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Metal (IV) compounds as heterogeneous catalysts for the Baeyer-Villiger oxidation of ketones with hydrogen peroxideHemming, Beverley Faith January 1999 (has links)
No description available.
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Friedel-Crafts acylation catalysed by heteropoly acidsKaur, Jaspalne January 2003 (has links)
No description available.
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Metal modified mesoporous ZSM-5 as catalysts for the oligomerization of 1- hexeneMlimi, Kenneth Mpemane January 2021 (has links)
>Magister Scientiae - MSc / The use of diesel engines in vehicles and heavy machinery throughout the world has been
slowly increasing in the past few decades. This has led to high demand for diesel and
gasoline with high octane number. Diesel and gasoline are in high demand due to its qualities
as fuels containing low or no sulfur and nitrogen compounds, making them environmentally
friendly and the anti- knocking properties respectively. With these reasons and more,
researchers have been studying processes like the catalytic oligomerization of olefins to
produce synthetic fuels with augmented qualities and properties. The effectiveness of the
process will depend on the quality of the catalyst.
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Roles of Non-thermal Plasma in Gas-phase Glycerol Dehydration Catalyzed by Supported Silicotungstic AcidLiu, Lu 01 May 2011 (has links)
Acrolein is an indispensable chemical intermediate with a rising demand in recent years. The concern of the increase of propylene prices due to the shrinking supply of nonrenewable crude oil makes the acid-catalyzed gas-phase glycerol dehydration to acrolein a prime candidate for research. Our analysis showed that the sustainable acrolein production from glycerol was both technically and economically viable. Alumina2700® (Al) and Silica1252® (Si) loaded with silicotungstic acid (HSiW) possessed distinct features while provided equally good acrolein yield (73.86mol% and 74.05mol%, respectively) optimally.
Due to the unique non-equilibrium characteristics, non-thermal plasma (NTP) could promote a variety of chemical reactions; however, its application in a dehydration process remained blank. This study used the reaction of glycerol dehydration to acrolein to probe whether NTP could 1) improve acrolein yield during dehydration, 2) suppress the coke formation and regenerate the catalyst, and 3) modify the properties of the catalyst.
The dielectric barrier discharge configuration was used to generate NTP; various NTP field strengths and also their interaction with temperature and the catalyst were investigated. The results showed that NTP improved the glycerol conversion and that NTP with a proper field strength increased acrolein selectivity. The optimal acrolein yields of 83.6 mol% and 83.1 mol% were achieved with 3.78 kV/cm NTP and 4.58 kV/cm NTP at 275°C for HSiW-Al and HSiW-Si, respectively.
The application of NTP-O2 (5% oxygen in argon, 4.58 kV/cm) during glycerol dehydration significantly suppressed coke formation on HSiW-Si. NTP-O2 could regenerate the deactivated HSiW-Si at low temperatures by removing both soft and hard coke at various rates. NTP-O2 with higher field strength, at medium operation temperature (150ºC) and in argon atmosphere was more effective for coke removal/catalyst regeneration.
Applying NTP to the catalyst fabrication showed some capabilities in modifying catalyst properties, including enlarging surface area, preserving mesopores, increasing acid strength and Brønsted acidity. NTP with argon as the discharge gas performed better in these modifications than NTP with air as the discharge gas.
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Matériaux à porosité contrôlée sulfonés : Synthèse, Caractérisation, Etude des propriétés catalytiques / Sulfonated ordered mesoporous materials : Synthesis, Charcacterization, Catalytic propertiesKaraki, Mariam 08 July 2013 (has links)
La catalyse solide acide a été pendant longtemps l'objet d'activité de recherche intense, en particulier pour l'industrie pétrochimique. Aujourd'hui, les catalyseurs solides acides sont de plus en plus étudiés dans d'autres domaines et en particulier dans celles liées à la «chimie verte» et à la valorisation des bioressources, telles que la synthèse de biodiesel et la transformation des polysaccharides. L’objectif de la thèse est d’étudier le potentiel des matériaux poreux sulfonés ayant une porosité contrôlée dans des réactions catalysées par un acide en condition eau surchauffé telle que l'hydrolyse de la cellobiose. Dans une première partie, nous décrivons la préparation et la caractérisation des organosilicates mésoporeux périodiques sulfonés de type SBA-15, SBA-1 et KIT-6 par co-condensation de 1,4-bis (triéthoxysilyl) benzène (BTEB). Les matériaux ont été acidifiés suivant des voies différentes à l'aide de 3-mercaptopropyltriméthoxysilane (MPTMS)/H2O2 ou d'acide chlorosulfonique (ClSO3H). Leur propriété acide a été étudiée par adsorption d’NH3 suivie par calorimétrie et par la réaction de déshydratation d'isopropanol (IPA) comme réaction modèle en phase gazeuse. Contrairement à notre attente, l'adsorption d’NH3 suivie par calorimétrie a mis en évidence l'hétérogénéité de la force des sites suggérant la présence de sites distincts de la sulfonation. Les solides sulfonés avec l'acide chlorosulfonique ont une activité équivalente à celle de la résine sulfonée, Amberlyst 15, mais ils sont moins stables en raison de la libération des espèces de soufre. Les catalyseurs préparés en utilisant un groupement mercapto-propyle suivie d’une oxydation sont moins acides et ils ont donné des niveaux d'activité plus basse dans la réaction de déshydratation d'IPA. Pour l'hydrolyse de la cellobiose, de bonnes performances ont été obtenues à 150°C, mais, ces matériaux se sont montrés instables dans des conditions hydrothermales avec une lixiviation totale de soufre réalisant alors la réaction en phase homogène. Un lavage dans l'eau surchauffée des matériaux contenant des groupements propyles-SO3H conduit à une diminution de leur efficacité dans l'hydrolyse de la cellobiose, mais un gain de stabilité a été obtenu, permettant le recyclage de ces matériaux. Dans une deuxième partie, des répliques carbonées sulfonées par l’acide chlorosulfonique ou l’acide sulfurique ont été synthétisé. La sulfonation par l’acide sulfurique suivi par un lavage dans l’eau bouillante puis un prétraitement thermique à 300°C sous azote, de ces matériaux aboutissent au meilleur catalyseur en termes d’activité/stabilité. / Catalysis with solid acids has been for a long time the subject of intense research activities, especially for the petrochemical industry. Nowadays, solid acid catalysts are more and more studied in other areas and particularly in those related to “green chemistry” and bioresources valorization such as biodiesel synthesis and now polysaccharides transformations. The present work aimed to investigate the potential of acidic ordered mesoporous materials with a controlled local environment of the acid sites for applications in acid catalyzed reactions in hot water such as cellobiose hydrolysis. First we described the synthesis of periodic mesoporous organosilicas SBA-15, SBA-1 and KIT-6 types, from the condensation of 1,4-Bis(triethoxysilyl)benzene. The material was sulfonated using 3-mercaptopropyltrimethoxysilane further oxidized with H2O2 or chlorosulfonic acid to give Brønsted solid acids which were fully characterised. Their acidic properties were studied by calorimetry of NH3 adsorption and in the model reaction of gas phase isopropanol dehydration. The calorimetry of NH3 adsorption has evidenced the heterogeneity of the acid strength distribution suggesting the presence of distinct sites of sulfonation contrary to our expectation. For gas phase isopropanol (IPA) dehydration, the solids sulfonated with the chlorosulfonic acid exhibited an activity equivalent to that of the sulfonated resin, Amberlyst 15, but were less stable due to sulphur species release, assumed to be sulfonated silanols. The acidic organosilicas obtained via H2O2 oxidation of the mercapto-propyl group are less acidic catalysts, showing a low activity for gas phase IPA dehydration. In the hydrolysis reaction, the solids were active at 150 °C however sulfur leaching analysis showed that the reaction preceded mainly homogeneously, especially for the material acidified with chlorosulfonic acid. A hot washing pre-treatment applied to the catalysts containing the sulfonated propyl groups, led to a decrease of their hydrolysis activity but along with a gain of stability allowing recycling. Second we described the synthesis of ordered mesoporous carbon and their sulfonation with chlorosulfonic acid or sulfuric acid. Sulfonation of carbon replicas with sulfuric acid followed by washing in hot water and thermal pretreatment at 300°C under nitrogen, lead to the best catalyst in terms of activity / stability.
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Études des procédés de conversion de la lignine de bois en hydrocarbures liquides et en aérogels / Studies of the conversion processes of the wood lignin to hydrocarbon liquids and aerogelsGrishechko, Liudmila 16 December 2014 (has links)
Cette thèse décrit le développement de procédés utilisables pour valoriser des extraits de bois afin de préparer : (1) des combustibles (hydrocarbures) liquides ; (2) des matériaux poreux avec des applications potentielles dans les domaines de l’énergie et l’environnement, notamment isolation thermique, catalyse, piégeage et séparation de micropolluants. Les extraits de bois en question sont des lignines, associées ou non à des tannins. Les deux types de matériaux sont actuellement peu valorisés, et l’on montre qu’ils peuvent être source de valeur ajoutée au travers des procédés rapportés dans ce mémoire / The present thesis describes the development of processes which can be used for valorizing wood extracts in the aim of preparing: (1) liquid (hydrocarbon) fuels; (2) porous materials with potential energy and environmental applications, namely thermal insulation, catalysis, abatement or separation of micropollutants. The wood extracts in question are lignins, associated or not with tannins. Both kinds of materials are presently poorly valorized, and it is shown here that they can lead to high added-value products through the processes reported in this PhD dissertation
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