The aim of this project was to design different chemical processes using Chemcad software. Following five Chemcad models that had industrial relevance were designed and discussed, production of nitric acid by ammonia oxidation process, Production of sodium carbonate by Solvay process, production of hydrogen by steam reforming of natural gas, production of sulphuric acid by Contact process and production of sulphur by Claus process. Equilibrium reactor, Gibbs reactor, absorption tower, heat exchangers, condensers, separators, pumps, compressors and mixers are designed on flow sheet diagram using Chemcad software. Mass balances and energy balances of Chemcad models were compared with bachelor thesis work and their differences and similarities were discussed in detail. In all processes reasonable results were obtained. Mostly in all cases results are the same as in the bachelor thesis. It was seen that equilibrium reactors give better results as compare to Gibbs reactors because when conversion factor of the chemical reaction was not known, Gibbs reactor was used and it adjust the conversion by itself according to equilibrium concentrations of the compounds. SI unit system was used in Chemcad models because in Sweden the SI system is very well established.

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Thesis (MscEng)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: Low-rise buildings with crest fastenedmetal cladding are susceptible to failures in the vicinity of the fasteners during strongwind uplift conditions. These localised failures often lead to the progressive removal of cladding, which can cause disastrous building damage. In South Africa, the current metal cladding design approach is inadequate, since it solely relies upon manufacturer design specifications. These specifications are typically designated as broad design guidelines for the maximum allowable cladding support spacings which are independent from any specified design loads. This research focuses on the investigation of 0.50 mm ISQ550 IBR cladding systems to understand basic cladding behaviour during static wind uplift conditions and to quantify the uplift performance of IBR systems. The research investigation also included the improvement and performance evaluation of a full-scale cladding test method which applies an air-bag loading method to simulate static wind uplift conditions according to the revised SANS 10237:201X code of practice. This thesis may serve as a basis for further cladding research, and the development of suitable standardised metal cladding test methods in South Africa. Several experimental investigation methods and limited finite element analyses (FEA) were used to investigate IBR and the performance of the test methods. Tensile testing was used to determine the material properties of the cladding metal. The full-scale cladding assembly testing was used to investigate the behaviour of IBR and to evaluate the performance of the air-bag test rig. The localised behaviour of the cladding around the fasteners was also investigated with a small cladding subassembly test method. The FEA served as a supplementary investigation for IBR performance evaluation. The experimental investigation confirmed that the static wind uplift resistances of IBR systems are mainly governed by localised deformations of their fastened crests and fastener pull-through failures. The behaviour and performance of IBR systems are heavily dependent on the crest fastening arrangement. IBR systems with every crest fastening demonstrated a considerably higher wind uplift resistance than IBR systems with the standard alternate crest fastening arrangement. The measured fastener loads were independent from span length, whereas the overall uplift resistance of IBR reduced with increased span lengths. Load-span resistance data for 0.50 mm ISQ550 IBR was derived from testing to provide a rational framework for design. The FEA provided a reasonable simulation of IBR subjected to static wind uplift and confirmed the presence of high stress and strain concentrations around the fastener holes which cause fastener pull-through failures. Therefore, FEA can be used as an effective tool to investigate the behaviour of IBR. In conclusion, the air-bag test method used in this research investigation provided an effective method for evaluating the uplift performance of crest fastened metal cladding. However, the air-bag load method is not capable of accurately simulating a true uniformly distributed uplift load. It is recommended that direct air pressure testing be adopted for any further research or commercial testing ofmetal cladding because direct air pressure testing is an effective and proven test method for accurate simulation of static and cyclic wind uplift conditions. / AFRIKAANSE OPSOMMING: Metaalbekleding met kruinvashegting op lae geboue is geneig om te faal by die vashegters tydens toestande van sterkwind-opheffing. As vashegters faal kan bekleding progressief verwyderwordomrampspoedige skade aan die gebou te veroorsaak. Die huidige ontwerpmetode vir metaalbekleding in Suid-Afrika is onvoldoende, aangesien dit slegs gegrond is op vervaardigers se ontwerpspesifikasies. Spesifikasies word gewoonlik verklaar as breë ontwerpriglyne vir die maksimum toelaatbare spasiërings van ondersteunings sonder enige oorwegings vir ontwerpbelastings. Hierdie navorsing fokus dus op 0.50mm ISQ550 IBR metaalbekleding omdie basiese gedrag van bekleding tydens wind-opheffing beter te verstaan en die ophefweerstand van IBR te kwantifiseer vir ontwerpdoeleindes. Verder ondersoek hierdie navorsing ook die verbetering en evaluasie van ’n volskaalse bekledingstoetsmetode wat statiese wind-opheffing naboots met verspreide lugsakbelasting volgens die hersiende SANS 10237:201X gebruikskode. Hierdie proefskrif kan dien as ’n grondslag vir verdere navorsing en die ontwikkeling van geskikte standaard-toetsmetodes vir metaalbekleding in Suid-Afrika. Verskeie eksperimentele toetsmetodes en beperkte eindige-element-analises (EEA) is gebruik om die gedrag van IBR en die toets-opstellings te ondersoek. Trektoetse is gebruik om die meganiese eienskappe van die bekledingsmetaal te bepaal. Volskaalse toets-opstellings is gebruik om die weerstand van IBR te ondersoek en die lugsaktoetsmetode te evalueer. Die gelokaliseerde gedrag van die bekleding rondom die vashegters was ook ondersoek met klein toets-opstellings. EEA het gedien as ’n aanvullende ondersoek om die gedrag van IBR te evalueer. Die eksperimentele ondersoek het bevestig dat die wind-ophefweerstande van IBR-stelsels hoofsaaklik bepaal word deur gelokaliseerde deformasies van die vasgehegde kruine en die vashegters se deurtrekweerstand. Die gedrag en weerstand van IBR-stelsels is ook grootliks afhanklik van die toegepaste vashegtingsmetode. IBR stelsels met vashegting deur elke kruin het ’n hoër ophefweerstand verskaf as IBR-stelsels met die standaard vashegtingsmetode deur elke tweede kruin. Die gemete vashegterbelastings was onafhanklik van die spanlengtes, terwyl die algehele ophefweerstand van IBR verminder het vir langer spanlengtes. Toetsdata is gebruik om ophefweerstande vir 0.50mm ISQ550 IBR oor verskeie spanlengtes af te lei sodat ’n rasionele raamwerk vir ontwerp bewerkstellig kan word. Die EEA het die gedrag van IBR tydens toestande van statiese wind-opheffing redelik goed nageboots en het ook die teenwoordigheid van hoë spannings- en vervormingskonsentrasies rondom die vashegtergate, wat vashegters laat deurtrek, bevestig. Daarom kan EEA as ’n effektiewe instrument gebruik word om die gedrag van IBR te ondersoek. Ten slotte word dit afgelei dat die lugsaktoetsmetode van hierdie navorsingsondersoek ’n effektiewe metode verskaf het vir die gedrag-evaluering van kruinvasgehegte bekleding tydens wind-opheffing. Die lugsaktoetsmetode kan egter nie ’n ware gelykverspreide ophefbelasting naboots nie. Daarom word dit voorgestel dat toetsmetodes wat direkte lugdruk aanwend gebruik moet word vir enige verdere navorsing of kommersiële toetse van metaalbekleding, aangesien dit ’n effektiewe en bevestigde toetsmetode is wat statiese en sikliese opheftoestande akkuraat kan naboots.

Empirical tests developed for an objective evaluation of noodle texture as well as sensory methods provide no information about the rheological parameters responsible for differences in the texture of Asian noodles. Therefore, there is a need for a technique to evaluate the rheological properties of Asian noodles that is fast, easy and inexpensive. Promising results from ultrasonic assessments of the rheological properties of wheat flour doughs and preliminary noodle studies were an encouragement to use ultrasound to address such need in this thesis. Using ultrasound at a relatively high frequency (1.4 MHz), the rheological properties of raw noodles made with three Canadian wheat varieties at various barley β-glucan (BBG) contents, sheeting work input levels and salt to kansui ratios (formulas) were evaluated. Conventional rheological, i.e., stress relaxation (SR) and uniaxial extension (Kieffer), measurements were employed for comparison purposes. The capability of ultrasound for evaluating the effects of BBG addition and sheeting work input on the rheological properties of raw wheat noodles of this study was confirmed. A greater sensitivity of ultrasound to microscopic changes in noodle dough structure, compared to SR and Kieffer tests, was reflected in differences between the results of ultrasound and those of the SR and Kieffer tests with respect to the influences of flour variety and formula on noodle rheology. Investigations of the density of raw noodles showed that air bubbles were present in the noodle dough matrix. A simple, fast and low-cost method, based on the measurement of noodle dough dimensions during the sheeting process, was proposed for a quick evaluation of noodle dough rheology. The results of the proposed method were in agreement with those of conventional rheological measurements on the effects of flour variety and sheeting work input on noodle texture. The time-dependent effect of kansui on noodle dough structure was confirmed by comparing the results of this new method with those of SR and Kieffer tests with respect to the effect of formula on noodle rheology. Further investigations are proposed to establish this method for quick assessment of Asian wheat noodle rheology. / February 2017

Master of Science / Department of Grain Science and Industry / Jon M. Faubion / Charles E. Walker / In commercial bakeries, the baker expects to get the same bread loaf, including weight and size, after sheeting the same size dough piece. Doughs made from different flours have different elastic recoveries to a great extent, which has an effect on the dough’s size and density. Products made from differently elastic doughs can’t have the same shape and height. Weight may also be affected. The dough rheological behaviors of five flours and their blends having different chemical and physical properties were measured as were changes in thickness and snapback (thickness of the machined dough sheet relative to the roll gap) immediately following sheeting. Dough snapback was determined to be a function of both processing parameters, reduction ratio, and dough rest time, as well as different flour properties. The predication equation for dough snapback is based on multiple flour properties and sheeting conditions. Among the variables, Mixograph work, reduction ratio, and dough rest time were the main factors affecting the elastic characteristics of the doughs. Minimum snapback occurred with the weakest flour experiencing the longest rest time and the smallest reduction ratio. A 7-factor equation was found to be robust to predict the snapback of several flours, by combining Mixograph work, reduction ratio, dough rest time, Mixograph peak height and mixing time, Alveograph P/L, and protein content.

The main idea behind stabilisation by diaphragm action is to create a deep beam thatcan resist horizontal loads acting on a structure. It is achieved by connecting the sheetingto the primary structure of the roof so that the edge beams resist the bending momentthrough normal stresses and the sheeting resists the shear force through shear stresses.An essential assumption of a functional diaphragm system is a sufficient connectionbetween the sheeting and the primary structure.In this thesis, the global behaviour of a diaphragm, as well as possible failure modesof sheeting of different thicknesses, are investigated.A laboratory experiment is conducted in the first part of the thesis. In the experiment,two types of self-drilling screws in combination with three different plate thicknesses aretested in shear. Slip flexibility of the screws is evaluated based on the experiment andcompared to flexibilities according to European Recommendations for the Application ofMetal Sheeting Acting as a Diaphragm.In the second part of the thesis, a finite element simulation is performed on two structuresto investigate the global behaviour of the diaphragm. The experimental results are,additionally, implemented into the finite element model.In the last part, hand calculations are performed based on analytical formulas given inEuropean Recommendations for the Application of Metal Sheeting Acting as a Diaphragmand the maximum horizontal displacement of the structure is compared to the FEAresults.