Resumo: O presente trabalho traz uma investigação experimental do escoamento em torno de um cilindro rotativo posicionado perpendicularmente à direção principal do escoamento, para números de Reynolds inferiores a 103. Os experimentos foram conduzidos em um túnel hidrodinâmico vertical, com seção de teste 146x146x500 mm e intensidade turbulenta da corrente livre inferior a 0,5%. O diâmetro do corpo de prova foi fixado em 6 mm, proporcionando um bloqueio sólido no interior da seção de testes pouco superior a 4%. A influência do número de Reynolds e da rotação específica do corpo de prova sobre a configuração do escoamento foi bastante estudada. A freqüência de emissão dos vórtices, necessária ao cálculo do número de Strouhal, foi determinada a partir da obtenção do sinal de velocidades, adquirido com o auxílio de um anemômetro de filme quente, ou através da técnica de contagem de fotogramas. Técnicas de visualização de escoamento foram, também, empregadas, em diferentes circunstâncias, tanto na análise qualitativa do escoamento, como para auxiliar o correto posicionamento das sondas de filme quente. Em vários ensaios, a visualização do escoamento por injeção de corante líquido a montante do corpo de prova foi utilizada, mostrando-se bastante eficiente, sobretudo no que concerne à qualidade das imagens obtidas. No entanto, esta técnica só possibilita a visualização de uma região bastante restrita do escoamento e, dependendo do posicionamento da agulha de injeção, diferentes configurações do escoamento podem ser observadas, dificultando a interpretação dos resultados. Para contornar esta situação, utilizou-se, também, a técnica de geração de bolhas de hidrogênio, que permite uma visão mais abrangente do campo de escoamento. De maneira geral, os resultados foram bastante satisfatórios quando comparados com a literatura, mostrando que a... (Resumo completo, clicar acesso eletrônico abaixo). / Abstract: This work presents an experimental investigation on the flow around a rotating cylinder positioned perpendicularly to the free stream, for Reynolds numbers up to 103. The experiments have been carried out inside a 146x146x500 mm test section of a vertical water tunnel, using a 6mm diameter cylinder, which has provided a lower than 4% blockage ratio inside the test section, under a less than 0.5% maximum free-stream turbulence intensity. The influence of both diameter-based Reynolds number and specific rotation of the cylinder on the flow configuration has been analyzed. The vortex shedding frequency, parameter necessary to evaluate the Strouhal number, has been determined from the velocity signal from hot film anemometer as well as directly through a framecounting technique. Two different methods of flow visualization, liquid dye and hydrogen bubble generation, has been also used under distinct circumstances, in order to provide a qualitative analysis of the flow, as well to obtain the correct location of the hot-film probes. In some experiments, flow patterns have been visualized by liquid dye injection upstream the test cylinder, propitiating a good image quality. Dye injection, however, allows for the visualization of a quite restricted area of the flow, in such a way that, depending on the needle location, several distinct flow configurations appear, making it very difficult the interpretation of the results. In order to mitigate those drawbacks, the technique of hydrogen bubble generation has also been employed, reaching for a far wider vision of the flow field. The achieved results have showed that the wake structure is strongly affected by the cylinder rotation, in such a way that the vortices generation can be totally inhibited for a values upper than 2, in the all range of the Reynolds number. / Orientador: Sérgio Said Mansur / Coorientador: Edson Del Rio Vieira / Banca: Marcos Pinotti Barbosa / Banca: André Luiz Seixlack / Mestre

Made available in DSpace on 2014-06-11T19:23:39Z (GMT). No. of bitstreams: 0 Previous issue date: 2003-08-29Bitstream added on 2014-06-13T19:09:40Z : No. of bitstreams: 1 carvalho_gb_me_ilha.pdf: 3399591 bytes, checksum: 93cf9ce80b863df9a4e44fe804f03aa6 (MD5) / O presente trabalho traz uma investigação experimental do escoamento em torno de um cilindro rotativo posicionado perpendicularmente à direção principal do escoamento, para números de Reynolds inferiores a 103. Os experimentos foram conduzidos em um túnel hidrodinâmico vertical, com seção de teste 146x146x500 mm e intensidade turbulenta da corrente livre inferior a 0,5%. O diâmetro do corpo de prova foi fixado em 6 mm, proporcionando um bloqueio sólido no interior da seção de testes pouco superior a 4%. A influência do número de Reynolds e da rotação específica do corpo de prova sobre a configuração do escoamento foi bastante estudada. A freqüência de emissão dos vórtices, necessária ao cálculo do número de Strouhal, foi determinada a partir da obtenção do sinal de velocidades, adquirido com o auxílio de um anemômetro de filme quente, ou através da técnica de contagem de fotogramas. Técnicas de visualização de escoamento foram, também, empregadas, em diferentes circunstâncias, tanto na análise qualitativa do escoamento, como para auxiliar o correto posicionamento das sondas de filme quente. Em vários ensaios, a visualização do escoamento por injeção de corante líquido a montante do corpo de prova foi utilizada, mostrando-se bastante eficiente, sobretudo no que concerne à qualidade das imagens obtidas. No entanto, esta técnica só possibilita a visualização de uma região bastante restrita do escoamento e, dependendo do posicionamento da agulha de injeção, diferentes configurações do escoamento podem ser observadas, dificultando a interpretação dos resultados. Para contornar esta situação, utilizou-se, também, a técnica de geração de bolhas de hidrogênio, que permite uma visão mais abrangente do campo de escoamento. De maneira geral, os resultados foram bastante satisfatórios quando comparados com a literatura, mostrando que a... . / This work presents an experimental investigation on the flow around a rotating cylinder positioned perpendicularly to the free stream, for Reynolds numbers up to 103. The experiments have been carried out inside a 146x146x500 mm test section of a vertical water tunnel, using a 6mm diameter cylinder, which has provided a lower than 4% blockage ratio inside the test section, under a less than 0.5% maximum free-stream turbulence intensity. The influence of both diameter-based Reynolds number and specific rotation of the cylinder on the flow configuration has been analyzed. The vortex shedding frequency, parameter necessary to evaluate the Strouhal number, has been determined from the velocity signal from hot film anemometer as well as directly through a framecounting technique. Two different methods of flow visualization, liquid dye and hydrogen bubble generation, has been also used under distinct circumstances, in order to provide a qualitative analysis of the flow, as well to obtain the correct location of the hot-film probes. In some experiments, flow patterns have been visualized by liquid dye injection upstream the test cylinder, propitiating a good image quality. Dye injection, however, allows for the visualization of a quite restricted area of the flow, in such a way that, depending on the needle location, several distinct flow configurations appear, making it very difficult the interpretation of the results. In order to mitigate those drawbacks, the technique of hydrogen bubble generation has also been employed, reaching for a far wider vision of the flow field. The achieved results have showed that the wake structure is strongly affected by the cylinder rotation, in such a way that the vortices generation can be totally inhibited for a values upper than 2, in the all range of the Reynolds number.

Ce travail concerne l’écoulement incompressible et stationnaire autour d’un cylindre semi-infini en rotation, et ses propriétés de stabilité linéaire. L’effet de la courbure et de la rotation sur la stabilité de cet écoulement est étudié de manière systématique. Avant d’étudier la stabilité, nous calculons d’abord l’écoulement de base. A grand nombre de Reynolds, une couche limite se développe le long du cylindre, ce qui permet d’utiliser l’approximation de couche limite des équations de Navier–Stokes. Ces équations dépendent de deux paramètres de contrôle sans dimension, le nombre de Reynolds (Re) et le taux de rotation (S), et sont résolues numériquement pour obtenir les profils de vitesse et de pression pour une large gamme des paramètres de contrôle. Une couche limite initialement mince s’épaissit avec la distance axiale; ainsi, son épaisseur devient comparable et finalement plus importante que le rayon du cylindre. Au-delà d’un certain taux de rotation, les effets centrifuges conduisent `a un jet de paroi le long d’une portion du cylindre. L’extension axiale de ce jet augmente avec le taux de rotation. L’intensité du jet augmente aussi avec S. Des analyses asymptotiques de l’écoulement à grande distance axiale et à fort taux de rotation sont aussi présentées. L’analyse de stabilité linéaire du précédent écoulement est effectuée dans l’approximation locale. Après une décomposition en modes normaux, les équations des perturbations sont transformées en un problème de valeur propre `a fréquence complexe (ω). Ce problème dépend de cinq paramètres sans dimension: Re, S, la distance axiale normalisée (Z), le nombre d’onde axial (α) et le nombre d’onde azimutal (m). Les équations de stabilité sont résolues numériquement pour étudier les régions instables dans l’espace des paramètres. On observe que de faibles taux de rotation ont un effet important sur la stabilité de l’écoulement. Cette forte déstabilisation est associée à la présence d’un mode quasi-marginal pour le cylindre fixe et qui devient instable pour de petites valeurs de S. Ce phénomène est confirmé par une analyse en perturbation `a petit S. Sans rotation, l’écoulement est stable pour tout Re < 1060, et pour Z > 0.81. Mais, en présence d’une faible rotation, l’instabilité n’est plus limitée par une valeur minimale de Re ou un seuil en Z. Les courbes critiques dans le plan (Z, Re) sont calculées pour une large gamme de S et les conséquences pour la stabilité de l’écoulement discutées. Enfin, un développement asymptotique pour le nombre de Reynolds critique est obtenu, valable aux grandes valeurs de Z. / This work concerns the steady, incompressible flow around a semi-infinite, rotating cylinder and its linear-stability properties. The effect of cylinder curvature and rotation on the stability of this flow is investigated in a systematic manner. Prior to studying its stability, we first compute the basic flow. At large Reynolds numbers, a boundary layer develops along the cylinder. The governing equations are obtained using a boundary-layer approximation to the Navier–Stokes equations. These equations contain two non-dimensional control parameters: the Reynolds number (Re) and the rotation rate (S), and are numerically solved to obtain the velocity and pressure profiles for a wide range of control parameters. The initially thin boundary layer grows in thickness with axial distance, becoming comparable and eventually larger than the cylinder radius. Above a threshold rotation rate, a centrifugal effect leads to the presence of a wall jet for a certain range of streamwise distances. This range widens as the rotation rate increases. Furthermore, the wall jet strengthens as S increases. Asymptotic analyses of the flow at large streamwise distances and at large rotation rates are presented. A linear stability analysis of the above flow is carried out using a local-flow approximation. Upon normal-mode decomposition, the perturbation equations are transformed to an eigenvalue problem in complex frequency (ω). The problem depends on five non-dimensional parameters: Re, S, scaled streamwise direction (Z), streamwise wavenumber (α) and azimuthal wavenumber m. The stability equations are numerically solved to investigate the unstable regions in parameter space. It is found that small amounts of rotation have strong effects on flow stability. Strong destabilization by small rotation is associated with the presence of a nearly neutral mode of the non-rotating cylinder, which becomes unstable at small S. This is further quantified using smallS perturbation theory. In the absence of rotation, the flow is stable for all Re below 1060, and for Z above 0.81. However, in the presence of small rotation, the instability becomes unconstrained by a minimum Re or a threshold in Z. The critical curves in the (Z, Re) plane are computed for a wide range of S and the consequences for stability of the flow described. Finally, a large-Z asymptotic expansion of the critical Reynolds number is obtained.

Composite materials are usually multi-phase materials, made up from two or more phases, which are combined to provide properties that the individual constituents cannot. This technology represents an economical way to improve product performances avoiding the use of expensive materials. Composite materials can be obtained as films by means of the electrolysis of electroplating solutions in which micrometre- or submicrometre-size particles are suspended: variable amounts of these particles become incorporated in the electrochemically produced solid phase, to which they impart enhanced properties. The main aims of the present work contributing to this thesis are the study of different parameters influencing the electroco-deposition process in order to promote and improve the applicability of such a technology in the high speed electroplating industry. Following a comprehensive review on the electroco-deposition of composite coatings, the phenomena have been analysed moving from a microscopic point of view i. e. the role of the metal ions present in the electrolyte and adsorption on the inert particles and their interactions with the growing metal layer, to a macroscopic point of view i. e. the electrolyte agitation, its influence on particle motion and all the issues related to the presence of particles in an electrolyte during electroplating. In particular the inert particle influence in terms of geometry, dimension and chemical nature (spherical polystyrene particles vs. irregular alumina particles with different dimensions), the metal matrix influence (nickel, copper and zinc), the influence of electrolyte agitation (using a Rotating Cylinder Electrode cell system) and the influence of the coating thickness on particle content in the final coating, using different deposition times, have been examined. The importance of the particle shape has been highlighted showing how incorporating irregular geometries gave higher particle incorporation densities than regular geometries. The influence of the substrate finishing in terms of imperfections has been related to the particle incorporation rate showing how small surface imperfections enhanced the incorporation of particles. Different hydrodynamic regimes have been analysed resulting three different regimes being discerned: laminar, transitional and turbulent. The consequence, in terms of particle incorporation levels, has been found showing how the amount of particles in the coating changed from one regime to another. Different rate-determining steps were related to the hydrodynamics: when the regime is laminar, particles were incorporated as agglomerates and the process was under particle transfer control, whilst in the turbulent zone, the rate determining step was the velocity of reduction of the ions adsorbed on the particle surface.

Generating an adverse pressure gradient (APG), using a rotating cylinder in the proximity of a plane wall under a laminar freestream flow, is studied numerically in this work. The magnitude of the generated APG is a function of the gap, G, between the cylinder and the wall, and the rotational speed of the cylinder, Ω. The flow in such a configuration is characterized by periodic transient vortex shedding at high Reynolds number. A numerical model for the computation of the transient flow for this configuration is developed using the ANSYS CFD simulation tool. The model is validated against published experimental and numerical data for similar flow configurations and excellent agreement is observed. A parametric study is carried out for different combinations of G and Ω for two different Reynolds numbers of 200 and 1000 to examine the development of the resulting separation bubble due to the generated APG. The mechanism of the boundary layer separation over the plane wall and the corresponding wake dynamics is investigated. Results are presented in terms of the distribution of the pressure coefficient as well as skin friction coefficient along the wall and flow patterns around and downstream of the cylinder in the proximity of the wall. The results of these computations confirm that using a rotating cylinder over a plane wall in a freestream flow is an effective technique to generate a controlled range of adverse pressure gradients.

No description available.

Made available in DSpace on 2014-12-17T14:08:46Z (GMT). No. of bitstreams: 1 AnelieseLF_DISSERT.pdf: 3198107 bytes, checksum: 808e93eb6952cb8e374d91afa53cabe1 (MD5) Previous issue date: 2011-07-01 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / This master thesis aims at developing a new methodology for thermochemical degradation of dry coconut fiber (dp = 0.25mm) using laboratory rotating cylinder reactor with the goal of producing bio-oil. The biomass was characterized by infrared spectroscopy with Fourier transform FTIR, thermogravimetric analysis TG, with evaluation of activation energy the in non-isothermal regime with heating rates of 5 and 10 ?C/min, differential themogravimetric analysis DTG, sweeping electron microscopy SEM, higher heating value - HHV, immediate analysis such as evaluated all the amounts of its main constituents, i.e., lignin, cellulose and hemicelluloses. In the process, it was evaluated: reaction temperature (450, 500 and 550oC), carrier gas flow rate (50 and 100 cm?/min) and spin speed (20 and 25 Hz) to condensate the bio-oil. The feed rate of biomass (540 g/h), the rotation of the rotating cylinder (33.7 rpm) and reaction time (30 33 min) were constant. The phases obtained from the process of pyrolysis of dry coconut fiber were bio-oil, char and the gas phase non-condensed. A macroscopic mass balance was applied based on the weight of each phase to evaluate their yield. The highest yield of 20% was obtained from the following conditions: temperature of 500oC, inert gas flow of 100 cm?/min and spin speed of 20 Hz. In that condition, the yield in char was 24.3%, non-condensable gas phase was 37.6% and losses of approximately 22.6%. The following physicochemical properties: density, viscosity, pH, higher heating value, char content, FTIR and CHN analysis were evaluated. The sample obtained in the best operational condition was subjected to a qualitative chromatographic analysis aiming to know the constituents of the produced bio-oil, which were: phenol followed by sirigol, acetovanilona and vinyl guaiacol. The solid phase (char) was characterized through an immediate analysis (evaluation of moisture, volatiles, ashes and fixed carbon), higher heating value and FTIR. The non-condensing gas phase presented as main constituents CO2, CO and H2. The results were compared to the ones mentioned by the literature. / O presente trabalho tem como objetivo o desenvolvimento de uma metodologia de degrada??o termoqu?mica da fibra do coco seco (dp = 0,25 mm) utilizando reator de cilindro rotativo em escala de laborat?rio, visando a produ??o de bio-?leo. A biomassa foi caracterizada por an?lise elementar (C, H, N), espectroscopia no infravermelho com transformada de Fourier - IVTF, an?lise termogravim?trica ATG, com avalia??o da energia de ativa??o no regime n?o isot?rmico com taxas de aquecimento de 5 e 10 oC/min, an?lise diferencial termogravim?trica - DTG, microscopia eletr?nica de varredura - MEV, poder calor?fico superior - PCS, an?lise imediata (avalia??o da umidade, materiais vol?teis, cinzas e carbono fixo) bem como avalia??o dos teores dos principais constituintes, ou seja, lignina, celulose e hemicelulose. No processo de pir?lise os seguintes par?metros foram estudados: temperatura da rea??o (450, 500 e 550 ?C), vaz?o do g?s de arraste (50 e 100 cm?/min) e velocidade de centrifuga??o para condensa??o do bio-?leo (20 e 25 Hz). O fluxo de alimenta??o da biomassa (540 g/h), a rota??o do cilindro rotativo (33,7 rpm) e o tempo de rea??o (30 33 min) foram mantidos constantes. Os produtos obtidos no processo da pir?lise da fibra do coco seco foram o bio-?leo, os finos de carv?o e a fase gasosa n?o condensada. Um balan?o de massa macrosc?pico aplicado tendo como base o peso de cada produto permitiu obter o rendimento dessas fases. O melhor rendimento de 18,1 % em bio-?leo foi obtido nas seguintes condi??es: temperatura de 500 ?C, vaz?o de g?s inerte 100 cm?/min e velocidade de centrifuga??o de 20 Hz. Nessas condi??es, o rendimento em finos de carv?o foi de 21,7 %, fase gasosa n?o condens?vel 37,6 % e perdas da ordem de 22,6 %. Algumas propriedades f?sicas do bio-?leo foram avaliadas, a saber, a densidade, viscosidade, pH, poder calor?fico superior, teor de finos de carv?o, an?lise por IVTF e CHN. A an?lise cromatogr?fica do bio-?leo mostrou que os principais constituintes de sua composi??o foram o fenol seguido do sirigol, aceto vanilona e vinil guaiacol. A fase s?lida (finos de carv?o) obtida foi caracterizada por an?lise imediata, poder calor?fico superior e IVTF. A fase gasosa n?o condensada apresentou como principais constituintes o CO2, CO e H2. Os resultados foram comparados com dados da literatura.

Made available in DSpace on 2014-12-17T15:01:32Z (GMT). No. of bitstreams: 1 KarenPBA_DISSERT.pdf: 3887883 bytes, checksum: 3ebc4a634530a0a4a6493a962284d14f (MD5) Previous issue date: 2013-10-18 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The bio-oil obtained from the pyrolysis of biomass has appeared as inter-esting alternative to replace fossil fuels. The aim of this work is to evaluate the influence of temperature on the yield of products originating from the pyrolysis process of the powder obtained from the dried twigs of avel?s (Euphorbia tirucalli), using a rotating cylinder reactor in laboratory scale. The biomass was treated and characterized by: CHNS, moisture, volatiles, fixed carbon and ashes, as well as evaluation of lignin, cellulose and hemicellulose, besides other instrumental techniques such as: FTIR, TG/DTG, DRX, FRX and MEV. The activation energy was evaluated in non-isothemichal mode with heating rates of 5 and 10 oC/min. The obtained results showed biomass as feedstock with potential for biofuel production, because presents a high organic matter content (78,3%) and fixed-carbon (7,11%). The activation energy required for the degradation of biomass ranged between 232,92 392,84 kJ/mol, in the temperature range studied and heating rate of 5 and 10?C/min. In the pyrolysis process, the influence of the reaction temperature was studied (350-520 ? C), keeping constant the other variables, such as, the flow rate of carrier gas, the centrifugal speed for the bio-oil condensationa, the biomass flow and the rotation of the reactor. The maximum yield of bio-oil was obtained in the temperature of 450?C. In this temperature, the results achieved where: content of bio-oil 8,12%; char 32,7%; non-condensed gas 35,4%; losts 23,8%; gross calorific value 3,43MJ/kg; pH 4,93 and viscosity 1,5cP. The chromatographic analysis of the bio-oil produced under these conditions shows mainly the presence of phenol (17,71%), methylciclopentenone (10,56%) and dimethylciclopentenone (7,76%) / O bio-?leo obtido da pir?lise da biomassa tem aparecido como alternativa interessante para substitui??o dos combust?veis f?sseis. O objetivo deste trabalho ? avaliar a influ?ncia da temperatura no rendimento dos produtos originados do processo de pir?lise do p? obtido dos galhos secos do avel?s (Euphorbia tirucalli), utilizando um reator de cilindro rotativo em escala de laborat?rio. A biomassa foi tratada e caracterizada por: CHNS, umidade, materiais vol?teis, cinzas e carbono fixo, bem como, avalia??o dos teores de lignina, celulose e hemicelulose, al?m de outras t?cnicas instrumentais, tais como: FTIR, TG/DTG, DRX, FRX e MEV. A energia de ativa??o foi avaliada no regime n?o isot?rmico com taxas de aquecimento de 5 e 10 oC/min. Os resultados obtidos mostraram a biomassa como mat?ria prima com potencial para produ??o de biocombust?veis, pois apresenta alto teor de mat?ria org?nica (78,3%) e carbono fixo (7,11%). A energia de ativa??o exigida para degrada??o da biomassa variou entre 232,92 392,84 kJ/mol, no intervalo de temperatura da rea??o estudado e taxa de aquecimento de 5 e 10oC/min. No processo de pir?lise, estudou-se a influ?ncia da temperatura da rea??o (350-520 ?C), mantendo-se constantes as demais vari?veis, ou seja, a vaz?o do g?s de arraste , a velocidade de centrifuga??o para condensa??o do bio-?leo, a vaz?o de biomassa e a rota??o do reator. O rendimento m?ximo em bio-?leo foi obtido na temperatura de 450?C. Nessa temperatura, os resultados alcan?ados foram: teor de bio?leo de 8,12%; carv?o 32,7%; fase gasosa n?o condensada 35,4%; perdas 23,8%; poder calor?fico superior 3,43MJ/kg; pH 4,93; viscosidade 1,5cP. A an?lise cromatogr?fica do bio-?leo produzido nessas condi??es mostra a presen?a, principalmente, de fenol (17,71%), metilciclopentenona (10,56%) e dimetilciclopentenona (7,76%)

Made available in DSpace on 2014-12-17T15:01:35Z (GMT). No. of bitstreams: 1 KarenPBA_DISSERT.pdf: 3887883 bytes, checksum: 3ebc4a634530a0a4a6493a962284d14f (MD5) Previous issue date: 2013-10-18 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The bio-oil obtained from the pyrolysis of biomass has appeared as inter-esting alternative to replace fossil fuels. The aim of this work is to evaluate the influence of temperature on the yield of products originating from the pyrolysis process of the powder obtained from the dried twigs of avel?s (Euphorbia tirucalli), using a rotating cylinder reactor in laboratory scale. The biomass was treated and characterized by: CHNS, moisture, volatiles, fixed carbon and ashes, as well as evaluation of lignin, cellulose and hemicellulose, besides other instrumental techniques such as: FTIR, TG/DTG, DRX, FRX and MEV. The activation energy was evaluated in non-isothemichal mode with heating rates of 5 and 10 oC/min. The obtained results showed biomass as feedstock with potential for biofuel production, because presents a high organic matter content (78,3%) and fixed-carbon (7,11%). The activation energy required for the degradation of biomass ranged between 232,92 392,84 kJ/mol, in the temperature range studied and heating rate of 5 and 10?C/min. In the pyrolysis process, the influence of the reaction temperature was studied (350-520 ? C), keeping constant the other variables, such as, the flow rate of carrier gas, the centrifugal speed for the bio-oil condensationa, the biomass flow and the rotation of the reactor. The maximum yield of bio-oil was obtained in the temperature of 450?C. In this temperature, the results achieved where: content of bio-oil 8,12%; char 32,7%; non-condensed gas 35,4%; losts 23,8%; gross calorific value 3,43MJ/kg; pH 4,93 and viscosity 1,5cP. The chromatographic analysis of the bio-oil produced under these conditions shows mainly the presence of phenol (17,71%), methylciclopentenone (10,56%) and dimethylciclopentenone (7,76%) / O bio-?leo obtido da pir?lise da biomassa tem aparecido como alternativa interessante para substitui??o dos combust?veis f?sseis. O objetivo deste trabalho ? avaliar a influ?ncia da temperatura no rendimento dos produtos originados do processo de pir?lise do p? obtido dos galhos secos do avel?s (Euphorbia tirucalli), utilizando um reator de cilindro rotativo em escala de laborat?rio. A biomassa foi tratada e caracterizada por: CHNS, umidade, materiais vol?teis, cinzas e carbono fixo, bem como, avalia??o dos teores de lignina, celulose e hemicelulose, al?m de outras t?cnicas instrumentais, tais como: FTIR, TG/DTG, DRX, FRX e MEV. A energia de ativa??o foi avaliada no regime n?o isot?rmico com taxas de aquecimento de 5 e 10 oC/min. Os resultados obtidos mostraram a biomassa como mat?ria prima com potencial para produ??o de biocombust?veis, pois apresenta alto teor de mat?ria org?nica (78,3%) e carbono fixo (7,11%). A energia de ativa??o exigida para degrada??o da biomassa variou entre 232,92 392,84 kJ/mol, no intervalo de temperatura da rea??o estudado e taxa de aquecimento de 5 e 10oC/min. No processo de pir?lise, estudou-se a influ?ncia da temperatura da rea??o (350-520 ?C), mantendo-se constantes as demais vari?veis, ou seja, a vaz?o do g?s de arraste , a velocidade de centrifuga??o para condensa??o do bio-?leo, a vaz?o de biomassa e a rota??o do reator. O rendimento m?ximo em bio-?leo foi obtido na temperatura de 450?C. Nessa temperatura, os resultados alcan?ados foram: teor de bio?leo de 8,12%; carv?o 32,7%; fase gasosa n?o condensada 35,4%; perdas 23,8%; poder calor?fico superior 3,43MJ/kg; pH 4,93; viscosidade 1,5cP. A an?lise cromatogr?fica do bio-?leo produzido nessas condi??es mostra a presen?a, principalmente, de fenol (17,71%), metilciclopentenona (10,56%) e dimetilciclopentenona (7,76%)