Coal mining carries significant impacts for surrounding livelihood practices. Yet, in order to explain how specific impacts become grounded within a particular community, attention must be given to the complex assemblage of socio-political and economic forces operating at the local scale. As such, this paper builds upon 3 months of field research in 2010 to describe the impact of decentralized extractive resource governance at coal mines near the rural coastal village of Sekerat, East Kalimantan. Employing evolutions in political ecology research, the analysis focuses on the evolving governance ‘space’ in order to explain how institutional analyses of resource extraction governance and livelihood governance can be integrated to understand how scalar processes construct a range of real and perceived impacts which condition the decision-making modalities of local villagers. A case is then made for giving greater consideration to the importance of temporality and materiality to explaining how land-based and wage-labour livelihood practices have become ‘reified’ within the local village.

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Unresolved Complex Mixtures (UCMs) of hydrocarbons are found in crude and refined oils and in water, sediments and biota polluted with oils. The concentrations of UCMs in oils are significant (e.g. >65% of the aliphatic hydrocarbons in fresh Kuwait crude) and it is perhaps surprising that virtually nothing is known about UCM composition. The present study sought to redress this paucity of information in three main ways: First, following two recent studies of aliphatic UCMs, an investigation of the composition of the "aromatic" UCM of Venezuelan Tia Juana Pesado crude oil was made by spectroscopic (IR, NMR, MS) and oxidative (CrO3, Ru04) methods. These showed that the UCM was, in fact, highly aliphatic. The major compounds identified were alkyl substituted naphthenoaromatics with one and two aromatic rings. Chemical oxidation indicated that the alkyl branched side chains extended to at least twenty three carbon atoms. Second, an investigation into the origins of UCMs was made. The products of hydrous pyrolysis of man-made (polythene) and biogenic (cutan) polymers under conditions proposed previously to simulate catagenesis, included, in the hydrocarbons, high proportions of UCMs (50% - >70%). Hydrous pyrolysis of polythene produced a mixture of saturated (56%) and olefinic (44%) hydrocarbons, whilst pyrolysis of cutan produced hydrocarbon (aliphatic and aromatic; 30-75%) and nonhydrocarbon (70-25%) fractions, both with >60% unresolved components. Oxidative characterisation of these UCMs produced mainly n-acids with somewhat similar results to those found when oil UCMs were oxidised. However, the laboratory generated UCMs are not perfect oil UCM models since some oil UCM oxidation products were not observed in the laboratory models. Finally, an attempt was made to release the geochemical information contained within UCMs. Replicate oxidations of milligram quantities of oil UCMs followed by quantitative GCMS characterisation and multivariate statistical analysis of the resolved oxidation products gave reproducible distributions with >80% similarity. Application of this method to two oil spill incidents where the source oil was known (Milford Haven and the Humber Estuary) gave good correlations between sediment and source. In contrast analysis of Mersey Estuary sediments contaminated with heavy asphaltic oil and of Sullom Voe sediments contaminated with UCMs failed to show any correlation between the sediments and the source oils. However, subsequent re-analysis of the data excluding the major UCM oxidation products (n-carboxylic acids) produced better correlations which indicated that the greatest correlation potential for these UCMs was contained within the minor oxidation products. A similar study of UCMs from two oil seeps from the Siljan Ring region of Sweden failed to show any correlation with potential source rocks, in agreement with biomarker data. This study has extended present knowledge of UCM composition and suggested a mechanism for UCM formation. Furthermore, quantitative and statistical analysis of UCM oxidation products has been shown to be useful for oil identification. There is still much to be learned about UCMs and the subject should provide a fruitful area for further research. Some possible approaches are suggested. Parts of this work have been published (Revill et al. 1991), Organic Geochemistry: Advances and Applications in Energy and the Natural Environment, Manchester University Press

Contentions that expansion of the British coal mining industry into predominantly rural areas may pose serious threats to agriculture and food production are reviewed in the light of the available evidence. It is considered that, whilst the severity of impacts and rate of future development may have been overstated, the conflicts are sufficiently significant to warrant close examination. Further, land use planners are responding for the first time to mining proposals affecting entire coalfields, thus making it essential to establish the correct principles of development from the outset. It is noted that past assessments of agricultural impacts have failed to reflect their diverse and pervasive nature, thus necessitating the identification of more appropriate methods of forecasting. In the light of current weaknesses in practice, it is argued that a formal system of impact assessment may prove necessary. Those characteristics of mining operations and associated end-uses which are likely to affect agriculture are analysed, as are those aspects of the farm enterprise most vulnerable to disruption. These various characteristics are then used as a basis for the assessment of mining-agriculture impacts. A review of the strategic nature of impacts arising from mining programmes is considered desirable, and limited proposals are made regarding assessment at this scale. More detailed consideration is given to an appraisal framework for individual mining proposals, and this is tested in relation to part of the 'Vale of Belvoirl coalfield. It is concluded that, although further methodological refinements and field investigations are necessary, the early implementation of an impact assessment procedure is nevertheless justified.

The aims of this research project were to identify and classify the binder-filler interfaces formed in carbon electrodes and to determine the effects of the interfacial quality on important electrode properties. The effects of raw materials and some fabrication process variables on interfacial characteristics and quality of laboratory produced test electrodes were also studied, and the development of binder-filler interfaces during the carbonisation process followed. Electrode quality was assessed by measurement of density, electrical resistivity and tensile strength. Pore structural data were also obtained by using a computerised image analysis system allied to an optical microscope. Interface quality data were obtained by examining etched surfaces in a scanning electron microscope and classifying the binder-filler interface observed into one of five categories. The category depending on the extent of contact between the binder and filler. Accordingly, test electrodes were produced from combinations of four filler carbons, comprising three grades of calcined petroleum coke and an electro-calcined anthracite, and four coal-tar binder pitches which varied in the type and quantity of insoluble matter content. Examination of these test electrodes showed that the nature of the filler carbon used had a dominant influence on the quality of the interface formed, as assessed by this technique. A combination of one filler carbon and one binder pitch was used to study the effects of some fabrication process variables. These were pitch content and, mixing time and temperature. Of these process variables, pitch content and mixing temperature were found to have the major effects on the binder-filler interface and electrode quality. Investigation of the development of the binder-filler interfaces during the carbonisation process showed three distinct zones of interface development and transformation. These zones were associated with three temperature dependent mechanisms; thermal stress relaxation between 200-350 degrees C, volatile gas evolution from coal-tar pitch decompositionb etween3 50-600 degrees C and stresses induced by thermal contraction of the binder phase between 600-1000 degrees C.

Of all coke properties the influence of the catalytic mineral matter on reactivity of metallurgical cokes is least understood. There is limited information about the form of minerals in the metallurgical cokes and no information about their relative concentration. A comprehensive study was undertaken for characterisation of mineral matter in coke (qualitative and quantitative), which enabled quantification of the effect of catalytic minerals on the reaction rate, and establishment of the effect of gasification on the mineral phases. Also, the relative importance of coke properties on the gasification reaction rate was determined. The reactivity experiments were performed at approximately 900??C using 100% CO2 under chemically controlled conditions. The mineralogical composition of the investigated cokes was found to vary greatly as did the levels of catalytic mineral phases. These were identified to be metallic iron, iron sulfides and iron oxides. The gasification reaction rate at the initial stages was strongly influenced by the content of catalytic mineral phases and also by the particle size of the catalytic mineral matter. The reaction rate increased as the contact surface between catalyst and carbon matrix increased. Catalytic mineral phases showed a strong influence on the reaction rate at early stages of reaction. But their influence diminished during gasification. At later stages of reaction the influence of micropore surface area became more important. The influence of the catalytic mineral phases diminished during gasification because the catalyst was inactivated to some degree and the contact surface between the catalyst and carbon matrix diminished due to the strong gasification of the carbon around the catalyst particles. The partial inactivation of the catalytic mineral phases occurred because metallic iron and pyrrhotite were oxidised by CO2 to iron oxide, and in turn iron oxide reacted with other mineral phases, which it is associated with, to form minerals that are not catalysts. It is noteworthy that a significant percentage of the mineral matter present in the investigated cokes was amorphous (44 - 75%). The iron, potassium and sodium present in the amorphous phase did not appear to catalyse gasification, but their potential contribution to gasification could not be completely excluded.

The PCI technology is well established for reducing the consumption of economic and environmentally expensive coke in blast furnace iron-making. Often, coal blends show unexpected combustion performance which cannot be explained on the basis of individual coal properties particularly coal rank and volatile matter. Several coals were combusted in this study under controlled conditions in a drop tube furnace. Fixed bed reactor, XRD, SEM and BET analyses were used to understand the mechanism of combustion of coal blends. Burnout of the coal blends did not change linearly with volatile matter of blends. The study demonstrated that combustion behaviour of coal blends was influenced by several properties of individual coals and cannot be estimated by using any single coal parameter. Carbon structure of coal as well as the interaction of volatile matter of individual coals was found to have a strong influence on the burnout of coal blends. Pet-cokes were generally found to burn with a greater difficulty. Carbon structure of pet-cokes was found to have a significant effect on the burnout such that coal blends with highly ordered pet-coke indicated lower burnout. The study shows that up to 10% of pet coke did not change the burnout of PCI blends significantly. As far as combustion is concerned, the drop tube furnace test provides a reasonable distinction of the effect of coal properties for PCI application.

Tailgate stability within longwall coal mining is critical to longwall productivity and safety of mine personnel. A mechanistic model was developed and tested to explain observed high deformation tailgate behaviour characterised by lateral strata movement. Field investigations were conducted at three Australian longwall mines with an emphasis on the measurement of; horizontal strata movement about gateroads during longwall extraction, and the load/deformation characteristics of standing supports. 3D numerical modelling was used to simulate tailgate deformation, and interaction of various support types and design strategies. The sensitivity of strata and support behaviour to; variations in roof geology, strength of sliding interfaces, depth of cover, pre-mining horizontal stress magnitude and orientation, and strength and stiffness characteristics of standing supports was modelled. Laboratory investigations of a standing support product, the ???Can???, at reduced scale (one third) were conducted. The tests determined the loading mechanics of the product and provided a basis for optimisation of the engineering properties (strength and stiffness). Horizontal strata movement about longwall extraction was found to have a significant impact on strata behaviour at two of the three mines investigated. The term ???skew roof??? was coined to describe the deformation process. Essentially the roof strata was found to ???skew??? towards the approaching goaf. The key geotechnical factors found to control the skew roof mechanism were; magnitude and orientation of the pre-mining horizontal stress, presence of weak interfaces along which sliding could occur, and shear strength of the interfaces. Measurement of the nature and extent of skew roof deformation specific to each mine provided a sound engineering basis for support design. These included; the relative roles of long tendons versus standing support, optimal pattern (position across and along the roadway) of standing supports, and appropriate strength and stiffness characteristics. The findings were successfully implemented at Metropolitan Colliery in particular, where adequate tailgate serviceability has been achieved within a high deformation environment, and whilst maintaining a relatively small chain pillar width. The research has achieved an alternative to empirical and trial and error tailgate support design methods.

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