We present an analysis of observations using the Spitzer Space Telescope and the James Clerk Maxwell Telescope of deeply embedded protostars in the Perseus Giant Molecular Cloud. Building on the results of Jørgensen et al. (2007), we attempt to characterize the physical properties of these deeply embedded protostars, discovered due to their extremely red near infrared colours and their proximity to protostellar cores detected at 850 μm. Using a grid of radiative transfer models by Robitaille et al. (2006), we fit the observed fluxes of each source, and build statistical descriptions of the best fits. We also use simple one dimensional analytic approximations to the protostars in order to determine the physical size and mass of the protostellar envelope, and use these 1D models to provide a goodness-of-fit criterion when considering the model grid fits to the Perseus sources. We find that it is possible to create red [3.6]-[4.5] and [8.0]-[24] colours by inflating the inner envelope radius, as well as by observing embedded protostars through the bipolar outflows. The majority of the deeply embedded protostars, however, are well fit by models seen at intermediate inclinations, with outflow cavity opening angles < 30o, and scattering of photons off of the cavity walls produces the red colours. We also discuss other results of the SED fitting.

A general analysis of the photon and lepton polarizations in the rare Bs &amp / #8594 / &amp / #61543 / l+l- decay by using the most general model independent form of the effective Hamiltonian is presented. The total and the differential branching ratios for these decays, when photon is in the positive and negative helicity states, are studied. The sensitivity of &quot / photon polarization asymmetry&quot / and the longitudinal, transverse and normal polarization asymmetries of final state leptons, as well as lepton-antilepton combined asymmetries in Bs &amp / #8594 / &amp / #61543 / l+l- decay to the new Wilson coefficients are also investigated. It is shown that all these physical observables are very sensitive to the existence of new physics beyond SM and their experimental measurements can give valuable information about it.

This thesis has addressed several of the fundamental challenges in correlating the structure thermal transport properties of complex nanoporous polycrystalline zeolite materials. Two types of zeolite materials, MFI and LTA, were employed in order to investigate the effects of temperature and both the framework and non-framework cations on the thermal conductivity of zeolite. The thermal conductivity values of both materials were measured using a well intergrown zeolite film 3-omega method. The thermal transport mechanisms in these materials were investigated by separately analyzing the contributions of different phonon scattering processes. This thesis represents our progress towards a robust framework for understanding and predicting thermal transport properties of zeolite materials and complex crystals in general. Furthermore, the important roles of boundary and defect scattering, as illustrated in this thesis, also imply that the thermal conductivity of zeolite materials can be tuned by exploiting not only the composition but also the pore structure. In addition, a non-equilibrium molecular dynamics simulation with external force was developed and employed to predict the thermal conductivity of materials. It has shown that this method can accurately predict the thermal conductivity of simple materials, such as argon and quartz; however, it failed to predict the thermal conductivity of complex materials, such as zeolite. This thesis presents possible factors that can explain the phenomena and future recommendations to elucidate this issue.

Ensemble simulations of smoke aerosol radiative effects with a regional climate model in the Amazon has been conducted to investigate the radiative effects of aerosols on clouds, rainfall, and circulation from dry to wet season. The results of the ensemble simulations suggest that the radiative effect of the smoke aerosols can reduce daytime surface radiative and sensible fluxes, the depth and instability of the planetary boundary layer (PBL), consequently the clouds in the lower troposphere in early afternoon in the smoke center, where the aerosols optical depth, AOD, exceeds 0.3. The aerosol radiative forcing also appears to weaken moisture transport into the smoke center and increase moisture transport and cloudiness in the region upwind to the smoke center, namely, the northern Amazon. Anomalous wind convergence over the equatorial western Amazon occurs to compensate the anomalous wind divergence in the southern Amazon, leading to an increase of both clouds and rainfall in that region. The increased atmospheric thermodynamic stability in Southern Amazonia also appears to block synoptic cyclonic activities propagated from extratropical South America, leading to an increased synoptic cyclonic activities and rainfall in southern Brazil, Paraguay and northern Argentina. Evidently, the dynamic response of the monsoon circulation plays a major role in determining the pattern of rainfall change induced by the radiative effect of the aerosols.

Ο σκοπός της παρούσας διδακτορικής διατριβής ήταν η μελέτη δύο σημαντικών φαινομένων μεσοαστρική ύλης όπως είναι τα Πλανητικά Νεφελώμάτα (ΠΝ) και η ράβδος των σπειροειδών γαλαξιών. Πιο συγκεκριμένα, μελετήθηκαν 44 ΠΝ στην περιοχή του Γαλαξιακού σφαιροειδούς (Boumis et al. 2003; 2006) και προσδιορίστηκαν οι φυσικοί παράμετροι τους, όπως είναι η ενεργός θερμοκρασία και η λαμπρότητα του κεντρικού αστεριού, η πυκνότητα και η θερμοκρασία των ηλεκτρονίων, η αφθονία των Ηe, N, O, S κτλ., χρησιμοποιώντας το μοντέλο φωτο-ιονισμού Cloudy (Akras et al. 2010a). Επίσης, μελετήθηκε η ράβδος των γαλαξιών, χρησιμοποιώντας το μοντέλο διάδοσης ακτινοβολίας CRETE, με σκοπό να ερευνηθεί πώς η ύπαρξη της ράβδου επηρεάζει την μορφολογία των γαλαξιών και την σκόνη τους. Ταυτόχρονα, προσδιορίστηκαν οι παράμετροι της ράβδου, όπως το μήκος, το ύψος, η γωνία κλίσης και η γωνία θέσης της για 4 ραβδωτούς σπειροειδείς γαλαξίες (NGC 4013, UGC 2048, IC 2531 και το Γαλαξία μας). Στο πρώτο μέρος της μελέτης, διαχωρίστηκαν τα ΠΝ ανάλογα με την μορφολογία τους σε σφαιρικά, ελλειπτικά και διπολικά και βρέθηκε ότι η αφθονία του Ηe και του Ν είναι μεγαλύτερη στην τελευταία κατηγορία σε σχέση με τις υπόλοιπες. Επιπλέον, η χρήση του στατιστικού εργαλείου PCA, έδειξε ότι τα κυκλικά και τα ελλειπτικά ΠΝ διαχωρίζονται από τα διπολικά, βάσει της τιμής του λόγου log(Ν/Ο), ο οποίος παίρνει αρνητικές και θετικές τιμές για τα διπολικά, ενώ μόνο αρνητικές τιμές στις υπόλοιπες κατηγορίες. Η κρίσιμη τιμή βρέθηκε ίση με -0.18 dex και αντιστοιχεί σε μάζα προγενέστερου αστεριού ίση με 2.6 (Akras & Boumis 2007). Στο δεύτερο μέρος, περιγράφηκε η ράβδος των γαλαξιών χρησιμοποιώντας την συναρτησιακή ελλειψοειδής υπερβολής. Μεταβάλλοντας την γωνία κλίσης του γαλαξία, η δομή σχήματος «Χ», η οποία παρατηρείται στις ράβδους, μπορεί να παρατηρηθεί μόνο για γωνίες μεγαλύτερες από 60ο. Επιπρόσθετα, στην περίπτωση του Γαλαξία μας, βρέθηκε ότι η γωνία θέσης της ράβδου είναι γύρω στις 25ο και το μήκος της 3.75 kpc (Akras et al. 2010b). Λαμβάνοντας υπόψη ότι η μέση τιμή του μήκους της ράβδου στους γαλαξίες είναι μεταξύ 3.0 και 4.0 kpc, προκύπτει ότι για τον NGC 4013 η γωνία θέσης του είναι μεταξύ 5 και 10 μοίρες, για τον UGC 2048 μεταξύ 40 και 50 μοίρες, για τον IC 2531 35 και 45 μοίρες ενώ τέλος για το Γαλαξία μας υπολογίζεται μεταξύ 20 και 30 μοίρες (Akras et al. 2010b). / The aim of this PhD thesis was the study of two very important interstellar medium phenomena like the Planetary Nebulae (PNe) and the stellar bar in spiral galaxies. In particular, we studied 44 PNe in the Galactic bulge region and we determined their physical parameters, like the effective temperature and luminosity of the central star, the electron temperature and density, the abundance of He, N, O, S etc., using the photo-ionization model “Cloudy” (Akras et al. 2010a). It was also pursued to study the stellar bar component using the 3D radiative transfer model CRETE, in order to investigate the effects of a stellar bar component to the morphology of the galaxy and its dust content. In addition, the parameters of the bar component such as the length, the height, the inclination angle and the position angle were determined for four spiral galaxies (NGC 4013, UGC 2048, IC 2531 and our Galaxy). In the first part of the thesis, the PNe were separated according to their morphology (spherical, elliptical and bipolar shape) and we found that the He and N abundances are greater in bipolar PNe. Moreover, by using the statistical tool PCA, it was found that the circular and the elliptical PNe are different from the bipolar, since the log(O/N) takes negative values in the first two and positive or negative values in the bipolar PNe. The critical value was found at -0.18 dex, which corresponds to a stellar mass of 2.6 (Akras & Boumis 2007). In the second part, we managed to accurately describe the morphology of the bar component by using the function of hyperbolic ellipse. For different inclination angles of the observed galaxies, it was found that the “X-shape" feature can be seen only in the case where the inclination angle is greater than 60 degrees. In the case of Milky Way, it was found that the position angle of the bar is approximately 25 degrees and the length equals to 3.75 kpc (Akras et al. 2010b). Considering that the mean length of the bar component is equal to 3.0-4.0 kpc, it was determined that the position angle of a) NGC 4013 takes values between 5 and 10 degrees, b) UGC 2048 takes values between 40 and 50 degrees, c) IC 2531 takes values between 35 and 45 degrees, and our Galaxy takes values between 20 and 30 degrees (Akras et al. 2010b).

Le carbone-suie, ou “black carbon” (BC), contribue au réchauffement climatique avec un forçage positif de l’ordre de +1.1 W m-2 dont l’incertitude reste haute (de l’ordre de 90%). Ce forçage s’effectue à travers l’interaction aérosol-radiation et l’interaction aérosols-nuage. Ces deux mécanismes sont affectés par le degré de mélange des particules du BC avec divers matériaux non-réfractaires et non-absorbants. Cependant, les estimations du forçage radiatif considèrent rarement les effets du mélange interne. Par ailleurs le rôle du BC comme noyau glaçogène qui influence l’interaction aérosol-nuage est largement inconnu. L’objectif de cette thèse est de mieux comprendre les mécanismes par lesquels le degré de mélange interne du BC influence la variabilité des propriétés optiques du BC et les propriétés d’activation des noyaux glaçogènes contenant du BC.Dans le premier chapitre de cette thèse, nous avons exploré la variabilité spatiale et saisonnière du coefficient d’absorption massique -mass absorption cross-section (MAC)- dans l’atmosphère en Europe. Les valeurs de MAC sont déterminées à partir de concentrations de carbone élémentaire et de coefficients d’absorption observée à différentes stations d’observation européenne du réseau ACTRIS (Aerosol, Cloud and Trace gases Research InfraStructure). Les résultats montrent une faible variabilité spatiale du MAC avec une moyenne de 10 ± 2.5 m2 g-1 à 637 nm de longueur d’onde qui peut être considérée comme représentative du BC en Europe. Le cycle saisonnier du MAC est probablement lié à la composition chimique de l’aérosol et son état de mélange, qui provoque une augmentation du MAC.Dans le second chapitre on s’est intéressé au lien entre l’absorption du BC et son état de mélange après transport sur longue-distance. Ce travail se base sur des mesures effectuées dans le cadre du projet CLIMSLIP (CLimate IMpact of Short-Lived Pollutants and methane in the Arctic). Une campagne de mesure a été conduite sur la station de recherche Zeppelin au Svalbard, Norvège en Avril 2012. Les données acquises avec un Single Particle Soot Photometer (SP2) révélaient que le BC est généralement présent en mélange interne dont l’épaisseur moyenne de la couche superficielle de matériel non-absorbant est de 47 nm pour des particules de BC de diamètre compris entre 170 et 280 nm. Ce mélange interne conduit à une augmentation d’absorption de 46%. Elle entraîne cependant une diminution relativement faible de l’albédo de simple diffusion, de l’ordre de 1%.Enfin, la capacité du BC à agir comme noyaux glaçogène pour la formation de cristaux de glace a été étudiée sur le site de haute altitude du Jungfraujoch (Suisse) dans le cadre du “cloud and aerosol characterization experiment” (CLACE) en 2013. Les différents éléments du nuage étaient séparé à partir d’une prise d’entrée type ice-CVI connectée au SP2. Ce dispositif permet de sélectionner uniquement les cristaux de glace et quantifier la fraction de BC activée. Une réduction de la présence de BC dans les résidus de glace a été observée. Des mesures de l’épaisseur de la couche de mélange interne des particules contentant du BC ont montré que les résidus de cristaux de glace présentaient des enrobages bien plus épais comparée à l’aérosol total.Les résultats obtenus au cours de ce travail ont permis de mieux comprendre l’impact du degré de mélange interne sur les propriétés optiques du BC et sur son rôle dans la formation de cristaux de glace. Les propriétés optiques du BC évoluent en fonction de la saison, tandis que la formation d’une couche superficielle amplifie sa capacité d’absorption du rayonnement solaire. De plus, cette étude souligne l’importance du vieillissement atmosphérique du BC sur sa capacité à servir de noyau de nucléation de la glace. Enfin, il fournit une avancée au sujet des propriétés sensibles mesurées dans l’atmosphère avec des techniques innovantes qui permettront la simulation plus précise du forçage radiatif. / Black carbon (BC) induces a warming effect (RFBC = +1.1 W m-2 ± 90%) through two main pathways: aerosol-radiation interaction (RFari) and aerosol-cloud interaction (RFaci). Both BC-radiation and BC-cloud interaction are affected by the mixing of black carbon with other non-refractory and non-absorbing matter present in the atmosphere. An estimation of the global radiative forcing of BC rarely accounts for internal mixing of BC while the net global cloud radiative forcing is sensitive to assumptions in the initiation of cloud glaciation, which is mostly unknown for black carbon particles. Within this thesis we investigated the variability of the light absorbing properties of black carbon, the mixing of black carbon, and the impact on light absorption and ice activation.In the first part of this thesis we investigated the spatial and seasonal variability of the mass absorption cross section (MAC) over Europe. MAC values were determined from ambient observations of elemental carbon mass concentrations (mEC) and absorption coefficients (σap). The data had been acquired during several years at different background ACTRIS supersites spread over Europe. Site specific MAC values were found to be spatially homogeneous, suggesting that the overall MAC average 9.5 ± 1.9 m2 g-1 at a wavelength of 637 nm might be representative of BC at European background locations. The MAC values showed a distinct seasonal cycle at every station. This seasonality might be related to chemical composition and aging. We observed that the MAC value has a linear and positive proportionality with the non-absorbing matter mass fraction.The second part of the work focuses on the coating acquisition of BC and the induced absorption enhancement after long-range transport. Within the CLIMSLIP (climate impact of short-lived pollutants and methane in the Arctic) project field experiments were conducted at the Zeppelin research site in Svalbard, Norway, during the Arctic spring. SP2 data were used to characterize the BC size distribution and mixing. BC containing particles having a core diameter between 170 and 280 nm were found to have a median coating thickness of 47 nm. The relationship between coating thickness and BC absorption was simulated. The observed coating thickness enhanced the mass absorption cross section by 46%, which led to a decrease of less than 1% in the single scattering albedo.In the final part of this work, the role of black carbon as ice nuclei in mixed phase clouds was investigated at the high elevation measuring site Jungfraujoch (Switzerland) during the cloud and aerosol characterization experiment (CLACE) held in 2013. The ice-CVI inlet and a single particle soot photometer were used to select and quantify the ice activated BC particles. According to the observations, BC containing particles were depleted in the ice residuals. The activation efficiency showed a size dependency, with larger BC containing particles being activated more efficiently compared to smaller ones. Activated BC cores having a diameter between 170 and 240 nm showed a larger coating thickness (median = 53 nm) compared to the total aerosol (median = 16 nm).The results obtained in this thesis shed new light on the effect of the mixing state on the optical properties and cloud activation of black carbon particles. Absorbing properties of BC showed a distinct seasonal pattern, while aging was found to consistently increase its absorption behavior. However, black carbon was found not to act as ice nuclei in low tropospheric mixed-phase clouds, where the coating thickness might play a role in the activation efficiency. This work provides freshly determined physical properties derived from ambient observations that will improve the accuracy of future aerosol and cloud radiative forcing estimations.

Le cycle de condensation/sublimation du CO2 contrôle le climat martien et forme en hiver des dépôts saisonniers glacés, contaminés en glace d’eau et en poussière. L’objectif de cette thèse est de comprendre, caractériser, et si possible quantifier les différents processus microphysiques des dépôts saisonniers durant ce cycle de condensation/sublimation à l’aide de la simulation, en laboratoire, de ces processus à l’intérieur de la cellule expérimentale CarboN-IR. La condensation de glace de CO2 polycristalline sur un régolithe minéral, la modification du régime de condensation de la glace de CO2 dans la nuit polaire en présence de gaz non condensables, la stratification de glace d’eau sur la glace de CO2 lors de la sublimation des dépôts saisonniers et la remontée d’albédo de la glace polycristalline de CO2 lors de sa sublimation au printemps sont les phénomènes ayant été reproduits avec succès dans la cellule expérimentale. La condensation de glace polycristalline de CO2 sur Mars a également été observée durant sa formation, en automne, aux latitudes plus basses que la nuit polaire à l’aide des données du spectromètre OMEGA, de la sonde Mars Express. L’objet le plus lointain du système solaire à avoir été exploré, Pluton, partage de nombreux points communs avec Mars, notamment la couverture d’une partie de sa surface par des glaces (de CH4, N2 et CO pour Pluton) en équilibre avec son atmosphère. L’évolution de ces glaces peut être considérée comme analogue en termes de processus de surface les affectant : stratification des glaces en fonction de leur volatilité lors de leur sublimation où condensation à la surface, formation de glace sous forme polycristalline,... . Les données d’imagerie hyperspectrale (LEISA) fournies par la sonde New Horizons lors de son survol de Pluton en juillet 2015 ont permis la cartographie précise des espèces chimiques présentes à sa surface, ainsi que de leur état physique, étapes préliminaires à toute interprétation géologique. / The condensation/sublimation cycle of CO2 controls the martian climate and, in winter, forms frozen seasonal deposits, contaminated with water ice and dust. This thesis’ objective is to unders- tand, characterize, and if possible, to quantify the different microphysical processes occuring in the seasonal deposits during this condensation/sublimation cycle, with the insight of experimental simulation of these processes inside the CarboN-IR experimental cell. The CO2 ice condensation in a polycristalline form on a mineral regolith, the modification of the CO2 ice condensation regime in the martian polar night due to the presence of non condensable gases, the stratification of water ice onto CO2 ice during the sublimation of the seasonal deposits and the increase of the albedo of CO2 slab ice during its springtime sublimation are all phenomena that have been reproduced successfully inside the experiemental cell. The CO2 slab ice condensation on the Martian surface has been observed during its formation, in autumn, at lower latitudes than polar night limit with hyperspectral imaging from the OMEGA spectrometer onboard of the Mars Express probe. Yet the farthest object explored in the solar system, Pluto, shares many similarities with Mars, parti- cularly a partial icy cover of its surface (of CH4, N2 and CO ices for Pluto) in equilibrium with its atmosphere. The evolution of these ices can be considered similar in terms of the surface pro- cesses affecting them : stratification of ices in function of their volatility during their sublimation or condensation at the surface, formation of slab ice ... The hyperspectral imagery data (LEISA), provided by the New Horizons probe during its Pluto’s flyby in july 2015, allowed to determine the accurate cartography of chemical species at the surface, along with their physical state - the preliminary steps of any geological interpretation.

The parameterization of radiative transfer is a part of numerical weather prediction and general circulation models that is both essential and computationally very expensive, and is therefore subject to never­ending compromises between accuracy and computational cost. The present thesis offers an improvement to the existing broadband radiation scheme by revising its critical components - gaseous transmissions, cloud optical properties, and calculation of internal longwave exchanges. The accuracy of the full­spectrum broadband approach is thus raised to the level required for the short range numerical weather forecast. The intermittent update of broadband gaseous transmissions is introduced as a new component, reducing computational cost while preserving the full cloud­radiation interaction. The scalability of longwave computations is ensured by adopting the net exchanged rate decomposition with bracketing, improved by an intermittently applied self­learning algorithm determining the interpolation weights. It has been demonstrated that under conditions of operational weather forecasting, this developed scheme is fully competitive with the mainstream approach, due to the improved error balance between the...

In this thesis, I study numerical and semi-analytical models of self-gravitating protostellar discs, with the aim of furthering our understanding of the role of disc-self gravity in planet formation. At the time of writing, the ALMA era of observational astronomy is upon us. Therefore, I place my research into this context with synthetic images of both numerical and semi-analytical models. I begin with an examination into the apparent lack of convergence, with increasing resolution, of the fragmentation boundary in Smoothed Particle Hydrodynamics (SPH) simulations of a protostellar disc. I run a suite of SPH with different numerical implementations, and find that even very similar implementations can fundamentally change the final answer. I analyse a suite of SPH simulations that fragment to form gravitationally bound objects, with the motivation of informing future population synthesis model development. I find that fragment-fragment and fragment-disc interaction dominates the orbital evolution of the system even at very early times, and any attempt to produce a population of objects from the gravitational instability process must include these interactions. Before a disc fragments, it will go through a self-gravitating phase. If the disc cools globally on a timescale such that it is balanced by heating due to gravitational stresses, the disc will be in a state of quasi-equilibrium. So long as the disc mass is sufficiently low, and spirals are sufficiently tightly wound, then angular momentum transport can be described by the local approximation, for which there is an analytical description. Using this analytical description, I develop an existing 1D model into 3D, and examine a wide range of parameter space for which disc self-gravity produces significant non-axisymmetry. Using radiative transfer calculations coupled with synthetic observations, I determine that there is a very narrow range of parameter space in which a disc will have sufficiently large gravitational stresses so as to produce detectable spirals, but the stresses not be so large as to cause the disc to fragment. By developing a simple analytical prescription for dust, I show that this region of parameter space can be broadened considerably. However, it requires grains that are large enough to become trapped by pressure maxima in the disc, so I conclude that if self-gravitating spiral arms are detected in the continuum, it is likely that at least some grain growth has taken place.

Simulações acopladas do escoamento reativo e dos processos de transferência de calor para o estudo de chamas são problemas dispendiosos computacionalmente. A transferência de calor por radiação em processos de combustão, devido às elevadas temperaturas, é o processo de troca energética dominante. Ainda, o comportamento altamente irregular do coeficiente de absorção com o comprimento de onda se constitui em uma dificuldade adicional na modelagem da transferência radiativa em meios participantes. Para contornar essa dificuldade modelos espectrais foram desenvolvidos com o objetivo de simular o comportamento de um gás real. Dentre esses modelos destacam-se o gás cinza (GG: Gray Gas), o mais simples, que negligencia o comportamento espectral do coeficiente de absorção, e o modelo da soma-ponderada-de-gases-cinza (WSGG: Weighted-Sum-of-Gray-Gases) onde a integração sobre todo o espectro é substituída por um número finito de gases cinza. Com o avanço de ferramentas computacionais, principalmente códigos CFD (Computational Fluid Dynamics), abordagens computacionais se tornaram atrativas frente ou em complemento às abordagens experimentais. Desse modo, o presente trabalho tem por objetivo a aplicação dos modelos WSGG e GG com novas correlações na simulação detalhada de chamas difusivas laminares de metano diluído com dióxido de carbono e nitrogênio com o código CFD comercial ANSYS/Fluent. Foram desenvolvidas rotinas de usuário (UDF: User-Defined Functions) para o acoplamento dos modelos espectrais ao código CFD. A verificação das rotinas de usuário foi realizada comparando os resultados obtidos via simulação Fluent com dados obtidos pelo modelo WSGG com um código FORTRAN próprio desenvolvido pelo grupo de pesquisa do Laboratório de Radiação Térmica (LRT/UFRGS) para o problema unidimensional de superfícies negras e infinitas preenchidas por um meio não-isotérmico e não-homogêneo. Os erros encontrados para o fluxo de calor radiativo nas superfícies e para o termo fonte radiativo ao longo do meio foram da ordem de 1% indicando o funcionamento correto das rotinas UDF acopladas ao Fluent. Por fim, as rotinas foram aplicadas na simulação numérica para chamas de potência constante com diluição dos reagentes e os dados obtidos com a solução numérica foram comparados com dados experimentais para a fração radiante e fluxo de calor radiativo. Os desvios médios encontrados para o fluxo de calor radiativo ficaram em torno de 10% para todas as chamas, excetuando as chamas com diluição de CO2 de 30%, 40% e 50%, em volume, para as quais os desvios médios ficaram em torno de 15%. O termo fonte para as chamas apontou para a predominância da emissão do meio em relação à absorção. Todas as chamas estudadas se encontram no regime opticamente fino (optically thin) para o qual, segundo apontam estudos da literatura, a escolha do modelo espectral possui impacto pequeno em resultados globais da chama como a temperatura e a concentração das espécies na mistura. Nesse aspecto os resultados encontrados concordaram com a previsão da literatura, entretanto para a transferência radiativa, o modelo GG se mostrou sensivelmente menos preciso em comparação ao modelo WSGG, principalmente para a fração radiante e para o fluxo radiativo na região da pluma aquecida, indicando a dependência do modelo espectral adotado. / Coupled simulations of the reactive flow with the heat transfer processes for flame studying are computationally demanding problems. The radiative transfer in combustion processes is the main heat transfer mechanism due to the high temperatures involved. However, the highly irregular behavior o f the absorption coefficient with the wavenumber composes in an additional difficulty on modeling the radiative transfer in participating media. In order to overcome this issue, spectral models were developed with the objective of simulate the behavior of real gases. Some of the most known models are the gray gas (GG) for which the spectral behavior of the radiative properties of the medium is neglected and the weighted-sum-of-gray-gases (WSGG) for which the integration over the entire spectrum is replaced by a summation over a finite number of gray gases with constant absorption coefficients. With the development of computational tools, mainly Computational Fluid Dynamics (CFD) codes, numerical approaches became attractive instead or in complement of experimental set ups. In this way, the present work aims to couple the WSGG and the GG models with new correlations in a detailed simulation of diffusive laminar flames of methane diluted with carbon dioxide and nitrogen with the commercial CFD code ANSYS/Fluent. User-defined functions (UDF) were developed to the coupling of the spectral models. The verification was carried out through the WSGG model by comparing the Fluent solution with a solution obtained with a FORTRAN code developed by the Thermal Radiation Laboratory (LRT/UFRGS) research group for the one-dimensional system of black surfaces filled with a non-homogeneous and non-isothermal medium. The deviations for the radiative heat flux for the walls and the radiative heat source along the domain were of 1% or less, indicating the correct coupling between the UDF routines and the CFD code. Finally, the UDF were applied in the solution of constant power flames with fuel diluted with carbon dioxide and nitrogen. The obtained data was then compared with experimental measurements for the radiant fraction and the radiative heat flux along the flame axis. The average deviations found were in order of 10% for all flames, except for the flames with 30%, 40% and 50% of CO2 dilution, in volume, for which the deviatioms found were in order of 15%. The radiative heat source was plotted and indicated for the medium emission predominance in comparison with the medium absorption. All flames studied were optically thin flames for which, studies pointed, the spectral model have minor impact over global results as flame temperature and mixture concentration. For this aspect the results found showed agreement with the literature studies predictions, however the GG model showed itself less accurate in comparison with the WSGG model for the radiant fraction and the radiative heat flux computations. So the spectral models have influence on the radiative transfer even if its effect on flame structure can be negligible.