Reclamation success is highly dependent upon final soil quality of stockpiled soils, such as those found Cold Lake Oil Sands Region. Stockpiled soils, however, are generally poor in quality. Soils were amended with, biochar (BC), humalite (HU), a sub-bituminous coal; and peat (PT), as well as 50:50 blends of biochar:humalite (BCH) and biochar:peat (BCP). These amendments were applied at rates of 0, 6.55, 13.1 and 26.2 g C kg-1 each. Biochar, PT, and BCP applied at the rate of 26.2 g C kg-1 were found to reduce N2O emissions by 34, 54, and 70%, respectively, relative to the control. Within the bioassay, BC and PT amendment resulted in a 38 and 40% increase in dry matter yield (DMY) respectively. Finally, amendment typically resulted in significant net decreases in Olsen P values, while nitrate and ammonium concentrations were high in PT amended soils. In general, PT had the best overall performance. / October 2015

It has been estimated that over 200,000 healthcare professionals may be exposed to waste anesthetic gases and are at risk of occupational injury. In 1977, the National Institute for Occupational Safety and Health (NIOSH) issued the publication: Criteria for a Recommended Standard....Occupational Exposure to Waste Anesthetic Gases and Vapors. This publication was based primarily on scientific evidence from human and animal studies suggesting that chronic exposures to anesthetic gases increases the risk of both spontaneous abortion and congenital abnormalities in offspring among female workers and wives of male workers exposed to waste anesthetic gases. In this recommended standard, NIOSH defines the recommended exposure limits (REL) for nitrous oxide and halogenated anesthetics. NIOSH recommended a time-weighted average (TWA) REL of 25 parts per million (ppm) for nitrous oxide over the period of administration. The REL for halogenated anesthetic gases is a ceiling limit of two ppm.In this study, waste anesthetic gas exposures to seven Post Anesthesia Care Unit (PACU) nurses were quantified during one day of air sampling within their breathing zones. Nitrous Oxide was sampled using a ChemExpressTM Personal Monitor (Assay Technology, Inc. Pleasanton, CA) attached to the nurse's lapel for approximately three hours. A total of 15 samples were collected. Isoflurane, desflurane, and sevoflurane were sampled using a ChemExpressTM Personal Monitor (Assay Technology, Inc. Pleasanton, CA) attached to the nurse's lapel for approximately three hours. A total of 15 samples were collected. In addition, Isoflurane, desflurane, and sevoflurane were also sampled using Anasorb© 747 sorbent tubes (SKC, Inc. Eighty Four, PA) to compare the passive and active sampling methods. The tubes were attached to the nurses lapel for one hour. A total of 15 samples were collected. The exposures to nitrous oxide and halogenated anesthetics were below the NIOSH RELs. An Analysis of Variance (ANOVA) showed a statistically significant difference (p < 0.05) in the active and passive sampling methodologies.

Globally, an estimated 25% of the CO2 and 90% of the N2O is believed to come from agroecosystems. The objective of this study was to investigate the dynamics of the below-ground CO 2 and N2O concentrations and efflux in corn and soybean systems. In our field study, changes in the below-ground concentrations of CO 2 and N2O were closely related to seasonal changes in soil moisture, with the first two months of the growing season being particularly critical to the production of these gases. Tillage significantly increased CO2 content in the soil profile, however, this effect was greater in the soybean plots than in the corn plots. In our greenhouse studies, an average of about 79% of the soil respiration in corn came from rhizosphere respiration, compared to an estimated 58% in the case of soybean. Specific rhizosphere respiration was significantly higher in soybean (0.29 mg C g -1 root h-1) than corn (0.09 mg C g-1 root h-1), which supports previous observations made with regards to slower-growing plants (e.g. soybean) having relatively higher root respiration than faster growing plants. We observed a nonsignificant difference between N2O efflux in the soybean-planted soil and unplanted bulk soil, which is in contrast to the perception that legumes could stimulate more N 2O production from the soil by increasing the N pool through N 2 fixation. While corn had the greatest uptake of fertilizer N, N 2O efflux in corn pots was higher (2.84 mug N pot-1 h-1) than the soybean pots (0.06 mug N pot-1 h-1). In the laboratory setting, denitrification in the microaggregates proceeded at about 4.4 to 39.6 times higher rate than in large macroaggregates, small macroaggregates or the bulk soil, and showed the greatest response to high moisture levels (80% WFPS).

A study was conducted in 2004 and 2005 to determine the effect of liquid hog manure fertilization on greenhouse gas emissions from the surface of a grassland pasture in south-eastern Manitoba. The objectives of this research were to determine the effects of manure application, itstiming and soil moisture on greenhouse gas emissions from pasture soil, cattle dung and urine patches. Nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) emissions were determined from grassland soil surface, and from cattle dung and artificial urine patches. Liquid hog manure treatments were no manure (Control); 153 kg ha-1 of available-nitrogen (N) (two year average) in spring (Spring); and 149 kg ha-1 as half-rate applications in fall and spring (Split). Four field experiments were conducted on grassland plots. The static-vented chamber technique was used to estimate gas emission rates. Two of the experiments focused on the effects of manure application timing and soil moisture on greenhouse gas emissions from the grassland soil surface. The other two experiments focused on the effects of manure application and soil moisture on greenhouse gas emissions from cattle dung and artificial urine patches. Fresh cattle dung was collected from steers grazing adjacent pastures receiving the same three manure treatments. Artificial cattle urine treatments were generated by converting blood urea concentrations of the steers into urine-N concentrations. Manure application increased (P≤0.01) cumulative N2O emissions from the grassland soil surface with Control, Split and Spring treatments averaging 7, 43 and 120 mg N2O-N m-2, respectively. Of the two manure treatments, the Spring treatment emitted higher (P≤0.10) N2O emissions than the Split treatment. Soil moisture was a major factor influencing the quantity and type of greenhouse gas emissions, with saturated areas emitting CH4 during warm periods, whereas drier areas emitted N2O. Nitrous oxide emissions from these dry areas were higher in manure-treated plots. Spring application increased root density by 45% in the top 5 cm of soil compared to the Control. An increase in soil organic carbon with root density may offset any increase in greenhouse gas emissions caused by manure treatment. Cattle dung from Split and Spring treatments had higher cumulative N2O emissions (30 and 82 mg N2O-N m-2, respectively) compared to dung from Control pastures (6 mg N2O-N m-2) over two study years. Dung from the Spring treatment emitted more N2O (P≤0.01) than the other two treatments. All cattle dung patches emitted CH4 after deposition though unaffected by manure treatment. Artificial urine having highest N concentration had greater (P≤0.05) cumulative N2O emissions (690 mg N2O-N m-2) than urine with the lowest N concentration (170 mg N2O-N m-2). Drier soil locations emitted more N2O from cattle dung and artificial urine patches than wetter areas. This study demonstrated that Split application of liquid hog manure to grassland emitted less N2O than a complete application in spring. Moisture greatly affected the location of N2O and CH4 emissions. Drier areas emitted more N2O than wetter ones. Particularly, the findings indicate a need to assess grassland on periodically saturated soils as sources rather than sinks for CH4. Application of manure increased greenhouse gas emissions from cattle dung and urine patches with urine potentially having the greatest impact because of their higher emissions of N2O. An increase in root growth seems to offset greenhouse gas emissions from manure application.

Agriculture contributes significantly to national and global greenhouse gas (GHG) inventories but there is considerable control over management decisions and changes in production methods could lead to a significant reduction and possible mitigation of emissions from the sector. For example, conservation tillage practices have been suggested as a method of sequestering atmospheric carbon dioxide (CO2), however, many questions remain unanswered regarding the short-term efficacy of the production method and knowledge gaps exist regarding possible interactions with essential nutrient cycles, and the production of non-CO2 GHGs, such as nitrous oxide (N2O). Between autumn 2005 and 2009, a micrometeorological flux system was used to determine net CO2 and N2O exchange from an annual cropping system situated on clay soil in the Red River Valley of southern Manitoba. Four plots (4-ha each) were independently evaluated and planted to corn in 2006 and faba bean in 2007; in 2008, two spring wheat plots were monitored. As well, during the non-growing season in 2006-2007 following corn harvest, a second micrometeorological flux system capable of simultaneously measuring stable C isotopologue (12CO2 and 13CO2) fluxes was operated at the site. Tillage intensity and crop management practices were examined for their influence on GHG emissions. Significant inter-annual variability in CO2 and N2O fluxes as a function of crop and related management activities was observed. Tillage intensity did not affect GHG emissions from the site. After accounting for harvest removals, the net ecosystem C budgets were 510 (source), 3140 (source) and -480 (sink) kg C/ha/year for the three respective crop years, summing to a three-year loss of 3170 kg C/ha. Stable C isotope flux measurements during the non-growing season following corn harvest indicated that approximately 70 % and 20 – 30 % of the total respiration flux originated from crop residue C during the fall of 2006 and spring of 2007, respectively. The N2O emissions at the site further exacerbated the net global warming potential of this annual agroecosystem.

A study was conducted to examine the impact of diet and cold weather on the excretion of nitrogen (N) and phosphorus (P) from beef cows, and the potential for these nutrients to be lost to waterways or as greenhouse gases (GHG). Feces and urine were collected from mature cows fed low-quality forage supplemented with DDGS to 0%, 10%, and 20% ww-1 in the fall of 2008 and winter of 2009. A detailed nutrient analysis was performed to determine forms of N and fractions of P in excreta. Feces, urine, and a simulated bedding pack were then applied to grassland to determine soil GHG emission. Cattle receiving DDGS supplementation excreted greater proportions of labile P in feces and greater concentrations of P in urine. The 20% DDGS diets had greater nitrous oxide emission from urine patches and greater proportions of available N in urine and feces.

Two laboratory incubation studies and a growth room bioassay of forage barley were conducted to investigate nitrogen (N) and phosphorus (P) mineralization, and nitrous oxide emission from two contrasting agricultural soils amended with anaerobically digested cattle manure (ADM). The ADM is a nutrient-rich co-product from manure-based biogas plants which is applied to cropland at rates used for raw manure since scientific information on nutrient release from ADM is lacking. Application of the separated solids fraction of ADM (SS) reduced nitrous oxide emission but resulted in lower N mineralization compared to raw manure in both soils. Raw manure- and SS- treatments had similar biomass yields and P supply capacities while the application of pelletized SS (PSS) caused net N immobilization, lower P release than manure and SS, and depressed barley yields relative to non-amended (control) soils.

Earthworms are well known to increase decomposition of organic matter and release of plant available nutrients. They can also increase CO 2 and N2O fluxes from the soil by stimulating respiration, denitrification, and nitrification caused by soil microorganisms. The objective of this thesis was to examine the influence of different earthworm species and population numbers on CO2 and N2O fluxes from a corn agroecosystem. In the field study, earthworm treatments had a significant effect on CO2 fluxes, but there was no difference between CO 2 fluxes from the two species (Lumbricus terrestris L., Aporrectodea caliginosa Savigny) or from the two population levels (1x and 2x the naturally-occuring population). Also, the earthworm treatments had no significant effect on N2O fluxes. Since all treatments contained mixed species and similar population levels at the end of the study, it is likely that CO2 and N2O fluxes in the field were affected more by soil temperature and moisture fluctuations than by the earthworm treatments. The study was repeated in laboratory microcosms under environmental control. Again, earthworm treatments had a significant effect on CO2 fluxes, but not on N2O fluxes. Interestingly, the N 2O fluxes from microcosms containing L. terrestris came solely from denitrification, while the N2O fluxes from A. caliginosa microcosms were produced mostly by nitrification. It is not known why these species stimulate different groups of microorganisms that can produce N2O, and this remains to be investigated.

Gas phase biofilters are used for controlling odors from animal facilities. Some characteristics can affect their performance and moisture content is one very important. A methodology for controlling and measuring moisture content is required to optimize these systems. An experiment was conducted to determine the appropriate placement of a set of soaker hoses 1.2 m in length for water application. It was found that the soaker hose installed in the lower region of the biofilter coupled with appropriate and timely application of water was able to minimize drying of the compost. Thermal conductance proved to be a reliable indicator for measuring the moisture content. Biofilters using the soaker hoses together with the thermal conductance as a media moisture sensor were able to maintain moisture content above 30% w.b. which provided sufficient water for microbial activity and ammonia abatement. A characterization of the ammonia and nitrous oxide concentrations was performed in order to compare the behavior of the gases when water was applied versus no water addition. These analyses revealed that the overall performance was not significantly different between treatments. But a more detailed assessment inside the biofilter media is performed; it is possible to identify different processes taking place.

Irrigated agriculture in the Canadian Prairies is in a position to play a prominent role in addressing global food demands imposed by a growing world population. Particularly within Saskatchewan there is potential to see large increases in the number of irrigated hectares, due to the large irrigable land base and supply of freshwater resources. Yet, how this increase will influence the agricultural greenhouse gas (GHG) balance is not well understood. Through the quantification and comparison of GHG emissions from a typical irrigated and dryland cropping system in Saskatchewan, this research aimed to better understand the role of irrigated agriculture on GHG dynamics in this region. A field-scale analysis of irrigated soil conditions and resulting soil greenhouse gas emissions identified that soil N availability was likely the dominant factor influencing soil N2O emissions from irrigated systems. Soil moisture was also a key factor in soil GHG fluxes, governing seasonal CH4 uptake and episodic N2O and CO2 emissions. The development of system-specific GHG budgets—incorporating on-site GHG sources and sinks—identified electricity as irrigated cropping’s largest contributor of global warming potential (GWP). Emissions from soil and diesel-combustion sources were less intensive under irrigated production; yet overall greenhouse gas intensity (GHGI) was greater from irrigated cropping. This research provides a first look into GHG dynamics from irrigated agriculture in Saskatchewan and identifies areas for potential mitigation as irrigated crop production expands in the Province.