abstract: Understanding the evolution of the Himalayan-Tibetan orogen is important because of its purported effects on global geodynamics, geochemistry and climate. It is surprising that the timing of initiation of this canonical collisional orogen is poorly constrained, with estimates ranging from Late Cretaceous to Early Oligocene. This study focuses on the Ladakh region in the northwestern Indian Himalaya, where early workers suggested that sedimentary deposits of the Indus Basin molasse sequence, located in the suture zone, preserve a record of the early evolution of orogenesis, including initial collision between India and Eurasia. Recent studies have challenged this interpretation, but resolution of the issue has been hampered by poor accessibility, paucity of robust depositional age constraints, and disputed provenance of many units in the succession. To achieve a better understanding of the stratigraphy of the Indus Basin, multispectral remote sensing image analysis resulted in a new geologic map that is consistent with field observations and previously published datasets, but suggests a substantial revision and simplification of the commonly assumed stratigraphic architecture of the basin. This stratigraphic framework guided a series of new provenance studies, wherein detrital U-Pb geochronology, 40Ar/39Ar and (U-Th)/He thermochronology, and trace-element geochemistry not only discount the hypothesis that collision began in the Early Oligocene, but also demonstrate that both Indian and Eurasian detritus arrived in the basin prior to deposition of the last marine limestone, constraining the age of collision to older than Early Eocene. Detrital (U-Th)/He thermochronology further elucidates the thermal history of the basin. Thus, we constrain backthrusting, thought to be an important mechanism by which Miocene convergence was accommodated, to between 11-7 Ma. Finally, an unprecedented conventional (U-Th)/He thermochronologic dataset was generated from a modern river sand to assess steady state assumptions of the source region. Using these data, the question of the minimum number of dates required for robust interpretation was critically evaluated. The application of a newly developed (U-Th)/He UV-laser-microprobe thermochronologic technique confirmed the results of the conventional dataset. This technique improves the practical utility of detrital mineral (U-Th)/He thermochronology, and will facilitate future studies of this type. / Dissertation/Thesis / Ph.D. Geological Sciences 2011

No description available.

No description available.

Impact spherules are sand-sized spherical particles that have been interpreted to have formed by the cooling, crystallization, and quenching of melt droplets condensed from vapor plumes that are created during large meteor impacts. Spherules may be deposited globally as unique marker beds, such as at the K-Pg boundary. A minimum of 11 spherule beds have been identified in the Archean and Paleoproterozoic, and provide a record of impact events that predate any known craters. This study of 3.24 Ga impact spherules from the S3 spherule layer in the Barberton Greenstone Belt (BGB) in the Kaapvaal Craton of South Africa focuses on the heterogeneity of textures and geochemistry produced during the cooling and crystallization of spherules within a vapor plume. Type 4b spherules are layered phyllosilicate spherules with discrete differences in texture and composition between the inner and outer layer, even after alteration. Compositionally layered phyllosilicate spherules were analyzed using Energy Dispersive X-ray Spectroscopy (EDS) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) to measure major, trace, and rare earth element (REE) concentrations. Backscatter Electron (BSE) images and elemental X-ray maps indicate a range of compositional differences between the inner and outer layers of type 4b spherules. The majority of REE plots have nearly flat patterns, with little to no light to heavy REE fractionation; however, the outer layers consistently have higher concentrations, averaging about 10x chondritic, whereas the interiors are at or below chondritic levels with a mid-REE enrichment. The trace and REE patterns of the type 4b spherules are consistent with a more mafic inner layer and a more intermediate outer layer. Mechanisms to produce this layered texture may include: (1) accretion of less mafic material from the plume onto existing melt droplets as the plume continues to fractionate, (2) collision of melt droplets of different viscosities, (3) by differentiation within the melt droplet prior to crystallization, or (4) by diagenetic effects. Based on textures, such as distinct boundaries between layers, and compositional patterns, such as an enrichment of Ti and REE in the outer layer, the data best fits the particle collision formation mechanism hypothesis, which has important implications for impact plume studies, such as plume density, turbulence, temperature, and opacity. / Geology

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No description available.

abstract: East African extensional basins have played a crucial role in revealing the evolution and characteristics of the early stages of continental rifting and for providing the geological context of hominin evolution and innovation. The numerous volcanic eruptions, rapid sedimentation and burial, and subsequent exposure through faulting and erosion, provide excellent conditions for the preservation of tectonic history, paleoenvironment data, and vertebrate fossils. The reconstruction of depositional environments and provision of geochronologic frameworks for hominin sites have been largely provided by geologic investigations in conjunction with paleontological studies, like the Ledi-Geraru Research Project (LGRP). High-resolution paleoclimate records that can be directly linked to hominin fossil outcrops have been developed by the Hominin Sites and Paleolakes Drilling Project (HSPDP) which collected sedimentary-paleolake cores at or near key hominin fossil sites. Two chapters of this dissertation are a result of research associated with the HSPDP. For HSPDP, I establish a tephrostratigraphic framework for the drill cores from the Northern Awash (Afar, Ethiopia) and Baringo-Tugen Hills-Barsemoi (Kenya) HSPDP sites. I characterize and fingerprint tephra through glass shard and feldspar phenocryst geochemistry. From tephra geochemical analyses, I establish chronostratigraphic ties between the HSPDP cores’ high-resolution paleoclimate records to outcrop stratigraphy which are associated with hominin fossils sites. Three chapters of this dissertation are a result of field work with the LGRP. I report new geological investigations (stratigraphic, tectonic, and volcanic) of two previously unmapped regions from the eastern Ledi-Geraru (ELG), Asboli and Markaytoli. Building upon this research I present interpretations from tephra analyses, detailed stratigraphic analyses, and geologic mapping, of the Pleistocene (~2.6 to < 2.45 Ma) basin history for the LGRP. My work with the LGRP helps to reconstruct a more complete Early Pleistocene depositional and geologic history of the lower Awash Valley. Overall, this dissertation contributes to the reconstruction of hominin paleoenvironments and the geochronological framework of the Pliocene and Pleistocene faunal/hominin records. It further contributes to rift basin history in East Africa by elaborating the later structural and stratigraphic history of the lower Awash region. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2019

Several previous Neoproterozoic microfossil diversity studies yield evidence for arelatively sudden biotic change prior to the first well‐constrained Sturtian glaciations. In an event interpreted as a mass extinction of eukaryotic phytoplankton followed by bacterial dominance, diverse assemblages of complex acritarchs are replaced by more uniform assemblages consisting of simple leiosphaerid acritarchs and bacteria. Recent data from the Chuar Group of the Grand Canyon (770‐742 Ma) suggest this biotic change was caused by eutrophication rather than the direct effects of Sturtian glaciation; evidence includes total organic carbon increases indicative of increasing primary productivity followed by iron speciation values that suggest sustained water column anoxia. A new data set (this study) suggests that this same eutrophication event may be recorded in shale units of the formation of Hades Pass and the Red Pine Shale of Utah’s Neoproterozoic Uinta Mountain Group (770‐742 Ma). Results of this study include a significant shift from a higher‐diversity (H’= 0.60) fauna that includes some ornamented acritarchs to a lower‐diversity (H’ = 0.11) fauna dominated by smooth leiosphaerids and microfossils of a bacterial origin (Bavlinella/ Sphaerocongregus sp.). This biotic change co‐occurs with a significant increase in total iii organic carbon values that directly follows a positive carbon‐isotopic excursion, suggesting increased primary productivity that may have been the result of elevated sediment influx and nutrient availability. Both the biotic change and period of increased total organic carbon values correspond with the onset of an interval of anoxia (indicated by total iron to aluminum ratios above 0.60) and a spike in sulfur concentration. Like those reported from the Chuar Group, these biotic and geochemical changes in the upper Uinta Mountain Group are independent of changes in lithofacies , and they suggest that either a eutrophication event or direct inhibition of eukaryotes by sulfide (or perhaps both) may have been the cause of the biotic turnover. These findings support current correlations between the Uinta Mountain and Chuar Groups, the idea that the biotic turnover preserved in both strata was at least a regional phenomenon, and current models of punctuated global ocean anoxia during mid‐ to late‐Neoproterozoic time. Whether or not this hypothesized eutrophication event was more than regional in extent remains a very interesting question and will certainly be a focus of future research.

I use time-constrained sediment volumes delivered by glaciers calving into Marinelli Fjord (55°S), an outlet glacier of the Cordillera Darwin Ice Cap, Southern Patagonia, to determine erosion rates across different timescales. These results indicate that modern sediment yields and erosion rates from temperate tidewater glaciers can exceed long-term values over the time of deglaciation after the LGM (centennial and millennial time scales) by up to two orders of magnitude. In northern Patagonia (Gualas glacier area, 46.5°S), an overall increase in sediment production in the late Holocene is interpreted as result of a sharp increase in centennial timescale precipitation (intensified westerly winds). Erosion rates values span two orders of magnitude from 0.03 mm/yr for Lapeyrere Bay at Anver Island (~64.5°S), up to 1.09 mm/yr for San Rafael glacier at northern Patagonia (~46.5°S). Rates from the Antarctic Peninsula glaciers are in general lower than the temperate Patagonian glaciers. A good correlation of erosion rates and modern (estimated sea level annual 1970 temperature) sea level annual temperature was found. Latitudinal decrease of millenial is interpreted as result of decreasing annual temperature although decreasing in annual precipitation is suggested. The pattern of thermochronology ages from other studies (Thompson et al., 2010; Guenthner et al., 2010), along with the values of 10 3 and 10 6 years timescales erosion rates from this study, indicate that long-term glacial erosion decreases significantly its efficiency with latitude, implying that long-term glacial cover acts as a protective blanket, hindering erosion and allowing mountain growth. We conclude that the pattern of erosion rate decrease with timescale reflects the sensitivity of glaciers to climate variability. Temperate glaciers have higher sensitivity and greater response amplitude to climatic stress than subpolar or polar glaciers. This results in a decrease in erosion rates (sediment production) with latitude, and also in a decrease of erosion rate gradients with timescale.

Master of Science / Geology / Matthew W. Totten / The Mississippian-aged St. Louis Limestone of Western Kansas is a carbonate resource play that has been producing oil, gas, and natural gas liquids (NGL) for over 50 years. The Mississippian Limestone is made up of heterogeneous limestones with interbedded layers of porous and non-porous units, abrupt facies changes, and diagenetic alterations. These factors combine to characterize the St. Louis Limestone's internal complexity, which complicates hydrocarbon exploration. This study focuses on improving the understanding of the geometry, distribution, and continuity of depositional facies within Kearny County, Kansas. Petrophysical analysis of a suite of geophysical logs integrated with core provided the basis for establishing facies successions, determining vertical stacking patterns within a sequence stratigraphic framework, and correlating areas of high porosity with a respective facies. The following depositional facies were identified; 1) porous ooid grainstone, 2) highly-cemented ooid grainstone, 3) quartz-carbonate grainstone, 4) peloidal grainstone, 5) micritic mudstone, and the 6) skeletal wackestone/packstone. The porous ooid grainstone is the chief reservoir facies, with log-derived porosity measurements between four and eighteen percent. In areas without available core, depositional facies were predicted and modeled using a neural network analysis tool (Kipling2.xla). Values derived from the evaluated core intervals and their respective geophysical logs served as the framework for the neural network model. This study illustrates the advantages of correlating depositional facies with reservoir quality and correlating those specific facies to geophysical logs, ultimately to create a greater understanding of the reservoir quality and potential within the St. Louis Limestone of western Kansas.