1 |
Heat and mass transfer during cooking of chickpea : measurements and computational simulationSabapathy, Nalaini Devi 03 March 2005
Chickpea is a food legume crop grown in tropical, sub-tropical and temperate regions. World chickpea production is roughly three times that of lentils. Among pulse crops marketed as human food, world chickpea consumption is second only to dry beans. Turkey, Australia, Syria, Mexico, Argentina and Canada are major chickpea exporters.
There are two types of chickpea, namely, the kabuli and the desi. The kabuli type is grown in temperate regions while the desi type chickpea is grown in the semi-arid tropics. Chickpea is valued for its nutritive seeds with high protein and starch content. They are eaten fresh as green vegetables, parched, fried, roasted, and boiled, as snack food, dessert and condiments. The seeds are ground and the flour can be used in soup, dhal and bread. Cooked chickpea is mostly preferred by consumers, especially the kabuli type.
In this thesis, the heat and moisture transfer behavior of kabuli chickpea when subjected to cooking at different temperatures was investigated. The thermo-physical properties of chickpea were studied to develop a model to simulate the temperature distribution and moisture absorption in a chickpea seed when cooked in water.
The thermo-physical properties determined experimentally were thermal conductivity, specific heat, moisture diffusivity, particle density and moisture content. Thermal diffusivity was calculated using the experimental values of thermal conductivity, specific heat and density. The water absorption in chickpea was determined when the seeds were soaked at different temperatures. It was observed that as the temperature of the soaking medium was increased, the rate of moisture absorption also increased. Soaking was done to enhance the gelatinization process during cooking. Cooking experiments were conducted for boiling temperatures ranging from 70 to 98°C for both soaked and unsoaked seeds. It resulted in the soaked seeds being cooked within 40-50 min, whereas the unsoaked seeds took around 250-300 min to cook. The amount of soluble solids lost during the cooking process is also reported which enables to predict the optimum soaking and cooking temperature.
Using linear regression simple models for dependency of thermal conductivity, specific heat, thermal diffusivity and density on temperature and moisture content were developed. The rate of moisture transfer and the center temperature in the seed during cooking was determined experimentally and also simulated with the constant thermal properties found experimentally. The closeness of the simulated and experimental results was proved by appropriate statistical analysis.
Based on the results obtained, it can be understood that soaking the chickpea seeds at temperatures ranging from 25 to 40°C for 8 h and cooking it at higher temperatures ranging from 90 to 100°C will improve the quality of the cooked seed with minimum mass loss. This optimum condition saves both energy and time.
|
2 |
Heat and mass transfer during cooking of chickpea : measurements and computational simulationSabapathy, Nalaini Devi 03 March 2005 (has links)
Chickpea is a food legume crop grown in tropical, sub-tropical and temperate regions. World chickpea production is roughly three times that of lentils. Among pulse crops marketed as human food, world chickpea consumption is second only to dry beans. Turkey, Australia, Syria, Mexico, Argentina and Canada are major chickpea exporters.
There are two types of chickpea, namely, the kabuli and the desi. The kabuli type is grown in temperate regions while the desi type chickpea is grown in the semi-arid tropics. Chickpea is valued for its nutritive seeds with high protein and starch content. They are eaten fresh as green vegetables, parched, fried, roasted, and boiled, as snack food, dessert and condiments. The seeds are ground and the flour can be used in soup, dhal and bread. Cooked chickpea is mostly preferred by consumers, especially the kabuli type.
In this thesis, the heat and moisture transfer behavior of kabuli chickpea when subjected to cooking at different temperatures was investigated. The thermo-physical properties of chickpea were studied to develop a model to simulate the temperature distribution and moisture absorption in a chickpea seed when cooked in water.
The thermo-physical properties determined experimentally were thermal conductivity, specific heat, moisture diffusivity, particle density and moisture content. Thermal diffusivity was calculated using the experimental values of thermal conductivity, specific heat and density. The water absorption in chickpea was determined when the seeds were soaked at different temperatures. It was observed that as the temperature of the soaking medium was increased, the rate of moisture absorption also increased. Soaking was done to enhance the gelatinization process during cooking. Cooking experiments were conducted for boiling temperatures ranging from 70 to 98°C for both soaked and unsoaked seeds. It resulted in the soaked seeds being cooked within 40-50 min, whereas the unsoaked seeds took around 250-300 min to cook. The amount of soluble solids lost during the cooking process is also reported which enables to predict the optimum soaking and cooking temperature.
Using linear regression simple models for dependency of thermal conductivity, specific heat, thermal diffusivity and density on temperature and moisture content were developed. The rate of moisture transfer and the center temperature in the seed during cooking was determined experimentally and also simulated with the constant thermal properties found experimentally. The closeness of the simulated and experimental results was proved by appropriate statistical analysis.
Based on the results obtained, it can be understood that soaking the chickpea seeds at temperatures ranging from 25 to 40°C for 8 h and cooking it at higher temperatures ranging from 90 to 100°C will improve the quality of the cooked seed with minimum mass loss. This optimum condition saves both energy and time.
|
3 |
De-oiling and Pre-treatments for High-Quality Potato ChipsKim, Tae Hoon 2010 December 1900 (has links)
A de-oiling step using a centrifuge ensures oil content reduction and improves the quality of fried snacks. A commercial deep-fat fryer with the basket loaded with potatoes and a sample holder was used to fry potato slices, non-pretreated, blanched in hot water (85°C/3.5min) and rinsed in 3 percent NaCl solution (25°C/5min). A de-oiling step (350 1 rpm and 457 1 rpm) for 1 min was conducted after the frying (145°, 165° and 185°C or 165°C) and cooling (0, 15, 30, 45 and 60 s or 0.60 and 120 s) steps.
Lower frying temperature, higher centrifuge speed, and shorter cooling time resulted in the lowest oil uptake in potato chips. Pre-treatments (blanching and soaking) decreased (5 percent and by at least 10 percent), respectively, compared to the untreated chips.
De-oiling led to increased hardness of the chips fried at 145° and 165°C (0 s cooling time), and the hardness decreased as cooling time. Pre-treatments (blanching and soaking) increased hardness (by 46 percent and 38 percent) and decreased work (by 20 percent and 27 percent), respectively, so that, during rupture, the pre-treated chips resulted in more crunchiness and firmness than the untreated chips.
Potato chips showed less lightness and redness when fried at 145°C, and more lightness and redness when fried at 185°C; yellowness increased b* values as temperature increased. As cooling time increased, the lightness of the chips decreased, and the redness and the yellowness of the chips increased. Pre-treated samples resulted in increasing in lightness (L*) and yellowness (b*), whereas the redness (a*) values of the final products fluctuated.
Higher frying temperature, centrifuge speed, and higher cooling time usually resulted in increasing shrinkage in thickness of potato chips; the chips fried at 165°C resulted in increasing in thickness. All the fried and de-oiled products resulted in a decrease in thickness, diameter, and volume except for the thickness of the chip soaked in NaCl, compared to raw slices.
A consumer test showed that, blanching and de-oiling without cooling enhanced texture and overall quality of the chip, soaking and de-oiling improved the color, flavor, and the overall quality, and the two pre-treatments did not significantly influence the odor of the chip.
|
4 |
Nutritional and functional properties of soaked and micronized Bambara groundnut seeds and their floursOgundele, Opeoluwa Mayowa January 2016 (has links)
Bambara groundnut (Vigna subterranean L.) is considered a good source of protein in some parts of sub Saharan African countries. Long cooking time of about three hours contributed to its limited consumption and utilisation. Micronisation is an infrared heating process. It can reduce the cooking time of pre-moisture conditioned legume small seeds size such as cowpea and lentil, but mostly tempering of seeds has been used as the pre-conditioning techniques. The resulting flour from the pre-conditioned micronised cowpea can reduce pasting viscosity and has potentials in food systems as an instant product. This study aimed at (1) determining the effects of micronisation of pre-soaked whole and dehulled bambara groundnut seeds on their cooking characteristics, (2) determining the effects of micronisation and dehulling treatment of pre-soaked bambara groundnut on physicochemical, microstructure and functional properties of the resulting flours and (3) determining the effects of micronisation of pre-soaked whole and dehulled bambara groundnut seeds on the viscosity, nutritional and health benefits of the cooked samples in order to produce a quick cooked bambara groundnut with functional, nutritional and health benefits.
Micronisation (130 ºC) at a different time (0, 5, 10 and 15 min) was used to optimise the process for pre-soaked (53% moisture) bambara groundnuts. Micronisation (130 ºC) reduced cooking time of pre-soaked (53% moisture) bambara groundnut (whole and dehulled) following cooking. Micronisation reduced the 162 min cooking of raw bambara groundnut to 109, 83, 75 and 62 min when micronized for 0, 5, 10 and 15 min. Micronisation (53% moisture, 130 ºC) caused molecular changes such as solubilisation of pectin which was responsible for the disruption of the middle lamella and separation of parenchyma cell observed by light microscopy and scanning electron microscopy (SEM). It also caused disruption in the structure of starch granule, protein matrix in the cotyledon. These changes in seeds structure and molecular properties of starch, protein and pectin, facilitate water hydration rate and cell separation during cooking, leading to the shorter cooking time of the bambara groundnuts.
Micronisation of pre-soaked (53% moisture) bambara groundnuts caused molecular changes such as partial starch gelatinisation and reduced protein solubility in the resulting flours. The changes in the starch and proteins modified the resulting flours functional properties such asincrease swelling of the resulting flours, while reducing the water solubility. The pasting viscosities of resulting flours of pre-soaked bambara groundnut reduced following micronisation due to the denatured protein matrix preventing embedded starch hydration, dispersibility and molecular entanglement during pasting.This was evident by light and confocal laser scanning microscopy (CLSM) that showed the aggregates of denatured protein matrix surrounding embedded pre-gelatinised starch granules increase with micronisation in the resulting flours and cooked soft porridge of bambara groundnut.
Micronisation has an effect on the apparent viscosity, nutritional, bioactive compound such as phenolics and hence the antioxidant properties of cooked soft porridge of bambara groundnut. All cooked soft porridge of bambara groundnut exhibited a shear thinning behavior and micronised bambara groundnut had lower viscosity increased in the starch and protein digestibility of cooked soft porridge of bambara groundnut. It also increased the phenolic content and antioxidant properties of cooked soft porridge of whole bambara groundnut, but these were reduced in cooked soft porridge of dehulled bambara groundnut due to seed coat absence.
Thus, micronisation of pre-soaked bambara groundnut (whole and dehulled) would contribute towards increased utilisation of bambara groundnut as well as improving house hold nutrition and health promoting properties.Micronisation of bambara groundnut has potential to produce a quick paste with low viscosity which depend on the pre-soaking and micronisation time of the bambara groundnut. Flours from micronised bambara groundnut can therefore be used as instant flour ingredient in food products. / Thesis (PhD)--University of Pretoria, 2016. / National Research Foundation (NRF) of South Africa / Food Science / PhD (Food Science) / Unrestricted
|
5 |
Mechanical properties and water resistance of cellulosic fiberboards with soybean protein based adhesivesLi, Xin January 1900 (has links)
Master of Science / Department of Grain Science and Industry / Xuzhi Susan Sun / Large amount of fiberboard are used for packaging applications every year, which generate
a large amount of solid wastes causing environmental pollution if these packaging materials are
not recycled. Also, a large amount of wood are needed for making fiberboard, which is limited
resource in the earth. Reducing the weight of fiberboard and recycling the fiberboard materials
are two methods to save quantities of wood fiber in fiberboard manufacture, which benefit the
environment and economy. Besides, most adhesives used for producing the fiberboard contain
environmental hazardous chemicals. It is necessary to develop new technology to produce
cellulosic fiberboards with environmental friendly bio-based adhesives.
The soybean is an agricultural product, and its resource is abundant. Soybean protein is a
bio- material that offers an alternative to the existing synthetic adhesives to reduce petroleum
dependence of the U.S. energy strategy. The newly developed soy-based adhesive is also
competitive in cost. Material cost based on food-grade soybean protein is around 20 cents/Lb.
The cost of commercial PF resin is about 14 ~ 17 cents/Lb. Price of hot-melt adhesive for
fiberboard is around $6/Lb.
In this study, soybean protein was modified with sodium dodecyl sulfate as an adhesive for
two bio-based fiberboards products, medium density fiberboard by dry processing and light
weight cardboard by wet processing. The mechanical and water soaking properties of these
cellulosic fiberboards were stronger than or as same as commercial solid fiberboard. This
research suggests that these cellulosic fiberboards with modified soybean protein based adhesive
have great potential as alternative to current commercial fiberboard.
|
6 |
Bioactivity testing of dental materialsEriksson, Alexander January 2019 (has links)
Ever since Hench et al. first discovered bioactive glass in 1969, extensive interest was created because of the materials ability to chemically bond with living tissue. In this project the bioactivity of three different compositions of the bioactive glass Na2O-CaO-SiO2 have been studied. The compositions of the different glasses were A (25% Na2O, 25% CaO and 50% SiO2), B (22.5% Na2O, 22.5% CaO and 55% SiO2) and C (20% Na2O, 20% CaO and 60% SiO2). Their bioactivity was tested through biomimetic evaluation, in this case by soaking samples of each glass in simulated body fluid (SBF) and phosphate buffered saline (PBS). After soaking, the samples were analyzed with Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), Grazing Incidence X-ray Diffraction (GIXRD) and Fourier-Transform Infrared Spectroscopy (FTIR) to analyze if hydroxyapatite formed on the glass surfaces. Both the A and B glass showed bioactivity in SBF and PBS, while the C glass did not. Further work is necessary to determine which of the A and B glass has the highest apatite formability and the reason why the C glass were not bioactive.
|
7 |
Effect of CdCl&esc;b2&esc;s treatment on CdTe and CdS solar cell characteristics after exposure to light for 1000 hours [electronic resource] / by Ashok Rangaswamy.Rangaswamy, Ashok. January 2003 (has links)
Title from PDF of title page. / Document formatted into pages; contains 71 pages. / Thesis (M.S.E.E.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: The CdTe solar cell is a leading candidate for cost-effective thin-film solar cells having demonstrated small area cell effciencies of 16.4%. A Key issue associated with CdTe thin film photovoltaic modules is the analysis of degradation behavior of the device. The analysis is complicated as changes due to degradation may be reversible. Solar cell measurement techniques were used to understand the changes in device parameters after light soaking for 1000 hours. An automated measurement setup was implemented as part of this thesis work. The main objective of this thesis was to study the effect of CdCl&esc;b2&esc;s heat treatment on the device stability. The temperature for this heat treatment was varied from 360oC to 400oC. Cells were stressed under illumination at both short circuit and open circuit conditions. It was found that the increase CdCl&esc;b2&esc;s heat treatment temperature slowed down the degradation rate.This was true for both short and open circuit stress conditions. Also short circuit stress condition slowed down the degradation of the device when compared with the open circuit condition. It became evident that the recombination current mainly got affected when the device was said to be degraded. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.
|
8 |
Desenvolvimento de metodologia e bancada para ensaio de exposição solar prolongada de módulos fotovoltaicos de filmes finosPiccoli Junior, Luiz Antonio January 2015 (has links)
A geração de energia fotovoltaica continua em crescimento e por isso estudos relacionados à aplicação de diferentes tecnologias fotovoltaicas se tornam muito importantes. A tecnologia de células fotovoltaicas de silício cristalino representa a maior parte da aplicação de energia solar fotovoltaica atualmente. Os módulos com tecnologias de filmes finos foram apresentados ao mercado como uma nova geração de módulos e atualmente são referenciados como módulos fotovoltaicos de segunda geração. As tecnologias de filmes finos possuem algumas vantagens em relação ao silício cristalino, como por exemplo: menor quantidade de material, menor custo de produção e possibilidade de se produzir células e módulos flexíveis, embora em geral apresentem eficiências menores. Existem tecnologias de filmes finos aplicadas à geração fotovoltaica que apresentam instabilidade quando expostas à radiação solar, variando a potência gerada do módulo nas primeiras horas de exposição. Esses efeitos motivaram a padronização de um ensaio de exposição solar, do inglês light-soaking, que atualmente é previsto por uma norma internacional de qualificação de módulos fotovoltaicos (IEC 61646). Neste trabalho, desenvolveu-se uma metodologia para realizar o ensaio lightsoaking e construiu-se uma bancada de testes para obter resultados experimentais a partir de módulos expostos na cobertura do prédio anexo do LABSOL. Para isso, foi realizada uma análise de área livre de sombra disponível, bem como montada a estrutura metálica de sustentação para os módulos. Também foram instaladas resistências elétricas para dissipação de potência dos módulos e montado painel elétrico dentro do prédio centralizando as conexões necessárias. O experimento também contou com o desenvolvimento de um programa em linguagem Visual Basic® para interagir com os instrumentos de medição e realizar o monitoramento do ensaio. Neste trabalho foram ensaiados quatro módulos com diferentes tecnologias de filmes finos, as quais: silício amorfo com tripla junção, silício amorfo com uma junção, CIGS (Disseleneto de Cobre, Índio e Gálio) e por último dupla junção de silício amorfo com silício microcristalino. O experimento foi conduzido por 55 dias, sendo que a cada minuto o programa registrou dados de irradiância, irradiação acumulada e temperatura dos módulos. Ao final do experimento, os módulos receberam no total 347 kWh/m2 de irradiação e, durante o ensaio, foram realizadas ao todo 8 medições de curva característica corrente versus tensão para verificar o desempenho dos módulos. Antes e após a exposição, também foram realizadas medições em um simulador solar a fim de se obter medidas em condições controladas de temperatura e irradiância. Ao aplicar o critério de estabilização previsto na norma IEC 61646, verificou-se que todos os módulos o atenderam. Contudo, os módulos com tecnologia de uma junção de silício amorfo e com tecnologia de tripla junção de silício amorfo voltaram a apresentar degradação acima do máximo estabelecido pela norma IEC 61646 após continuarem expostos à radiação solar. Sendo assim, pode ser necessário alterar o critério para um maior valor de irradiação acumulada entre cada avaliação de degradação destes módulos, principalmente quando o ensaio é realizado com temperatura externa elevada. A metodologia mostrou que esse ensaio pode ser realizado em ambiente externo com luz natural de maneira prática e econômica, porém realizar as medições de curva característica com luz natural e temperatura não controlada implica em adicionar algumas incertezas ao ensaio. / The photovoltaic (PV) power generation continues to grow and so studies related to the application of different photovoltaic technologies become very important. The crystalline silicon solar cells technology is the most current application of PV power generation. The photovoltaic modules with thin film technologies were presented to the market as a new generation of modules and are currently referred to as second generation PV modules. The thin film technologies have some advantages compared to crystalline silicon, for example, less material, lower cost of production and ability to produce flexible cells and modules, although generally have lower efficiencies. There are thin film technologies for photovoltaic conversion that show instability when exposed to the sun, varying the power generated in the early hours of sun exposure. These effects led to the standardization of a sun exposure test, the light-soaking test, which is currently standardized by an international standard of qualification of photovoltaic modules (IEC 61646). In this study, we developed a methodology to perform the light-soaking test and built a workbench to obtain experimental results from PV modules set out in the LABSOL building. For this purpose, a shadow analysis was performed as well as the metal structure mounted to support the photovoltaic modules. Resistive loads were also installed in order to dissipate the power of the modules. An electrical panel was mounted inside the building to centralize the necessary connections. The workbench also included the development of a program in Visual Basic® to interact with the measuring instruments and carry out the monitoring of the experiment. In this work we tested four modules with different thin film technologies, including: triple junction amorphous silicon, single junction amorphous silicon, CIGS (Copper Indium Gallium Diselenide) and tandem junction of amorphous silicon and microcrystalline silicon. The experiment was conducted over 55 days, and every minute the program recorded irradiance data, accumulated irradiation and module temperature. At the end of the experiment, the modules received 347 kWh/m2 of irradiation. During the test, there were a total of 8 characteristic curve (I x V) measurements to verify the performance of the modules. Before and after exposure, were also performed measurements in a solar simulator. By applying the stabilization criteria presented in IEC 61646 it was found that all the modules have been considered stabilized. However, after being exposed to more hours of sunlight, the single junction amorphous silicon module and the triple junction amorphous silicon module presented degradation above the maximum established by IEC 61646 standard. Thus, it may be necessary to change the criteria for a higher value of accumulated irradiation between assessments of degradation of these modules, especially when the test is performed with high external temperature. The methodology showed that this test may be performed outdoors under natural light in a practical and economical way, but the characteristic curve measurements with natural light and uncontrolled temperature add some uncertainty to the test.
|
9 |
Desenvolvimento de metodologia e bancada para ensaio de exposição solar prolongada de módulos fotovoltaicos de filmes finosPiccoli Junior, Luiz Antonio January 2015 (has links)
A geração de energia fotovoltaica continua em crescimento e por isso estudos relacionados à aplicação de diferentes tecnologias fotovoltaicas se tornam muito importantes. A tecnologia de células fotovoltaicas de silício cristalino representa a maior parte da aplicação de energia solar fotovoltaica atualmente. Os módulos com tecnologias de filmes finos foram apresentados ao mercado como uma nova geração de módulos e atualmente são referenciados como módulos fotovoltaicos de segunda geração. As tecnologias de filmes finos possuem algumas vantagens em relação ao silício cristalino, como por exemplo: menor quantidade de material, menor custo de produção e possibilidade de se produzir células e módulos flexíveis, embora em geral apresentem eficiências menores. Existem tecnologias de filmes finos aplicadas à geração fotovoltaica que apresentam instabilidade quando expostas à radiação solar, variando a potência gerada do módulo nas primeiras horas de exposição. Esses efeitos motivaram a padronização de um ensaio de exposição solar, do inglês light-soaking, que atualmente é previsto por uma norma internacional de qualificação de módulos fotovoltaicos (IEC 61646). Neste trabalho, desenvolveu-se uma metodologia para realizar o ensaio lightsoaking e construiu-se uma bancada de testes para obter resultados experimentais a partir de módulos expostos na cobertura do prédio anexo do LABSOL. Para isso, foi realizada uma análise de área livre de sombra disponível, bem como montada a estrutura metálica de sustentação para os módulos. Também foram instaladas resistências elétricas para dissipação de potência dos módulos e montado painel elétrico dentro do prédio centralizando as conexões necessárias. O experimento também contou com o desenvolvimento de um programa em linguagem Visual Basic® para interagir com os instrumentos de medição e realizar o monitoramento do ensaio. Neste trabalho foram ensaiados quatro módulos com diferentes tecnologias de filmes finos, as quais: silício amorfo com tripla junção, silício amorfo com uma junção, CIGS (Disseleneto de Cobre, Índio e Gálio) e por último dupla junção de silício amorfo com silício microcristalino. O experimento foi conduzido por 55 dias, sendo que a cada minuto o programa registrou dados de irradiância, irradiação acumulada e temperatura dos módulos. Ao final do experimento, os módulos receberam no total 347 kWh/m2 de irradiação e, durante o ensaio, foram realizadas ao todo 8 medições de curva característica corrente versus tensão para verificar o desempenho dos módulos. Antes e após a exposição, também foram realizadas medições em um simulador solar a fim de se obter medidas em condições controladas de temperatura e irradiância. Ao aplicar o critério de estabilização previsto na norma IEC 61646, verificou-se que todos os módulos o atenderam. Contudo, os módulos com tecnologia de uma junção de silício amorfo e com tecnologia de tripla junção de silício amorfo voltaram a apresentar degradação acima do máximo estabelecido pela norma IEC 61646 após continuarem expostos à radiação solar. Sendo assim, pode ser necessário alterar o critério para um maior valor de irradiação acumulada entre cada avaliação de degradação destes módulos, principalmente quando o ensaio é realizado com temperatura externa elevada. A metodologia mostrou que esse ensaio pode ser realizado em ambiente externo com luz natural de maneira prática e econômica, porém realizar as medições de curva característica com luz natural e temperatura não controlada implica em adicionar algumas incertezas ao ensaio. / The photovoltaic (PV) power generation continues to grow and so studies related to the application of different photovoltaic technologies become very important. The crystalline silicon solar cells technology is the most current application of PV power generation. The photovoltaic modules with thin film technologies were presented to the market as a new generation of modules and are currently referred to as second generation PV modules. The thin film technologies have some advantages compared to crystalline silicon, for example, less material, lower cost of production and ability to produce flexible cells and modules, although generally have lower efficiencies. There are thin film technologies for photovoltaic conversion that show instability when exposed to the sun, varying the power generated in the early hours of sun exposure. These effects led to the standardization of a sun exposure test, the light-soaking test, which is currently standardized by an international standard of qualification of photovoltaic modules (IEC 61646). In this study, we developed a methodology to perform the light-soaking test and built a workbench to obtain experimental results from PV modules set out in the LABSOL building. For this purpose, a shadow analysis was performed as well as the metal structure mounted to support the photovoltaic modules. Resistive loads were also installed in order to dissipate the power of the modules. An electrical panel was mounted inside the building to centralize the necessary connections. The workbench also included the development of a program in Visual Basic® to interact with the measuring instruments and carry out the monitoring of the experiment. In this work we tested four modules with different thin film technologies, including: triple junction amorphous silicon, single junction amorphous silicon, CIGS (Copper Indium Gallium Diselenide) and tandem junction of amorphous silicon and microcrystalline silicon. The experiment was conducted over 55 days, and every minute the program recorded irradiance data, accumulated irradiation and module temperature. At the end of the experiment, the modules received 347 kWh/m2 of irradiation. During the test, there were a total of 8 characteristic curve (I x V) measurements to verify the performance of the modules. Before and after exposure, were also performed measurements in a solar simulator. By applying the stabilization criteria presented in IEC 61646 it was found that all the modules have been considered stabilized. However, after being exposed to more hours of sunlight, the single junction amorphous silicon module and the triple junction amorphous silicon module presented degradation above the maximum established by IEC 61646 standard. Thus, it may be necessary to change the criteria for a higher value of accumulated irradiation between assessments of degradation of these modules, especially when the test is performed with high external temperature. The methodology showed that this test may be performed outdoors under natural light in a practical and economical way, but the characteristic curve measurements with natural light and uncontrolled temperature add some uncertainty to the test.
|
10 |
Desenvolvimento de metodologia e bancada para ensaio de exposição solar prolongada de módulos fotovoltaicos de filmes finosPiccoli Junior, Luiz Antonio January 2015 (has links)
A geração de energia fotovoltaica continua em crescimento e por isso estudos relacionados à aplicação de diferentes tecnologias fotovoltaicas se tornam muito importantes. A tecnologia de células fotovoltaicas de silício cristalino representa a maior parte da aplicação de energia solar fotovoltaica atualmente. Os módulos com tecnologias de filmes finos foram apresentados ao mercado como uma nova geração de módulos e atualmente são referenciados como módulos fotovoltaicos de segunda geração. As tecnologias de filmes finos possuem algumas vantagens em relação ao silício cristalino, como por exemplo: menor quantidade de material, menor custo de produção e possibilidade de se produzir células e módulos flexíveis, embora em geral apresentem eficiências menores. Existem tecnologias de filmes finos aplicadas à geração fotovoltaica que apresentam instabilidade quando expostas à radiação solar, variando a potência gerada do módulo nas primeiras horas de exposição. Esses efeitos motivaram a padronização de um ensaio de exposição solar, do inglês light-soaking, que atualmente é previsto por uma norma internacional de qualificação de módulos fotovoltaicos (IEC 61646). Neste trabalho, desenvolveu-se uma metodologia para realizar o ensaio lightsoaking e construiu-se uma bancada de testes para obter resultados experimentais a partir de módulos expostos na cobertura do prédio anexo do LABSOL. Para isso, foi realizada uma análise de área livre de sombra disponível, bem como montada a estrutura metálica de sustentação para os módulos. Também foram instaladas resistências elétricas para dissipação de potência dos módulos e montado painel elétrico dentro do prédio centralizando as conexões necessárias. O experimento também contou com o desenvolvimento de um programa em linguagem Visual Basic® para interagir com os instrumentos de medição e realizar o monitoramento do ensaio. Neste trabalho foram ensaiados quatro módulos com diferentes tecnologias de filmes finos, as quais: silício amorfo com tripla junção, silício amorfo com uma junção, CIGS (Disseleneto de Cobre, Índio e Gálio) e por último dupla junção de silício amorfo com silício microcristalino. O experimento foi conduzido por 55 dias, sendo que a cada minuto o programa registrou dados de irradiância, irradiação acumulada e temperatura dos módulos. Ao final do experimento, os módulos receberam no total 347 kWh/m2 de irradiação e, durante o ensaio, foram realizadas ao todo 8 medições de curva característica corrente versus tensão para verificar o desempenho dos módulos. Antes e após a exposição, também foram realizadas medições em um simulador solar a fim de se obter medidas em condições controladas de temperatura e irradiância. Ao aplicar o critério de estabilização previsto na norma IEC 61646, verificou-se que todos os módulos o atenderam. Contudo, os módulos com tecnologia de uma junção de silício amorfo e com tecnologia de tripla junção de silício amorfo voltaram a apresentar degradação acima do máximo estabelecido pela norma IEC 61646 após continuarem expostos à radiação solar. Sendo assim, pode ser necessário alterar o critério para um maior valor de irradiação acumulada entre cada avaliação de degradação destes módulos, principalmente quando o ensaio é realizado com temperatura externa elevada. A metodologia mostrou que esse ensaio pode ser realizado em ambiente externo com luz natural de maneira prática e econômica, porém realizar as medições de curva característica com luz natural e temperatura não controlada implica em adicionar algumas incertezas ao ensaio. / The photovoltaic (PV) power generation continues to grow and so studies related to the application of different photovoltaic technologies become very important. The crystalline silicon solar cells technology is the most current application of PV power generation. The photovoltaic modules with thin film technologies were presented to the market as a new generation of modules and are currently referred to as second generation PV modules. The thin film technologies have some advantages compared to crystalline silicon, for example, less material, lower cost of production and ability to produce flexible cells and modules, although generally have lower efficiencies. There are thin film technologies for photovoltaic conversion that show instability when exposed to the sun, varying the power generated in the early hours of sun exposure. These effects led to the standardization of a sun exposure test, the light-soaking test, which is currently standardized by an international standard of qualification of photovoltaic modules (IEC 61646). In this study, we developed a methodology to perform the light-soaking test and built a workbench to obtain experimental results from PV modules set out in the LABSOL building. For this purpose, a shadow analysis was performed as well as the metal structure mounted to support the photovoltaic modules. Resistive loads were also installed in order to dissipate the power of the modules. An electrical panel was mounted inside the building to centralize the necessary connections. The workbench also included the development of a program in Visual Basic® to interact with the measuring instruments and carry out the monitoring of the experiment. In this work we tested four modules with different thin film technologies, including: triple junction amorphous silicon, single junction amorphous silicon, CIGS (Copper Indium Gallium Diselenide) and tandem junction of amorphous silicon and microcrystalline silicon. The experiment was conducted over 55 days, and every minute the program recorded irradiance data, accumulated irradiation and module temperature. At the end of the experiment, the modules received 347 kWh/m2 of irradiation. During the test, there were a total of 8 characteristic curve (I x V) measurements to verify the performance of the modules. Before and after exposure, were also performed measurements in a solar simulator. By applying the stabilization criteria presented in IEC 61646 it was found that all the modules have been considered stabilized. However, after being exposed to more hours of sunlight, the single junction amorphous silicon module and the triple junction amorphous silicon module presented degradation above the maximum established by IEC 61646 standard. Thus, it may be necessary to change the criteria for a higher value of accumulated irradiation between assessments of degradation of these modules, especially when the test is performed with high external temperature. The methodology showed that this test may be performed outdoors under natural light in a practical and economical way, but the characteristic curve measurements with natural light and uncontrolled temperature add some uncertainty to the test.
|
Page generated in 0.0582 seconds