The objectives of this study were to determine how seed reserves varied with depth in topsoil stockpiles and to evaluate the effect of length of time of storage on the number of viable seeds and number of species of seeds. Soil samples were taken from five topsoil piles representing zero to three years of storage on the Elkol-Sorenson mine near Kemmerer in southwestern Wyoming. Seeds were extracted using flotation/separation methods and were tested for viability using 2,3,5-triphenyl tetrazolium chloride solution. Data were analyzed using nonparametric statistical tests. Overall density of seeds in topsoil piles was low. No relationship was found between depth into the topsoil pile and the number of seeds or species. The number of seeds and species in the topsoil pile showed no decrease with increasing length of time of storage. The proportion of annual species in the seed reserve was not shown to increase with length of time of storage. Comparisons were made between the species composition of the seed reserve in the topsoil piles and the species composition of vegetation on sites selected to represent the sites of origin of the topsoil. Factors affecting the density, species composition and species richness of stored topsoil were suggested to be the plant community on the soil to be removed, depth of soil removed, and timing of topsoil removal.

The subsidence characteristics of the Collie Basin sediments have been investigated to provide site specific design criteria for the Wongawilli method of coal extraction. As historical coal extraction (bord and pillar) methods did not generally give rise to large scale subsidence, there were very few details on mining subsidence in the Collie Basin available to base any design methodology on. Consequently, the investigation was conducted on a Green fields basis. Firstly, the mechanisms involved in the development of mining subsidence needed to be investigated and identified. It was then necessary to determine the effects that mining subsidence would have on mine and ground mass (specifically aquitards) structures and surface features. Once these two areas of work were completed, design criteria were formulated to manage the effects of mining subsidence by controlling the critical mechanisms of subsidence development.The results from this study have greatly enhanced the level of understanding of the subsidence mechanisms involved, and allowed for the development of predictive models which can be used for the design of coal extraction by the panel/pillar mining method in the Collie Basin. Mine planning engineers can now use this design information to derive the most cost effective methods for the extraction of coal within the Collie Basin.

Mathematical models were developed to understand cavity growth mechanisms, heat and mass transfer in combination with chemical reaction, and the factors which affect gas production from an underground coal gasifier. A model for coal gasification in a one-dimensional spatial domain was developed and validated through comparison with experimental measurements of the pyrolysis of large coal particles and cylindrical coal blocks. The effects of changes in operating conditions and coal properties on cavity growth were quantified. It was found that the operating conditions which have the greatest impact on cavity growth are: temperature, water influx, pressure and gas composition, while the coal properties which have the greatest impact are: the thermo-mechanical behaviour of the coal, the coal composition and the thickness of the ash layer. Comparison of the model results with estimates from field scale trials, indicate that the model predicts growth rates with magnitudes comparable to those observed. Model results with respect to the effect of ash content, water influx and pressure are in agreement with trends observed in field trials. A computational fluid dynamics model for simulating the combined transport phenomena and chemical reaction in an underground coal gasification cavity has been developed. Simulations of a two-dimensional axi-symmetric cavity partially filled with an inert ash bed have shown that when the oxidant is injected from the bottom of the cavity, the fluid flow in the void space is dominated by a single buoyancy force due to temperature gradients established by the combustion of volatiles produced from the gasification of carbon at the cavity walls. Simulations in which the oxidant was injected from the top of the cavity reveal a weak fluid circulation due to the absence of strong buoyancy forces, leading to poor gasification performance. A channel model of gas production from underground coal gasification was developed, which incorporates a zero-dimensional cavity growth model and mass transfer due to natural convection. A model sensitivity study is presented and model simulations elucidate the effects of operating conditions and coal properties on gas production.

As carbon dissolution rates have been determined for a few chars only, a systematic and comprehensive study was undertaken in this project on the dissolution behaviour of carbon from non-graphitic materials into liquid iron. In addition to measuring the kinetics of carbon dissolution from a number of coal chars into liquid iron as a function of parent coal and coal ash composition, the influence of chemical reactions between solute/solid carbon and ash oxides was also investigated. These studies were supplemented with investigations on one metallurgical coke for the sake of comparison. The wettability of coal chars and coke with liquid iron at 1550 degrees C was measured as a function of time. Being essentially non-wetting, only a marginal improvement in contact angles was observed with time. The accumulation of alumina at the interface was detected for all materials and was seen to increase with time in all cases. Calcium and sulphur also appeared to preferentially accumulate at the interface, concentrating at levels in excess of those expected from the ash composition alone. Despite the high levels of silica in the ash initially, very little silica was detected in the interfacial region, implying ongoing silica reduction reactions. A small amount of silicon was however detected in the iron droplets, indicating silica reduction with solute carbon. It was identified that the reduction reactions can also consume solute carbon in the liquid iron. As this is occurring simultaneously with carbon dissolution into liquid iron, the interdependency of silica reduction and carbon dissolution could potentially limit the observed carbon dissolution rate. A theoretical model was developed for estimating the interfacial contact area between chars and liquid iron. Wettability was found to have a very significant effect on the area of contact. A two-step behaviour was observed in the carbon dissolution of two chars and coke. Slow rates of carbon dissolution in stage II were attributed to very high levels of interfacial blockage by reaction products leading to much reduced areas of contact between carbonaceous material and liquid iron. The first order dissolution rate constants for four chars/coke and the observed trend in first order dissolution rate constants were calculated. These dissolution results compare well with the previously measured dissolution rate constants. The trends in dissolution can be adequately explained on the basis of carbon structure, silica reduction, sulphur concentration in the metal and ash impurities.

In Victoria, Australia, brown coal is utilised as a major source of energy for the power generation industry. Victorian and South Australian brown coals have a very high moisture content and therefore, the efficiencies of power generation in traditional pulverised fuel fired furnaces are low. Fluidised beds offer a number of advantages over conventional furnaces, leading to improvements in efficiency and environmental impact. A disadvantage with implementing fluidised bed technology is the issue of scale-up. Fluidised bed behaviour can alter significantly with changes in scale, because of their strong dependence on the bed hydrodynamics. Hence, there is a need to accurately model bed behaviour to ensure that the effect of changes in scale are well understood and will not become costly and time consuming. Computational Fluid Dynamics (CFD) techniques can be applied to fluidised bed systems to gain a better understanding of the hydrodynamic behaviour involved. In the past, numerical models have considered only single particle sizes due to the added complexity of interaction between particles of differing sizes and densities. Industrial fluidised beds typically contain more than one particle size and density, therefore there is a need to develop a numerical model which takes this into account. The aim of this thesis is to develop and validate CFD techniques for modelling the behavior of a gas-solid fluidised bed containing more than one particle size and density. To provide validation data for the numerical model, physical experiments are undertaken on a small two-dimensional bubbling gas-solid fluidised bed. Mixing and segregation behaviour of different materials are investigated. The experiments demonstrate that whilst only a small proportion of the bed consists of different size/density particles, significant changes in bed behaviour are apparent. Changes in bubble rise velocity, bubble size and bubble shape are observed. A number of constitutive equations must be included in the numerical model, including relationships for the momentum transfer between various phases and solids pressure. Different combinations of these constitutive equations are investigated. A new equation for particle-particle interactions is derived and included in a CFD model. The CFD model is validated against both data in the literature and physical experiments. From the validation studies, an optimum equation set is identified. This optimum equation set produces numerical results that closely resemble experimental bed behaviour, thus bringing the goal of solving scale-up problems one step closer. The use of this type of CFD model will ultimately result in timely and cost effective solutions for both the power generation and chemical processing industries.

Includes an addendum. / Bibliography : leaves 217-233. / iii, 284 leaves : ill. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Chemical Engineering, 1994

Geological carbon sequestration, as a method of atmospheric greenhouse gas reduction, is at the technological forefront of the climate change movement. During sequestration, carbon dioxide (CO���) gas effluent is captured from coal fired power plants and is injected into a storage saline aquifer or depleted oil reservoir. In an effort to fully understand and optimize CO��� trapping efficiency, the capillary trapping mechanisms that immobilize subsurface CO��� were analyzed at the pore-scale. Pairs of proxy fluids representing the range of in situ supercritical CO��� and brine conditions were used during experimentation. The two fluids (identified as wetting and non-wetting) were imbibed and drained from a flow cell apparatus containing a sintered glass bead column. Experimental and fluid parameters, such as interfacial tension, fluid viscosities and flow rate, were altered to characterize their relative impact on capillary trapping. Computed x-ray microtomography (CMT) was used to identify immobilized CO��� (non-wetting fluid) volumes after imbibition and drainage events. CMT analyzed data suggests that capillary behavior in glass bead systems do not follow the same trends as in consolidated natural material systems. An analysis of the disconnected phases in both the initial and final flood events indicate that the final (residual) amount of trapped non-wetting phase has a strong linear dependence on the original amount of non-wetting phase (after primary imbibition), which corresponds to the amount of gas or oil present in the formation prior to CO��� injection. More importantly, the residual trapped gas was also observed to increase with increasing non-wetting fluid phase viscosity. This suggests that CO��� sequestration can be optimized in two ways: through characterization of the trapped fluid present in the formation prior to injection and through alterations to the viscosity of supercritical CO2. / Graduation date: 2013

Thesis (Ph.D. (Environmental Science)--North-West University, Potchefstroom Campus, 2007.

<p>It was hypothesized that South African FA and brine could sequester CO2 through mineral carbonation. A statistical approach was undertaken to optimize the % CaCO3 formed from FA/brine/CO2 interaction with input parameters of temperature, pressure, particle size and solid/liquid ratio (S/L) being varied. The ranges adopted for the input parameters were: temperature of 30 &ordm / C or 90 &ordm / C / pressure of 1 Mpa or 4 Mpa / four particle sizes namely bulk ash, &gt / 150 &mu / m, &lt / 20 &mu / m and 20 &mu / m- 150 &mu / m particle size range / S/L ratios of 0.1, 0.5 or 1. The FA/ brine dispersions were carbonated in a high pressure reactor varying the above mentioned input parameters. The fresh Secunda FA of various size fractions was characterized morphologically using scanning electron microscopy, chemically using X-ray fluorescence and mineralogically using qualitative X-ray diffraction. The carbonated solid residues on the other hand were characterized using quantitative X-ray diffraction, scanning electron microscopy, thermal gravimetic analysis and Chittick tests. The raw brine from Tutuka together with the carbonation leachates were characterized using inductively coupled mass spectrometry and ion chromatography. Total acid digestion was carried out to evaluate the differences in the total elemental content in both the fresh ash and the carbonated solid residues. The results suggested that South African FA from Secunda belongs to class F based on the CaO content as well as the total alumina, silica and ferric oxide content, while the RO brine from Tutuka were classified as NaSO4 waters...</p>

This dissertation contends that efforts to reduce air pollution in Birmingham, Alabama, from the 1940s through the early 1970s relied on citizens who initially resisted federal involvement but eventually realized that they needed Washington's help. These activists had much in common with clean air groups in other U.S. cities, but they were somewhat less successful because of formidable industrial opposition. In the 1940s the political power of the Alabama coal industry kept Birmingham from following the example of cities that switched to cleaner-burning fuels. The coal industry's influence on Alabama politics had waned somewhat by the late 1960s, but U.S. Steel and its allies wielded enough political power in 1969 to win passage of a weak air pollution law over one favored by activists. Throughout this period the federal government gradually increased its involvement in Alabama's air pollution politics, culminating in the late 1960s and early 1970s with the enactment of environmental laws that empowered federal officials to pressure Alabama to pass a revised 1971 air pollution law that met national standards. After the passage of this law, but before the appointment of an air pollution control board to enforce it, a federal judge temporarily shut down Birmingham-area industries at the request of the Environmental Protection Agency, the first time that the agency had used such emergency powers. Over time, grassroots activists in Birmingham came to the realization that their efforts were doomed to fail, or at least to be significantly delayed, without the aid of the federal government. For nearly twenty-five years after the enactment of the 1945 smoke ordinance, supporters of air pollution control wanted the state government to deal with the problem of air pollution, with the federal government only providing technical expertise and funding for scientific research. But with their defeat in the 1969 legislative session, when the industry-backed air pollution bill passed, clean air campaigners in Alabama realized--and publicly stated--that only pressure from Washington would force Montgomery to clean up Alabama's air.