Natural Fibre Composites (NFCs) offer new opportunities to mitigate negative impact of engineering activities on the environment. Due to their lost cost, light weight and environmental benefits, they find applications in building, furniture and automotive industry. This study seeks to improve mechanical properties of composites made from waste recyclable plastics and natural fibres from agricultural byproduct sources such as Agave americana leaves, corn, wheat and seed flax straws. The approach used is a holistic one which includes investigating the availability and properties of natural fibres and their composites with waste plastic for use in Canada and Lesotho, a small country in Southern Africa. The social and environmental implications of using these materials are also investigated. In both Lesotho and Canada, there are enough raw materials which can be used in NFCs if the necessary environment is developed. The unique microstructural and interfacial behaviour of Agave americana fibres were investigated and their possible impact on the composites forecasted. Composites made with a variety of underutilized natural fibres: Agave americana, corn, seed flax and wheat were also manufactured and tested. The addition of natural fibres and milled straw to the waste plastic improved mainly the tensile and flexural moduli of the composites. The environmental properties of NFCs were also analyzed through a case study using Life Cycle Assessment (LCA) as tool. The results suggest that NFCs could be seen as a more environmentally friendly alternative than conventional composites. / Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2008-12-03 12:32:23.095

In today’s world the significance of bio-based materials are increasing rapidly because ofthe environmental concern. Material scientists are nowadays engaged in development ofsuch materials which have natural origin and degrade in its environment. Several workshave already been reported in area of thermoplastic biocomposites. However biocompositesbased on thermosets is comparatively new area of research. In this work biobasedcomposites have been developed from two different bio-based thermoset resins.The main objective of the work was room temperature curing of poly lactic acid basedresin (POLLIT™) and AESO, acrylated epoxidized soy-bean oil (TRIBEST®). These tworesin systems were impregnated with different natural fibre mats. Cure behavior wascharacterized by means of DSC (Differential Scanning Calorimeter) and results showsthat the resins have been cured at room temperature. The mechanical properties ofprepared composites were assessed by the means of flexural testing and charpy impacttesting. The viability of using these composites in structural applications are also beendiscussed. / Uppsatsnivå: D