Mixing efficiency in stirred tanks is an important consideration in the design of many industrial processes. Computational fluid dynamics (CFD) techniques have been employed in the present work to study the hydrodynamics in a tank stirred by a Rushton turbine. The effect of the impeller clearance on the velocity field and mixing has been investigated. It has been shown that at a low impeller clearance, the Rushton turbine generates a flow field that evolves from the typical two loops to a single loop flow pattern similar to that of an axial impeller. This single loop flow pattern resulted in an increase in axial flow and a decrease in mixing time at a constant power number. It has been found that a draft tube can be used with a single Rushton turbine, at a low clearance to aid axial flow and mixing, and this resulted in 50% reduction in mixing time. There was a good comparison between laser Doppler velocimetry (LDV) experimental and CFD simulation flow fields, both of which showed that the draft tube improved mixing in the tank by suppressing secondary circulation loops.

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Understanding the flow in stirred vessels can be useful for a wide number of industrial applications, like in mining, chemical and pharmaceutical processes. Remodeling and redesigning these processes may have a significant impact on the overall design characteristics, affecting directly product quality and maintenance costs. In most cases the flow around the rotating impeller blades interacting with stationary baffles can cause rapid changes of the flow characteristics, which lead to high levels of turbulence and higher shear rates. The flow is anisotropic and inhomogeneous over the entire volume. A better understanding and a detailed documentation of the turbulent flow field is needed in order to design stirred tanks that can meet the required operation conditions. This thesis describes efforts for accurate estimation of the velocity distribution and the turbulent characteristics (vorticity, turbulent kinetic energy, dissipation rate) in a cylindrical vessel agitated by a Rushton turbine (a disk with six flat blades) and in a tank typical of flotation cells. Results from simulations using FLUENT (a commercial CFD package) are compared with Time Resolved Digital Particle Image Velocimetry (DPIV) for baseline configurations in order to validate and verify the fidelity of the computations. Different turbulence models are used in this study in order to determine the most appropriate for the prediction of turbulent properties. Subsequently a parametric analysis of the flow characteristics as a function of the clearance height of the impeller from the vessel floor is performed for the Rushton tank as well as the flotation cell. Results are presented for both configurations along planes normal or parallel to the impeller axis, displaying velocity vector fields and contour plots of vorticity turbulent dissipation and others. Special attention is focused in the neighborhood of the impeller region and the radial jet generated there. This flow in this neighborhood involves even larger gradients and dissipation levels in tanks equipped with stators. The present results present useful information for the design of the stirring tanks and flotation cells, and provide some guidance on the use of the present tool in generating numerical solutions for such complex flow fields. / Master of Science

In this thesis, we discuss three image processing topics: High Dynamic Range (HDR) image creation in scenes with motion, Tone Mapping (TM), and Demosaicking. The first part of this thesis focuses on the creation of HDR images using gradient fusion techniques, and proposes a method that deals with motion and avoids bleeding and ghost artifacts. In the second part, we tackle the TM problem, whose goal is to produce a low dynamic range picture from an HDR image that reproduces the sensation of an observer in the scene. We review the perceptual principles that we find important for TM purposes and present a new method that compares well to the state of the art. Finally, we propose a new method to reconstruct the three color channels of a picture taken with a Bayer filter. This problem is called Demosaicking and will be presented in the third part of this thesis. / En esta tesis tratamos tres temas de procesamiento de imagen: creación de imágenes de alto rango dinámico o HDR, Tone Mapping (TM) y Demosaicking. En la primera parte proponemos un método para la creación de imágenes HDR con movimiento que permite generar resultados sin artefactos de tipo bleeding y ghosting. En la segunda parte de la tesis tratamos el problema de TM cuyo objetivo es comprimir el rango dinámico de una imagen HDR para ser mostrada en una pantalla o impresa, simulando lo mejor posible la percepción de un sujeto en la escena. Presentaremos los principios sicofísicos que consideramos relevantes para TM y propondremos un método nuevo que mejora los resultados del estado del arte. Finalmente, en la tercera parte presentamos un método de Demosaicking o reconstrucción de los tres canales de color de una imagen tomada con un filtro de Bayer.

A theoretical study on the hydrodynamics of mixing processes in stirred tanks is described. The primary objective of this study is to investigate flow field and power consumption generated by the six blades Rushton turbine impeller in baffled, flat-bottom cylindrical tank both at laminar and turbulent flow regime both qualitatively and quantitatively. Experimental techniques are expensive and time consuming in characterizing mixing processes. For these reasons, computational fluid dynamics (CFD) has been considered as an alternative method. In this study, the velocity field and power requirement are obtained using FASTEST, which is a CFD package. It employs a fully conservative second order finite volume method for the solution of Navier-Stokes equations. The inherently time-dependent geometry of stirred vessel is simulated by a multiple frame of reference approach. The flow field obtained numerically agrees well with those published experimental measurements. It is shown that Rushton turbine impeller creates predominantly radial jet flow pattern and produces two main recirculation flows one above and the other below the impeller plane. Throughout the tank impeller plane dimensionless radial velocity is not affected significantly by the increasing impeller speed and almost decreases linearly with increase in radial distance. Effect of the baffling on the radial and tangential velocities is also investigated. It is seen that tangential velocity is larger than radial velocity at the same radial position in unbaffled system. An overall impeller performance characteristic like power number is also found to be in agreement with the published experimental data. Also power number is mainly affected by the baffle length and increase with increase in baffle length. It is concluded that multiple frame of reference approach is suitable for the prediction of flow pattern and power number in stirred tank.

This thesis explores what I call 'physical spectatorship' as it is generated by a group of films concerned with the mutilation of the human body. Focusing on the representation of mutilation on the screen and the physical responses this evokes, the thesis is organised around the study of a series of dynamic engagements that reconfigure the film-viewer relationship; these include: corporeal mimicry and the cinematic visualisations of mutilation; generalised anxiety and experimental use of sound; and the nausea generated by audio-visual techniques that both signify and locate the filmic gut in the viewer's body. Combining close textual analyses with theoretical approaches, this thesis draws upon psychoanalytic, phenomenological and feminist theories of film and spectatorship. Throughout the chapters, my argument builds upon the work of Vivian Sobchack and Laura Marks in order to interrogate further what might be meant by the notion of the embodied spectator. The chapters explore this notion, alongside that of the film viewer, to generate a dialogue with previous theorists of the cinematic spectator, including Christian Metz and Richard Rushton. Exploring through close textual analyses the specific filmic techniques that generate intense physical responses, this thesis argues that the mutilation film demands a rethinking of some of the key categories in theories of spectatorship. Extending across national cinemas and reaching beyond conventional generic distinctions, the mutilation film produces a visceral aesthetic that has yet to be analysed. Focusing on particular aspects of the mutilation film, such as the assault narrative sequence, use of extreme frequencies and haptic sounds and images, the thesis offers detailed readings of the following texts: Dans Ma Peau (Marina de Van, 2002), Irréversible (Gaspar Noé, 2002), Saw II (Darren Lynn Bousman, 2005) Saw III (Darren Lynn Bousman, 2006) Saw IV (Darren Lynn Bousman, 2007) Saw V (David Hackl, 2008) Saw VI (Kevin Greutert, 2009) Saw 3D (Kevin Greutert, 2010), Hostel (Eli Roth, 2005), À l'intérieur (Alexandre Bustillo and Julien Maury, 2007), The Human Centipede: First Sequence (Tom Six, 2009) and The Human Centipede: Full Sequence (Tom Six, 2011).The analyses that form this thesis demonstrate the problems with separating notions of the 'spectator as textual construction' from that of the 'viewer as physically embodied'; yet these readings also indicate the necessity of continuing the task of conceptualising their interrelatedness, rather than simply using them interchangeably. The conclusion argues that the concept of physical spectatorship offers one way to understand how particular contemporary aesthetics have reconfigured the boundary between viewer and film.

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No. of bitstreams: 1 DissMMB.pdf: 2553777 bytes, checksum: 21e951a2087a84913403141b819234c7 (MD5) Previous issue date: 2016-02-26 / Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) / The type and operational conditions of a bioreactor chosen during the production phase of a product of interest affect not only the morphology and growth of filamentous microorganisms but also the product itself. Still the most common process to produce bioproducts is submerged cultures in conventional stirred and aerated bioreactors, with impeller of type six flat-blade turbine, or Rushton turbine (RT), which promotes good mixing and suitable oxygen transfer, but its power consumption is high and it causes high shear rate to the broth creating a hostile environment to the microorganisms. Alternatively, an impeller of the type “Elephant Ear” (EE) is shown in the literature as a “low shear” impeller, more suitable for the cultivation of shear sensitive microorganisms. This impeller creates a mixed flow (axial and radial) of broth with down flow (EEDP) or up (EEUP) depending on its geometry. This study aimed to evaluate the best association of impellers for filamentous fungi cultures in a conventional bioreactor. Initially the volumetric coefficient of oxygen transfer (kLa) and the power consumption of seven different association of impellers were evaluated. The results obtained the factorial design methodology showed that the associations EEDP-EEUP, RT-EEDP, and EEDP-RT, showed the best results regarding the oxygen transfer and the power consumption, being up to 87% more efficient than the standard RT-RT association. Two of the better performing association and the traditional (RT-RT) were selected to be evaluated regarding the shearing, by using empirical equations and the size of the eddies, evaluated by the Kolmogorov microscale. The association that showed higher values on the Kolmogorov scale and least shearing was EEDPEEUP, with shearing up to 60% lower than the RT-RT association. In the last step the effects of shear on the morphology of the fungi Aspergillus niger was evaluated. Short-term cultures (4h) were cultivated so that the cellular growth would not harm the analysis. The results showed that on the culture that used the EEDP-EEUP association the morphological form of cell clumps predominated, while on the culture that used the RT-RT association the morphological form of branched hyphae predominated, suggesting that the RT-RT association causes more shearing and can cause irreversible damage to the fungal cells. / O crescimento celular e a morfologia de microrganismos filamentosos, bem como o produto de interesse são afetados pelo modelo de biorreator e pelas condições de operação adotadas durante a etapa de produção. O processo mais adotado industrialmente para produção de bioprodutos ainda são os cultivos submersos em biorreatores convencionais tipo tanque agitado e aerado, sendo o impelidor tipo turbina de seis pás planas ou turbina de Rushton (RT) o mais utilizado por promover boa mistura e adequada transferência de oxigênio, porém seu consumo de potência é alto além de impor alto cisalhamento ao caldo gerando um ambiente hostil ao microrganismo. Alternativamente, o impelidor tipo “orelha de Elefante” ou “Elephant ear” (EE) é apresentado na literatura como um impelidor de “baixo cisalhamento” mais adequado para o cultivo dos microrganismos sensíveis ao cisalhamento. Esse impelidor promove um escoamento misto (axial e radial) do caldo com escoamento para baixo (EEDP) ou para cima (EEUP) dependendo da sua geometria. O presente trabalho teve como objetivo avaliar as melhores associações de impelidores para cultivos de fungos filamentosos em biorreator convencional. Primeiramente sete diferentes associações foram avaliadas em relação ao coeficiente volumétrico de transferência de oxigênio (kLa) e consumo de energia. Os resultados obtidos utilizando a metodologia de planejamento experimental fatorial mostraram que as configurações EEDP-EEUP, RT-EEDP e EEDP-RT foram as que apresentaram melhores resultados em relação à transferência de oxigênio e consumo de potência, com eficiência até 87% superior à associação padrão RT-RT. Foram então selecionadas duas das associações de melhor desempenho e a tradicional (RT-RT) para serem avaliadas em relação ao cisalhamento, através de equações empíricas e em relação ao tamanho dos turbilhões, avaliado pela microescala de Kolmogorov. A associação que apresentou maiores valores para microescala de Kolmogorov e menor cisalhamento foi a EEDP-EEUP, com cisalhamento até 60% inferior que a observada quando utilizada a associação RT-RT. Na última etapa verificou-se os efeitos do cisalhamento na morfologia do fungo Aspergillus niger. Foram realizados cultivos de curta duração (4 h) para evitar que o crescimento celular prejudicasse a análise. Os resultados mostraram que no cultivo utilizando o sistema EEDP-EEUP predominou a forma morfológica de aglomerados celulares (clumps), enquanto que no cultivo com impelidores Rushton (RT-RT) predominou a forma morfológica de hifas ramificadas, sugerindo um cisalhamento mais intenso provocado por este sistema de agitação, que pode acarretar danos irreversíveis às células fúngicas.

The present work seeks to fully investigate, describe and characterize the distinct flow regimes existing within a mixing vessel at various rotational speeds. This investigation is computational in nature and simulates the flow within a baffled tank containing a Rushton turbine of the standard configuration. For a Re based on impeller diameter and blade rotational speed (Re â ¡ Ï ND2/μ) the following flow regimes were identified and investigated in detail: Reverse/reciprocating flows at very low Re (<10); stalled flows at low Re (â 10); laminar pumping flow for higher Re and transitional pumping flow (10 squared < Re <10 to the 4th). For the three Re numbers 1, 10 and 28, it was found that for the higher Re number (28), the flow exhibited the familiar outward pumping action associated with radial impellers under turbulent flow conditions. However, as the Re number decreases, the net radial flow during one impeller revolution was reduced and for the lowest Re number a reciprocating motion with negligible net pumping was observed. In order to elucidate the physical mechanism responsible for the observed flow pattern at low Re, the forces acting on a fluid element in the radial direction were analyzed. Based on this analysis, a simplified quasi-analytic model of the flow was developed that gives a satisfactory qualitative, as well as quantitative representation of the flow at very low Re. Investigation of the transitional flow regime (Re â 3000) includes a compilation and characterization of ensemble and turbulent quantities such as the Reynolds stress components, dissipation length η and time scales Ï , as well a detailed investigation of the near-impeller flow and trailing vortex. Calculation and compilation of all terms in the turbulent kinetic energy transport equation was performed (including generation and the illusive turbulent pressure work). Specifically, the most important transport mechanism was turbulent convection/diffusion from the impeller disk-plane/trailing vortex region. Mean flow transport of turbulent kinetic energy was primarily towards the impeller disk-plane and radially outward from the trailing vortex region. The turbulent pressure work was found to partially counteract turbulent convection. Turbulent dissipation followed by turbulent viscous work were found to be the least important mechanism responsible for turbulent transport with both terms being maximized within the vortex region and at the disk-plane down-stream from the vortices. / Ph. D.

Une étude thermodynamique et cinétique systématique a été entreprise sur l'extraction liquide-liquide du nickel(II) par la 2-ethylhexanal oxime (EHO) seule ou en mélange avec l'acide di-(2-éthylhexyl) phosphorique (D2EHPA) en solution dans le dodécane.<br />La caractérisation des différentes agrégations de la EHO et du D2EHPA par osmométrie VPO a montré l'existence de monomères (notés respectivement HOx et HA), de dimères et de trimères ainsi que l'absence d'espèce mixte EHO-D2EHPA.<br />L'étude de l'extraction du nickel par l'oxime seule à partir de différents milieux aqueux a montré que la cinétique est relativement lente et que seuls les chlorure permettent l'extraction en milieu acide. Les différents types de complexes organiques extraits ont été mis en évidence. En l'absence de sel ou avec NH4NO3, les complexes extraits sont respectivement Ni(Ox)2(HOx)n où n vaut 3 ou 4 pour de plus fortes concentrations en oxime. En présence de chlorure, les complexes extraits sont NiCl2(HOx)n en milieu acide (pH<4) ou NiCl(Ox)(HOx)n pour un milieu moins acide, n valant 3 ou 4 selon la concentration de l'oxime.<br />L'étude cinétique, conduite dans une cellule agitée de type Rushton, a montré que le processus est contrôlé par une étape interfaciale. Elle correspond à la réaction de solvatation du complexe neutre NiCl2(H2O), (pH<4), ou NiCl(Ox)(H2O) adsorbé, (pH>4), par une molécule d'oxime dans le cas des chlorures ; pour les autres électrolytes, il s'agit de l'échange cationique entre Ni(Ox)(H2O)5+ et HOx.<br />L'ajout d'un co-extractant (D2EHPA) provoque une accélération cinétique significative. Le complexe extrait est NiA2(HOx), confirmé par ailleurs par une étude iso-moléculaire. L'étape limitante est une réaction interfaciale d'échange cationique entre NiA(H2O)5+ adsorbé et HA. Pour comparaison, l'étude cinétique a été également conduite dans une cellule à aire interfaciale constante de type Armollex et a permis une estimation de l'aire interfaciale spécifique développée dans la cellule agitée.