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The autocausticizing of sodium carbonate with colemaniteSozen, Gulgun January 1985 (has links)
Autocausticizing, a new method to regenerate sodium hydroxide from the sodium carbonate, is intended to replace the conventional Kraft Recovery System which uses calcium hydroxide produced in a lime kiln for this purpose. It is defined as the self-induced expulsion of carbon dioxide bound in the smelt by using certain amphoteric oxides. Thus autocausticizing can eliminate the need for a lime cycle and hence reduce the Kraft process capital and operating costs.
The reactions between sodium carbonate and a number of amphoteric oxides have been reported in the literature. Patents have been issued on the use of titanium dioxide, iron oxide and sodium borates for this purpose.
The sodium borates have the advantage of a high reaction rate, but are totally soluble and must be carried throughout the whole Kraft cycle. In this research colemanite (calcium borate) which is mined as a cheap mineral in California and in Turkey was studied as an autocausticizing agent. Since it is partially soluble and most likely can be recycled, it would eliminate the problems associated with the use of soluble borates.
Experiments were performed both isothermally and under constant heating rate conditions. Isothermal studies were made with Ti0₂, alumina and colemanite to compare their performances as autocausticizing agents at 900°C and 1000°C for various reaction times in an electric furnace. The second group of experiments was made using a differential Chermogravimetric (TG) analyzer. In these experiments mixtures with 20 to 80 weight percent colemanite in sodium carbonate were heated at a constant heating rate of 10°K/min in the range of 190-1000°C. The results indicate that two reaction were involved. Above the stoichiometric colemanite concentration the colemanite and sodium carbonate had reacted completely by a temperature of about 700°C. Above that temperature the impurities in the colemanite appeared to catalyze the decomposition of sodium carbonate if the colemanite concentration was less than the stoichiometric amount needed.
TG data were analyzed for the first and second reactions between the temperature ranges of 190-700°C and 700-1000°C respectively. Kinetic models were developed In terms of the reaction order, activation energy and frequency factor. The first reaction was found to be zero order on sodium carbonate concentration. The results also showed that the activation energy and frequency factor were functions of the colemanite concentration in the mixtures. As a result the rate was affected by the amount of colemanite used. The same was true for the second reaction except the reaction was first order. The concentrations
predicted for the isothermal tests by the model were compared with the results of the isothermal study for various colemanite concentrations. Reasonable agreement was found except for the values at lower conversions, which might be due to the Increased importance of the diffusion of CO₂ from the mixtures in the case of Isothermal runs. It was also found that it is possible to obtain conversions as high as 85 percent with 40 percent colemanite in 20 minutes. Promising results were obtained from the recycle tests as well. / Applied Science, Faculty of / Chemical and Biological Engineering, Department of / Graduate
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Avaliação do processo SuperBatchTM para produção de polpa celulósica a partir de Bambusa vulgaris / Evaluation of SuperBatch(TM) process for the production of pulp from Bambusa vulgarisSarto, Camila 21 September 2012 (has links)
O presente estudo teve como objetivo avaliar e comparar os processos de polpação kraft convencional e SuperBatchTM para Bambusa vulgaris visando a produção de polpa celulósica não branqueável (número kappa 58±2). A matéria prima foi caracterizada com relação à densidade básica, composição química e dimensões de fibras; foi realizado um estudo de pré-extração aquosa com as temperaturas de 50, 70 e 90°C durante 5 horas pesando-se os cavacos a cada 15 minutos para avaliar a absorção de água. Este mesmo procedimento foi feito à temperatura de 110°C com tempos de 15 minutos, 1, 2 e 5. Posteriormente foram avaliados os teores de extrativos totais e lignina dos cavacos oriundos das temperaturas 50, 70, 90 e 110°C nos tempos de 1 e 5 horas. Para os processos de polpação avaliou-se, o rendimento bruto, rendimento depurado, teor de rejeitos, ácidos hexenurônicos e alvura, além da eficiência da adição de um estágio de préextração aquosa. Os resultados obtidos mostram que a matéria-prima apresentou valores típicos para a espécie em questão no que diz respeito à densidade básica, composição química e morfologia das fibras. Através de uma regressão com os resultados de absorção de água e extrativos totais nas diferentes temperaturas foi estabelecido a temperatura 80°C e tempo de 1 hora como a ideal para a préextração aquosa. Para o processo de polpação kraft convencional o nível de deslignificação foi obtido com carga alcalina de 14% (base NaOH); para o processo SuperBatchTM o nível de deslignificação estabelecido foi obtido com uma carga de reagentes químicos de 16% (base NaOH). A impregnação aquosa contribuiu para uma melhor deslignificação somente no processo convencional. / The present study aimed to evaluate and compare the kraft pulping conventional processes and SuperBatchTM for Bambusa vulgaris aiming the production of pulp unbleached (kappa number 58 ± 2). The raw material was characterized with respect to basic density, chemical composition and morphology of fibers, was analyzed an aqueous pre-extraction temperatures of 50, 70 and 90 ° C for 5 hours weighing the chips to every 15 minutes to evaluate the absorption of water. The same procedure was done for 110 ° C were used time of 15 minutes, 1, 2 and 5 hours. After this stage were evaluated the total extractives and lignin content from the chips of the temperatures 50, 70, 90 and 110 ° C for 1 and 5 hours. For the pulping processes were evaluated, the total yield, screened yield, reject content, HexA and brightness, besides the efficiency of the addition of a pre-stage aqueous extraction. The results show that the raw material had values typical for the species in question with regard to density, chemical composition and fibers morphology. Through a regression with the results of water absorption and extractives was set at different temperatures the temperature 80 ° C as optimal for pre-aqueous extraction. For the conventional kraft pulping process the level of delignification was obtained with the alkali charge of 14% (based on NaOH); SuperBatchTM process for the level of delignification has been achieved with a set of chemical reactants load 16% (base NaOH). The aqueous pre-extraction contributed to a better delignification only in the conventional process.
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Polpação kraft de cavacos de espessura reduzida / Kraft pulping of thin chipsSchmidt, Flavia 28 August 2014 (has links)
Este trabalho teve como objetivo analisar os cavacos de dimensões reduzidas inseridos em cozimentos que se utilizam de menores tempos e maiores temperaturas, de maneira a se obter as bases para o estabelecimento de um novo processo e/ou a otimização dos sistemas atualmente utilizados em escala industrial. Amostras de cavacos de referência (3,6 mm, obtidas pelo processo convencional de picagem) e de cavacos com espessura de 0,5 mm, 1 mm e 2 mm (obtidas por um gerador de partículas), do híbrido de Eucalyptus urophylla x Eucalyptus grandis com 7 anos foram analisadas quanto à densidade básica, composição química e morfologia das fibras. Após a caracterização, os materiais foram submetidos à polpação kraft pelo processo convencional e foram testados três níveis de fator H com quatro níveis de álcali ativo de maneira a se estabelecer uma equação que representasse o processo e pudesse ser utilizada em cozimentos futuros. Através das equações obtidas foi possível calcular os parâmetros de rendimento depurado, álcali ativo residual, álcali ativo consumido, teor de sólidos secos, fator H e álcali ativo em função de um número kappa 18. Os resultados mostram que a densidade básica, a composição química e a morfologia das fibras da madeira não foram afetadas pelo processo de picagem. No entanto, a densidade a granel foi afetada pela espessura dos cavacos, sendo de 0,037, 0,081, 0,110 e 0,141 g.cm-³ para os cavacos de 0,5 mm, 1 mm, 2 mm e 3,6 mm respectivamente. No processo de polpação, as espessuras se comportaram de maneira semelhante, no entanto, a espessura de 2 mm apresentou o melhor número kappa para o fator H de 451, o de maior interesse, com o mesmo rendimento que as demais espessuras. Na análise de regressão, a espessura de 2 mm apresentou melhor rendimento, menor teor de sólidos e menor fator H (de 461), compatível com o que se pretende utilizar em processos de polpação com tempo reduzido de cozimento. / The objective of this work was to evaluate the performance of thin chips inserted on a short time and higher temperatures in cooking process, to obtain the basis for the establishment of a new process and / or the optimization of the currently systems used on an industrial scale. Samples of the reference chips (3,6 mm obtained by the conventional process of chipping) and thin chips with 0,5 mm, 1 mm and 2 mm (obtained by a particle generator) of the Eucalyptus urophylla x Eucalyptus grandis hybrid with 7 years of age had their density, chemical composition and fibers morphology evaluated. After the characterization, the materials were submitted to conventional kraft pulping process and three levels of H factor with four levels of active alkali were tested to establish an equation to represent the process that can be used on future cookings. Yield, residual active alkali, consumed active alkali, dry solids, H factor and active alkali were calculated through equations, according to a kappa number 18. The results show that the basic density, chemical composition and morphology of the wood fibers were not affected by the chipping process. However, the bulk density of 0,037, 0,081, 0,110 and 0,141 g.cm-³ for the 0,5 mm, 1 mm, 2 mm and 3,6 mm chips, respectively, was affected by the chip thickness. On the pulping process, the different chips had the same behavior, however, 2 mm chips showed the best kappa number to H factor 451, with the same yield as the other thickness. On the regression analysis, the 2 mm chips showed better performance, lower solids content and lower H factor (461), consistent with a short time pulping process.
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High consistency refining of mechanical pulps during varying refining conditions : High consistency refiner conditions effect on pulp qualityMuhic, Dino January 2008 (has links)
The correlation between pulp properties and operating conditions in high consistency (HC) refiners at Holmen Paper AB were studied. Two types of HC refiners were investigated: the Andritz RTS refiner at the Hallstavik Mill and the Sprout-Bauer Twin 60 refiner at the Braviken Mill. The objective of the study was to clarify the relationship between the pulp properties and refining conditions such as electrical energy input, housing- and feed- pressure and plate wear in high consistency refining. The results of this project show that worn segments reduce the operating energy maximum input and the pulp and handsheet properties in negative aspects such as lower tensile- and tear index, and shorter average fibre length. Energy input is an important factor in the refining process and influence Canadian Standard Freeness and the tensile index as evident from the probability residuals. Housing pressure and feed pressure influence the pulp quality and should be adjusted in order to optimise the refining process, although the effect is not as great as for energy input or plate wear. The results of the study indicate that Braviken Mill is operating at its optimum for the parameters measured in this project. Hallstaviks goal, to avoid fibre shortening and to obtain better tensile index, can be reached by making slight changes in pressure condition.
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An overall model of the combustion of a single droplet of kraft black liquorKulas, Katherine A. 01 January 1990 (has links)
No description available.
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An investigation of some factors affecting the corrosion of carbon steel boiler tube material exposed to simulated kraft smeltKulas, Gregory S. 01 January 1989 (has links)
No description available.
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Sulfur release during the pyrolysis of kraft black liquorHarper, Frank D. 01 January 1989 (has links)
No description available.
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Color removal from softwood, kraft, caustic extract effluent by polyaminesKisla, T. C. (Thomas Carl) 01 January 1976 (has links)
No description available.
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An investigation of the coloring matter of sulfite liquorSimerl, Linton Earl 01 January 1939 (has links)
No description available.
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The high temperature alkaline degradation of phenyl β-D-glucopyranosideMolinarolo, William E. 01 January 1989 (has links)
No description available.
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