The growing demand for high-quality middle distillates is increasing worldwide, whereas the demand for low-value oil products, such as heavy oils and residues, is decreasing. Thus, maximizing the production of more liquid distillates of very high quality is of immediate interest to refiners. At the same time, environmental legislation has led to more strict specifications of petroleum derivatives. Hydrotreatment (HDT) of crude oil is one of the most challenging tasks in the petroleum refining industry, which has not been reported widely in the literature. In this work, crude oil was hydrotreated upon a commercial cobalt¿molybdenum on alumina (Co¿Mo/¿-Al2O3) catalyst presulfided at specified conditions. Detailed pilot-plant experiments were conducted in a continuous-flow isothermal trickle-bed reactor (TBR), and the main hydrotreating reactions were hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodeasphaltenization (HDAs), and hydrodemetallization (HDM), which includes hydrodevanadization (HDV) and hydrodenickelation (HDNi). The reaction temperature (T), the hydrogen pressure (P), and the liquid hourly space velocity (LHSV) were varied with certain ranges, with constant hydrogen to oil (H2/Oil) ratio. The effects of T, P, and LHSV on the conversion of sulfur, nitrogen, vanadium, nickel, and asphaltene were studied. The results showed that high T and P and low LHSV in HDS, HDN, HDV, HDNi, and HDAs of crude oil improve the sulfur (S), nitrogen (N), metals [vanadium (V) and nickel (Ni)], and asphaltene (Asph) conversion. The hydrotreated crude oil has been distilled into the following fractions: light naphtha (LN), heavy naphtha (HN), heavy kerosene (HK), light gas oil (LGO), and reduced crude residue (RCR), to compare the yield of these fractions produced by distillation after the HDT process to those produced by conventional methods (i.e., HDT of each fraction separately after the distillation). The yield of the middle distillate showed greater yield compared to the middle distillate produced by conventional methods. The properties of RCR produced using both methods are also discussed.

This paper presents an innovative experimental approach for simultaneous measurements of the suction head, volumetric water content, and the acoustic admittance of unsaturated sands. Samples of unsaturated sands are tested under controlled laboratory conditions. Several types of uniform sand with a wide range of particle sizes are investigated. The reported experiments are based on a standard Buchner funnel setup and a standard acoustic impedance tube. It is a novel, nondestructive, and noninvasive technique that relates the key geotechnical parameters of sands such as volumetric water content, density, and grain-size distribution to the acoustic admittance and attenuation. The results show a very sensitive dependence of the acoustic admittance on the volumetric water content controlled by the value of suction head applied. Analysis of the obtained data demonstrates that the relationship between the volumetric water content and the real part of the surface admittance in the frequency range of 400–1,200 Hz can be represented using a logarithmic equation. It is found that the coefficients in the proposed equation are directly related to the uniformity coefficient and the acoustic admittance of the dry sample, which can easily be measured or predicted for a broad range of sands. A validation exercise is conducted to examine the accuracy of the proposed equation using a sand sample with markedly different properties. The results of the validation exercise demonstrate that the proposed relations can be used to determine very accurately the volumetric water content within the porous specimen from the acoustical data. The error in the acoustically measured volumetric water content is found to be ±2.0% over the full range of volumetric water contents ( 0≤θ≤n , where n is the sample porosity).

This paper presents results of a comprehensive investigation undertaken to quantify the efficiency of using reinforcement layers in order to enhance the bearing capacity of soils that are characterised by the existence of localised soft pockets. Small-scale model experiments using two dimensional tank were conducted with beds created from well graded sand with mean particle size of 300 μm but prepared with different dry densities. A relatively softer material was embedded at predetermined locations within the sand beds so as to represent localised soft pockets. Various arrangements of soil reinforcement were tested and compared against comparable tests but without reinforcement. In total 42 tests were carried out in order to study the effect of the width and depth of the soft pocket, the depth of one reinforcing layer and the length and number of reinforcing layers on the soil bearing capacity. The results show clearly that the ultimate bearing capacity reduces by up to 70% due to the presence of a soft pocket. It was also noted that the proximity of the soft pocket also influenced the bearing capacity. Reinforcing the soil with a single layer or increasing the length of reinforcement is not as effective as was anticipated based on previous studies. However, bearing capacity increased significantly (up to 4 times) to that of unreinforced sand when four layers of reinforcement were embedded. The results suggest that rupture of the bottom reinforcement layer is imminent in heavily reinforced sand beds overlying soft pockets and therefore its tensile strength is critical for successful reinforcement.

Central Asia and the Caucasus are of immense geopolitical importance for the US and Russia, but neither power has successfully established regional hegemony. After the collapse of the Soviet Union in 1991, the states of the Caspian region began to develop their oil and gas reserves, and as a result their importance on the international stage is increasing rapidly. Considering the impact of events such as 9/11 and the wars in Afghanistan and Iran, alongside issues including national security, energy policies and American ambitions to limit Russian influence, Christopher Bluth explains why the US has failed to establish authority in this globally significant region. Examining US policy from Clinton to Obama and drawing on interviews with leading figures in the US administration, this study presents the first systematic analysis of US policy towards the Caspian states.

No / Dependent Communities investigates the political situations in contemporary Cambodia and East Timor, where powerful international donors intervened following deadly civil conflicts. This comparative analysis critiques international policies that focus on rebuilding state institutions to accommodate the global market. In addition, it explores the dilemmas of politicians in Cambodia and East Timor who struggle to satisfy both wealthy foreign benefactors and constituents at home-groups whose interests frequently conflict. Hughes argues that the policies of Western aid organizations tend to stifle active political engagement by the citizens of countries that have been torn apart by war. The neoliberal ideology promulgated by United Nations administrations and other international NGOs advocates state sovereignty, but in fact "sovereignty" is too flimsy a foundation for effective modern democratic politics. The result is an oppressive peace that tends to rob survivors and former resistance fighters of their agency and aspirations for genuine postwar independence. In her study of these two cases, Hughes demonstrates that the clientelist strategies of Hun Sen, Cambodia's postwar leader, have created a shadow network of elites and their followers that has been comparatively effective in serving the country's villages, even though so often coercive and corrupt. East Timor's postwar leaders, on the other hand, have alienated voters by attempting to follow the guidelines of the donors closely and ignoring the immediate needs and voices of the people. Dependent Communities offers a searing analysis of contemporary international aid strategies based on the author's years of fieldwork in Cambodia and East Timor.

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No / Crystallization of an isotactic polypropylene (iPP) homopolymer and two propylene/ethylene random copolymers (RACO), induced by high-stress shear, was studied using in situ synchrotron wide-angle X-ray diffraction (WAXD) at 137 °C. The “depth sectioning” method (Fernandez-Ballester Journal of Rheology 2009, 53 (5), 1229−1254) was applied in order to isolate the contributions of different layers in the stress gradient direction and to relate specific structural evolution to the corresponding local stress. This approach gives quantitative results in terms of the specific length of fibrillar nuclei as a function of the applied stress. As expected, crystallization becomes faster with increasing stress—from the inner to the outer layer—for all three materials. Stress-induced crystallization in a RACO with 7.3 mol % ethylene content was triggered at only 1 °C below its nominal melting temperature. The comparison of iPP and RACO’s with 3.4 and 7.3 mol % ethylene monomer reveals the effect of ethylene defects on high-stress shear induced crystallization at 137 °C. It is found that, for a given applied stress, the specific nuclei length formed by flow increases with ethylene content—which is attributed to a greater high molecular weight tail. However, the linear growth rate is significantly reduced by the presence of ethylene comonomers and it is found that this effect dominates the overall crystallization kinetics. Finally, a time lag is found between development of parent lamellae and the emergence of daughter lamellae, consistent with the concept of daughter lamellae nucleated by homoepitaxy on the lateral faces of existing parent lamellae.