The Environmental Conditioning System (ECS) was designed to evaluate the water sensitivity of asphalt concrete mixtures. The ECS subjects asphalt concrete specimens to a series of conditioning cycles including water flow, elevated and/or lowered temperature, and repeated axial loading. The purpose of this research was to: (1) evaluate the ECS test apparatus and procedure, and (2) determine whether the ECS can identify asphalt concrete mixtures that will perform well, or poorly, in the field with regard to water sensitivity. Twelve primary field test sections were identified. For each section, specimens were prepared in the laboratory using the original mix design (or the mix design identified by extraction), and the original aggregates, asphalts, and admixtures. Specimens were tested using two procedures: the ECS and the Oregon State University (OSU) wheel tracker. Field cores were used to evaluate in-situ mixture performance. Nine additional mixtures that have historically experienced water damage were tested in a limited secondary test program. Analyses were performed to determine the mixture properties that were significant in the prediction of mixture performance in the ECS. Mixture type was consistently the most significant predictor of ECS modulus ratio (change in mixture stiffness), degree of visual stripping, and binder migration, which were the performance indicators for water sensitivity evaluated in the ECS. Additional analysis indicated the existence of correlations among the ECS response variables. Significant correlations were found between the coefficient of water permeability and the degree of visual stripping; and between specimen deformation and the degree of visual stripping and binder migration. Mixture performance was compared between the ECS and the OSU wheel tracker and the field. Results indicate that the ECS test procedure can distinguish the relative performance of mixtures, with regard to water sensitivity, and mixture performance in the ECS correlates well with performance in the OSU wheel tracker. No correlation was found between mixture performance in the ECS and mixture performance in the field for the primary test sections. However, the primary field sections are relatively young, and water damage is expected to manifest itself in the future in those pavements identified as water sensitive by the ECS. The ECS predicted failure in the secondary mixtures which were identified as having had poor performance with regard to water sensitivity. / Graduation date: 1994

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第21075号 / 工博第4439号 / 新制||工||1690(附属図書館) / 京都大学大学院工学研究科化学工学専攻 / (主査)教授 前 一廣, 教授 吉田 潤一, 教授 長谷部 伸治 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

The demand for clean and environmentally benign energy resources has been a great concern in the last two decades. To alleviate the associated environmental problems, reduction of the use of fossil fuels by developing more cost-effective renewable energy technologies becomes more and more significant. Among various types of renewable energy sources, solar energy and bioenergy take a great proportion. This dissertation focuses on the heat transfer and flow in solar energy and bioenergy systems, specifically for Thermal Energy Storage (TES) systems in Concentrated Solar Power (CSP) plants and open-channel algal culture raceways for biofuel production. The first part of this dissertation is the discussion about mathematical modeling, numerical simulation and experimental investigation of solar TES system. First of all, in order to accurately and efficiently simulate the conjugate heat transfer between Heat Transfer Fluid (HTF) and filler material in four different solid-fluid TES configurations, formulas of an effective heat transfer coefficient were theoretically developed and presented by extending the validity of Lumped Capacitance Method (LCM) to large Biot number, as well as verifications/validations to this simplified model. Secondly, to provide design guidelines for TES system in CSP plant using Phase Change Materials (PCM), a general storage tank volume sizing strategy and an energy storage startup strategy were proposed using the enthalpy-based 1D transient model. Then experimental investigations were conducted to explore a novel thermal storage material. The thermal storage performances were also compared between this novel storage material and concrete at a temperature range from 400 °C to 500 °C. It is recommended to apply this novel thermal storage material to replace concrete at high operating temperatures in sensible heat TES systems. The second part of this dissertation mainly focuses on the numerical and experimental study of an open-channel algae culture raceway for biofuel production. According to the proposed flow field design of ARID-HV algal raceway, experiments and numerical simulation have been conducted to understand the enhancement of flow mixing in the flow field of ARID-HV raceway by cutting slots on top of the dam near the dead zones. A new method was proposed to quantitatively evaluate the flow mixing by using the statistics of temporal and spatial distribution of the massless fluid particles (centered in each cell at the inlet surface) in the raceway collecting the data of path-lines of fluid particles from CFD results. It is hoped that this method can be applied to assist the algal raceway flow field design as well as other engineering applications. The third part introduces the details about the construction work of a high temperature molten salt test loop. Because of the limited operating temperature of conventional synthetic oils, in order to obtain higher energy conversion efficiency, higher operating temperature is always desirable in a CSP plant which leads to the requirement of new generation of HTF. Currently, a halide salt eutectic mixture (NaCl-KCl-ZnCl₂) as a potential HTF for future CSP applications has been proposed by a multi-institute research team, led by University of Arizona. The thermophysical properties of the halide eutectic salt have been measured. However, this new developed halide eutectic salt has not been tested in a circulating loop at a high operating temperature for the measurement of heat transfer coefficient. It is a significant effort to build such a test system due to extremely high operating temperature. As a consequence, in the third part of this dissertation, details about the design of the lab-scale test system and all the equipment items will be introduced. The investigations included in this dissertation for the heat transfer and flow in solar energy and bioenergy systems are of particular interest to the renewable energy engineering community. It is expected that the proposed methods can provide useful information for engineers and researchers.