Reactive transport modelling has wide applications in geosciences. In the field of hydrogeology, it has been utilised to simulate the biogeochemical processes that disperse and degrade contaminants in the aquifer. For geotechnical applications, such as geological CO2 sequestration, the reaction of CO2 with the ambient saline aquifer determines the final success of storage. In a radioactive waste repository, scientists rely on reactive transport models to predict the mobilisation of hazardous radionuclides within space and time. In this work, the multi-component mass transport code OpenGeoSys, was coupled with two geochemical solvers, the Gibbs Energy Minimization Selektor (GEM) and the Biogeochemical Reaction Network Simulator (BRNS). Both coupled codes were verified against analytical solutions and simulation results from other numerical models. Moreover, the coupling interface was developed for parallel simulation. Test runs showed that the speed-up of reaction part had a very good linearity with number of nodes in the mesh. However, for three dimensional problems with complex geochemical reactions, the model performance was dominated by solving transport equations of mobile chemical components. OpenGeoSys-BRNS was applied to a two dimensional groundwater remediation problem. Its calculated concentration profiles fitted very well with analytical solutions and numerical results from TBC. The model revealed that natural attenuation of groundwater contaminants is mainly controlled by the mixing of carbon source and electron donor. OpenGeoSys-GEM was employed to investigate the retardation mechanism of radionuclides in the near field of a nuclear waste repository. Radium profiles in an idealised bentonite column was modelled with varying clay/water ratios. When clay content is limited, Ba-Sr-Ra sulfate solid solutions have a very strong retardation effect on the aqueous radium. Nevertheless, when clay mineral is abundant, cation exchange sites also attract Sr and Ba, thus dominates the transport of Ra.

Reactive transport modelling has wide applications in geosciences. In the field of hydrogeology, it has been utilised to simulate the biogeochemical processes that disperse and degrade contaminants in the aquifer. For geotechnical applications, such as geological CO2 sequestration, the reaction of CO2 with the ambient saline aquifer determines the final success of storage. In a radioactive waste repository, scientists rely on reactive transport models to predict the mobilisation of hazardous radionuclides within space and time. In this work, the multi-component mass transport code OpenGeoSys, was coupled with two geochemical solvers, the Gibbs Energy Minimization Selektor (GEM) and the Biogeochemical Reaction Network Simulator (BRNS). Both coupled codes were verified against analytical solutions and simulation results from other numerical models. Moreover, the coupling interface was developed for parallel simulation. Test runs showed that the speed-up of reaction part had a very good linearity with number of nodes in the mesh. However, for three dimensional problems with complex geochemical reactions, the model performance was dominated by solving transport equations of mobile chemical components. OpenGeoSys-BRNS was applied to a two dimensional groundwater remediation problem. Its calculated concentration profiles fitted very well with analytical solutions and numerical results from TBC. The model revealed that natural attenuation of groundwater contaminants is mainly controlled by the mixing of carbon source and electron donor. OpenGeoSys-GEM was employed to investigate the retardation mechanism of radionuclides in the near field of a nuclear waste repository. Radium profiles in an idealised bentonite column was modelled with varying clay/water ratios. When clay content is limited, Ba-Sr-Ra sulfate solid solutions have a very strong retardation effect on the aqueous radium. Nevertheless, when clay mineral is abundant, cation exchange sites also attract Sr and Ba, thus dominates the transport of Ra.

Die Bildung und Beständigkeit von CSH-Phasen wurde in Abhängigkeit von Zeit, Ca/Si-Verhältnis, Temperatur, SiO2-Reaktivität, w/s-Verhältnis und NaCl-Sättigung der Lösung untersucht. Semikristalline CSH-Phasen bilden tobermoritähnliche Schichtstrukturen aus und weisen trotz ihrer Metastabilität hohe Beständigkeit bei 25 °C auf. Durch Erhöhung von Temperatur und w/s-Verhältnis wird deren Umwandlung zu kristallinen CSH-Phasen begünstigt, während NaCl-Sättigung der wässrigen Lösung die Kristallisation hemmt. Die Löslichkeit von CSH-Phasen ändert sich ebenfalls durch Variation von Temperatur und NaCl-Konzentration. Die NaCl-Sättigung führt in Folge der teilweisen Substitution von Ca2+ durch Na+ in den Festphasen zu einer deutlichen Erhöhung der Ca2+-Konzentrationen in Lösung. Mischphasenmodelle beschreiben dieses Verhalten in Berechnungen zumeist nicht hinreichend. Die Erweiterung der Datenbasis und Anpassungen der Modelle sind nötig. Mg2+-haltige Kontaktlösungen führen zur Auflösung von CSH- unter Bildung von MSH-Phasen.

The aim of this doctoral dissertation is to assess the probable impact of ionizing radiation on the public health and the environment (including fauna and flora) in the vicinity of nuclear power engineering objects (in case of the Maišiagala near-surface radioactive waste repository – by evaluating the possible impact on the human health, while in case of the Ignalina NPP cooling basin, Lake Drūkšiai – by evaluating the possible impact on the freshwater ecosystem biota) by applying probabilistic methods as well as to determine whether this activity after assessment of its character and impact on the environment meets the standards valid in the Republic of Lithuania or in the European Union and is permissible at a selected site at present or in the future. In the work two main programs, RESRAD-OFFSITE and ERICA, using scattering of site-specific parameter values and probabilistic (correlation, regressive, sensitivity, etc.) analysis, have been applied. It has been determined that in the environment of the Maišiagala repository after installation of additional protective barriers the annual effective human exposure dose is significantly lower as compared to the limited dose and 95th percentile dose not exceed the exposure of 1 mSv per year regulated in the hygiene standards. The exposure dose rate of standardized organisms of Lake Drūkšiai, the Ignalina NPP cooler, freshwater ecosystem biota due to the INPP discharges and waterway radionuclide migration from a hypothetic... [to full text] / Šios daktaro disertacijos tikslas - įvertinti galimą jonizuojančiosios spinduliuotės poveikį visuomenės sveikatai ir aplinkai (tame tarpe gyvūnijai ir augalijai) branduolinės energetikos objektų aplinkoje (Maišiagalos radioaktyviųjų atliekų saugyklos atveju - vertinant galimą poveikį žmogui, ir IAE aušintuvo Drūkšių ežero atveju - vertinant galimą poveikį gėlavandenės ekosistemos biotai), taikant tikimybinius metodus; nustatyti, ar ši veikla, įvertinus jos pobūdi ir poveikį aplinkai, atitinka Lietuvos Respublikoje arba Europos Sąjungoje galiojančius standartus, yra leistina pasirinktoje vietoje dabartiniu laikotarpiu arba ateityje. Darbe buvo taikomos 2 pagrindinės programos: RESRAD-OFFSITE ir ERICA., naudojant vietines sąlygas atitinkančius parametrų verčių išbarstymą, taikant tikimybinę (koreliacinę, regresinę, jautrio ir kt.) analizę. Nustatyta, kad, įrengus papildomus apsauginius barjerus, Maišiagalos saugyklos aplinkoje metinė efektinė gyventojų apšvitos dozė yra ženkliai mažesnė lyginant su apribotosios dozės dydžiu, 95 procentilė nesiekia higienos normose patvirtintos 1mSv per metus ribinės dozės dydžio. Ignalinos AE aušintuvo Drūkšių ežero gėlavandenės ekosistemos biotos standartizuotųjų organizmų apšvitos dozės galia dėl IAE nuotekų ir radionuklidų sklaidos vandens keliu iš hipotetinio Stabatiškės radioaktyviųjų atliekų kapinyno rodo, kad apšvitos dozės galia dėl antropogeninės kilmės radionuklidų jonizuojančiosios spinduliuotės poveikio neviršija Europos Sąjungoje... [toliau žr. visą tekstą]

Šios daktaro disertacijos tikslas - įvertinti galimą jonizuojančiosios spinduliuotės poveikį visuomenės sveikatai ir aplinkai (tame tarpe gyvūnijai ir augalijai) branduolinės energetikos objektų aplinkoje (Maišiagalos radioaktyviųjų atliekų saugyklos atveju - vertinant galimą poveikį žmogui, ir IAE aušintuvo Drūkšių ežero atveju - vertinant galimą poveikį gėlavandenės ekosistemos biotai), taikant tikimybinius metodus; nustatyti, ar ši veikla, įvertinus jos pobūdi ir poveikį aplinkai, atitinka Lietuvos Respublikoje arba Europos Sąjungoje galiojančius standartus, yra leistina pasirinktoje vietoje dabartiniu laikotarpiu arba ateityje. Darbe buvo taikomos 2 pagrindinės programos: RESRAD-OFFSITE ir ERICA., naudojant vietines sąlygas atitinkančius parametrų verčių išbarstymą, taikant tikimybinę (koreliacinę, regresinę, jautrio ir kt.) analizę. Nustatyta, kad, įrengus papildomus apsauginius barjerus, Maišiagalos saugyklos aplinkoje metinė efektinė gyventojų apšvitos dozė yra ženkliai mažesnė lyginant su apribotosios dozės dydžiu, 95 procentilė nesiekia higienos normose patvirtintos 1mSv per metus ribinės dozės dydžio. Ignalinos AE aušintuvo Drūkšių ežero gėlavandenės ekosistemos biotos standartizuotųjų organizmų apšvitos dozės galia dėl IAE nuotekų ir radionuklidų sklaidos vandens keliu iš hipotetinio Stabatiškės radioaktyviųjų atliekų kapinyno rodo, kad apšvitos dozės galia dėl antropogeninės kilmės radionuklidų jonizuojančiosios spinduliuotės poveikio neviršija Europos Sąjungoje... [toliau žr. visą tekstą] / The aim of this doctoral dissertation is to assess the probable impact of ionizing radiation on the public health and the environment (including fauna and flora) in the vicinity of nuclear power engineering objects (in case of the Maišiagala near-surface radioactive waste repository – by evaluating the possible impact on the human health, while in case of the Ignalina NPP cooling basin, Lake Drūkšiai – by evaluating the possible impact on the freshwater ecosystem biota) by applying probabilistic methods as well as to determine whether this activity after assessment of its character and impact on the environment meets the standards valid in the Republic of Lithuania or in the European Union and is permissible at a selected site at present or in the future. In the work two main programs, RESRAD-OFFSITE and ERICA, using scattering of site-specific parameter values and probabilistic (correlation, regressive, sensitivity, etc.) analysis, have been applied. It has been determined that in the environment of the Maišiagala repository after installation of additional protective barriers the annual effective human exposure dose is significantly lower as compared to the limited dose and 95th percentile dose not exceed the exposure of 1 mSv per year regulated in the hygiene standards. The exposure dose rate of standardized organisms of Lake Drūkšiai, the Ignalina NPP cooler, freshwater ecosystem biota due to the INPP discharges and waterway radionuclide migration from a hypothetic... [to full text]