The present study investigates experimentally the laminar mixing and heat transfer of a range of helical ribbon and anchor impellers for both Newtonian and inelastic non-Newtonian fluids. The work also correlates the experimental data empirically in the form of dimensionless groups. In order to estimate the relative importance and the effect of all the geometrical parameters on the mixing power and heat transfer, data from the published literature sources will be utilized and combined with the results from this study. Thus, reliable empirical correlations will be obtained which are applicable over the widest range of operating conditions. The study also investigates the ablity of the various impellers to level out temerature distributions. The measurement of these temperature gradients and the impeller power requirements gives a measure of the mixing efficiency of the impeller used.

Orientador: Geraldo de Freitas Maciel / Resumo: No contexto de Desastres "Naturais", as corridas de lama têm sido objeto de estudo devido ao seu poder erosivo e, muitas vezes, destrutivo, acarretando perdas materiais vultosas e ceifando vidas. Nestes escoamentos, quando em condições favoráveis de vazão, inclinação e reologia do fluido, podem surgir instabilidades que se propagam em forma de trem de ondas na superfície, denominadas roll waves. A literatura acerca do assunto trata, geralmente, dos critérios de geração, estabilidade, e determinação das características principais do fenômeno, como amplitude, comprimento e celeridade de onda. Nesta dissertação buscou-se estudar a tensão de cisalhamento no fundo na presença de roll waves, em duas vertentes: a primeira apresenta as roll waves em água limpa, baseando-se no trabalho clássico de Dressler (1949); a segunda, dando continuidade aos trabalhos do Grupo de Pesquisa de Reologia de Materiais Viscosos e Viscoplástcos (Grupo RMVP), focou no estudo de roll waves desenvolvendo-se em fluidos do tipo Herschel-Bulkley, em duas situações - canal de fundo impermeável e fundo com condição de permeabilidade, grande contribuição desta dissertação. Os modelos matemáticos foram desenvolvidos com base nas equações de águas rasas, cuja implementação numérica permitiu confrontar resultados experimentais e numéricos, que apresentaram boa aderência. Para o modelo com condição de permeabilidade no fundo, verificou-se a influência do fator de porosidade nas características das roll waves (ampli... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Mudflows have been the focus of studies because of their erosive ability and often destructive power, causing material losses and taking away lives. Under favorable conditions of discharge, slope, disturbance, and rheology, these flows can develop a specific type of instability that is propagated downstream as shock waves, called roll waves. Most of the roll waves literature provides information on generation criteria, stability, and information of amplitudes, wavelengths, and celerity. This works brings a study of bottom shear stress in pulsating flows (roll waves) in 2 parts. In the first part, we present roll waves in clean water, based on Dressler’s work. In the second part, we continue the works of research team about roll waves developing in Herschel-Bulkley fluid under 2 conditions: impermeable bottom and porous bed. The mathematical models developed were based on shallow water equations. The results of these models were compared to Fluent and experimental results, showing a good agreement. For the mathematical model with porous bed condition, we evaluated the effect of porosity factor in properties of roll waves, and we observed that the amplitude of the roll wave usually increases, whereas the length and the celerity decrease with the presence of this factor. Finally, considering an impermeable bottom, the bottom shear stress presented an increase of 12% to 27%, depending on nature (laminar-turbulent) and dynamics (Froude number) of flow. Taking in account a porous b... (Complete abstract click electronic access below) / Mestre

Cette thèse a pour objet le développement d’un modèle de transport sédimentaire avec la méthode SPH (Smoothed Particle Hydrodynamics). Si les modèles couramment proposés dans la littérature reposent sur un solveur hydrodynamique couplé à des lois semi-empiriques qui modélisent le transport sédimentaire, une approche différente est proposée ici. Dans le modèle proposé dans ce travail, la dynamique du sédiment est également résolue. Celui-ci est assimilé à un milieu continu dont la loi de comportement rend compte de la nature granulaire.Pour ce faire, le modèle élastique-viscoplastique d’Ulrich (2013) a été implémenté dans un code SPH préexistant programmé en langage Cuda, et amélioré du point de vue physico-numérique. Le comportement mécanique du sédiment dépend donc d’une contrainte de rupture déterminée conformément au critère de Drucker-Prager. Dans les zones du matériau où la rupture n’a pas eu lieu, les contraintes de cisaillement sont calculées selon la loi de Hooke généralisée. Dans les zones où la contrainte de rupture a été dépassée, le matériau est assimilé à un fluide rhéofluidifiant. Numériquement, la transition entre les deux états est opérée à l’aide d’une fonction de raccord qui dépend notamment du l’amplitude du taux de déformation et des propriétés granulaires du sédiment.L’eau et le sédiment sont modélisées comme deux phases immiscibles, dans le cadre d’une formulation SPH multi-phase. Pour ce faire, le modèle de Hu et Adams (2006) a été adapté aux modèles de conditions limites semi-analytiques (Ferrand, 2013). Enfin, un schéma d’intégration implicite des forces visqueuses a été développé dans ce contexte, afin d’améliorer les performances du solveur lors de modélisation d’écoulement à bas Reynolds.Plusieurs cas tests sont proposés pour valider le modèle multiphasique, le schéma implicite et le modèle élastique-viscoplastique. De manière générale, les résultats sont en bon accord avec les données expérimentales et analytiques. Le modèle permet de représenter des écoulements multi-fluide avec une bonne précision, même en présence de grand rapport de densité entre les phases. Il en va de même pour les écoulements de fluide non-newtonien et les écoulements à bas Reynolds, pour lesquels le schéma implicite conduit à des résultats très satisfaisants. Enfin, le modèle élastique-viscoplastique a été appliqué à divers cas d’écoulements granulaires, dans le cas d’un matériau sec et saturé, ainsi qu’à des cas d’érosion et d’affouillement. Là encore, les résultats sont globalement en bon accord avec l’expérience / This thesis presents the development and application of a Smoothed Particle Hydrodynamics (SPH) model to bed-load transport. While state of the art simulation methods commonly rely on a fluid dynamics solver coupled to semi-empirical relationships to model the sediment transport, a completely different approach is investigated in this work. The sediment is treated as a continuum whose behaviour law takes account for its granular nature. citepos{ulrich2013smoothed} elastic-viscoplastic model is thus implemented in an in-house code based on the Cuda language, and improved on physical and numerical aspects. The sediment behaviour depends on a yield stress determined according to Drucker-Prager's criterion. In unyielded regions, the shear stresses are calculated in line with the linear elastic theory. In yielded regions, a shear thinning rheological law is used and the transitions between solid and liquid states are ensured by a blending function driven by the strain rate magnitude and sediment granular properties. Water and sediment are modelled as two immiscible phases in the frame of a multi-phase SPH model with semi-analytical wall boundary conditions cite{ferrand2013unified}. An implicit viscous forces integration scheme is also developed to improve the code performance as for low-Reynolds flows.The multi-phase model, as well as the implicit viscous forces integration scheme, were validated on analytical test cases and good agreement was obtained. The multi-phase formulation has also proven its capability to handle flows involving high density ratio, while the implicit viscous forces integration scheme was successfully applied to the simulation of a non-Newtonian flow. The elastic-viscoplastic model was tested on dry and submerged granular flow problems. The model was able to correctly capture the liquid and solid states of the granular material, as well as the failure and the regime transitions. It was also applied to bed-load transport problems for which a good agreement with the experiment was generally found

Este trabalho tem como propósito investigar como a variação geométrica de determinados parâmetros envolvidos na construção de uma geometria bifurcada de seção circular, em forma de Y, afeta a resistência ao escoamento, tanto de fluidos newtonianos como não newtonianos. As geometrias estudadas foram construídas utilizando-se o princípio do Design Construtal. Os parâmetros variados foram a relação entre os comprimentos dos dutos pais e filhos, a relação entre os diâmetros dos mesmos dutos, e o ângulo central da estrutura em forma de Y. Para as relações geométricas lineares foram utilizados os valores de 0,5; 0,6; 0,7; 0,8; 0,9 e 1, enquanto para os ângulos, foram utilizados os valores de 155°, 135°, 115°, 95°, 75°, 45°, 25° e 10°. Os fluidos utilizados foram do tipo newtoniano e não newtoniano, dentre estes últimos, foram estudados fluidos pseudoplásticos e dilatantes. O trabalho foi realizado através de simulações numéricas, implementadas com a utilização do software comercial Ansys Fluent, o qual resolve as equações governantes através do método dos volumes finitos. As malhas utilizadas foram do tipo poliédrica. Os resultados indicam que há uma diferença em relação ao que se espera da literatura para as relações entre os diâmetros e os comprimentos. A Lei Hess-Murray indica que estas relações ótimas seriam de 2-1/3 para as relações entre os diâmetros e comprimentos. No presente trabalho, foram determinadas relações entre os diâmetros próximas de 0,6, e entre os comprimentos, iguais a 1. Os ângulos ótimos ficaram localizados no intervalo entre 100° e 135°. / This work aims to investigate how the geometric variation of certain parameters involved in the construction of a bifurcated Y-shaped circular cross-section geometry affects the flow resistance of both Newtonian and non-Newtonian fluids. The geometries studied were constructed using the Constructal Design principle. The parameters were the relationship between the lengths of the daughter and parent ducts, the relationship between the diameters of the same ducts, and the central angle of the Y-shaped structure. For the linear geometric relations, values of 0.5; 0.6; 0.7; 0.8; 0.9 and 1 where used, for the angles, the values of 155 °, 135 °, 115 °, 95°, 75 °, 45 °, 25 ° and 10 ° were used. The fluids used were of the Newtonian and non-Newtonian type, among the latter, pseudo plastic and dilatant fluids were studied. The work was carried out through numerical simulations, implemented with the commercial software Ansys Fluent, which solves the governing equations through the finite volume method. The meshes used were of the polyhedral type. The results indicate that there is a difference in relation to what is expected from the literature for the relationships between diameters and lengths. The Hess-Murray Law indicates that these optimal relations would be 2-1/3 for the relationships between diameters and lengths. In the present work, relationships between the diameters close to 0,6 were found and s equal to 1 between the lengths. The optimum angles were located in the range between 100 ° and 135 °.

Many cells exploit the bending or rotation of flagellar filaments in order to self-propel in viscous fluids. Often swimming occurs in complex, nonlinear fluids, e.g. mucus. Futhermore even in simple Newtonian fluids, if swimming appendages are deformable then locomotion is subject to fluid-structure interactions. The fundamental question addressed in this thesis is how exactly locomotion is impacted, in particular if it is faster or slower, with or without these effects. First we study locomotion in shear-thinning and viscoelastic fluids with rigid swimming appendages. Following the introductory Chapter, in Chapter 2 we propose empirical extensions of the classical Newtonian resistive-force theory to model the waving of slender filaments in non-Newtonian fluids, based on experimental measurements for the motion of rigid rods in non-Newtonian fluids and on the Carreau fluid model. We then use our models to address waving locomotion in shear-thinning fluids, and show that the resulting swimming speeds are systematically lowered a result which we are able to capture asymptotically and to interpret physically. In Chapter 3 we consider swimming using small-amplitude periodic waves in a viscoelastic fluid described by the Oldroyd-B constitutive relationship. Using Taylor’s swimming sheet model, we show that if all travelling waves move in the same direction, the locomotion speed of the organism is systematically decreased. However, if we allow waves to travel in two opposite directions, we show that this can lead to enhancement of the swimming speed, which is physically interpreted as due to asymmetric viscoelastic damping of waves with different frequencies. A change of the swimming direction is also possible. Secondly we consider the affect of fluid-structure interactions. In Chapter 4, we use Taylor’s swimming sheet model to describe an active swimmer immersed in an Oldroyd-B fluid. We solve for the shape of an active swimmer as a balance between the external fluid stresses, the internal driving moments, and the passive elastic resistance. We show that this dynamic balance leads to a generic transition from hindered rigid swimming to enhanced flexible locomotion. The results are physically interpreted as due to a viscoelastic suction increasing the swimming amplitude in a non-Newtonian fluid and overcoming viscoelastic damping. In Chapter 5 we consider peritrichously flagellated bacteria, such as Escherichia coli. The rotation of each motor is transmitted to a flexible rod called the hook which in turns transmits it to a helical filament, leading to swimming. The motors are randomly distributed over the body of the organism, and thus one expects the propulsive forces from the filament to almost cancel out leading to negligible swimming. We show that the transition to swimming is an elasto-hydrodynamic instability arising when the flexibility of the hook is below a critical threshold.

Extraction processes employing emulsion liquid membranes (ELMs), water-in-oil emulsions dispersed in aqueous phase, have been shown to be highly efficient in removing a variety of organic and inorganic contaminants from industrial wastewaters. As a result, they have been considered as alternative technologies to other more common separation processes such as pressure-driven membrane processes. Unfortunately, a widespread use of the ELM process has been limited due to the instability of emulsion globules against fluid shear. Breakup of emulsions and subsequent release of the internal receptor phase to the external donor phase would nullify the extraction process. Numerous studies have been, therefore, made in the past to enhance the stability of ELMs. Examples include adding more surfactants into the membrane phase and increasing the membrane viscosity. However, increased stability has been unfortunately accompanied by loss in extraction efficiency and rate in most reported attempts. The primary objective of this research is to apply the ELMs in a unique contacting device, a Taylor-Couette column, which provides a relatively low and uniform fluid shear that helps maintaining the stability of emulsion without compromising the extraction efficiency of a target compound. The ELM used in this study is made of membrane phase converted into non-Newtonian fluid by polymer addition, which provides additional uncommon remedy for the problem. This innovative ELM process was optimized to treat various types of simulated industrial wastewaters containing selected phenolic compounds and heavy metals. Experiments performed in this study suggested that the newly developed ELM process achieved exceptionally high overall removal efficiencies for the removal of these target compounds in relatively short contact time. Mechanistic predictive models were further developed and verified with the experimental data. Combined with the experimental data and novel mathematical predictive models, this study is expected to have a high impact on immediate practices of emulsion liquid membrane technologies in relevant industries.

Mixing is a crucial process for many large scale and small scale applications from food industry to cosmetics, from drug industry to petrochemical processes, etc. Changes in parameters (temperature, viscosity, velocity distribution, etc.) during the mixing affect the production process and the end product quality and the cost. Thus, these parameters, mostly the hydrodynamic parameters, should be monitored closely during the process. In order to ensure good and efficient mixing in the solution, high degree of turbulence is maintained while dead zones in the tank should be avoided. In chemical industry, the mixing processes generally involve complex solutions that exhibit non-Newtonian flow behavior that merits a study on the agitation hydrodynamics and mixing time. Thus, in this study agitation of carboxymethyl cellulose (CMC) solution in a laboratory scale mixing tank is investigated. The effects of CMC concentration and agitation speed on the hydrodynamics of the solution and mixing time are studied in detail. CMC concentrations studied are 0.5 wt%, 1 wt% and 2 wt%. Impeller speeds, on the other hand, are set as 150 rpm, 300 rpm and 600 rpm. The hydrodynamics of mixing can be studied easily by Ultrasound Doppler Velocimetry (UDV) which is a fast, non-invasive measuring technique in fluid dynamics. Also, the mixing time measurements were carried out through electrical conductivity of the agitated solution. UDV results show that the flow field has a typical pattern produced by the Rushton turbine. The main characteristics of the flow are that, in the impeller region radial components of the flow dominate. Near the wall flow occurs mainly in the axial direction towards the top and bottom of the tank. Mixing time measurements reveal that mixing time increases with decreasing impeller speed and with increasing solution concentration (i.e. viscosity). Typical mixing time values are in the range of 250-2600 seconds for different impeller speeds and CMC concentrations.

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The goal of this thesis is to study the ground or metastable state structure of nematic liquid crystal systems confined inside handled shapes such as a torus or double torus. We begin our work by introducing a new method to generate a toroidal droplet from a Newtonian liquid inside another, immiscible, Newtonian liquid. In this situation, a toroidal droplet is unstable and follows one of two routes in transforming into a spherical droplet: (i) its tube breaks in a way reminiscent to the breakup of a cylindrical jet, or (ii) its tube grows until it finally coalesces onto itself. However, to be able to probe the nematic structure, we need to address the issue of instabilities. This is done by replacing the outer liquid with a yield stress material, which ultimately leads to the stabilization of the toroidal droplet. Through the experimental investigation, we are able to establish the stabilization conditions. Finally, we generate and stabilize toroidal droplets with a nematic liquid crystal as the inner liquid and a yield stress material as the outer medium. Here we observe that in the ground state, the nematic liquid crystal exhibits an intriguing twisted structure irrespective of the aspect ratio of the torus. While there are no defects observed in a toroidal droplet case, two defects with -1 topological charge each emerge each time we increase the number of handles.

Este trabalho tem como propósito investigar como a variação geométrica de determinados parâmetros envolvidos na construção de uma geometria bifurcada de seção circular, em forma de Y, afeta a resistência ao escoamento, tanto de fluidos newtonianos como não newtonianos. As geometrias estudadas foram construídas utilizando-se o princípio do Design Construtal. Os parâmetros variados foram a relação entre os comprimentos dos dutos pais e filhos, a relação entre os diâmetros dos mesmos dutos, e o ângulo central da estrutura em forma de Y. Para as relações geométricas lineares foram utilizados os valores de 0,5; 0,6; 0,7; 0,8; 0,9 e 1, enquanto para os ângulos, foram utilizados os valores de 155°, 135°, 115°, 95°, 75°, 45°, 25° e 10°. Os fluidos utilizados foram do tipo newtoniano e não newtoniano, dentre estes últimos, foram estudados fluidos pseudoplásticos e dilatantes. O trabalho foi realizado através de simulações numéricas, implementadas com a utilização do software comercial Ansys Fluent, o qual resolve as equações governantes através do método dos volumes finitos. As malhas utilizadas foram do tipo poliédrica. Os resultados indicam que há uma diferença em relação ao que se espera da literatura para as relações entre os diâmetros e os comprimentos. A Lei Hess-Murray indica que estas relações ótimas seriam de 2-1/3 para as relações entre os diâmetros e comprimentos. No presente trabalho, foram determinadas relações entre os diâmetros próximas de 0,6, e entre os comprimentos, iguais a 1. Os ângulos ótimos ficaram localizados no intervalo entre 100° e 135°. / This work aims to investigate how the geometric variation of certain parameters involved in the construction of a bifurcated Y-shaped circular cross-section geometry affects the flow resistance of both Newtonian and non-Newtonian fluids. The geometries studied were constructed using the Constructal Design principle. The parameters were the relationship between the lengths of the daughter and parent ducts, the relationship between the diameters of the same ducts, and the central angle of the Y-shaped structure. For the linear geometric relations, values of 0.5; 0.6; 0.7; 0.8; 0.9 and 1 where used, for the angles, the values of 155 °, 135 °, 115 °, 95°, 75 °, 45 °, 25 ° and 10 ° were used. The fluids used were of the Newtonian and non-Newtonian type, among the latter, pseudo plastic and dilatant fluids were studied. The work was carried out through numerical simulations, implemented with the commercial software Ansys Fluent, which solves the governing equations through the finite volume method. The meshes used were of the polyhedral type. The results indicate that there is a difference in relation to what is expected from the literature for the relationships between diameters and lengths. The Hess-Murray Law indicates that these optimal relations would be 2-1/3 for the relationships between diameters and lengths. In the present work, relationships between the diameters close to 0,6 were found and s equal to 1 between the lengths. The optimum angles were located in the range between 100 ° and 135 °.