Damp building materials are subjected to degradation processes due to moisture and also microbial growth, with both of these giving rise to emissions of volatile organic compounds (VOCs) that may contribute to indoor air health problems. The overall aim of this thesis was to investigate emissions of reactive and non-reactive VOCs from damp building materials and from the microorganisms growing on them, and also to investigate the possible health impact of these compounds. Three studies were carried out in order to study emissions of VOCs. The first investigated emissions from a mixture of five fungi (Aspergillus versicolor, Fusarium culmorum, Penicillium chrysogenum, Ulocladium botrytis and Wallemia sebi) and the second emissions from the bacterium Streptomyces albidoflavus. In both studies the microorganisms were cultivated on three different building materials (pine wood, particle board and gypsum board) and one synthetic media, MEA and TGEA respectively. The bacterium was also cultivated on sand. Air samples from the cultures were collected on six different adsorbents and chemosorbents to sample a wide range of compounds such as VOCs, aldehydes, amines and light-weight organic acids. The samples were analyzed with gas chromatography, high-pressure liquid chromatography and ion chromatography. Mass spectrometry was used for identification of the compounds. Alcohols and ketones were the predominant compound groups identified. The bacterial culture growing on TGEA emitted ammonia, methylamine, diethylamine and ethylamine. The third study dealt with secondary emissions collected from buildings with moisture and mould problems. Samples were taken when the materials were dry and also after they had been wet for a week. Most alcohols and ketones could be identified from the wet materials. Trimethylamine and triethylamine, were identified from sand contaminated by Bacillus. One study looked at the development of a method for analysis of primary and secondary amines with LC-MS/MS. A three-step process was developed, with the first step screening the samples for NIT derivatives with selected reaction monitoring, SRM. In the second step a precursor ion scan gave the [M+H]+ ion, and the last step involved fragmentation with a product ion scan. It was possible to separate and identify all the investigated amines, which showed that the method was both specific and selective and therefore well suited for the analysis of amines in complex environments. The last study comprised two exposure studies. In study 1 each participant took part in two exposure conditions, one with air from mouldy building materials and one with blank air for a 60 minute period. In study 2 each participant was exposed four times (for a period of 10 min) at random to air from mouldy building materials and blank air, with and without nose-clip. The participants rated air quality and symptoms before, during and after each exposure. Exposure to moderate VOC levels resulted in reports of perceived poor air quality, but no such results were received when exposing the participants to low VOC levels.

The main objectives of this thesis are to determine if the addition of an energy wheel in an HVAC system can improve the indoor air relative humidity (RH), and perceived air quality (PAQ), as well as reduce energy consumption. An energy wheel is an air-to-air energy exchanger that transfers heat and moisture between the outdoor air entering and the exhaust air leaving a building. This thesis uses the TRNSYS computer package to model two buildings (an office and a school) in four different cities (Saskatoon, Saskatchewan; Vancouver, British Columbia; Tampa, Florida and Phoenix, Arizona).<p>The results with and without an energy wheel are compared to see if the energy wheel has a significant impact on the RH and PAQ in the buildings. The energy wheel reduces peak RH levels in Tampa, (up to 15% RH), which is a humid climate, but has a smaller effect on the indoor RH in Saskatoon (up to 4% RH) and Phoenix (up to 11% RH), which are dry climates. The energy wheel also reduces the number of people that are dissatisfied with the PAQ within the space by up to 17% in Tampa. <p>The addition of the energy wheel to the HVAC system creates a reduction in the total energy consumed by the HVAC system in Saskatoon, Phoenix and Tampa (2% in each city). There is a significant reduction in the size of the heating equipment in Saskatoon (26%) and in the size of the cooling equipment in Phoenix (18%) and Tampa (17%). A cost analysis shows that the HVAC system including an energy wheel has the least life-cycle costs in these three cities, with savings of up to 6%. In Vancouver, the energy wheel has a negligible impact on the indoor RH, PAQ and energy consumption.

The main objectives of this thesis are to determine if the addition of an energy wheel in an HVAC system can improve the indoor air relative humidity (RH), and perceived air quality (PAQ), as well as reduce energy consumption. An energy wheel is an air-to-air energy exchanger that transfers heat and moisture between the outdoor air entering and the exhaust air leaving a building. This thesis uses the TRNSYS computer package to model two buildings (an office and a school) in four different cities (Saskatoon, Saskatchewan; Vancouver, British Columbia; Tampa, Florida and Phoenix, Arizona).<p>The results with and without an energy wheel are compared to see if the energy wheel has a significant impact on the RH and PAQ in the buildings. The energy wheel reduces peak RH levels in Tampa, (up to 15% RH), which is a humid climate, but has a smaller effect on the indoor RH in Saskatoon (up to 4% RH) and Phoenix (up to 11% RH), which are dry climates. The energy wheel also reduces the number of people that are dissatisfied with the PAQ within the space by up to 17% in Tampa. <p>The addition of the energy wheel to the HVAC system creates a reduction in the total energy consumed by the HVAC system in Saskatoon, Phoenix and Tampa (2% in each city). There is a significant reduction in the size of the heating equipment in Saskatoon (26%) and in the size of the cooling equipment in Phoenix (18%) and Tampa (17%). A cost analysis shows that the HVAC system including an energy wheel has the least life-cycle costs in these three cities, with savings of up to 6%. In Vancouver, the energy wheel has a negligible impact on the indoor RH, PAQ and energy consumption.

Passive removal materials (PRMs) are building materials or furnishings that can effectively control indoor pollution without substantial formation of chemical byproducts and without energy penalty. To assess clay wall plaster as an effective PRM for improving air quality by controlling ozone, perceived air quality (PAQ) was determined in the presence of eight combinations of an emitting and reactive pollutant source (new carpet), clay plaster applied to gypsum wallboard, and chamber air with and without ozone. A panel of 18 to 23 human subjects assessed air quality in twin 30 m3 chambers using a continuous acceptability scale. Air samples were collected immediately prior to panel assessment to quantify concentrations of C5 to C10 saturated n-aldehydes and two aromatic aldehydes that are commonly produced by reaction of ozone with carpet. Perceived Air Quality was most acceptable and concentrations of aldehydes were lowest when only clay plaster or both clay plaster and carpet were present in the chambers without ozone. The least acceptable PAQ and the highest concentrations of aldehydes were observed when carpet and ozone were present together; addition of clay plaster for this condition improved PAQ and considerably decreased aldehyde concentrations. Ozone deposition and byproduct emissions of the clay wall plaster were also assessed using 48 liter stainless steel chambers. Clay plaster applied to gypsum wallboard that had been exposed in a test house (UTest House) for one year effectively removed 88% of the ozone, and emitted high aldehyde concentrations when exposed to high purity air that did not increase when the material was exposed to ozone. The outcome of these experiments leads to speculation that the clay plaster adsorbed contaminants in the test house and then re-emitted them upon exposure to clean air in the small chambers. / text

Spaces with high occupancy density like classrooms are challenging to ventilate and use a lot of energy to maintain comfort. Usually, a compromise is made between low energy use and good Indoor Environmental Quality (IEQ), of which poor IEQ has consequences for occupants’ health, productivity and comfort. Alternative strategies that incorporate elevated air speeds can reduce cooling energy demand and provide occupant’s comfort and productivity at higher operative temperatures. A ventilation strategy, Intermittent Air Jet Strategy (IAJS), which optimizes controlled intermittent airflow and creates non-uniform airflow and non-isothermal conditions, critical for sedentary operations at elevated temperatures, is proposed herein. The primary aim of the work was to investigate the potential of IAJS as a ventilation system in high occupancy spaces. Ventilation parameters such as air distribution, thermal comfort and indoor air quality are evaluated and the system is compared with a traditional system, specifically, mixing ventilation (MV). A 3-part research process was used: (1) Technical (objective) evaluation of IAJS in-comparison to MV and displacement ventilation (DV) systems. (2) An occupant response study to IAJS. (3) Estimation of the cooling effect under IAJS and its implications on energy use. All studies were conducted in controlled chambers. The results show that while MV and DV creates steady airflow conditions, IAJS has  cyclic airflow profiles which results in a sinusoidal temperature profile around occupants. Air distribution capability of IAJS is similar to MV, both having a generic local air quality index in the occupied zone. On the other hand, the systems overall air change rate was higher than a MV. Thermal comfort results suggest that IAJS generates comfortable thermal climate at higher operative temperatures compared to MV. Occupant responses to IAJS show an improved thermal sensation, air quality perception and acceptability of indoor environment at higher temperatures as compared to MV. A comparative study to estimate the cooling effect of IAJS shows that upper HVAC setpoint can be increased from 2.3 – 4.5 oC for a neutral thermal sensation compared to a MV. This implies a substantial energy saving potential on the ventilation system. In general, IAJS showed a potential for use as a ventilation system in classrooms while promising energy savings. / Lokaler där många människor vistas, som t.ex. klassrum, är ofta svåra att ventilera. Att upprätthålla en bra termisk komfort kräver en hög energianvändning. Vanligtvis blir det en kompromiss mellan låg energianvändning och bra kvalitet på inomhusmiljön (IEQ). Dålig IEQ får konsekvenser för människors hälsa, produktivitet och komfort. Alternativa ventilationsstrategier, som använder förhöjda lufthastigheter, kan minska kylbehovet och därmed energianvändningen. I denna avhandling utvärderas en ny ventilationsstrategi, Intermittenta luftstrålar (IAJS), där korta perioder med hög lufthastighet genererar en svalkande effekt, när rummets temperatur upplevs som för hög. Det primära syftet med arbetet var att undersöka potentialen hos IAJS som ett ventilationssystem för klassrum, där den termiska lasten ofta är hög. Strategin jämförs mot traditionella ventilationsprinciper som omblandande ventilation (MV) och deplacerande ventilation (DV). Parametrar som luftdistributionsindex, termisk komfort, luftkvalitet och energibesparing har utvärderats. Alla studier utfördes i klimatkammare. Resultaten visar att medan MV och DV skapar konstanta luftflödesförhållanden genererar IAJS cykliska hastighetsprofiler samt en sinusformad temperaturvariation i vistelsezonen. IAJS klarar att bibehålla ett bra termiskt klimat vid högre operativa temperaturer jämfört med MV. I en jämförelse med ett traditionellt HVAC-system visar beräkningar  att dess börvärde kan höjas från 2.3 till 4.5 °C med bibehållen termisk komfort. Detta indikerar en avsevärd energibesparingspotential vid användande av IAJS.