The aim of this thesis was to develop a new energy model that predicts the energy infrastructure required to maintain the oil production in the Oil Sands operation at minimum cost. Previous studies in this area have focused on the energy infrastructure for fixed energy demands, i.e., the production schemes that produce synthetic crude oil (SCO) and commercial diluted bitumen remained fixed in the optimal infrastructure calculation. The key novelty of this work is that the model searches simultaneously for the most suitable set of oil production schemes and the corresponding energy infrastructures that satisfy the total production demands under environmental constraints, i.e., CO2 emissions targets. The proposed modeling tool was validated using historical data and previous simulations studies for the Oil Sands operation in 2003. Likewise, the proposed model was used to study the 2020 Oil Sands operations under three different production scenarios. Also, the 2020 case study was used to show the effect of CO2 capture constraints on the oil production schemes and the energy producers. The results show that the proposed model is a practical tool to determine the production costs for the Oil Sands operations, evaluate future production schemes and energy demands scenarios, and identify the key parameters that affect the Oil Sands operation

Thesis (Ph.D.)--University of Alberta, 2010. / Title from PDF file main screen (viewed on Apr. 23, 2010). A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Process Control, Department of Chemical and Materials Engineering, University of Alberta. Includes bibliographical references.

Reclamation of the boreal landscape, including both wetlands and uplands integrated into complex watersheds, has presented a challenge over the past decade with few attempts. Relevant today is wetland/peatland reclamation on reclaimed landscapes positioned on saline sand deposits left on ‘in-pits’ from open pit oil sands mining. The study site for the following questions was an experimental watershed, Sandhill Fen, located north of Fort McMurray, Alberta. Part of the reclamation challenge lies in choosing characteristic species that are tolerant of conditions present on the reclaimed landscape. Species need to both survive harsh environmental conditions and facilitate succession from mineral-based wetlands (marshes) to peat-based ones (fens).Beckmannia syzigachne is a species associated with rich fens in boreal Alberta but its potential to tolerate the given conditions of an open pit mine has yet to be explored. Thus the first question investigated was: How does Beckmannia syzigachne, respond to stress inherent in open pit mines, specifically sodium and soil wetness? Once plants are established, their success and health can be assessed by their physiological responses to the inherent conditions of an open pit mine and further compared to naturally occurring reference populations, called benchmarks, associated with boreal wetlands and peatlands.Carex aquatilis, Scirpus atrocinctus, and Triglochin maritima are three species naturally occurring or strong associated with rich fens and have established on an open pit reclamation site. The second question investigated was: how do Carex aquatilis, Scirpus atrocinctus, and Triglochin maritima physiologically respond to the soil moisture, sodium in the soil, and conductivity of the reclamation site and compare to benchmark populations? Given the large size and isolation from the natural landscape, revegetating the reclamation site may be difficult. Many species have begun to naturally colonize a reclamation site and the assemblage of species and how they might change affect the progression of fen reclamation is unknown. The third question investigated was: what does the early assemblage of species on a reclamation site consist of and do the species give indications of successional trajectory toward a peat-forming wetland? Lastly, active management of the reclamation site can have a great effect on the trajectory of the established species. Actively planting specific assemblages could assist in the trajectory of succession by encouraging the proliferation of desirable species and hindering the establishment of undesirable species. Planting assemblages of high diversity could be more beneficial than planting monocultures. Thus the last question investigated was: does the planting of diverse assemblages effect the establishment of desirable and undesirable species on a reclamation site? Overall, the investigation of these questions revealed some interesting results and concluded strong recommendations for ongoing and future fen reclamation of open pit mines. Beckmannia syzigachne shows decreased morphological and physiological performance with higher sodium concentrations, but tolerates the expected soil wetness and sodium concentrations of the reclamation site, Sandhill Fen. Carex aquatilis, Scirpus atrocinctus, and Triglochin maritima had very strong physiological relationships with percent soil moisture, but weak or no relationships with sodium in the soil or soil water electrical conductivity, and responded similarly to benchmark populations. Soil moisture may be the most important factor during the early development of an open pit reclamation site, as the different assemblages of species found at Sandhill Fen was strongly tied the percent soil moisture, the wetter the soil, the more desirable species were abundant. After one year, it does not appear planting diverse assemblages has nearly a strong effect on the species abundances as soil moisture does. Sandhill Fen serves as a model for future reclamation of fens on oil sands and these experiments have shown soil moisture is an important abiotic factor that requires attention and manipulation if fen reclamation is to be successful on open pit mines. Overall, at Sandhill Fen the establishment and proliferation of desirable species is a positive observation and the physiological responses similar to natural populations bodes well for the success of fen reclamation.

The behaviour of sands during loading has been studied in great detail. However, little work has been devoted to understanding the response of sands in unloading. Drained triaxial tests indicate that, contrary to the expected elastic behaviour, sand often exhibit contractive behaviour when unloaded. Undrained cyclic simple shear tests show that the increase in pore water pressure generated during the unloading cycle often exceeds that generated during loading. The tendency to contract upon unloading is important in engineering practice as an increase in pore water pressure during earthquake loading could result in liquefaction. This research contributes to filling the gap in our understanding of soil behaviour in unloading and subsequent reloading. The approach followed includes both theoretical investigation and numerical implementation of experimental observations of stress dilatancy in unload-reload loops. The theoretical investigation is done at the micromechanical level. The numerical approach is developed from observations from drained triaxial compression tests. The numerical implementation of yield in unloading uses NorSand — a hardening plasticity model based on the critical state theory, and extends upon previous understanding. The proposed model is calibrated to Erksak sand and then used to predict the load-unload-reload behaviour of Fraser River sand. The trends predicted from the theoretical and numerical approaches match the experimental observations closely. Shear strength is not highly affected by unload-reload loops. Conversely, volumetric changes as a result of unloading-reloading are dramatic. Volumetric strains in unloading depend on the last value of stress ratio (q/p’) in the previous loading. It appears that major changes in particles arrangement occur once peak stress ratio is exceeded. The developed unload-reload model requires three additional input parameters, which were correlated to the monotonic parameters, to represent hardening in unloading and reloading and the effect of induced fabric changes on stress dilatancy. The calibrated model gave accurate predictions for the results of triaxial tests with load-unload-reload cycles on Fraser River sand. / Applied Science, Faculty of / Civil Engineering, Department of / Graduate

In-situ oil sands operations have been the dominant method of bitumen extraction in Canada since 2012; however, research on contaminants attributed to this method is limited in the peer-reviewed scientific literature, compared to that of open-pit mining. The Cold Lake oil sands region operates using exclusively thermal in-situ extraction techniques, raising the issue of whether oil sands activity is resulting in petroleum hydrocarbon (PHC) contamination in the absence of open-pit mines, upgraders, refineries, tailings ponds, and other bitumen processing operations. The lack of baseline contamination levels prior to oil sands development hampers debate on contamination from the oil sands industry. We address this shortcoming by using regional lake sediment cores to characterize petroleum hydrocarbons and trace their origin within the Cold Lake oil sands deposit. Petroleum hydrocarbons are hydrophobic compounds that bind to sediments, therefore persisting and accumulating in aquatic environments. This thesis examines historical levels of polycyclic aromatic hydrocarbons (PACs), petroleum biomarkers, and n-alkanes in radiometrically dated sediment cores collected from the depocenter of lakes within the Cold Lake heavy oil field. We used alkylated PACs and a suite of petroleum biomarkers to evaluate in-situ operations as potential petroleum-derived contamination sources. We predicted that similarly to open-pit mining, concentrations of PHCs in lake sediments would increase with industrial activity corresponding to proximity from in-situ operations. Like open-pit regions, alkylated PACs in Cold Lake sediments were elevated when compared to unsubstituted parent PACs and were significantly enriched in lake sediments deposited after the onset of oil sands operations. These findings imply that in-situ oil sands activity is driving the enrichment; however, diagnostic ratios and pyrogenic indices confirm a strongly pyrogenic origin in both pre-industrial and more recent sediments. When compared to a Cold Lake bitumen sample, the principal components driving PHC enrichment do not resemble bitumen. Likewise, diagnostic ratios of petroleum biomarkers and n-alkanes do not support bitumen as a significant source of hydrocarbons. PHC inputs in lake sediments are instead from terrestrial vegetation and plant waxes. These findings suggest that bitumen is not significantly contributing to petroleum hydrocarbon enrichment to lakes within the Cold Lake oil field; however, emissions from in-situ activity (natural gas burning, diesel trucks, seismic line cutting etc.) is increasingly abundant in more recent sediment. With >80 % of Canadian bitumen reserves requiring in-situ techniques for extraction, this thesis provides the first assessment of the spatial and temporal relationship between contaminant loading and proximity to in-situ oil sands operations. Additionally, this study allows for the environmental implications of open-pit mining operations to now be compared to that of in-situ techniques.

Bitumen exploitation in Alberta’s oil sand region generates considerable amounts of waste including tailings and process-affected water that needs reclamation. Water capped tailings technology (WCTT) is currently being assessed as a potential wet reclamation strategy in the oil sand by the commission of Base Mine Lake (BML), the first commercial scale Pit Lake. Pit Lakes consist of ~40m of fluid fine tailings (FFT) deposited in old mine pit covered with a ~10m water cap. In order to be successful, pit lakes much achieve the ecological roles of a natural lake, which includes colonization of the water by macrofauna therefore necessitating the water cap to be oxic. Due to the reductive nature of the tailings, oxygen consuming constituents (OCC) such as methane, sulfide and ammonia are released from the FFT into the water cap potentially posing a threat to the success of the reclamation. Additional seasonal effects such as stratification and ice cover may further affect oxygen consumption by isolating parts of the water cap therefore allowing accumulation of OCC. Results shows that BML thermally stratifies during the summer and winter and that oxygen persist throughout the water cap despite reaching low level at the FFT-water interface (FWI) during summer. Consistent with the FFT acting as an OCC source, aqueous CH 4 and NH 4+ concentrations were highest closer to the FWI, decreasing upwards into the water cap. Using linear regression CH 4 was shown to be an important OCC during the summer of 2015 while NH 4+ and CH 4 were both important for the summer of 2016 highlighting the emergence of nitrification in BML. Detailed analysis of seasonal data revealed that accumulation of OCC below the hypolimnion depletes oxygen and favors methanotrophic activity. Results from both studies suggest that methanotrophs have a competitive advantage at low oxygen levels against nitrifiers. / Thesis / Master of Science (MSc) / Bitumen extraction in Alberta’s oil sand region generates substantial amounts of waste including tailings that needs reclamation. Pit Lakes have been proposed as a reclamation strategy, where tailings are deposited into a mined-out pit and covered with a water cap. To achieve the reclamation goal, the lake must be able to sustain life and must therefore maintain an oxic water cap. The underlying tailings poses a threat to the oxygenation of the lake because of the constant release of compounds that have the potential to consume oxygen. Additional seasonal effects due to temperature change may further affect oxygen consumption by isolating parts of the water cap. In this thesis the results of two years of field sampling and analyses show that despite active oxygen consumption from tailings-released compounds, oxic status is achieved in the upper layer of the lake during summer and under ice.

No description available.

An essential element of the reclamation strategy proposed by the oil sands mining industry in northern Alberta, Canada, includes the creation of wetlands for the bioremediation of mining waste materials. The mining process used to extract oil from these deposits results in the production of large volumes of process-affected water (OSPW) and sediments (OSPS), which must be incorporated into wetlands as a component of the reclaimed landscapes. Wood frogs (<i>Rana sylvatica</i>) are an abundant native species that might be expected to inhabit these reclaimed wetlands. The objective of this study was to determine potential detrimental effects of OSPW and OSPS on the growth and development of wood frogs. Several morphological (weight, length, condition factor) and biochemical (whole body tadpole thyroid hormone and triglyceride concentrations and metamorph hepatic glycogen concentration) endpoints were assessed in conjunction with hatchability and survivability of wood frog eggs and tadpoles exposed to process-affected materials (OSPM) under field and laboratory conditions.<p> As part of this study, assay techniques were optimized to enable simultaneous measurement of whole body 3,5,3-triiodothyronine (T3), thyroxine (T4) and triglyceride (TG) concentrations in wood frog tadpoles. These assays were used to monitor changes in T3, T4 and TG in wood frog tadpoles during development from hatching to metamorphosis (Gosner stages 19-46), to establish baseline levels for subsequent application of the assays to evaluate contaminant effects. The results indicated peak T3 and T4 concentrations occurred during metamorphic climax (Gosner stages 40-46) and prometamorphosis (Gosner stages 31-40), respectively. Maximal TG concentrations were also observed during prometamorphosis. These assays were further employed to assess body condition and development in wood frogs during a field study in 2005, and the following laboratory studies in 2006 and 2007.<p> In summer 2005, 29 reclaimed and five unimpacted wetlands were monitored for use by native amphibians, and tadpoles and newly-metamorphosed wood frogs were collected from a subset of sites as a preliminary assessment of contaminant effects. Endpoints such as metamorph hepatic glycogen and whole body tadpole T3, T4 and triglyceride concentrations were compared among six impacted and three reference wetlands. The surveys indicated 60% of OSPW-impacted wetlands were used by breeding adult amphibians, while wood frog tadpoles and newly-metamorphosed frogs were observed in 37 and 30% of OSPW wetlands, respectively. In general, lower whole body tadpole T3 and triglyceride concentrations were observed in wood frogs from wetlands containing OSPM. In contrast, hepatic glycogen concentrations in newly-metamorphosed frogs and whole body tadpole T4 and T3/T4 concentrations were comparable among the reference and impacted wetlands. In addition, the differences observed in total body weight and length of tadpoles and newly-metamorphosed wood frogs among OSPM and reference sites were likely due to minor differences in developmental stages of the animals collected from the various wetlands, rather than any contaminant effect.<p> In 2006 and 2007, wood frog eggs and tadpoles were exposed to several sources of OSPW and OSPS collected from reclaimed Suncor and Syncrude wetlands under controlled laboratory conditions. Hatchability was reduced in eggs exposed to water from only one of the OSPW sites, compared with the other process-affected ponds and the control water (P<0.05). In contrast, survivability of tadpoles was significantly reduced (P<0.05) in all the impacted sites in both years, with nearly all OSPW sites having <10% survival. The exposure study evaluated the toxicity of five types of OSPS. Results indicated no impact of OSPS exposure on survivability of tadpoles, but showed reduced whole body weight (in three OSPS treatments), length (in two OSPS treatments) and body condition (in one OSPS) of tadpoles exposed to process-affected substrates tested (P<0.05). Whole body T3 and T4 concentrations in tadpoles from OSPS treatments were not different from the control treatment, but tadpole TG concentration was reduced in groups exposed to two impacted substrates (P<0.05). Water quality measurements, including determination of dissolved metals were conducted in an initial attempt to relate any potential toxic effect on wood frog growth and development to specific contaminants.<p> Results of the laboratory studies strongly suggest that exposure to OSPW and OSPS may adversely affect wood frog growth and survival. However, these findings were not entirely consistent with field observations and results of concurrent mesocosm studies. Further research is therefore needed to fully evaluate the suitability of reclaimed oil sands wetlands to support indigenous amphibian population. Future work should focus on the cumulative effects of water and substrates, as well as the effect of OSPM ageing on acute and chronic toxicity.

An essential element of the reclamation strategy proposed by the oil sands mining industry in northern Alberta, Canada, includes the creation of wetlands for the bioremediation of mining waste materials. The mining process used to extract oil from these deposits results in the production of large volumes of process-affected water (OSPW) and sediments (OSPS), which must be incorporated into wetlands as a component of the reclaimed landscapes. Wood frogs (<i>Rana sylvatica</i>) are an abundant native species that might be expected to inhabit these reclaimed wetlands. The objective of this study was to determine potential detrimental effects of OSPW and OSPS on the growth and development of wood frogs. Several morphological (weight, length, condition factor) and biochemical (whole body tadpole thyroid hormone and triglyceride concentrations and metamorph hepatic glycogen concentration) endpoints were assessed in conjunction with hatchability and survivability of wood frog eggs and tadpoles exposed to process-affected materials (OSPM) under field and laboratory conditions.<p> As part of this study, assay techniques were optimized to enable simultaneous measurement of whole body 3,5,3-triiodothyronine (T3), thyroxine (T4) and triglyceride (TG) concentrations in wood frog tadpoles. These assays were used to monitor changes in T3, T4 and TG in wood frog tadpoles during development from hatching to metamorphosis (Gosner stages 19-46), to establish baseline levels for subsequent application of the assays to evaluate contaminant effects. The results indicated peak T3 and T4 concentrations occurred during metamorphic climax (Gosner stages 40-46) and prometamorphosis (Gosner stages 31-40), respectively. Maximal TG concentrations were also observed during prometamorphosis. These assays were further employed to assess body condition and development in wood frogs during a field study in 2005, and the following laboratory studies in 2006 and 2007.<p> In summer 2005, 29 reclaimed and five unimpacted wetlands were monitored for use by native amphibians, and tadpoles and newly-metamorphosed wood frogs were collected from a subset of sites as a preliminary assessment of contaminant effects. Endpoints such as metamorph hepatic glycogen and whole body tadpole T3, T4 and triglyceride concentrations were compared among six impacted and three reference wetlands. The surveys indicated 60% of OSPW-impacted wetlands were used by breeding adult amphibians, while wood frog tadpoles and newly-metamorphosed frogs were observed in 37 and 30% of OSPW wetlands, respectively. In general, lower whole body tadpole T3 and triglyceride concentrations were observed in wood frogs from wetlands containing OSPM. In contrast, hepatic glycogen concentrations in newly-metamorphosed frogs and whole body tadpole T4 and T3/T4 concentrations were comparable among the reference and impacted wetlands. In addition, the differences observed in total body weight and length of tadpoles and newly-metamorphosed wood frogs among OSPM and reference sites were likely due to minor differences in developmental stages of the animals collected from the various wetlands, rather than any contaminant effect.<p> In 2006 and 2007, wood frog eggs and tadpoles were exposed to several sources of OSPW and OSPS collected from reclaimed Suncor and Syncrude wetlands under controlled laboratory conditions. Hatchability was reduced in eggs exposed to water from only one of the OSPW sites, compared with the other process-affected ponds and the control water (P<0.05). In contrast, survivability of tadpoles was significantly reduced (P<0.05) in all the impacted sites in both years, with nearly all OSPW sites having <10% survival. The exposure study evaluated the toxicity of five types of OSPS. Results indicated no impact of OSPS exposure on survivability of tadpoles, but showed reduced whole body weight (in three OSPS treatments), length (in two OSPS treatments) and body condition (in one OSPS) of tadpoles exposed to process-affected substrates tested (P<0.05). Whole body T3 and T4 concentrations in tadpoles from OSPS treatments were not different from the control treatment, but tadpole TG concentration was reduced in groups exposed to two impacted substrates (P<0.05). Water quality measurements, including determination of dissolved metals were conducted in an initial attempt to relate any potential toxic effect on wood frog growth and development to specific contaminants.<p> Results of the laboratory studies strongly suggest that exposure to OSPW and OSPS may adversely affect wood frog growth and survival. However, these findings were not entirely consistent with field observations and results of concurrent mesocosm studies. Further research is therefore needed to fully evaluate the suitability of reclaimed oil sands wetlands to support indigenous amphibian population. Future work should focus on the cumulative effects of water and substrates, as well as the effect of OSPM ageing on acute and chronic toxicity.

As with most dune fields, the White Sands Dune Field in New Mexico forms in a wind regime that is not unimodal. In this study, dune behavior at White Sands was documented from a time series of five lidar-derived digital elevation models (DEM) and compared to a record of wind direction and speed during the same period. For the study period of June 2007 - June 2010, 244 sand-transporting wind events occurred and define a dominant wind mode from the SW and lesser modes from the NNW and SSE. Based upon difference maps and tracing of dune brinklines, overall dune behavior consists of migration to the NE, but with along-crest migration of dune sinuosity to the SE. Permutations of the DEMs allow matching specific dune behavior with wind modes. The SW winds are transverse to dune orientations and cause most forward migration. The NNW winds cause along-crest migration of dune sinuosity and low stoss bedforms, as well as SE migration of NE-trending dune terminations. The SSE winds cause ephemeral dune deformation, especially crestal slipface reversals. Dune deformation occurs because of unequal deposition along the lee face as a function of the incidence angle formed between the wind and the local brinkline orientation. Incidence-angle control on dune deformation and types of lee-face surface processes allows for an idealized model for White Sands dunes. The dunes behave as complex systems in which each wind event deforms the dune shape, this new shape then serves as the configuration for the next wind event. / text