e MTA Fillapex em subcutâneo de ratos. MATERIAL E MÉTODOS: Para este estudo foram utilizados 60 ratos Holtzman, sendo distribuídos aleatoriamente em três grupos (n= 20): NeoMTA Plus (Avalon Biomed Inc. Bradenton, FL, EUA), MTA Fillapex (Angelus Ciência e Tecnologia, Londrina - PR – Brasil) e Controle (tubos de polietileno vazios). Para avaliar a reação tecidual provocada pelos materiais, foram implantados tubos de polietileno preenchidos com os cimentos endodônticos no tecido conjuntivo do subcutâneo na região dorsal dos ratos. No grupo controle (GC), tubos de polietileno vazios foram implantados. Após os períodos de 7, 15, 30 e 60 dias, cinco animais de cada grupo por período foram eutanásiados e os tubos implantados com os tecidos adjacentes foram removidos e submetidos ao processamento para inclusão em parafina. A partir dos cortes corados com HE, foram realizadas análises morfológicas, mensuração da espessura da cápsula e densidade numérica de células inflamatórias. Os cortes foram também submetidos à reação imuno-histoquímica para detecção de interleucina-6 (IL-6), uma citocina pró-inflamatória, e o número de células imunopositivas foi computado. A quantidade de colágeno nas cápsulas foi estimada a partir de cortes submetidos ao método do picrosirius-red e analisados sob luz polarizada. A bioatividade dos cimentos endodônticos foi avaliada por meio da reação histoquímica von Kossa e a análise so... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: To evaluate the tissue reaction and bioactivity caused by NeoMTA Plus and MTA Fillapex in connective tissue of subcutaneous. MATERIAL AND METHODS: For this study, 60 Holtzman male rats were used, which were randomly distributed in three groups (n = 20): NeoMTA Plus (Avalon Biomed Inc. Bradenton, FL, USA), MTA Fillapex (Angelus Ciência e Tecnologia, Londrina - PR - Brazil) and Control (empty polyethylene tubes). To verify the tissue reaction caused by root canal sealers, the polyethylene tubes were filled with endodontic sealers and were implanted into dorsal subcutaneous tissues. In the control group (CG), empty polyethylene tubes were implanted. After 7, 15, 30 and 60 days, five animals from each group per period were sacrificed and implants surrounded by tissues were removed and processed for paraffin-embedding. From HE-stained sections, the morphological analysis, measurement of capsule thickness and numerical density of inflammatory cells were carried out. Sections were also subjected to immunohistochemical reaction to detect interleukin-6, a pro-inflammatory cytokine, and the number of immunopositive cells was computed. The amount of collagen in the capsules was measured in the sections stained with picrosirius-red method and analyzed under polarized light. The bioactivity of endodontic sealers was evaluated by von Kossa histochemical reaction and the analysis of under polarized light. The data were submitted to two-way ANOVA and post-hoc Tukey test (p < 0.05). RESULTS: ... (Complete abstract click electronic access below) / Doutor
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The Experimental and Analytical Characterization of the Macromechanical Response for Triaxial Braided Composite MaterialsLittell, Justin 17 December 2008 (has links)
No description available.
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Fracture resistance of porcelain-veneered gold-alloy and zirconia molar crownsNilsson, Eddie, Drazic, Marko January 2013 (has links)
AbstraktSyfte:Studiens syfte var att utreda maxlasttoleransen mellan yttria-stabiliserad zirkoniumdioxid- (Y-TZP) och metallkeramiska- (MC) molarkronor med en ny design på in vitro belastningsformen. En stålkula användes för att utöva last på kusparna istället för i fissuren för att framställa en sprickbildning liknande den som ses kliniskt. Materialochmetod:26 kronor tillverkades, varav 13 högädla MC och 13presintrade Y-TZP. 7 av MC göts av 50% tidigare icke-gjuten och 50% omgjuten legering medan de kvarvarande 6 göts av 100% tidigare icke gjuten legering. Kronorna täcktes av ett fasadporslinoch cementerades på stansar av ett resinmaterial. Av de 26 kronorna genomgick 24 förbelastingstester och belastades slutligen till fraktur. Resultat: MC klarade signifikant högre belastningar än Y-TZP, P>0,001. Frakturerna skiljde sig också grupperna emellan där MC-gruppen uppvisade enbart adhesiva frakturer av fasadporslinet under det att Y-TZP-gruppen uppvisade kohesiva brott i ytporslinet undantaget en Y-TZP-krona som uppvisade total fraktur. Ingen signifikant skillnad kunde ses mellan MC-kronor bestående av enbart tidigare icke gjuten legering och MC-kronor med 50% omgjuten legering, P=0,370. Konklusion: MC-kronor klararsignifikant högre belastningar än Y-TZP-kronor och testet genererar kliniskt relevanta frakturer av ytporslinet snarare än totala frakturer. Frakturbeteendet skiljer sig mellan MC och Y-TZP där MC uppvisar endast adhesiva fraktureroch Y-TZP främst kohesiva brott av ytporslinet.
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Electrical characterization of carbon black filled rubberParris, Donald R. January 1986 (has links)
DC resistance and AC conductance and capacitance have been measured under various conditions in an effort to electrically characterize and make electrical-mechanical correlations for 15 carbon black filled rubber samples.
Resistance, conductance and capacitance have been monitored as functions of uniaxial compressive stress, time, temperature, and mechanical and thermal history. Capacitance and conductance have also been monitored as functions of frequency under various degrees of compressive loading and before and after specific heat treatments.
A direct relationship has been found between sample • conductance and capacitance under any thermal and/or mechanical condition. This is in agreement with previous theories of conduction network formation and percolation. Various conduction mechanisms have been enumerated and an equivalent circuit of a network of lumped R-C "microelements'' has been qualitatively described. Stress, relaxation, frequency, and temperature dependences of the macroscopic parameters measured ( conductivity and capacitance) are discussed in terms of this model. / M.S.
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Shear and extensional rheology of hydroxypropyl cellulose melt using capillary rheometryParadkar, Anant R, Kelly, Adrian L., Coates, Philip D., York, Peter January 2009 (has links)
No / With increasing interest in hot melt extrusion for preparing polymer-drug systems, knowledge of the shear and extensional rheology of polymers is required for the formulation and process design. Shear and extensional rheology of three commercial grades of hydroxypropyl cellulose (HPC) was examined at 140, 145 and 150 degrees C using twin bore capillary rheometry at range of processing rates. The power law model fitted for shear flow behaviour up to shear strain rates of approximately 1000s(-1), above which measured shear viscosities deviated from the power law and surface instabilities were observed in the extrudate, particularly for higher molecular weight grades. Shear thinning index was found to be relatively independent of temperature and molecular weight, whilst the consistency index, indicative of zero shear viscosity increased exponentially with increase in molecular weight. Extensional viscosity of all grades studied was found to decrease with increasing temperature and increasing processing rate. Foaming of the extrudate occurred especially at low temperatures and with the high molecular weight grade. An understanding of the relationships between shear and extensional flows with temperature, processing rate and molecular weight is a useful tool for process design; optimisation and troubleshooting of Hot melt extrusion (HME) of pharmaceutical formulations.
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hiResilient response and performance of bitumen stabilized materials with foam incorporating reclaimed asphaltDal Ben, Matteo 04 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: The increased use of reclaimed asphalt (RA) in Bitumen Stabilised Materials (BSMs), shortcomings in the existing design guidelines and manuals and ongoing developments in the concepts and understanding of these materials require further research into the fundamental properties and behaviour of BSMs. The state-of-the-art of foamed bitumen techniques is reviewed in the literature study. Current best practices in the design of BSMs and pavements incorporating such materials are also included in this literature study. Shortcomings and areas for further improvement of the design practice have been identified. With new environmental legislation, the importance of BSM technology including RA as an environmentally-friendlier and more sustainable construction technique is set to increase in the coming years.
Changes in the behaviour of materials and failure mechanisms of BSM mixes are long-term phenomena. This implies that the study of the physico-chemical and mechanical properties of the mixes with increasing amount of RA is vital. Therefore, fundamental understandings of moisture damage and thermo-physical characteristics, which are related to material properties, are required. The main objective of this study is to advance BSM technology by assessing the influence of the selected materials on durability behaviour, temperature distribution and long-term performance in all phases of application (i.e. mix design, construction, and in-service condition).
This study begins with a comprehensive literature review of research dealing with the interactions between RA and mineral aggregates. The properties of RA and mineral aggregates were reviewed. This was followed by a review into the mechanical properties of BSM-foam mixes with high percentage of RA and its durability performance. Factors influencing the temperature gradient of BSMs were then identified. Achieving a better understanding of the fundamental performance properties and temperature influence on the behaviour of BSMs with high percentage of RA is one of the key factors of this research, with a view to using the extended knowledge for improvements to current mix design and structural design practices. Finally, the fundamental theories on thermo-conductivity and the mechanical properties of the BSM were used to create a relationship between temperature and mechanical properties in a pavement section. A laboratory testing programme was set up to study the properties and behaviour of BSMs and to establish links with the compositional factors, i.e. the type of binder used, the percentage of RA in the mix and the addition of a small amount of cement as active filler. BSMs were blended in three different proportions of RA and good quality crushed stone materials: 100% RA (with 2 % bitumen content), 50% RA and 50% G2 Hornfels crushed stone (with 2.1% bitumen content) and 100% G2 (with 2.3 % bitumen content). Tri-axial testing was carried out to determine shear parameters, resilient modulus and permanent deformation behaviour, while brushing testing was carried out to determine the possible durability performance of the BSMs. The mixture durability in terms of moisture damage was investigated.
Temperature data were collected and a model to accurately simulate the temperature distribution in the BSMs was identified and proposed for further investigation and validation. It was found from the laboratory temperature data collected in this study that the temperature gradient varied according to the depth of the BSMs. A considerable part of the efforts of this study were dedicated to characterise and model the temperature distribution in a pavement section, taking into account the mechanical properties and performance of the BSMs at different temperature layers.
The study provides an insight into fundamental mechanical performance, material durability properties, and the thermal capacity and conductivity of the BSM-foam mixes with high percentage of RA. This will assist in improving the current procedure for selection, combining and formulation of the mix matrices for BSMs. In addition, the study provides guidelines that will enable practitioners to confidently understand the relationship between temperature gradient and mechanical behaviours of BSM-foam pavement section. The specific durability-related issues addressed in this study are substance for future research. / AFRIKAANSE OPSOMMING: Die toenemende gebruik van herwonne asfalt (Engels: reclaimed asphalt (RA)) in bitumen gestabiliseerde materiaal (Engels: Bitumen Stabilised Materials (BSMs)), tekortkominge in die bestaande ontwerpriglyne- en handleidings en deurlopende verbeteringe in die konsepte en begrip van hierdie material vereis verdere navorsing oor die fundamentele eienskappe en gedrag van BSM. In die literatuurstudie word die huidige stand van kennis van die ontwerp van skuimbitumentegnieke ondersoek. Die literatuurstudie dek ook die huidige beste praktyke in die ontwerp van BSM en plaveisels wat hierdie materiale insluit. Tekortkominge en areas van verdere verbetering in die ontwerppraktyke is geïdentifiseer. Onlangse omgewingswetgewing verhoog die belangrikheid van BSM tegnologie, insluitend RA, as ‘n meer omgewingsvriendelike en volhoubare konstruksie-tegniek. Hierdie faktor sal in die toekoms al hoe belangriker word.
Die verandering in die gedrag van materiaal en die falingsmeganismes van BSM mengsels is langtermynverskynsels. Dit impliseer dat die studie van die fisio-chemiese en meganiese eienskappe van mengsels met toenemende verhoudings van RA van kardinale belang is’n Fundamentele begrip van die vogskade en temo-fisiese eienskappe, wat verwant is aan die materiale se eienskappe, word vereis. Die primêre doelwit van die studie is die bevordering van BSM tegnologie deur die invloed van die geselekteerde materiale op duursaamheid, temperatuurverspreiding en langtermyn gedrag in al die fases van toepassing (mengselontwerp, konstruksie en in-dienstoestand) te bepaal.
Die verhandeling begin met ‘n omvattende literatuuroorsig van navorsing oor die interaksie tussen RA en mineraalaggregate. Die eienskappe van RA en die mineraalaggregate word bespreek. Dit word gevolg deur ‘n oorsig van die meganiese eienskappe van die BSM-skuimbitumenmengsels met ‘n hoë persentasie RA en die duursaamheidgedrag daarvan. Faktore wat die temperatuurgradient van BSM beïnvloed word dan aangetoon.
‘n Beter begrip van die fundamentele gedragseienskappe en die invloed van temperatuur op die gedrag van BSM met ‘n hoë persentasie RA is een van die sleutelfaktore van hierdie navorsing. Dit het ten doel om die uitgebreide kennis te gebruik om huidige mengselontwerp en strukturele ontwerppraktyke te verbeter. Laastens is die fundamentele teorie van termogeleiding en die meganiese eienskappe van BSM gebruik om ‘n verhouding tussen temperature en meganiese eienskappe in ‘n plaveiselsnit te ontwikkel. ‘n Laboratoriumtoetsprogram is opgestel om die eienskappe en gedrag van BSM te bestudeer en om verwantskappe tussen samestellende faktore soos die tipe bindmiddel gebruik, die persentasie RA in die mengsel en die toediening van klein hoeveelhede sement as aktiewe vuller te bepaal. BSM is in drie verskillende verhoudings van RA en goeie gehalte gebreekte klipmateriaal vermeng: 100% RA met 2 % bitumen, 50% RA en 50 % G2 Hornfels gebreekte klip met 2.1 % bitumen en 100% G2 met 2.3 % bitumen. Drie-assige druktoetse is gebruik om skuifsterkteparameters, elastiese modulus en permanente vervormingsgedrag te bepaal. Borseltoetse is gebruik om die duursaamheidgedrag van BSM te bepaal. Die mengsels se duursaamheid is ook in terme van vogskade ondersoek.
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Flexibility and performance properties of bitumen stabilised materialsNwando, Tiyon Achille 04 1900 (has links)
Thesis (MScEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: This research investigates the flexibility and the performance properties of bitumen stabilised
materials under the influence of mix variables. The laboratory testing consisted of two main phases.
During the first phase (mix design), the strength and the flexibility of the mixes were assessed
through ITS (Indirect Tensile Strength), UCS (Unconfined Compressive Strength), displacement at
break, strain at break and fracture energy. The second phase consisted of a series of triaxial tests
done to assess the performance properties (shear strength: cohesion and angle of internal friction; and
stiffness: resilient modulus) of the mixes.
The mineral aggregates used in this study were milled from different locations of the R35, near
Bethal. This was a blend of granular material (dolerite, from various locations of the existing base
and subbase layer of the R35) and Reclaimed Asphalt (RA) milled from the existing surfacing.
During the mix design phase, two types of bituminous binders were used (bitumen emulsion and
foamed bitumen) at bitumen content ranges of 2%, 2.4% and 2.8% each. Two types of active filler
were used separately and in combination at a proportion of 1% and 2%. Finally, specimens were
tested in wet and dry conditions for each mix combination. During the triaxial testing phase, only the
optimum bitumen content of 2.4% was used, both for bitumen emulsion and foamed bitumen, with
only cement as active filler in a proportion 1% and 2%. The specimens were tested at different
ranges of densities and saturation levels. The flexibility of the mix was assessed through the fracture energy, the strain and the displacement at
break parameters. An analysis of variance (ANOVA) was conducted on the data to assess the
significance of experimental variables on this property. This property was found to be very sensitive
to bitumen and cement content added to the mix. When assessing the combined effect and the
significance of the variables on the flexibility of the mixes, it was found that fracture energy is
mostly influenced by the cement content, followed by the bitumen content, then the type of treatment
and finally the testing condition. However, the level of significance was not in the same order for the
other two parameters (displacement and strain at break). It was also found that the combined effect
of some independent variables (cement content + testing condition, type of treatment + cement
content + bitumen content) had a significant effect on the fracture energy and the strain at break
respectively.
From the ITS and UCS tests, an increase in strength was noticed with the increase of cement content.
On the other hand, the increase in bitumen content led to a decrease in strength of the material. The
statistical analysis on the ITS and UCS values show that the independent variable with the most significant effect on the ITS is the cement content, followed by the testing conditions, then the
bitumen content and finally the type of treatment. The combined effect of cement content + bitumen
content was found to be significant both for ITS and UCS.
In the second phase triaxial tests were performed in order to evaluate the performance properties of
the mixes. It was found that the increase of the active filler content significantly improves the shear
strength of the material. It was also found that at a fixed cement content, specimens tested at low
density and/or high level of saturation show low shear strength. The Mr-θ model was used to model
the resilient modulus of the mixes and the model coefficients used to evaluate the effect of
experimental variables on the resilient modulus. It was found that the resilient modulus of the mixes
increases as the bulk stress increases. This confirms the stress dependent behaviour of bitumen
stabilised materials. The analysis show that increasing the percentage of active fillers content results
in a significant increase in the resilient modulus values. An increase in relative density also resulted
in an increase in the resilient modulus of the mixes, while the opposite effect was observed with the
increased of the saturation level.
Besides the engineering properties and the mechanical test parameters, other parameters such as the
Tensile Strength Ratio (TSR) was calculated in order to evaluate the moisture sensitivity of the
mixes. Weakening due to moisture was found to be more predominant in the mixes with less active
filler. In addition, bitumen emulsion mixes were found to have a better resistance to moisture
weakening effects compared to foamed bitumen. In addition, a comparison between the rapid curing
and the accelerated curing was done. Higher ITS and UCS results were obtained for specimens cured
using long term curing compared to specimens cured using the accelerated curing method. In conclusion, flexibility is an important property of bitumen road construction material (bitumen
stabilised material include) however, it is not an easy property to measure. Although,
displacement/strain at break and fracture energy from ITS and UCS were able to give us some
indications on the main factors governing the flexibility of bitumen stabilised materials (the bitumen
and active filler content), more accurate and adequate tests are required to evaluate the parameter. / AFRIKAANSE OPSOMMING: Die buigsaamheid en gedragseienskappe van bitumen gestabiliseerde materiale was getoets om
sodoende die invloed van verskeie mengselveranderlikes te evalueer. Die ondersoek het uit twee
fases bestaan. Tydens die eerste fase (mengfase) is die sterkte en buigsaamheid deur middel van
indirekte treksterkte toetse (ITS), onbegrensde druksterkte toetse (UCS), verplasing – en vervorming
by breekpunt sowel as breek-energie toetse gedoen en ondersoek. Die tweede fase het bestaan uit ʼn
reeks drie-assige triaksiaal toetse. Triaksiaaltoetse is uitgevoer om die gedragseienskappe soos die
skuifsterkte, kohesie, hoek van interne wrywing, styfheid en weerstand modulus te ondersoek.
Die gemaalde mineraal-aggregaat wat in hierdie ondersoek gebruik is, was verkry op verskeie areas
van die R35, geleë naby Bethal. Die materiaal is ʼn mengsel van granulêre materiaal (van die
bestaande kroonlaag en stutlaag van die pad) en herwonne asfalt (RA). Tydens die mengontwerp fase
is twee tipes bitumen gebruik naamlik bitumenemulsie en skuimbitumen in hoeveelhede van 2%,
2.4% en 2.8%. Twee tipes aktiewe vulstof (hoeveelhede van onderskeidelik 1% en 2%) was saam
met elk van die verskeie bitumen-hoeveelhede gebruik. Proefstukke van elk van hierdie mengsel
kombinasies is onder beide nat en droë kondisies getoets. Tydens die tweede fase, is slegs die
optimum binder inhoud (2.4%) gebruik vir beide emulsie- en skuimbitumen, gekombineer met 1%
en 2% aktiewe vulstof. Proefstukke was getoets by ʼn reeks van verskillende digthede en
versadigingvlakke. Die buigsaamheid was ondersoek deur middel van breek-energie, vervorming en die verplasing by
breekpunt. ʼn Analise van variasie (ANOVA) is uitgevoer op die toetsdata om sodoende die te
evalueer of die veranderlikes beduidend is ten opsigte van buigsaamheid. Daar is gevind dat die
buigsaamheideienskap sensitief is vir beide bitumen en sement inhoud. Met assessering van die
gekombineerde effek en betekenis van die veranderlikes op die buigsaamheid van die mengsels, is
daar gevind dat die hoogste beduidende veranderlike t.o.v breek-energie die sement inhoud is, gevolg
deur die bitumeninhoud, tipe behandeling en laastens die toetskondisie. Die orde van belangrikheid
verskil vir die ander twee parameters (verplasing en vervorming by breekpunt). Daar is ook gevind
dat die gekombineerde effek van sommige veranderlikes (sement inhoud en toets kondisie, tipe
behandeling en sement inhoud tesame met bitumen inhoud) ook beduidend was t.o.v breek-energie
en vervorming by breekpunt.
Vanuit die ITS en UCS toetse was daar ʼn toename in sterkte waargeneem soos die sementinhoud
toeneem. Aan die anderkant, het ʼn toename in bitumeninhoud ‘n afname in sterkte veroorsaak. Die
statistiese analise van ITS en UCS resultate, toon dat die grootste beduidende onafhanklike t.o.v ITS waardes ook die sement inhoud was, gevolg deur toets kondisies die grootste effek, bitumen inhoud
en die tipe behandeling. Die gekombineerde effek van sementinhoud en bitumeninhoud, was
betekenisvol vir beide ITS en UCS.
Drie-assige triaksiaaltoetse was uitgevoer om die gedragseienskappe van die mengsels te evalueer.
Daar is gevind dat die toename in sement inhoud, die skuif sterkte van die materiaal grootliks
verbeter. By ʼn konstante sementinhoud, wys toetsresultate van proefstukke wat getoets is by lae
digthede en hoë vlakke van versadiging, lae skuif sterkte.
Die Mr – θ model was gebruik om die veerkragsmodulus van die mengsels te moduleer en die
modelkoëffisiënte is gebruik om die effek van eksperimentele veranderlikes op die weerstand
modulus te evalueer. Met toename in die omhullende spanning is ‘n toename in die
veerkragsmodulus waargeneem, wat bevestig dat die gedrag van bitumen gestabiliseerde materiale
spannings afhanklik is. ʼn Toename in die sement en relatiewe digtheid het ʼn merkwaardige toename
in die veerkragsmodulus tot gevolg gehad, terwyl die teenoorgestelde waargeneem is met toename in
versadigingsvlakke.
Buiten die ingenieurseienskap en meganiese toetsfaktore, is ander faktore (soos die trekspanning
verhouding) bereken om die vogsensitiwiteit van die mengsels te evalueer. Mengsels met laer sement
inhoud het groter verswakking ervaar met blootstelling aan water. Bitumenemulsie proefstukke toon
beter weerstand teen water as skuimbitumen. Vergelyking tussen versnelde en korttermyn
nabehandelingsprosedure van proefstukke, toon hoër ITS en UCS waardes vir die versnelde
nabehandelingsprosedure prosedure. Buigsaamheid is ‘n belangrike eienskap van bitumen in padkonstruksie materiale (insluitend bitumen
gestabiliseerde materiale), maar word moeilik gemeet. Alhoewel verplasing/vervorming by
breekpunt en breek energie, bepaal vanaf ITS en UCS, ‘n indikasie toon van die hooffaktore (binder
en sement) wat buigsaamheid van bitumen gestabiliseerde materiaal beïnvloed, word meer akkurate
toetse benodig om die eienskap te ondersoek.
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