Certain types of fuel used for combustion in land-based gas turbines can contain traces of ash when introduced into a gas turbine. Examples include synfuel, from the gasification of coal, and heavy fuel oil. When these ash particles travel through the hot gas path of the gas turbine they can deposit on turbine vanes and blades. As deposits grow, they can reduce turbine efficiency and damage turbine hardware. As turbine inlet temperatures increase, ash deposition rates increase as well.Experiments were conducted in the Turbine Accelerated Deposition Facility (TADF) at Brigham Young University to better understand ash deposition behavior at modern turbine inlet temperatures. Experiments were conducted that varied deposition duration, gas temperature, surface temperature, ash type and characteristics, and film-cooling blowing ratio. Analysis included measuring and calculating the capture efficiency, deposit surface roughness, deposit density, and deposit surface temperature. Test results indicate that capture efficiency increases with time and as the gas temperature increases. Previous studies have shown that the capture efficiency increases with increasing surface temperature as well, but the results from this study show that at a gas temperature of 1400°C, the capture efficiency of the ash used in these tests initially increased but then began to decrease with increasing surface temperature. It was also shown that different ashes, with differing ash chemistries and densities, deposit at very different rates and produce different surface structures. The film-cooling tests showed that film cooling does reduce the capture efficiency at modern turbine temperatures, but has a smaller relative effect than at lower temperatures. Tests performed with heavy fuel oil ash and increased SO2 levels (similar to those found in heavy fuel oil combustion environments) indicate that the increased sulfur levels result in the formation of more sulfur compounds in the deposit and change which elements are dissolved by water, but has little effect on the amount of deposit that dissolves. CFD simulations were performed to model the fluid dynamics and particle trajectories in the TADF. The resulting particle impact data (particle impact velocity, temperature, diameter, etc.) were used in sticking models to evaluate the models' performance at high temperatures. Results indicate that while the models can be fit fairly well to specific data, they need to be able to better account for changing surface conditions and high temperature particle behavior to accurately model deposition at high temperatures.

An increasing emphasis on mitigating global climate change (global warming) over the last few decades has created interest in a broad range of sustainable or alternative energy systems to replace fossil fuel combustion. Biomass, when harvested responsibly, is a renewable fuel with many uses in replacing fossil fuels. Cofiring biomass with coal in traditional large-scale coal power plants represents one of the lowest risk, least costly, near-term methods of CO2 mitigation. Simultaneously, it is one of the most efficient and inexpensive uses of biomass. Alternatively, biomass can be transformed into useful products through gasification to produce clean syngas for highly efficient gas turbines, or feedstock to produce light gases, fuels, chemicals or other products. A large portion of this investigation focused on the effect of cofiring biomass on the near burner region of a commercial coal flame. This research included first-of-their-kind field measurements of flame structure and particle properties in front of a full-scale burner fired with biomass and coal, including measurements of particle size and composition, gas velocity, composition, and temperature in the near-burner region of multiple cofired flames in a 350 MWe full-scale power plant in Studstrup, Denmark. A novel sampling and analysis technique was developed enabling the estimation of the fraction of biomass in the flow as a function of position and the burnout of biomass and coal particles separately. These data show that biomass particles do not follow gas stream lines to the same extent that coal particles do. This is consistent with the larger sizes, slower heating and reaction rates, and higher momentum of biomass particles. This research also includes first-of-their-kind single particle continuous measurements of particle mass, surface and internal temperature, size, shape, during biomass pyrolysis and gasification. The single particle measurements provided among the most highly resolved and repeatable biomass gasification results reported to date for wood, switchgrass and corn stover. All three samples showed greater gasification reactivity to H2O than to CO2. The experiments included results in both reactants individually and combined. One of the most important findings of this work was the experimental confirmation that as the char particles gasify, their ash fractions increase and reaction rates decrease on both an intrinsic and external surface area basis. The analyses in this work show that this decrease in burnout quantitatively corresponds to the change in the predicted fraction of the surface that is ash and does not reflect any change in organic reactivity. Reaction rate parameters suitable for relatively simple power-law models based on external surface area describe all the data reasonably well.

This thesis explores the emotional, physical, and familial repercussions of coal mining in the Appalachian region, especially in regards to relationships within the community. The thesis is divided into two parts; a critical essay in which the objective facts, statistics, and histories of coal mining are addressed, and a short story which shares the subjective experience of the Hicks family.

The greatest political, scientific, and engineering challenge of the 21st century is finding a viable solution to limit anthropogenic greenhouse gas emissions (CO2) to curb the effects of global climate change. All sectors of society need to contribute to alleviate this problem, but industrial operations must play a significant leadership role. Some of these industries include: metallurgy, cement, power, agriculture and forestry. In particular, the iron/steel, cement, and power generation industries use coal on account of its high energy density among solid fuels. Coal combustion yields 720 tonne CO2/GWh, and produces fine particulates, sulphur and nitrous oxides, along with excess CO2 contributing to climate change. In comparison, biomass (such as agricultural and forestry residues) has a solid fuel rating of 25-100 tonne CO2/GWh; therefore, biomass fuels are considered more sustainable since the living biomass consumed CO2 in the early part of its life cycle. However, biomass has significant industrial shortcomings for its use as fuel at large scale, including low energy content, density, and hydrophobicity relative to coal. In short, biomass fuels cannot be substituted without major infrastructure changes which add economic penalties that industry is currently unwilling to absorb. Biomass upgrading routes were considered in this thesis. These include densification, torrefaction, and integrated torrefaction and densification (ITD). The first half of the methodology involved converting woody biomass (willow residue and poplar bark), agricultural residue (switchgrass plants), and pulp mill waste via a single pellet/briquette press at different densification temperatures and pressures. The second half of the methodology involved product characterization of each batch of pellets and briquettes. In this work, pellets and briquettes were tested for physical characteristics (density and durability), chemical differences (energy content and hydrophobicity), and transport phenomena characteristics (drying profiles). First, results showed that extrusion of torrefied biomass at 300°C with an estimated pressure of 10 MPa creates partially formed pellets from agricultural residues. Using the concept of ITD (temperature range 220-325°C and pressure range 40 and 215 MPa), the density was found to be 1000-1250 kg/m3 for pellets and briquettes. The degree of compression from the loose biomass was on the order of 3-10 which corresponds with theoretical expectations. Material density increased with increasing pressure. The solid yield of pellets and briquettes decreased with increasing temperature, and results aligned with micro-scale thermogravimetric analysis. The larger ITD briquettes (produced at T = 325°C, P = 40 MPa) were evaluated for calorific value and found to fall in the lignite classification (O/C < 0.4 and H/C < 1.2) on a van Krevelen diagram. The resulting ITD pellets and briquettes were found to have a durability similar to commercial materials (durability > 97%), and to be more hydrophobic (8 wt% moisture absorption compared to 35 wt%). The drying time of ITD materials was faster than commercial torrefied briquettes, with an effective diffusivity of 1.5×10-6 m2/s compared to 7.3×10-9 m2/s likely because of a smaller pore volume in ITD briquettes. Further pilot scale studies would help improve the ITD methodology and make the process more appealing for the replacement of coal fuels.

Spontaneous combustion of coal has historically been a major problem for the coal industry, predominantly during storage and transportation. Various methods have been used in the laboratory for evaluating the propensity of different coal sources to self-heat. However, the heterogeneity of coal and the complexity of the system has resulted in inconsistencies and sometimes conflicting results as indicated by the findings reported in several publications. The primary objective of the current study was to build a laboratory scale apparatus that simulates the condition of a coal stockpile to evaluate the events leading to spontaneous combustion and develop potential remedies. As such, the influential factors can be identified with confidence, thereby providing an improved understanding of the spontaneous combustion. An adiabatic heating apparatus was designed and constructed which included instrumentation to closely monitor the oxidation process and the stages leading to spontaneous combustion under various conditions. The device was equipped with thermocouples which measured the temperature rise as a function of time leading to the determination of an index value that indicated the propensity of a given coal source to spontaneously combustion. The index was referred to as the R70 value which was measured as the temperature was increased during the period of rapid oxidation. The units for the index was degrees Celsius per hour. As such, a high index value reflected the likelihood of spontaneous combustion for a given coal source. To standardize the test procedure, a detailed three-level statistical experimental design was conducted involving three critical parameters, i.e., particle size, oxygen flow rate and the duration of the drying period prior to feeding oxygen to the system. Using empirical models describing the R70 value as a function of the parameter values developed from the test data, it was determined that R70 was sensitive to the sample particle size and drying time. A decrease in particle size and drying time significantly increased the R70 value while the oxygen rate did not have a significant impact over the range of values tested. Based on the results of the test program, a standard test procedure was established to evaluate various coal sources and identify chemicals that could be used to remediate the spontaneous combustion issue. Several sub-bituminous coal sources collected from the Powder River Basin were tested in the apparatus and found to be prone to spontaneous combustion as indicated by R70 values that approached 50oC per hour. Several chemicals were evaluated as a means of eliminating or slowing the spontaneous combustion process. These agents included anti-oxidants, binders and humectants. Organic binders were used to agglomerate the fine coal particles which limited surface area exposure. The effect significantly reduced the oxidation rate as indicated by a reduction in the R70 index from 44.07oC/hr to 5.71oC/hr. However, after entering the latent heat stage, the temperature increased rapidly at a rate of 27.58oC/hr. Humectants were evaluated which contained several hydrophilic groups, mainly hydroxyl groups, and thus have an affinity for water. As a result, when the coals were treated with humectant, the latent heat rate was reduced to 4.24oC/hr although the R70 remained relatively high. By using a combination of humectant and binder, the optimum result was obtained with an R70 value of 5.04oC/hr and a latent heat rate of 11.06oC/hr. These findings were successfully implemented into industrial practice for significantly delaying the spontaneous combustion event.

Dust generation at an underground coal mine working face continues to be a health and safety issue. Prolonged exposure to high concentrations of airborne respirable dust can cause a debilitating and often fatal respiratory disease called Black Lung. In addition, the deposition of float dust in mine return airways poses a serious safety hazard if not sufficiently diluted with inert rock dust. A localized methane explosion can transition into a self-propagating dust explosion. Since dust is a byproduct of various mining activities, such as cutting and loading, crushing, and transportation, the dust-related issues cannot be totally eliminated. However, the adverse health effects and safety concerns can be minimized if a significant amount of the generated dust is removed from the ventilation air by a mechanical device, such as a dust scrubber. Over the last three decades, flooded-bed dust scrubbers integrated into continuous miners have been successfully applied for capturing and removing airborne dust generated at the working face. According to the National Institute for Occupational Safety and Health (NIOSH), a flooded-bed scrubber can achieve more than 90% capture and cleaning efficiencies under optimum conditions. Although flooded-bed scrubbers have proven useful in the vast majority of cases, they have not yet been successfully applied to a longwall face. In the United States, numerous attempts have been made to reduce dust concentration at a longwall face through the application of a scrubber; but, none were successfully implemented. Encouraged by the successful use of a flooded-bed scrubber system at continuous miner faces, this research revisits the flooded-bed scrubber concept for a longwall shearer. For this investigation, a full-scale physical model of a Joy 7LS longwall shearer, modified with an integrated flooded-bed dust scrubber, was designed and fabricated at the University of Kentucky. The scope of work for this research was limited to capturing and cleaning dust generated near the shearer headgate drum only. The mock-up was transported to, and assembled in, the full-scale longwall dust gallery at the NIOSH Pittsburgh Research Laboratory (PRL). Tests were conducted to examine: (1) the effect of the scrubber on headgate-drum dust reduction and (2) the combined effect of the scrubber and splitter sprays on headgate drum dust reduction. Analysis of test results for the scrubber-alone condition indicates a significant dust reduction of up to 57% in the return airway and 85% in the test gallery walkway, whereas the combination of scrubber and splitter-arm sprays shows dust reduction of up to 61% and 96% in the return and walkway, respectively. These results indicate that a flooded-bed scrubber integrated into a longwall shearer can be used as a viable technique to reduce a large portion of airborne dust at a longwall face. Subsequently, a Computational Fluid Dynamics (CFD) model of the longwall gallery and shearer was developed and validated using the results of the experimental study. The CFD simulation results are in good agreement with the experimental results with a maximum of 9.7% variation. This validated CFD model can be used in future research to predict the effects of modifications to the scrubber system, including modifications to the scrubber inlet, to optimize the scrubber design, and to evaluate the effectiveness of adding a tailgate drum dust scrubber.

The demand for rare earth elements (REEs) has increased over the last decade due to applications in high technology devices including those in the defense industry. The recovery of REEs from primary sources such as rare earth minerals are viable using physical separations followed by chemical processing. However, weak market values and environmental concerns have limited the viability of such operations. On the other hand, REE recovery from secondary sources such as apatite ore, bauxite waste, and waste recycling, provides an opportunity to take advantage of a resource that does not require mining costs as well as other associated costs given that these expenses are covered by the revenue generated from the production of the primary material. Coal-based materials represent a potential source for REEs which may be extracted and concentrated by the use of physical and/or chemical processes. The current study focused on developing a leaching process to extract REEs from the pre-combustion coal sources including coarse and fine refuse and low-valued material obtained from coal preparation plants. Materials collected for leaching characteristic studies were found to have average total REE concentrations in the range of 200-350 ppm on a whole sample basis. Mineralogy studies performed on Fire Clay seam coal refuse using SEM-EDS detected micro-dispersed rare earth phosphate mineral particles which are generally difficult to dissolve in strong acid solutions. On the other hand, XRD analysis results from a high REE content segment of the West Kentucky No. 13 coal seam indicated the presence of fluorapatite which is soluble in weak acid solutions. The mineral associations of REEs were studied by extracting REEs using different types of acids under various pH conditions. Differential extraction of the REEs was examined along with the associated impurity elements such as iron, aluminum, and calcium among others. The findings showed that the light REEs were primarily associated in a phosphate mineral form, whereas the heavy REEs were mostly present in an ion substitution form associated with clay minerals. Relatively high concentrations of REEs were discovered in mixed-phase particles consisting of both coal and mineral matter. By reducing the particle size, more leachable forms of REEs were liberated and recovered along with the associated mineral matter embedded in the coal structure. The type of lixiviant played an important role during the initial stage of leaching but was found to be insignificant as the system reached equilibrium. Solids concentration in the leaching medium has an important role in establishing the throughput capacity of the leaching system. Test results found that an increase in solids concentration had a significant negative effect on rare earth recovery. This finding may be explained by higher concentrations of soluble calcium-based minerals such as calcite which provided localized pH increases near and within the pores of the solids. The result was precipitation of CaSO4 within the pores which blocked access for the lixiviants. This hypothesis was supported by the findings from BET and XPS analyses which found lower pore volume in high solid concentration systems and the existence of CaSO4 on the surface of the solids. Leaching test results obtained using sulfuric acid over a range of temperatures showed that the leaching process was mainly driven by a diffusion control process. The activation energy determined for an Illinois No. 6 coal source was 14.6 kJ/mol at the beginning of the reaction and 35.9 kJ/mol for the rest of the leaching process up to 2 hours. For material collected from the Fire Clay coal seam, the apparent activation energy was 36 kJ/mol at the start of the leaching reaction and decreased to 27 kJ/mol over the remaining period of the test. The activation energy values were nearly equivalent to the upper-level values that generally define a diffusion control process and the lower values of a chemical reaction control process. The lack of clarity in defining a clear control mechanism is likely associated with the variability in associated mineralogy, various modes of occurrence of the REEs and the interfacial transfer of product through the porous structure of the coal-based particles which requires relatively high activation energy. As such, both diffusion control and chemical reaction control mechanisms are likely occurring simultaneously during the leaching process with diffusion control being more dominant.

A study of a 250 ft. (76.2 m) stratigraphic interval that includes the Eocene-age Felix coal of the Wasatch Formation was undertaken in the Powder River Basin of Wyoming to establish a depositional model based on the interrelations of coal-seam geometry, coal maceral composition, and spatial distribution of adjoining rocks. Regional cross sections and maps of major rock bodies were prepared from 147 measured stratigraphic sections and 56 geophysical logs. Trends in maceral and chemical properties within the Felix coal were identified from petrographic and geochemical analyses of 72 coal channel samples. The combined data sets indicate that the thickest portions of the coal are underlain by widespread, interconnected, sandstone-dominated fining-upward sequences (< 50 ft. or 15 m thick over a 300 sq. mi. or 777 sq. km area) whereas areas of thin or split coal are underlain by stacked predominantly fine grained, coarsening-upward sequences (< 50 ft. or 15 m thick). Above the coal, fining-upward sequences are concentrated over thin coal areas and widespread (> 20 mi., 32 km wide) coarsening-upward sequences overlie thick coal areas. Megascopic and petrographic description of the coal indicates that the brightest coal contains the greatest amount of huminite. This type coal occurs in the lowest portion of the seam and directly above clay partings in thick coal areas and in split benches · on the margin of the deposit. The central and upper portion of the seam is predominantly dull, and inertinite percentages increase towards the top of the seam. The deposits below the Felix resulted from north-northwest flowing meandering rivers. Thick peat represented by thick portions of the Felix coal accumulated upon this sandstone-dominated, poorly compactible platform that was free of sediment influx. Areas of thin and split Felix coal, underlain by fine-grained, more-compactible sediments, attracted water-borne elastics that interrupted peat accumulation. The base and split portions of the seam are the remains of predominantly coniferous trees that grew within a nutrient-rich environment, and the duller central and upper portions of the seam indicate oxidation associated with a raised peat deposit. Ash falls and fires during late stages of peat accumulation may have contributed to the demise of the swamp. After vegetation died large lakes formed and were subsequently filled by crevasse deposits from streams. The final phase of compaction of the fine-grained lake sediments and the thick underlying peat attracted anastomosed alluvial channels.

In the early 1990s many scientists claimed that there was a scientific consensus that the anthropogenic production of greenhouse gases was causing global warming. Carbon dioxide is produced in far greater quantities than other greenhouse gases. Over 80 percent of the carbon dioxide produced in the United States comes from coal-fired power plants. If global warming is a threat to the welfare and survival of future generations, the United States, as one of the greatest producers of greenhouse gases,has an obligation to reduce its production of these gases. In order to determine the most effective way to reduce the production of greenhouse gases in the United States, this study examines recent efforts by the Clinton and Obama administrations to reduce greenhouse gas emissions from coal-fired power plants.The Clinton and Obama administrations were selected for this study because both administrations were Democratic, and both had avowed political agendas to reduce greenhouse gas emissions. For the first two years each administration enjoyed the support of Democratic majorities in both Houses of Congress, and they had similar political support for the remainder of their time in office. This study will show that President Obama’s executive approach to reducing carbon dioxide emissions from coal-fired power plants has been more effective than the legislative approach of the Clinton administration. The study will indicate that a scientific consensus about anthropogenic global warming and the political will to reduce greenhouse gas emissions from coal-fired power plants did not exist during the 1990s. The study also shows that, despite the effectiveness of the Obama administration in reducing carbon dioxide emissions, there are many problems with the executive approach to the problem. The study suggests that the Clean Air Act has ceded to much legislative power to the Executive branch of government, and that success in reducing carbon dioxide emissions from coal-fired power plants is too dependent on the will of the Executive.

A study was initiated in 1981 to investigate the redevelopment of plant communities on a recontoured, surface-mined site in southwestern Wyoming. The landscape pattern of vegetation was compared with topographic position, the initial topsoil pattern, and cultural practices including shrub planting density, shrub planting pattern and topsoil treatments for the years 1982-1985. In addition, differences in vascular plant species diversity within these various factors and treatments were determined, along with the trend in intracommunity (alpha), intercommunity (beta) and landscape (gamma) diversity for the entire study area. The influence of site factors and tested cultural practices on the differentiation of the landscape vegetation pattern generally declined over time. There were no persistent differences in diversity among any cultural treatments or topographic positions, with the exception of plan ting pattern. The vegetation classified by cultural treatment, topographic position, or the initial plant comm uni ties identified in 1982 showed strong successional convergence by 1985. This is reflected in a decline in be ta and gamma diversity over the period 1984-1985. Alpha diversity remained stable over this same period, though species richness increased, indicating that a subset of species is becoming more dominant. The landscape vegetation pattern apparently converged to a rather uniform composition, increasingly dominated by perennial grasses, forbs and shrubs.