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Developing renewable alternatives for energy production is one of the main methods for climate change mitigation and sustainable development. As the key component in permanent magnets, neodymium is considered as one of the most critical elements in the rare earth family in the development of modern society. It plays a significant role in increasing efficiency and reducing weight in many applications like hard disc drives, audio equipment, direct- driven gearless and conventional wind turbine design, as well as electric vehicles designs with NiMH batteries. The emerging problem of neodymium production is the peak neodymium issue, which implies a potential risk of supply in the future due to the unsustainable production pathway. Now, China is producing more than 90% of the rare earth elements with an around 40% reserves and is facing severe problems of environmental pollution, smuggling, and increasing domestic demand. This paper makes efforts to see if the risk of supply would constrain future wind power development with a special focus on the China’s dominance in production and policies. By fitting historic production data with three curve models (logistic, Gompertz, and Richards) and designing future demand based on IEA’s scenarios, the projections of future supply and demand trends of neodymium was obtained. This paper shows that though neodymium-based wind turbine construction might not be the cause for neodymium shortage, it would be confronted with material constraints in the future. Thus, more consideration should be taken in the investment of wind turbines with permanent magnet. Also, a mineral strategy, which integrates technological innovation, joint effort from different stakeholders, and better resource management, is required for a sustainable production of neodymium in the long run.

This study aims to investigate the stable isotopic characteristics of meteoric and ground waters, and to obtain spring flow rates in the Coronet Peak Skifield, Queenstown. Spring flows were gathered during the winters of 2008 and 2009, whilst water samples were collected from precipitation, springs, reservoirs and groundwater during July, August and September 2009. The spring flows were examined and the water samples were analysed for δD and δ¹⁸O values using the CF-IRMS at the University of Canterbury. A database has been gathered from all natural water sources to give a local meteoric water line (LMWL) for the area that fits clearly with the global meteoric water line. The LMWL has an R2 value of 0.97 and the equation is δD = 8 δ¹⁸O +10. An understanding of evaporation as it occurs in the water storage reservoirs of the mountain has also been obtained, giving rise to a local evaporation line. The stable isotope ratios of hydrogen and oxygen within precipitation have been used extensively to characterise the hydrogeology with emphasis on altitude effects, storm duration and variations in storm track trajectories. Of these three phenomena, it is the trajectory of the storm track that is best shown to affect the composition of precipitation in this area. The air masses advancing on the study area from the north being more depleted in their isotopic signatures, with approximate δD and δ¹⁸O values of –130‰ and -16‰. The air masses approaching from a southerly direction are more positive in comparison, having approximate δD and δ¹⁸O values of –65‰ and -9‰. The altitude effect in precipitation on the Skifield has led to an altitude gradient being found: for every 100-metre increase in elevation, δ¹⁸O decreases by 0.71‰. However there were some inconsistencies. The influence on precipitation from storm duration is also inconsistent in this area. The R2 values range from 0.14 to 0.99, but this method does not take into account the position of the individual samples. Some samples did not plot in the expected order that is governed by a decrease in stable isotopic ratios with storm duration. The stable isotopic compositions within meteoric waters can be used as tracers of water sources. The isotope date of the springs also infers an altitude effect. The springs gave an altitude gradient of a decrease –0.43‰ with each 100-metre increase in elevation. This indicates that precipitation is the main influence on the stable isotopic composition of the springs in this area. However, data shows differences between the current precipitation and the groundwater compositions, indicating that present precipitation is not flowing from the springs, past precipitation is. The stable isotopic compositions of the springs have also been correlated with groundwater isotope data and suggest the sources of the springs are groundwater dominated. Although some springs compositions indicate an influence by current precipitation. This is shown by a negative stable isotopic trend in the precipitation sampled in August, corresponding with a relatively negative stable isotopic composition in some springs during this time period. Monitoring of spring flows on Coronet Peak have led to an average winter flow rate being established of 26.5 litres per second. Spring flow rates range from 0.25 – 6 litres per second. This monitoring has indicated the springs of the greatest yield that are not already being utilised on the Skifield. It is these springs that should be further investigated as to whether they would provide a sustainable source of water on the mountain. This locally derived water would then be utilised for the purposes of artificial snowmaking and other activities and amenities that are currently operated by NZ Ski on Coronet Peak.

A connection is established between uniform rational approximation, and approximation in the mean by polynomials on compact nowhere dense subsets of the complex plane C. Peak points for R(X) and bounded point evaluations for Hp(X, dA), 1 ≤ p < ∞, play a fundamental role.

An explosive growth in demand for broadband mobile wireless services is currently being fuelled by cellular telephone users who, encouraged by service providers, are no longer content with voice transmission only but are demanding real-time video services, including multi-user, interactive games and 'movie' programmes. As these applications develop, expectations mount in other mobile user markets, especially the public safety arena, for comparable user features but with greater emphasis on reliability and robustness of the equipment and supporting network in adverse propagation conditions, remote locations and emergencies. These applications all have in common the requirements for efficient use of wireless bandwidth and of battery power, as well as seamless operation when moving, sometimes at high vehicle speeds, from one type of environment to another in a multi-user scenario. Orthogonal frequency-division multiplexed (OFDM) signals have been found to compare favourably with other modulation systems in these applications, the multi-carrier format being more tolerant of delay spread. It has been used in both code-division (MC-CDMA) and frequency-division (OFDMA) multi-user schemes, the latter having the advantage of maintaining orthogonality among users in fading-signal environments, with consequent simplification of signal processing. The major drawback of OFDM has been the high peak-to-average power ratio (PAPR) that is characteristic of signals with multiple sub-carriers. A result of this is that the transmitter requires a linear power amplifier (PA) that generally has to be 'backed off' to accommodate the high PAPR. Additional back-off is required to achieve linearity, as well as sometimes-complex linearisation circuitry. The power usage and cost of such a transmitter is more acceptable in a base station, tending to limit the application of OFDM to downlinks. The potential application to hand-portable terminals has severe constraints of size, cost and battery life, exacerbated by the use of video-capable LCD displays, increasing motivation for the use of MIMO (multi-antenna) technology and the development of mobile ad-hoc networks, the latter being particularly applicable in the public safety arena. Previous efforts to ameliorate the PAPR problem have been principally directed at two areas, the reduction of signal PAPR, by block coding, clipping or other techniques, and methods of achieving PA linearisation with improved power efficiency. The first object of the present research was to establish, as far as practicable, the current state of the art in these areas, to set a performance baseline. The next step was to develop an improved transmitter modulation scheme that would not only be able to take advantage of any existing peak reduction methods but would transmit a signal that would be compatible with existing OFDM receivers. A novel modulation technique is now presented, termed Quadrature Phase-Time Modulation (QPTM), that has been found to meet the requirements for linearity, simplicity and low cost, whilst being able to take advantage of constant-envelope PA technology, with its attendant power efficiency. After final amplification, the signal is restored by a passive narrow-band filter to standard OFDM form, having both phase and amplitude modulation. The QPTM system of modulation relies on a dual baseband pulse-width modulation process, performed at a substantially-higher rate than the upper baseband frequency, followed by direct quadrature modulation of a carrier signal. The work undertaken has been in the nature of a feasibility study, commencing with the theoretical basis of the technique, from which a behavioural system model was designed and simulated. After the system was simulated successfully, in several forms, a model was designed for realisation with available high-frequency integrated circuits. From this design, prototypes were constructed and tested. The prototype circuit boards also included an experimental UHF Class-D PA circuit, excluding the output filter, to facilitate ongoing development of the PA and filter subsystem as a separate project. This type of PA was seen as a potential complement to the QPTM modulator, although the technology was at an early stage of development. The prototype PA has a novel push-pull arrangement of GaAs FETs that employs a broadside-coupled tapered-stripline balun instead of the usual transformer. Preliminary measurements were made on the PA using both a spectrum analyser and a newly-available 8GHz-bandwidth digital oscilloscope to confirm basic operating characteristics. The performance of the QPTM technique at frequencies needed for broadband operation is dependent on its practical implementation, which has therefore been a major focus. The inherent difficulties in realising a highly-linear 40MHz triangle-wave reference generator, with a precise ultra-high-speed comparator and modulator system, have been overcome with the chosen design techniques and attention to several critical aspects. The result has been the successful demonstration of QPTM as an efficient PA modulation technique that is equally applicable to either narrow-band, high-capacity UHF or broadband OFDM microwave systems.

An experimental investigation into fully developed high aspect ratio channels was undertaken. A review of the literature reveals that there is a need for accurate measurement of the inner peak value of streamwise turbulence intensity despite the large number of studies already completed. The scattered data on this subject could be attributed either to insufficient channel size (aspect ratio or length) or to hot-wire spatial filtering. A new, high quality, channel flow facility was designed and constructed, considering the most recent geometric limitation provided in the literature. To obtain accurate results, data were acquired using hot-wire probes with constant viscous-scale sensing length and were corrected using the most recent correction formula proposed by Smits et al. (2011). The results show dependence of inner peak value on Reynolds number in channels flow - its magnitude increasing with increasing Reynolds number.

Coal has been used as a fuel for electricity generation for centuries. Inexpensive electricity from coal has been a key component in building large industrial economies such as USA and China. But in recent decades the negative aspects of coal, mainly carbon dioxide emissions, has changed the view on the fuel. Carbon capture and storage (CCS) is a solution to be able to continue using coal as an energy source, while limiting carbon emissions. One of the drawbacks of CCS is the energy need associated with the capture process, the energy penalty. This study aims to gather and analyze the energy penalties for the most developed types of carbon capture technologies. It also aims to model how the implementation of CCS would affect the future coal consumption. The results show that the range of energy penalties for a given type of technology is wide. Despite obtaining the energy penalty with the same simulation software, the energy penalty for post- combustion with MEA can range between 10.7% and 39.1%. Comparing mean energy penalties show that pre-combustion capture is the most efficient capture method (18.4% ± 4.4%) followed by oxy- fuel (21.6% ± 5.5%) and post-combustion (24.7% ± 7.9%). Further on, CCS implementation scenarios were compared and used as a starting point for coal consumption calculations. Three pathways were constructed in order to investigate how different distributions of technologies would affect the amount of needed coal. The pathways describe a implementation with only the most efficient technology, the least efficient and a middle option. The results suggest that a large scale implementation of CCS on coal power plant will have a significant impact on the global coal consumption. Under certain assumptions it takes up to 35 % more coal to deliver the same amount electricity with CCS in comparison without CCS. It is also found that certain implementation scenarios will struggle to produce the amount of coal that is needed to power the plants. A sensitivity analysis was performed to examine the impact of assumptions made on for instance plant efficiencies. The analysis shows that optimistic assumptions on development in plant efficiency and deploying only the best technology, uses less coal than a development without CCS and with current plant efficiencies.

Risk is an increasingly important factor of our modern society, but that does not mean that risks have become higher today versus any other epoch of human history. Especially in the developed world, risks have been progressively lowered over time. In opposition to the declining risk in everyday life of our modern society, there seems to be an apparent increasing prevalence of risk-taking in our leisure pursuits. More people are willing to take unenforced risks and the fast growing development of adventure tourism is a good example of this. The main purpose of this thesis is to create an understanding how service providers of dangerous activities manage the balance risk and safety in interaction with their customer. Our research objective is to obtain an understanding of risk management practice in a context with the potential physical risks inherent in adventure tourism. The organizational structure for a service provider in extreme environments can be similar to a temporary organizational structure and can therefore be seen from a project management perspective. This research is conducted through a qualitative case-study, which was carried out in the context of a mountaineering expedition in the attempt to summit Mount Everest. Our empirical data are gathered from a database created by the research project Extreme Environments – Everyday Decisions (Triple ED). This database contains numerous transcribed interviews, tracking records, and field notes that was used in order to interpret and analyze the expedition and encounters happening during the process of this mountaineering expedition. Our empirical findings suggest that management of a balance between risk and safety is highly dependent on honest communication. Educated personnel that have the experience and knowledge necessary to manage an expedition or group in a similar setting are another key feature. Furthermore, managing a balance between physical risk and safety is an on-going process in the context of adventure tourism with a large amount interaction between the service provider’s representatives and their customers. For these reasons, the building of a well-functioning relationship between the incorporated strong stakeholders is of importance when balancing risk and safety in a dangerous activity with inherent risks for physical harm.

A rapid growth in the national electricity demand is placing an ever-increasing demand on the national electricity supply utility, Eskom. Projections show that the load demand in South Africa may exceed the installed capacity by as early as 2007. This is mainly due to the increase in demand in the residential sector as a result of the electrification of rural and previously disadvantaged communities. However, the industrial and commercial sectors also have a role in this increase. In an attempt to reduce the demand for electricity Eskom has adopted its Demand Side Management (DSM) initiative. This initiative is aimed at lowering the electricity demand in peak times through energy efficiency (EE) or load shift, out of peak demand times. Eskom is implementing the DSM strategy by financing Energy Service Companies (ESCOs) to reduce the demand load of major electricity end-users during peak times. Buildings consume a large percentage of the total energy supply in the world. Most of the energy consumed in buildings is used by the heating, ventilation and air-conditioning (HVAC) systems, as well as lighting. However, a large potential for energy savings exists in buildings. Studies have shown that up to 70% of the electricity consumption of a building can be saved through retrofit studies. However, to capitalise on these opportunities, the ESCOs require tools and procedures that would enable them to accomplish energy savings studies quickly and efficiently. It should be a holistic approach to the typical ESCO building audit. A study of current available software programs showed the lack of holistic tools aimed specifically at retrofit audits, and therefore also the need for such a program. The building simulation program most suited to the retrofit study was chosen and it was used in a retrofit audit. By emulating a retrofit audit with this software, its performance in the field, both positive and negative, could be established. With the experience gained from the retrofit study, as well as input from ESCOs in the industry, a need for such a retrofit tool was established. The simulation program that was tested in the retrofit study is the tool Quickcontrol, as well as the newer version of the program, entitled QEC. The case study showed that even though these packages are well suited to ESCO work, they have certain drawbacks in view of the holistic project approach. The ESCOs require a simple, fast, and integrated procedure for energy audits. This procedure should be embodied in a software program. This study proposes a new integrated procedure for energy audits and the analyses of buildings, in the form of a software tool. This new tool is geared towards the ESCO building audit, in both South A6ica and internationally. It is designed to enable a diplomate engineer to accomplish a building energy and retrofit analysis in two weeks, leading the user through all the main project steps, from data acquisition to writing of the final project report. This is a significant improvement, since it normally takes 50 man-days for an experienced and trained engineering team to complete a full building audit. This tool was used in a case study to test its validity and accuracy. It was found that certain situations would arise in which the criteria that were set for the program would not be adequate. The results from the case study were favourable and satisfied the criteria that were set for the procedure. / Thesis (Ph.D. (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2004.

Knee function after more than 20 years post injury is rarely described and none of the few follow-up studies have evaluated functional performance tasks. This thesis investigated self-reported knee function, physical activity level, physical capacity and movement pattern in the long-term perspective (on average 23 years) in persons who had suffered a unilateral ACL injury, treated either with physiotherapy in combination with surgery (ACLR, n=33) or physiotherapy alone (ACLPT, n=37) and compared to age-and-gender matched controls (n=33).  This thesis shows that regardless of treatment, there are significant negative long-term consequences on self-reported knee function and physical activity more than 20 years after injury. In comparison to the controls, the ACL-groups (ACLR and ACLPT) had lower knee function as measured by the Lysholm score and the Knee injury and Osteoarthritis Outcome Score (KOOS). The persons with an ACL injury also had a lower knee-specific physical activity level (Tegner activity scale), while no differences were seen in general physical activity level (International Physical Activity Questionnaire, IPAQ) compared to healthy controls. Regarding physical capacity, both ACL groups showed inferior jump capacity in the injured leg compared to the non-injured leg. However, compared to controls the ACL-injured had a relatively good jump performance. Knee extension peak torque, concentric and eccentric, was also lower for the injured leg compared to the non-injured leg for both ACLR and ACLPT. In addition, the ACLPT group showed reduced eccentric knee flexion torque of the injured leg. The non-injured leg, on the other hand, showed almost equal jump capacity and strength as controls. Balance in single-limb stance (30s) was inferior in persons who had an ACL injury. This was true for both the injured and non-injured leg and regardless of treatment. Movement pattern during the one-leg hop was analysed by a set of kinematic variables consisting of knee angles (flexion, abduction, rotation) and Centre of Mass (CoM) placement in relation to the knee and ankle joints. Both ACLR and ACLPT displayed movement pattern asymmetries between injured and non-injured legs. In comparison to controls, the ACLR group had a similar movement pattern with the exception of larger external knee rotation at Initial contact and less maximum internal rotation during the Landing. ACLPT showed several differences compared to controls both regarding knee angles and CoM placement. The ACL-injured persons with no-or-low knee osteoarthritis (OA) had better knee function as reflected by higher scores on Lysholm and KOOS subscale ‘symptom’ compared to those with moderate-to-high OA. The degree of OA had no influence on reported physical activity level, jump capacity, peak torque or the kinematic variables.  In conclusion, this thesis indicates that persons with a unilateral ACL injury, regardless of treatment, have some negative long-term consequences e.g. self-reported knee function, knee-specific activity level, strength and balance deficits, when compared to age-and-gender matched controls. The results, however, also indicate that the ACL-injured can manage reasonably well in some jumps and general activity level but have an inferior performance in more knee-demanding tasks. The ACLR group had similar movement pattern with the exception of knee rotation, indicating that a reconstruction may restore the knee biomechanics to some extent. The ACLPT group on the other hand, seem to use compensatory movement strategies showing several differences compared to controls.