Ultrafast spectroscopy is used to study essential characteristics of solid-state materials. We use ultrafast techniques to study semiconductors at THz frequencies, as well as demonstrate new single-shot measurement techniques. The future of electronics is in the THz regime. We study a crucial characteristic of semiconductors used in devices: the critical field at which the material becomes conductive. GaAs is a promising semiconductor for high-speed devices, and we use enhanced THz electric fields to measure the critical fields at 0.7, 0.9, 1.1, and 1.5 THz frequencies. Single-shot spectroscopy is a technique used to measure ultrafast time scale laser pulses. We show that a new, optical-fiber-based single-shot technique can map out the electric field of THz pulses. Also, we show two variants on this single-shot theme that can be used to measure ultrafast signals. We compare a classic pump-probe measurement to two types of single-shot measurements that use either a spectrometer or a 3 km fiber optic cable and oscilloscope, and we discuss important considerations to recovering the sample response.

The first topic of this thesis proposes a digital negative phase shifter circuit which generates a clock with adjustable negative delays (phase shift) in order to avoid multi-locking hazards. Arbitrary negative phase can be generated by using multiplexers and voltage variable delay cells to select the required phase shift. The proposed design is implemented by 0.35 um CMOS 1P4M technology. A single-shot locking method is adopted to reduce the locking time. Most important of all, the negative phase shifter is predictable and adjustable. The simulation results show that the accuracy of the proposed design is better than 6%. The second topic is to describe a 10-bit, 80 MS/s analog-to-digital converter (ADC) for digital video broadcasting over terrestrial (DVB-T) receivers. The ADC is based on a four-channel parallel pipeline architecture which employs dynamic comparators and switch-capacitance sample-and-hold circuit to achieve high speed operation and low power consumption. Simulation results using a TSMC 0.35um 2P4M process show that the proposed ADC achieves 56dB spurious-free dynamic range (SFDR) and 9.01-bit ENOB.

Landauer's principle states that it costs at least k_BT ln 2 of work to reset one bit in the presence of a heat bath at temperature T. The bound of k_BT ln 2 is achieved in the unphysical infinite-time limit. Here we consider two different finite-time protocols - one with discretised time and the second in the continuous limit. We prove analytically that the discrete time protocol enables one to reset a bit with a work cost close to k_BT ln 2 in a finite time. We construct an explicit protocol that achieves this, which involves thermalising and changing the system's Hamiltonian so as to avoid quantum coherences. Using concepts and techniques pertaining to single-shot statistical mechanics, we furthermore prove that the heat dissipated is exponentially close to the minimal amount possible not just on average, but guaranteed with high confidence in every run. Moreover we exploit the protocol to design a quantum heat engine that works near the Carnot efficiency in finite time. We further contrast this to a continuous time version of the protocol which is substantially less energy sufficient. We also consider the fluctuations in the work cost, and calculate how their magnitude is suppressed by a factor depending on the length of the protocol. We demonstrate with an experiment how molecules are a natural test-bed for probing fundamental quantum thermodynamics. Single-molecule spectroscopy has undergone transformative change in the past decade with the advent of techniques permitting individual molecules to be distinguished and probed. By considering the time-resolved emission spectrum of organic molecules as arising from quantum jumps between states, we demonstrate that the quantum Jarzynski equality is satisfied in this set-up. This relates the heat dissipated into the environment to the free energy difference between the initial and final state. We demonstrate also how utilizing the quantum Jarzynski equality allows for the detection of energy shifts within a molecule, beyond the relative shift.

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Cette thèse présente une étude des impulsions électroniques ultra-brèves en utilisant le nouveau microscope électronique en transmission ultrarapide (UTEM) à Strasbourg. La première partie porte sur le mode d’opération stroboscopique, basé sur l’utilisation d’un train d’impulsions d’électrons de l’ordre de la picoseconde pour l’étude des phénomènes réversibles ultrarapides. L’étude paramétrique effectuée a permis de révéler les dynamiques fondamentales des impulsions électroniques. Des mécanismes inconnus jusqu’alors et décisifs dans les caractéristiques des impulsions ont été dévoilés. Il s’agit des effets de trajectoire, qui limitent la résolution temporelle, et du filtrage chromatique, qui impacte la distribution en énergie et l’intensité du signal. Ces connaissances permettent aujourd’hui un paramétrage affiné de l’UTEM de manière à satisfaire les divers besoins expérimentaux. La deuxième partie concerne l’installation du mode d’opération complémentaire : le mode « singel-shot ». Ce mode fait appel à une impulsion unique d’intensité élevé et d’une durée de l’ordre de la nanoseconde pour l’étude des phénomènes irréversibles. L’UTEM de Strasbourg étant le premier instrument single-shot équipé d’un spectromètre de perte d’énergie des électrons (EELS), l’influence de l’aberration chromatique a pu été étudiée en détail. Elle s’est dévoilée être une limitation majeure pour la résolution en imagerie, nécessitant d’ajuster le bon compromis avec l’aberration sphérique d’une part et l’intensité du signal d’autre part. Enfin, la faisabilité de mener des études en EELS ultrarapide avec une seule impulsion nanoseconde a pu être démontrée, ceci constituant une première mondiale. Ce résultat très prometteur ouvre un tout nouveau domaine d’expériences résolu en temps. / This thesis presents a study of ultrashort electron pulses by using the new ultrafast transmission electron microscope (UTEM) in Strasbourg. The first part focuses on the stroboscopic operation mode which works with trains of picosecond multi-electron pulses in order to study ultrafast, reversible processes. A detailed parametric study was carried out, revealing fundamental principles of electron pulse dynamics. New mechanisms were unveiled which define the pulse characteristics. These are trajectory effects, limiting the temporal resolution, and chromatic filtering, which acts on the energy distribution and signal intensity. Guidelines can be given for optimum operation conditions adapted to different experimental requirements. The second part starts with the setup of the single-shot operation mode, based on intense nanosecond electron pulses for the investigation of irreversible processes. Having the first ns-UTEM equipped with an electron energy loss spectrometer, the influence of chromatic aberration was studied and found to be a major limitation in imaging. It has to be traded off with spherical aberration and signal intensity. For the first time, the feasibility of core-loss EELS with one unique ns-electron pulse is demonstrated. This opens a new field of time-resolved experiments.

This thesis presents techniques constructed to aid the radiologists in detecting breast cancer, the second largest cause of cancer deaths for western women. In the first part of the thesis, a computer-aided detection (CAD) system constructed for the detection of stellate lesions is presented. Different segmentation methods and an attempt to incorporate contra-lateral information are evaluated. In the second part, a new method for evaluating such CAD systems is presented based on constructing credible regions for the number of false positive marks per image at a certain desired target sensitivity. This method shows that the resulting regions are rather wide and this explains some of the difficulties encountered by other researchers when trying to compare CAD algorithms on different data sets. In this part an attempt to model the clinical use of CAD as a second look is also made and it shows that applying CAD in sequence to the radiologist in a routine manner, without duly altering the decision criterion of the radiologist, might very well result in suboptimal operating points. Finally, in the third part two dual-energy imaging methods optimized for contrast-enhanced imaging of breast tumors are presented. The first is based on applying an electronic threshold to a photon-counting digital detector to discriminate between high- and low-energy photons. This allows simultaneous acquisition of the high- and low-energy images. The second method is based on the geometry of a scanned multi-slit system and also allows single-shot contrast-enhanced dual-energy mammography by filtering the x-ray beam that reaches different detector lines differently. / QC 20100819

Airburst projectiles increase the effectiveness of air defense, by forming clouds of small pellets. In this work, in order to evaluate the effectiveness of airburst projectiles, Single Shot Kill Probability (SSKP) is computed at different burst distances by using three lethality functions defined from different measures of effectiveness. These different measures are target coverage, number of sub-projectile hits on the target and kinetic energy of sub-projectiles after burst. Computations are carried out for two different sub-projectile distribution patterns, namely circular and ring patterns. In this work, for the determination of miss distance, a Monte Carlo simulation is implemented, which uses Modified Point Mass Model (MPMM) trajectory equations. According to the results obtained two different distribution patterns are compared in terms of effectiveness and optimum burst distance of each distribution pattern is determined at different ranges.

¡@¡@The first topic of this thesis is a high-speed digital clock generator circuit is presented to provide negative delays in order to avoid a multi-locking hazard. The negative delay also results in small power consumption and shorter access time if the proposed circuit is used in the clock generator circuit of memory devices. Meanwhile, an accurately locked clock signal is also provided. The locked clock signal can be as high as 1.0 GHz at the presence of a random noise with 10% of power supply voltage when the design is implemented by TSMC (Taiwan Semiconductor Manufacturing Company) 0.35um CMOS 1P4M technol- ogy. ¡@¡@The second topic of this thesis is an 1-to-4 joystick enhanced interface which can be attached to SONY PS2 (playstation 2) is developed. The enhanced interface can allow 4 persons to play simultaneously through one port at the original game console. A total of 8 players can be supported when two of the interfaces hook up with both joystick ports of the console. The multiple player entertainment effect can be drastically enhanced by the usage of such an interface.

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