Thesis (S.M.)--Joint Program in Marine Geology and Geophysics (Massachusetts Institute of Technology, Dept. of Civil and Environmental Engineering; and the Woods Hole Oceanographic Institution), 2012. / Cataloged from PDF version of thesis. / Includes bibliographical references (p. 77-79). / This study describes the spatial distribution of sediment deposition in the wake of a circular patch of model vegetation and the effect of the patch on turbulence and mean flow. Two difference types pf vegetation were used along with two different stem densities totaling four different case studies. The spatial location of enhanced deposition correlated with the steady wake zone, which has length, L1. The steady wake zone only occurred downstream of the rigid emergent patches of vegetation and was not seen downstream of the flexible submerged patches of vegetation. The enhanced deposition occurred when both turbulence and mean velocity was below the upstream, initial values. The enhanced deposition occurred when the mean velocity was less than or equal to half of the initial velocity. For the four cases studied, theses parameters of low velocity and low turbulence were primarily met within the steady wake region immediately downstram of the two rigid emergent patches of vegetation. In all four cases, large coherent structures are created in the flow due to the patch. Lateral vortices are formed downstream of the patch in a von-Karman vortex street that meets at the center of the flow a distance, Lw, downstream of the patch. For the flexible submerged cases, streamlines reattach to the bed of the flume a distance, Lv, downstream of the patch. In addition, for the flexible submerged cases, a secondary circulation is generated with flow moving laterally away from the patch at the surface and toward the centerline of the patch at the bed. / by Alejandra C. Ortiz. / S.M.

Thesis: Ph. D., Joint Program in Chemical Oceanography (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2015. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Fifty-six million years ago Earth experienced rapid global warming (~6°C) that was caused by the release of large amounts of carbon into the ocean-atmosphere system. This Paleocene-Eocene Thermal Maximum (PETM) is often cited as an analogue of anthropogenic climate change. Many trigger mechanisms for the carbon release at the PETM have been proposed. Common to all scenarios is rapid release of isotopically light carbon (<¹³C/¹²C values) from methane hydrates, terrestrial or marine organic matter, as indicated by a pronounced excursion to light carbon isotope values across the PETM. I test the hypothesis that the PETM warming and isotope excursion were caused by the intrusion of a magmatic sill complex into organic-rich sediments in the North Atlantic. The intrusion of magma into sedimentary rocks will cause heating and metamorphic reactions in a thermal aureole around the intrusion. If these sediments are rich in organic matter, large volumes of isotopically light carbon are rapidly released. I examine geochemical evidence from lead, osmium, and organic carbon to place constraints on the extent the carbon isotope excursion during the PETM may have been caused by contact metamorphism of organic-rich sediments. Potential terrestrial and submarine analogs are examined to determine the behavior of these elements during thermal alteration. Furthermore, geochemical evidence from sediment cores at the PETM provides additional information about what might have caused the carbon isotope excursion. I find that lead is not a suitable proxy for carbon mobilization to the overlying seawater during contact metamorphism. Osmium, however, is mobilized together with carbon. Making reasonable assumptions for the ¹⁸⁷Os/¹⁸⁸Os of the sediments from the North Atlantic Magmatic Province (NAMP), constrained by the ¹⁸⁷Re/¹⁸⁸Os of organic-rich sediments and the depositional age of the sediment, the entire marine osmium isotope anomaly at the PETM could be explained without the need to invoke enhanced continental weathering. Based on estimates of the extent of mobilization of organic carbon relative to osmium, approximately 47% to 60% of the carbon released at the PETM may have been derived from thermal alteration of organic-rich sediments in the NAMP. / by Andrea Rose Dubin. / Ph. D.

Thesis: Ph. D., Joint Program in Oceanography (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2016. / Page 231 blank. Cataloged from PDF version of thesis. / Includes bibliographical references. / Marine microbes produce a wide variety of metal binding organic ligands that regulate the solubility and availability of biologically important metals such as iron, copper, cobalt, and zinc. In marine environments where the availability of iron limits microbial growth and carbon fixation rates, the ability to access organically bound iron confers a competitive advantage. Thus, the compounds that microbes produced to acquire iron play an important role in biogeochemical carbon and metal cycling. However, the source, abundance, and identity of these compounds are poorly understood. To investigate these processes, sensitive methodologies were developed to gain a compound-specific window into marine iron speciation by combining trace metal clean sample collection and chromatography with inductively coupled plasma mass spectrometry (LCICPMS) and electrospray ionization mass spectrometry (LC-ESIMS). Coupled with isotope pattern assisted search algorithms, these tools provide a means to quantify and isolate specific iron binding ligands from seawater and marine cultures, identify them based on their mass and fragmentation spectra, and investigate their metal binding kinetics. Using these techniques, we investigated the distribution and diversity of marine iron binding ligands. In cultures, LC-ICPMS-ESIMS was used to identify new members of siderophore classes produced by marine cyanobacteria and heterotrophic bacteria, including synechobactins and marinobactins. Applications to natural seawater samples from the Pacific Ocean revealed a wide diversity of both known and novel metal compounds that are linked to specific nutrient regimes. Ferrioxamines B, E, and G were identified in productive coastal waters near California and Peru, in oligotrophic waters of the North and South Pacific Gyre, and in association with zooplankton grazers. Siderophore concentrations were up to five-fold higher in iron-deficient offshore waters (9pM) and were dominated by amphibactins, amphiphilic siderophores that partition into cell membranes. Furthermore, synechobactins were detected within nepheloid layers along the continental shelf. These siderophores reflect adaptations that impact dissolved iron bioavailability and thus have important consequences for marine ecosystem community structures and primary productivity. The ability to map and characterize these compounds has opened new opportunities to better understand mechanisms that link metals with the microbes that use them. / by Rene M. Boiteau. / Ph. D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2005. / Includes bibliographical references. / This thesis uses trace elements and radiogenic isotope tracers to define elemental abundances in reservoirs of the Earth's mantle, including EM2 (the Enriched Mantle 2), as seen in the Samoan hotspot track, and DMM (the depleted upper mantle), which is sampled at mid-ocean ridges. Together these components comprise up to [approx.] 50% of the total mantle mass. Much of the mantle's chemical heterogeneities are suspected to originate by either the removal of mass from the mantle (in the case of DMM) or the addition of mass to the mantle through subduction zones (in the case of EM2). We show that DMM represents mantle that 1) has been previously depleted by 2-3% melt removal, 2) mass-balances well with the continental crust, 3) has only 15% of the radiogenic heat production in primitive upper mantle and 4) can generate present-day ocean crust by 6% aggregated fractional melting. EM2 is classically interpreted as mantle material enriched in trace elements through the ancient, subduction-zone recycling of terrigenous sediments; here we show this model is unlikely and provide two other working hypotheses. / (cont.) The first is recycling of melt- impregnated oceanic lithosphere; the second is recycling of a mantle wedge impregnated with melt from a subducting oceanic plate. / by Rhea K. Workman. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2006. / Includes bibliographical references. / To provide a new perspective on the fate of both natural organic matter and hydrophobic organic contaminants (HOCs) in marine sediments, we have investigated the relationship between radiocarbon (14C) age and the different modes of association in aquatic sediments and soils. Radiocarbon is a sensitive tracer of OM provenance, with variations in its natural abundance reflecting the age and origin of material. The main objective has been to determine the significance of these associations, and to assess how they affect the transport, bioavailability, preservation and residence times of organic compounds in the environment. Our results indicate that the majority of HOCs that persist in marine sediments are solvent-extractable and incorporation into insoluble sediment residues is not quantitatively significant. For pristine sediments, systematic variations in 14C content are observed between different chemically defined sedimentary organic fractions. These variations are dependent on organic matter inputs and/or the affects of diagenesis. Our observations also provide evidence for the protection of labile marine carbon by chemical binding. / (cont.) Finally, the persistence of n-alkanes from biogenic sources compared to those derived from petroleum indicates that protective matrix association can play a crucial role in determining the long-term fate of a compound. Overall, it is clear that both natural organic compounds and HOCs can undergo very different fates depending on their mode of introduction to, and physical disposition in environmental matrices. / by Helen K. White. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), February 2006. / Includes bibliographical references. / Benthic and planktonic foraminiferal [delta]18O ([delta 18Oc) from a suite of well-dated, high-resolution cores spanning the depth and width of the Straits of Florida reveal significant changes in Gulf Stream cross-current density gradient during the last millennium. These data imply that Gulf Stream transport during the Little Ice Age (LIA: 1200-1850 A.D.) was 2-3 Sv lower than today. The timing of reduced flow is consistent with cold conditions in Northern Hemisphere paleoclimate archives, implicating Gulf Stream heat transport in centennial-scale climate variability of the last 1,000 years. The pattern of flow anomalies with depth suggests reduced LIA transport was due to weaker subtropical gyre wind stress curl. The oxygen isotopic composition of Florida Current surface water ([delta]18Ow) near Dry Tortugas increased 0.4%0/ during the course of the Little Ice Age (LIA: -1200-1850 A.D.), equivalent to a salinity increase of 0.8-1.5 psu. On the Great Bahama Bank, where surface waters are influenced by the North Atlantic subtropical gyre, [delta]18Ow increased by 0.3%o during the last 200 years. Although a portion (-O. 1%o) of this shift may be an artifact of anthropogenically-driven changes in surface water [Epsilon]CO2, the remaining [delta]18Ow signal implies a 0.4 to 1 psu increase in salinity after 200 yr BP. / (cont.) The simplest explanation of the [delta]18Ow, data is southward migration of the Atlantic Hadley circulation during the LIA. Scaling of the [delta]18Ow records to salinity using the modern low-latitude 180,w-S slope produces an unrealistic reversal in the salinity gradient between the two sites. Only if [delta]18Ow is scaled to salinity using a high-latitude [delta]18Ow-S slope can the records be reconciled. Changes in atmospheric 14C paralleled shifts in Dry Tortugas [delta]18Ow, suggesting that variable solar irradiance paced centennial-scale Hadley cell migration and changes in Florida Current salinity during the last millennium. / by David C. Lund. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2007. / Includes bibliographical references (p. 194-197). / Oceanic spreading centers are sites of magmatic, tectonic, and hydrothermal processes. In this thesis I present experimental and seismological constraints on the evolution of these complex regions of focused crustal accretion and extension. Experimental results from drained, triaxial deformation experiments on partially molten olivine reveal that melt extraction rates are linearly dependent on effective mean stress when the effective mean stress is low and non-linearly dependent on effective mean stress when it is high. Microearthquakes recorded above an inferred magma reservoir along the TAG segment of the Mid-Atlantic Ridge delineate for the first time the arcuate, subsurface structure of a long-lived, active detachment fault. This fault penetrates the entire oceanic crust and forms the high-permeability pathway necessary to sustain long-lived, high-temperature hydrothermal venting in this region. Long-lived detachment faulting exhumes lower crustal and mantle rocks. Residual stresses generated by thermal expansion anisotropy and mismatch in the uplifting, cooling rock trigger grain boundary microfractures if stress intensities at the tips of naturally occurring flaws exceed a critical stress intensity factor. / (cont.) Experimental results coupled with geomechanical models indicate that pervasive grain boundary cracking occurs in mantle peridotite when it is uplifted to within 4 km of the seafloor. Whereas faults provide the high-permeability pathways necessary to sustain high-temperature fluid circulation, grain boundary cracks form the interconnected network required for pervasive alteration of the oceanic lithosphere. This thesis provides fundamental constraints on the rheology, evolution, and alteration of the lithosphere at oceanic spreading centers. / by Brian J. deMartin. / Ph.D.

Thesis (Ph. D.)--Joint Program in Chemical Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2009. / Includes bibliographical references. / The application of elemental and isotopic metal palaeoredox tracers to the geologic past rests on an understanding of modern metal cycles. This study reevaluates the surface-cycling of Mo and Re in near-surface reservoirs. Revised river averages of Mo and Re are 1.8- and 7.9-fold larger than previous estimates. The river concentrations of 8.0 nmol Mo kg-1 and 11.2 pmol Re kg- (pre-anthropogenic), result in shorter seawater response times of 4.4 x 105 yr ([Tau]Mo) and 1.3 x 105 yr ([Tau]Re pre-anthropogenic). These metals, especially Re, are more sensitive to changing source and sink fluxes than previously thought. Evaluation of Mo and Re concentrations in high temperature fluids from the Manus Basin indicate that Re is essentially absent from the hydrothermal end member and Mo is present at concentrations considerably lower than ambient seawater. The sink fluxes represented by hydrothermal circulation are negligible in comparison to the revised river source fluxes. Anthropogenic contributions to the Re flux to seawater are seen in the high concentrations of certain impacted water samples such as those associated with mining sites. It may also be seen in a significant, variable, Re enrichment feature in the Hudson River estuary. This Re enrichment feature is not the result of estuarine mixing or the remobilization of sediment-hosted Re. On the basis of a Re - SO2- correlation we are able to quantify and correct for the anthropogenic Re, which corresponds to ~33% of the modern river average. This study documents the development of an analytical method for stable Re isotopes. / (cont.) Though complicated by analyte requirements and 187Re 1870s decay, Re isotope measurements have a reproducibility of ±0.05%o for analyte concentrations of 20 ng Re mL-1. Total Re isotopic variability to date is 0.9%o. This includes 0.3%0 across five commercially available Re products, and 0.5%0 across a black shale weathering profile. 6187Re variability across the weathering profile was systematic with the most weathered samples showing the most significant [delta]187Re depletions. The Re isotopic weathering profile is well described by both two-component mixing and Rayleigh fractionation. There are currently insufficient data to discriminate between the two models. / by Christian Alexander Miller. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), February 1988. / Vita. / Includes bibliographical references (p. 243-259). / by Michael Anthony Kaminski. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), February 2000. / Includes bibliographical references (p. 255-270). / This thesis studies the dynamics of mantle melting during continental breakups by geophysical, geochemical, and numerical analyses. The first part focuses on the mantle melting and crustal accretion processes during the formation of the Southeast Greenland margin, on the basis of deep-crustal seismic data. A new seismic tomographic method is developed to jointly invert refraction and reflection travel times for a compressional velocity structure, and a long-wavelength structure with strong lateral heterogeneity is successfully recovered, including 30- to 15-km-thick igneous crust within a 150-km-wide continent-ocean transition zone. A nonlinear Monte Carlo analysis is also conducted to establish the absolute uncertainty of model parameters. The derived crustal structure is first used to resolve the origin of a margin gravity high, with new inversion schemes using both seismic and gravity constraints. Density anomalies producing the gravity high seem to be confined within the upper crust, not in the lower crust as suggested for other volcanic margins. A new robust framework is then developed for the petrological interpretation of the velocity structure of igneous crust, and the thick igneous crust formed at the continentocean transition zone is suggested to have resulted from vigorous active upwelling of mantle with only somewhat elevated potential temperature. In the second part, the nature of mantle melting during the formation of the North Atlantic igneous province is studied on the basis of the major element chemistry of erupted lavas. A new fractionation correction scheme based on the Ni concentrations of mantle olivine is used to estimate primary melt compositions, which suggest that this province is characterized by a large degree of major element source heterogeneity. In the third part, the nature of preexisting sublithospheric convection is investigated by a series of finite element analyses, because the strength of such convection is important to define the "normal" state of mantle, the understanding of which is essential to identify any anomalous behavior of mantle such as a mantle plume. The results suggest that small-scale convection is likely in normal asthenosphere, and that the upwelling velocity in such convection is on the order of 1- 10 cm/yr. / by Jun Korenaga. / Ph.D.