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In a high competitive market, the development of new alloys, new applications, price pressure and increases in product forces quality wire manufacturers to ask for increased mechanical characteristics without losing conductivity. As a particular example, development of new copper alloys such as CuZr, CuSn, CuMg and CuAg have been developed for automotive cables. Continuous extrusion is currently the most prevalent manufacturing technology in terms of chemical composition, mechanical properties and electrical properties, resulting in the production of high quality rods. However, continuous casting has good potential to also be adapted to the mass production of various copper alloy wires. Comparison of the continuous casting process to other thermal methods such as continuous extrusion highlighted that, in general, the mechanical properties of continuous cast materials are lower than that of material from thermomechanical methods. However, continuously cast alloys rods are cheap to produce and simple to manufacture. So, the key aims of this research were (a) to increase the understanding of the solidification behaviour of some industrially important continuously cast non-ferrous alloys, (b) to define an increased range of alloys and downstream processing techniques which could be performed using continuous casting technology, (c) to determine improved continuous casting process validation capabilities and (d) to define new capabilities in terms of casting equipment. The majority of this PhD thesis was focused on improving the current continuous casting technologies and development of casting capability of a range of copper and non-copper alloys. The analysis in this PhD thesis illustrated that the metallurgical and mechanical properties of components mainly produced by continuous casting are acceptable, and that this method could be a replacement production method for materials such as lead alloys and various copper alloy rod, e.g. CuMg and CuAg. However, in the case of Deoxidized High Phosphorus (DHP) copper tubes, the performance of the as-cast material was significantly lower than that of from extrusion or planetary rolling process. This PhD thesis also makes comment on the parameters controlling the solidification process in order to improve the quality of as cast alloys rods/tubes. Using specific casting parameters, a significant difference based on tensile strength and elongation percentage has been illustrated, and it was found that these parameters could improve the mechanical properties of continuously cast copper rods and tubes. This significant difference is as a result only of the change in casting parameters, with no difference in the chemical composition of the material, or the general method of production. These parameters were (1) water flow rate, (2) casting speed, (3) pull distance, (4) melt temperature, (5) cleanout cycle, (6) continuous casting direction and (7) super-cooler size. The new knowledge created and understanding gained during the course of this research improved the company’s capability in the marketplace, enabling it to supply equipment with improved competitive capabilities and the potential to enter new markets, leading to sales growth in existing sectors and significant longer-term growth into new technically challenging application areas.

Riser sleeve thermophysical properties for simulation are developed using an inverse modeling technique. Casting experiments using riser sleeves are performed in order to measure temperatures in the liquid steel, the riser sleeve, and the sand mold. Simulations are created and designed to replicate the casting experiments. Riser sleeve material thermophysical properties are iteratively modified until agreement is achieved between the simulation and the measured data. Analyses of sleeve material performance are carried out using the developed thermophysical properties. The modulus extension factor (MEF) is used to quantify sleeve performance and is determined for all riser sleeve materials studied here. Values are found to range from 1.07 to 1.27. A sleeve material's effects on casting yield are shown to depend only on the MEF and therefore a sleeve's exothermic or insulating properties serve only to increase the overall quality of the sleeve, expressed by the MEF, and do not independently affect the casting yield at any casting size studied here. The use of riser sleeves is shown to increase the maximum yield up to 40% for chunky castings, however increases of only 8% are observed for very rangy castings. Riser sleeve thickness is shown to be extremely influential on casting yield. Scaling the sleeve thickness by the riser diameter shows that, for a typical sleeve, an optimum riser sleeve thickness is 0.2 times the riser diameter for chunky castings. A scaled sleeve thickness of 0.1 is found to be an optimum sleeve thickness for very rangy castings. Below a scaled sleeve thickness of 0.1 sleeve performance is found to be highly sub-optimal.

Published Article / In this paper the time and cost parameters of tooling manufacturing by metal casting in rapid prototyping sand moulds are assessed and comparison is made with alternative tool making processes such as computer numerical control machining and investment casting (Paris Process). To that end two case studies obtained from local companies were carried out. The tool manufacturing was conducted according to a five steps process chain referred to as Rapid Casting for Tooling (RCT). These steps include CAD modelling, casting simulation, rapid prototyping, metal casting and finishing operations. In particular the Rapid Prototyping (RP) step for producing the sand moulds was achieved with the aid of an EOSINT S 550 Laser Sintering machine and a Spectrum 510 Three Dimensional Printer. The results indicate that RP is the rate determining step and cost driver of the proposed tooling manufacturing technique. In addition it was found that this tool making process is faster but more expensive than machining and investment casting.

"Tautologically, castability is a critical requirement in any casting process. The two most important factors impacting castability are the susceptibility of a metal to hot tearing and the degree of casting fluidity a material possesses. This work concerns itself with fluidity of molten metal. Since experimental investigations into casting fluidity began, researchers have sought to maximize fluidity through superheat, mold temperature, alloy chemistry, melt cleanliness, and mold design. Researchers who have examined the published results in the field have remarked on the difficulty of making quantitative comparisons and drawing conclusions from the data. Ragone developed a horizontal vacuum fluidity apparatus and an analytical expression for fluid length to help resolve these issues. This was expanded on by Flemings et al. Still, the comparison of results is complicated by experimental uncertainties and a plurality of experimental procedures. This work seeks to resolve these issues through an analysis of experimental uncertainties present in existing fluidity tests and the development of an improved test and procedure which is very precise, accurate, and reliable. Certain existing tests and software packages have been shown to be unsuitable for quantitative fluidity measurement. Expressions for experimental uncertainty in fluidity testing have been derived. The capability to predict variations in fluidity as a function of alloy chemistry and other variables whose range of values are intrinsic to the economics of the process will help to more accurately determine the superheat needed for successful castings and will in turn lead to a decrease in scrap rates. This will enable metal casters to more reliably cast thin sections, and to reduce cycle time or scrap rate to achieve productivity goals. Superheat was shown to remain the dominant factor in fluidity, but the test allowed investigation of alloy modifications within an alloy specification in this alloy system. Factors known to have negative effects on structural properties were found often to have neutral or positive impacts on fluidity. A deep understanding of variations in fluidity measurements is the next necessary step in a century-long quest to understand how best to make metal castings through the use of fluidity experiments."

Among all casting defects, shrinkage porosities could significantly reduce the strength of metal parts. As several critical components in aerospace and automotive industries are manufactured through casting processes, ensuring these parts are free of defects and are structurally sound is an important issue. This study investigates the formation of shrinkage-related defects in alloy solidification. To have a better understanding about the defect formation mechanisms, three sets of experimental studies were performed. In the first experiment, a real-time video radiography technique is used for the observation of pore nucleation and growth in a wedge-shaped A356 aluminum casting. An image-processing technique is developed to quantify the amount of through-thickness porosity observed in the real-time radiographic video. Experimental results reveal that the formation of shrinkage porosity in castings has two stages: 1-surface sink formation and 2- internal porosity evolution. The transition from surface sink to internal porosity is defined by a critical coherency limit of . In the second and third experimental sets, two Manganese-Steel (Mn-Steel) castings with different geometries are selected. Several thermocouples are placed at different locations in the sand molds and castings to capture the cooling of different parts during solidification. At the end of solidification, castings are sectioned to observe the porosity distributions on the cut surfaces. To develop alloys’ thermo-physical properties, MAGMAsoft (a casting simulation software package) is used for the thermal simulations. To assure that the thermal simulations are accurate, the properties are adjusted to get a good agreement between simulated and measured temperatures by thermocouples. Based on the knowledge obtained from the experimental observations, a mathematical model is developed for the prediction of shrinkage porosity in castings. The model, called “advanced feeding model”, includes 3D multi-phase continuity, momentum and pore growth rate equations which inputs the material properties and transient temperature fields, and outputs the feeding velocity, liquid pressure and porosity distributions in castings. To solve the model equations, a computational code with a finite-volume approach is developed for the flow calculations. To validate the model, predicted results are compared with the experimental data. The comparison results show that the advanced feeding model can accurately predict the occurrence of shrinkage porosity defects in metal castings. Finally, the model is optimized by performing several parametric studies on the model variables.

Underwater excavations of a Late Bronze Age shipwreck at Uluburun, Turkey recovered a combined 475 oxhide and plano-convex discoid copper ingots. While the hoard of ingots excavated at Uluburun brings the total number of copper ingots from the Late Bronze Age to over 1000, interestingly, only one ingot mold from the that period has been identified. Scholars have speculated over the means behind the creation of these ingots for decades, but with a relative absence of archaeological molds the most promising method of reaching any conclusions as to the types of molds used in antiquity seems to be experimentation. Experimental archaeology, has, in recent years been responsible for many breakthroughs in how the past is viewed. In the face of an overwhelming disparity of copper ingot molds from the Late Bronze Age, trials designed around testing different mold materials and casting techniques have the potential to determine, with relative certainty, how copper ingots were cast over 3000 years ago. This thesis examines the possible materials used to create copper ingot molds through a study of their prevalence in antiquity and also details experiments in which these materials were used, in concert with different casting techniques, to create copper ingots. The results of these experiments are combined with analyses of the Uluburun ingots in an effort to bring some closure to the debate surrounding copper ingot molds in the Late Bronze Age.

In this study, by considering different mechanical properties such as wear resistance and toughness of two different metal alloys in design and production stages, bi-metal casting technique was used for producing composite material which will be a solution for the cracking and wear problem in coal crushing hammer heads. The failure analysis of the classical hammer heads which are made from Hadfield steels (austenitic steel) showed that there are crack formations through austenitic grains and also the phase transformation from austenite to martensite is not completed until the material consumed its life. Thermal analysis is the basic technique in this study to determine the solidification conditions. By using thermocouples with a suitable set-up, the cooling curves of the materials which were used in bi-metal casting had been taken and analysed. By using these cooling curve data with a written software program which is based on Newton Thermal Analysis, the solid fraction values by time and by temperate were obtained. According to these values, the interface was investigated by changing experimental conditions and solid fractions. At the last part of the study, a new approach was tried in white cast iron production.

O objetivo principal da tese foi desenvolver um método multicriterial de seleção de processos de fundição de metais (MMSPF) para fabricação de componentes, considerando-se critérios técnicos, ambientais e econômicos para ser aplicado nas fases iniciais do desenvolvimento do componente. O MMSPF é constituído pelos módulos de seleção técnica e econômica. O módulo de seleção técnica é destinado a antecipar as atividades de seleção de processos, a serem desenvolvidas na fase de projeto preliminar, enquanto o módulo de seleção econômica é destinado a antecipar as atividades de seleção de processos, necessárias à fase de projeto detalhado. O MMSPF realiza a seleção de processos de forma sequencial. Inicialmente, avaliando aspectos técnicos e, posteriormente, considerando aspectos econômicos. O MMSPF contempla as seis classes de ligas metálicas mais utilizadas na produção de componentes fundidos: aços, ferros fundidos, ligas de alumínio, ligas de cobre, ligas de magnésio e ligas de zinco, apropriadas aos processos de fundição de metais destinados à produção de peças. O MMSPF contempla os quinze principais processos de fundição de metais destinados a produção de peças: areia verde – manual (P1), areia verde – mecanizada (P2), areia verde – automatizada (P3), areia silicato - CO2 (P4), areia com resina – cura frio (P5), areia com resina – shell molding (P6), processo molde de gesso – plaster molding (P7), processo molde cerâmico (P8), investment casting (P9), molde cheio - lost foam (P10), fundição centrífuga - molde metálico (P11), molde permanente – gravidade (P12), molde permanente - baixa pressão (P13), fundição sob pressão - die casting (P14) e squeeze casting (P15) como conjunto solução da seleção. As inovações propostas pelo MMSPF foram: (i) consolidação das diferentes fontes de informação dos processos a serem utilizadas no MMSPF, por meio de uma função de agregação; (ii) utilização de aspectos ambientais como critérios para seleção de processos de fundição de metais; (iii) consideração da estimação de custos de fabricação para realizar a seleção de processos de fundição de metais a partir de um índice de custo de fabricação, relativo ao desempenho técnico. Também foi desenvolvido um aplicativo computacional para implementar o MMSPF composto por três elementos principais: um software de planilha eletrônica (Microsoft Excel), no qual são realizadas todas as operações matemáticas necessárias ao desenvolvimento das etapas operacionais do MMSPF; um banco de dados, o software livre SQLite, responsável por armazenar as informações utilizadas no aplicativo computacional do MMSPF; e a interface gráfica do usuário, que atua como elemento de conexão entre o banco de dados, o software de planilha eletrônica e o usuário. / The main objective of this thesis was to develop a Multi-criteria Method for metal Casting Process Selection (MMCPS) to manufacturing components, considering technical criteria, environmental and economic to be applied in the early stages of design of the component. The MMCPS consists modules for the technical and economic selection. The technique selection module is designed to anticipate the activities of processes selection to be developed in the embodiment design, while the economic selection module is designed to anticipate selection process activities, necessary the detailed design phase. The MMCPS conducts the selection process sequentially. Initially, evaluating technical aspects and, subsequently, considering economic aspects. The MMCPS includes the six classes of metal alloys more used in the production of cast components: steel, cast iron, aluminum alloys, copper alloys, magnesium alloys and zinc alloys, suitable for metal shape casting processes. The MMCPS covers the fifteen main metal shape casting processes: green sand – hand molding (P1), green sand – mechanized molding (P2), green sand - automatic molding (P3), silicate-CO2 (P4), air-set/nobake (P5), shell molding (P6), plaster molding (P7), ceramic mold (P8), investment casting (P9), lost foam (P10), centrifugal casting – metallic mold (P11), permanent mold-gravity (P12), permanent mold-low pressure (P13), die casting (P14) and squeeze casting (P15) as the set solution for the selection process. The innovations proposed by MMCPS were: (i) consolidation of different sources of information processes to be used in MMCPS through an aggregation function; (ii) use of environmental aspects as criteria for selection of metal casting processes; (iii) consideration of the cost estimation of manufacturing to make the metal casting process selection from an index of manufacturing cost on the technical performance. Also developed a computational tool to implement the MMCPS composed of three main elements: a spreadsheet software (Microsoft Excel), which are held every mathematical operations necessary for the development of operational steps MMCPS; a database, freeware SQLite, responsible for storing information used in the application of computational MMCPS, and the graphical user interface, which acts as a link between the database, the spreadsheet software and the user.