Many reports, scientific papers, patents, and scientific news investigate the feasibility and affordability of direct carbon dioxide capture from the atmospheric air (DAC). Since carbon dioxide (CO2) is extremely diluted in the atmosphere, large volumes of air have to be handled to capture comparable amounts of CO2. Therefore, both the energy consumption and the plant size are expected to be 'prohibitive'. On the other hand, some analyses have shown that DAC is feasible and can become affordable with essential research and development. DAC has been regarded as an optional bridging or a transitional technology for mitigating CO2 emissions in the medium-term. Priorities include investing in renewable and low-carbon technologies, efficiency and integration of energy systems, and realisation of additional environmental benefits. A heavy reliance on negative emission technologies (NETs), and consequently DAC, may be extremely risky as NETs interact with a number of societal challenges, i.e. food, land, water and energy security. Although, "... capturing carbon from thin air may turn out to be our last line of defence, if climate change is as bad as the climate scientists say, and if humanity fails to take the cheaper and more sensible option that may still be available today" MacKay (2009). Certainly, more research is necessary to bring down both cost and energy requirements for DAC. This work firstly predicts the adsorption equilibrium behaviour of a novel temperature swing adsorption process, which captures carbon dioxide directly from the air, concentrates, and purifies it at levels compatible to geological storage. The process consists of an adsorption air contactor, a compression and purification train, which is a series of packed beds reduced in size and connected in-line for the compression and purification purposes, and a final storage bed. The in-line beds undergo subsequent adsorption and desorption states. The final desorbed stream is stored in a storage bed. This cyclic process is repeated for a number of times imposed by the required purity and pressure in the final bed. The process is been thermodynamically verified and optimised. Since, the overall performance of this process does not only depend on the design of the process cycle and operating conditions but also on the chosen adsorbent material, further optimisation of the adsorptive and physical properties of the solid adsorbent is investigated. Thus, the optimal parameters of the potentially used porous materials is identified. Continuing the research on different adsorbent materials, an experimental investigation on the equilibrium properties of two competitive adsorbents is also performed. Besides the thermodynamic analysis, a dynamic model is presented for the investigation of the mass and heat transfer and its influence on the adsorption rate and consequently on the overall process performance. Since the initial stream is very dilute, it is expected that the adsorption rate will be low compared to other temperature swing processes and the capture rate will be affected by the heat transfer. Finally, the design and development of an experimental laboratory-scale apparatus is presented and analysed. Future design improvements are also discussed.

Human-caused emissions of CO2 and other greenhouse gases are an established reason for the climate changes that affect planet Earth. Negative emission technologies (NETs), for example, bio-accelerated silicate weathering bioreactors, seek to capture and store carbon from the atmosphere. Bio-acceleratedsilicate weathering utilizes microorganisms to increase natural silicate weathering processes.This project aimed to evaluate the potential bio-accelerated weathering of two silicate rock types, Basalt Lavagestine, and La Palma lapilli, using a mixture of microorganisms, Bacillus Subtilis, Cupriavidus Metallidurans, Aureobasidium Pullulans, and Suillus Variegatus. Straw was used as an organic carbon and nutrient source for the organisms. There were six types of reactors, biotic, abiotic,and mineral controls for each of the two minerals, with triplicates. The reactors were watered five times a week with 50 mL of autoclaved distilled water, after each week the leachate from each reactor wascollected. Geochemical analyses of all leachates were performed, these were pH, conductivity, alkalinity, and carbon analyses. After the experiment, the mineral grains and straw were examined in a scanning electron microscope (SEM) to observe the growth of organisms and the differences between reactor types.The biotic reactors for both minerals showed signs of enhanced weathering compared to their controls. The geochemical analyses showed that the alkalinity was doubled between the abiotic and biotic reactors for the basalt, and increased by roughly a third for the lapilli. The DIC was tripled for thebiotic basalt and doubled for the biotic lapilli. This indicated increased weathering rates and more sequestered carbon for the biotic reactors. SEM showed growth of fungi and bacteria in all biotic reactors. The extensive growth of fungi and biofilm formation was prominent in the basalt Lavagestineand a possible reason for the increased weathering compared to lapilli. The contrast in the surface structure of the minerals could be a second reason for the result. The two bacteria were colonizing one mineral each, which indicates differences in chemical composition. The C.Metallidurans were observed on the basalt grains and B.Subtilus on the lapilli. This report concludes that bio-enhanced weathering isa promising aspirant for NETs and that the selection of minerals is an important factor.