Nanoporous materials for gas purification and thermal insulation have been studied and developed for application in many areas. It is known that a single adsorbent may not adequately control multiple contaminants. Further the utilization of nanoporous material as thermal insulator in building applications is limited due to high cost. Moreover, in view of the global environmental movement for clean air and reduction of heating energy consumption in built environment, the development of new and better nanoporous materials will not only facilitate major advances in gas adsorption and thermal insulation technology, but also meet the new challenges that cannot be met with the nanoporous materials that are currently available. This thesis presents a synthesis of new nanoporous silica based materials, and the characterization and application of these materials for molecular filtration and thermal insulation. Commercial nanoporous materials have been used for benchmarking for the pore properties, the applicability, and the performance of these new materials. First a double metal-silica adsorbent has been synthesized. The preparation procedure is based on the use of sodium silicate coagulated with various ratios of magnesium and calcium salts which yields micro-meso porous structures in the resulting material. The results show that molar ratios of Mg/Ca influence the pore parameters as well as the structure and morphology. The bimodal pore size can be tailored by controlling the Mg/Ca ratio. In the second synthesis, pure mesoporous silica, SNP has been prepared using glycerol as pore forming agent and monovalent salts as coagulant. This leads to material with large surface area and uniformed pore size centred at 43 or 47 nm.  The materials further exhibits a low bulk density in the range of 0.077 to 0.122 g/ml and possess a high porosity in the range of 95-97%. The influence of acid type (organic or inorganic) on the pore parameters and on the tapped density has also been investigated.   A synthesis method has also been developed for the preparation of carbon-silica composites. The method involves a number of routes, which can be summarised as addition of activated carbon particles to (I) the paste, (II) the salt solution, or (III) with the sodium silicate solution. In route II and III the activated carbon is present before coagulation. The routes presented here leads to carbon-silica composites possessing high micro porosity, meso porosity as well as large surface areas. The results further shows that pore size distribution may be tailored based on the route of addition of the carbon particles. Following route I and III a wide pore size (1-30 nm) was obtained whereas by route II a narrow pore size (1-4 nm) was observed.     MgCa-silica chemisorbents were also developed using either potassium hydroxide or potassium permanganate as impregnate chemicals. A direct or post-impregnation procedure was employed. The results revealed that the impregnate route and amount cause a reduction in both specific surface area and pore volume. Finally the thermal conductivity and dynamic adsorption of H2S, SO2 andtoluene were measured. Results show that at room temperature and atmospheric pressure, a thermal conductivity of 28.4 and 29.6 mW/m.K were obtained for the SNP mesoporous silicas. The dynamic adsorption behaviour of the chemisorbents and composites indicate their ability to absorbed H2S, SO2 andtoluene respectively. The highest H2S uptake corresponds to chemisorbents with 11.2-13.6 wt% KMnO4. The effect of impregnation route, amount of KMnO4 and its location in the pore system are likely the key factors in achieving a large H2S uptake. For SO2 adsorption, the highest uptake capacity was observed for MgCa-68/32-KOH. The results further suggest that the key to large SO2 uptake is as a result of the synergetic effect between large mesopore diameter and extensive mesopore volumes. Carbon-silica composites with carbon content 45 wt % exhibits high toluene adsorption with composite via route I having the highest toluene adsorption capacity (27.6 wt % relative to carbon content). The large uptake capacity of this composite was attributed to the presence of high microporosity volume and a wide (1-30 nm) bimodal pore system consisting of extensive mesopore channels (2-30 nm) as well as large surface area. These capacity values of carbon-silica composites are competitive to results obtained for commercial coconut based carbon (31 wt %), and better than commercial alumina-carbon composite (9.5 wt %). / <p>QC 20130408</p>

Adsorbent materials for gas purification have been studied and developed for application in many areas. It is known that a single adsorbent may not adequately control multiple contaminants. Therefore, the development of adsorbent materials has accelerated over the past two decades, and is today an area attracting a lot of attention. In view of the global environmental movement for clean air, the development of improved sorbents will help address new challenges that cannot efficiently be met with the generic sorbents that are presently commercially available. On the other hand, the utilization of these new sorbents for specific applications within the area of molecular filtration remains largely unexplored. This thesis presents a synthesis of new sorbent materials, and the characterization and application of these materials for molecular filtration. Commercial adsorbents have been used for benchmarking for the pore properties, the applicability, and the performance of these new adsorbents. A double metal-silica adsorbent has been synthesized. The preparation procedure is based on the use of sodium silicate coagulated with various ratios of magnesium and calcium salts which yields micro-meso porous structures in the resulting material. The results show that molar ratios of Mg/Ca influence the pore parameters as well as the structure and morphology. The bimodal pore size can be tailored by controlling the Mg/Ca ratio. The effect of thermal treatment on pore parameters of these adsorbents has been investigated. The results show that heat treatment had a notable effect on the pore parameters, and that the pore structure was thermally stable even at 600°C.  A synthesis method has also been developed for the preparation of carbon-silica composites. The method involves a number of routes, which can be summarised as addition of activated carbon particles to (I) the paste, (II) the salt solution, or (III) with the sodium silicate solution. In route II and III the activated carbon is present also before coagulation. The routes presented here leads to carbon-silica composites possessing high micro porosity, meso porosity as well as large surface areas. The increase in micro porosity and surface areas was linear with carbon content. The results shows further that pore size distribution may be tailored based on the route of addition of the carbon particles. Following route I and III a wide pore size (1-30nm) was obtained where as by route II a narrow pore size (1-4nm) was observed. KOH or KMnO4 modified MgCa adsorbent varieties were also prepared. The impregnationwas performed by either a direct synthesis or post-synthesis procedure. Potassium hydroxide and potassium permanganate have been chosen as impregnate chemicals. Results revealed that theimpregnate amount significantly affected both the structural and the gas adsorption characteristics of the impregnated MgCa adsorbents. The properties of double- metal adsorbents, impregnated adsorbents and carbon-silica composites were characterized by various methods (X-ray diffraction, scanning electron microscopy, thermo gravimetric analysis, and nitrogen adsorption at 77K) to study the material structure and morphology, thermal stability, ignition temperature and porous parameters with regard to surface area, pore size, pore size distribution and porosity volume, which is important for optimizing their use in many practical application. The up-take performance of adsorbents for dynamic adsorption of SO2, H2S and toluene was performed in a system similar to the setup usedin ASHRAE 145.1. Finally the applicability and performance of the impregnated modified MgCa-silica adsorbents and composites have been evaluated for H2S, SO2 and toluene adsorption and compared to some commercial adsorbent materials. Results revealed that a potassium permanganate modified MgCa-adsorbent has a H2S adsorption capacity in the range of 0.08-3.19 wt % at 50% efficiency, and that the uptake capacity was relative to the amount of potassiumpermanganate loading. Moreover, KOH modified MgCa-adsorbent shows highest SO2 adsorption capacity (1.7 wt %) which is 3.47 times higher than commercial alumina impregnate with potassium permanganate (0.49 wt %). Carbon-silica composites on the other hand shows adsorption of toluene and high adsorption capacity was obtained when carbon content was 45 wt %. The results further shows that a composite with 45 wt % carbon and obtained via route I present the highest toluene adsorption capacity ( 27.6 wt % relative to carbon content) at 0% efficiency. The large uptake capacity of this composite was attributed to the presence of high microporosity volume and a wide (1-30nm) bimodal pore system consisting of extensive mesopore channels (2-30nm) as well as large surface area. These capacity values of carbon-silica composites are competitive to results obtained for commercial coconut based carbon (31 wt %), and better than commercial alumina-carbon composite. / QC 20110405

La propagation des ondes sismiques dans les milieux poreux multiphasiques présente des enjeux nombreux, tant sur le plan environnemental (risques naturels, géotechnique, pollutions de nappes...) que pour les réservoirs (aquifères, hydrocarbures, stockages de CO2...). L'utilisation des ondes sismiques pour étudier ces milieux se justifie par le fait qu'en se propageant, les ondes sont déformées par le milieu qu'elles traversent et contiennent ainsi des informations aux capteurs sur les phases fluides et solides et sur le squelette poreux. Ce travail de thèse s'intéresse aux caractéristiques des ondes sismiques dans les milieux multiphasiques (plusieurs phases fluides et solides), depuis la description physique jusqu'à la caractérisation des paramètres constitutifs par inversion, en passant par la modélisation numérique 2D de la propagation. La première partie du travail a consisté à décrire la physique des milieux multiphasiques (phase par phase et leurs intéractions dynamiques) en utilisant des méthodes d'homogénéisation pour se ramener à un milieu équivalent défini par sept paramètres. Ainsi, dans des milieux simple porosité saturés et dans des milieux plus complexes (double porosité, partiellement saturés ou visco-poroélastiques), je peux calculer la propagation des ondes sismiques sans approximation. En effet, j'utilise une méthode numérique dans le domaine fréquence-espace qui permet de prendre en compte tous les termes qui dépendent de la fréquence sans approximation. La discrétisation spatiale utilise une méthode d'éléments finis discontinus (Galerkin discontinu) qui permet de considérer des milieux hétérogènes.Je montre notamment que les attributs sismiques (vitesses et atténuations) des milieux poreux complexes sont fortement dispersifs et les formes d'ondes complètes, calculées sans approximation, sont fortement dépendantes de la description physique du milieu. La caractérisation des paramètres poroélastiques s'effectue par inversion. Une méthode en deux étapes a été proposée : la première consiste en une inversion ``classique`` (tomographie, inversion des formes d'ondes complètes) des données (sismogrammes) pour obtenir des paramètres macro-échelles (attributs sismiques). La seconde étape permet de reconstruire, à partir des paramètres macro-échelles, les paramètres poroélastiques micro-échelles. Cette étape d'inversion utilise une méthode d'optimisation semi-globale (algorithme de voisinage). Une analyse de sensibilité montre qu'en connaissant a-priori certains paramètres, on peut inverser avec précision les paramètres du squelette poroélastique ou retrouver la nature du fluide saturant, à partir des vitesses de propagation. En revanche, pour retrouver la saturation en fluide, il est préférable de connaître les atténuations. Deux applications réalistes (monitoring de réservoir et hydrogéophysique) mettent en oeuvre ce type d'inversion en deux étapes et démontrent qu'à partir de données estimées par des méthodes classiques d'imagerie, on peut remonter à certains paramètres poroélastiques constitutifs. / Seismic wave propagation in multiphasic porous media have various environmental (natural risks, geotechnics, groundwater pollutions...) and ressources (aquifers, oil and gas, CO2 storage...) issues. When seismic waves are crossing a given material, they are distorted and thus contain information on fluid and solid phases. This work focuses on the characteristics of seismic waves propagating in multiphasic media, from the physical complex description to the parameter characterisation by inversion, including 2D numerical modelling of the wave propagation. The first part consists in the description of the physics of multiphasic media (each phase and their interactions), using several upscaling methods, in order to obtain an equivalent mesoscale medium defined by seven parameters. Thus, in simple porosity saturated media and in complex media (double porosity, patchy saturation, visco-poroelasticity), I can compute seismic wave propagation without any approximation. Indeed, I use a frequency-space domain for the numerical method, which allows to consider all the frequency dependent terms. The spatial discretisation employs a discontinuous finite elements method (discontinuous Galerkin), which allows to take into account complex interfaces.The computation of the seismic attributes (velocities and attenuations) of complex porous media shows strong variations in respect with the frequency. Waveforms, computed without approximation, are strongly different if we take into account the full description of the medium or an homogenisation by averages. The last part of this work deals with the poroelastic parameters characterisation by inversion. For this, I develop a two-steps method: the first one consists in a classical inversion (tomography, full waveform inversion) of seismograms data to obtain macro-scale parameters (seismic attributes). The second step allows to recover, from the macroscale parameters, the poroelastic micro-scale properties. This downscaling step uses a semi-global optimisation method (neighbourhood algorithm), which allows the sampling of the full model space (thanks to the low numerical cost of the analytic direct model). With the a-priori knowledge of some parameters, a sensibility analysis shows that I can invert precisely skeleton parameters or the saturating fluid type, from the velocities only. Nevertheless, to recover the fluid saturation, it is preferable to use the attenuations. This two-steps procedure is tested on two realistic applications (reservoir monitoring and subsurface hydrogeophysics) and show that we can recover some constituve poroelastic parameters.