In this thesis we present results from quantum Monte Carlo for the fully-frustrated honeycomb lattice. The XXZ model is of interest in the classical limit, as there is a mapping between the classical fully-frustrated honeycomb Ising model groundstates and the classical hard-core dimer model groundstate. The aim of this work is to explore the effect of quantum fluctuations on the fully-frustrated honeycomb model to see what sort of interesting physics arises. One might expect unusual physics due to the quantum hard-core dimer model, where interesting physics are known to exist. This is because there is a duality mapping between the classical dimer model and the classical fully-frustrated honeycomb Ising model. Indeed, by studying the fully-frustrated honeycomb XXZ model we find that in some cases the system orders into crystal-like structures, a case of order-by-disorder. The most interesting case, when the frustrating bonds are chosen randomly, reveals to us a novel state without any discernible order while at the same time avoiding the freezing one would expect of a glass. This state is a featureless system lacking low temperature magnetic susceptibility---a candidate ``quantum spin liquid''. Future work that might more easily measure quantum spin liquid criteria is suggested.

In this thesis we present results from quantum Monte Carlo for the fully-frustrated honeycomb lattice. The XXZ model is of interest in the classical limit, as there is a mapping between the classical fully-frustrated honeycomb Ising model groundstates and the classical hard-core dimer model groundstate. The aim of this work is to explore the effect of quantum fluctuations on the fully-frustrated honeycomb model to see what sort of interesting physics arises. One might expect unusual physics due to the quantum hard-core dimer model, where interesting physics are known to exist. This is because there is a duality mapping between the classical dimer model and the classical fully-frustrated honeycomb Ising model. Indeed, by studying the fully-frustrated honeycomb XXZ model we find that in some cases the system orders into crystal-like structures, a case of order-by-disorder. The most interesting case, when the frustrating bonds are chosen randomly, reveals to us a novel state without any discernible order while at the same time avoiding the freezing one would expect of a glass. This state is a featureless system lacking low temperature magnetic susceptibility---a candidate ``quantum spin liquid''. Future work that might more easily measure quantum spin liquid criteria is suggested.

量子擾動及挫折性兩者均可破壞絕對零溫的磁序，為近代凝態物 理關注的有趣現象。在外加橫場下的三角晶格易辛反鐵磁兼具量子臨 界現象(quantum criticality)及幾何挫折性，可謂量子磁性物質之一典 範理論模型。本論文利用平衡態及非平衡態量子蒙地卡羅(quantum Monte Carlo)方法探測三角晶格易辛反鐵磁之量子相變，其界定零溫 時無磁性的順磁態及具 Z6 對稱破缺的有序態(所謂時鐘態)。這裡的 量子蒙地卡羅方法為運用算符的零溫投射(zero-temperature projector) 及隨機序列展開(stochastic series expansion)演算法。在非平衡模擬 中，我們分別沿降溫過程及量子絕熱過程逼近量子相變點，藉此我們 得到動力學指數，及其它相關臨界指數。 / The destruction of magnetic long-range order at absolute zero temperature arising from quantum fluctuations and frustration is an interesting theme in modern condensed-matter physics. The triangular lattice Ising antiferromag- net in a transverse field provides a playground for the study of the combined effects of quantum criticality and geometrical frustration. In this thesis we use quantum Monte Carlo methods both in equilibrium and non-equilibrium setups to study the properties of the quantum critical point in the triangular lattice antiferromagnet, which separates a disordered paramagnetic state and an ordered clock state exhibiting Z6 symmetry breaking; The methods are based on a zero-temperature projector algorithm and the stochastic series ex- pansion algorithm. For the non-equilibrium setups, we obtain the dynamical exponent and other critical exponents at the quantum critical point approached by slowly decreasing temperature and through quantum annealing.