To obtain the rupture history of the Parkfield, California, earthquake, we perform 12 kinematic inversions using elliptical sub-faults. The preferred model has a seismic moment of 1.21 x 10^18 Nm, distributed on two distinct ellipses. The average rupture speed is ~2.7 km/s. The good spatial agreement with previous large earthquakes and aftershocks in the region, suggests the presence of permanent asperities that break during large earthquakes. We investigate our inversion method with several tests. We demonstrate its capability to retrieve the rupture process. We show that the convergence of the inversion is controlled by the space-time location of the rupture front. Additional inversions show that our procedure is not highly influenced by high-frequency signal, while we observe high sensitivity to the waveforms duration. After considering kinematic inversion, we present a full dynamic inversion for the Parkfield earthquake using elliptical sub-faults. The best fitting model has a seismic moment of 1.18 x 10^18 Nm, distributed on one ellipse. The rupture speed is ~2.8 km/s. Inside the parameter-space, the models are distributed according the rupture speed and final seismic moment, defining a optimal region where models fit correctly the data. Furthermore, to make the preferred kinematic model both dynamically correct while fitting the data, we show it is necessary to connect the two ellipses. This is done by adopting a new approach that uses b-spline curves. Finally, we relocate earthquakes in the vicinity of the Darfield, New-Zealand earthquake. 40 years prior to the earthquake, where there is the possibility of earthquake migration towards its epicentral region. Once it triggers the 2010-2011 earthquake sequence, we observe earthquakes migrating inside regions of stress increase. We also observe a stress increase on a large seismic gap of the Alpine Fault, as well as on some portions of the Canterbury Plains that remain today seismically quiet.

Over the past century, a series of large (> 6.5) magnitude earthquakes have struck along the North Anatolian Fault Zone (NAFZ) in Turkey in a roughly East to West progression. The progression of this earthquake sequence began in 1939 with the Ms 8.0 earthquake near the town of Erzincan and continued westward, with two of the most recent ruptures occurring near the Sea of Marmara in 1999. The sequential nature of ruptures along this fault zone implies that there is a connection between the location of the previous rupture and that of the future rupture zones. This study focuses on understanding how previous rupture events and tectonic influences affect the stress regime of the NAFZ and how these stress changes affect the probability of future rupture along any unbroken segments of the fault zone using a two dimensional finite element modeling program. In this study, stress changes due to an earthquake are estimated using the slip history of the event, estimations of rock and fault properties along the fault zone (elastic parameters), and the far-field tectonic influence due to plate motions. Stress changes are not measured directly. The stress regime is then used to calculate the probability of rupture along another segment of the fault zone. This study found that when improper estimates of rock properties are utilized, the stress changes may be under- or over- estimated by as much as 350% or more. Because these calculated stress changes are used in probability calculations, the estimates of probability can be off by as much as 20%. A two dimensional model was built to reflect the interpreted geophysical and geological variations in elastic parameters and the 1939 through 1999 rupture sequence was modeled. The far-field tectonic influence due to plate motions contributed between 1 and 4 bars of stress to the unbroken segments of the fault zone while earthquake events transferred up to 50 bars of stress to the adjacent portions of the fault zone. The 1999 rupture events near Izmit and Düzce have increased the probability of rupture during the next ten years along faults in the Marmara Sea to 38% while decreasing the probability of rupture along the faults near the city of Bursa by ~6%. Large amounts of strain accumulation are interpreted along faults in the Marmara Sea, further compounding the case for a large rupture event occurring in that area in the future. / Ph. D.

An extensive review of multi-seam under-mining literature was conducted and a data base of case studies was compiled. A critical review of the design principles outlined in this literature resulted in the compilation of specific design criteria for the design of lower seam mines. Analysis of this criteria demonstrated the necessity for a protocol for the design of unsymmetrically loaded pillars. Such a design criteria was developed using finite element methods for a wide range of possible loading conditions. This design criteria can be utilized for underlying pillar design when the loading conditions can be determined. To facilitate using all the under-mining research results by field/planning engineers a Windows™ based software package was developed. This software package contains a multi-seam tutorial, analytical tools and a case history database. The software is very friendly and fully interactive and results of analysis can be verified against case study data included in the program. / Master of Science

Les effets du caoutchouc nitrile (NBR), du traitement de la surface des fibres et du noir de carbone sur les propriétés des composites à base de caoutchouc naturel renforcé par des fibres d'ananas (NR / PALF) ont été étudiés. L'incorporation de NBR et le traitement de surface de la fibre ont été utilisés pour améliorer les propriétés mécaniques des composites à faible déformation, alors que le noir de carbone a été utilisé pour améliorer ces propriétés à forte déformation. La teneur en fibres a été fixée à 10 phr. Les matériaux composites ont été préparés à l'aide d'un mélangeur à cylindres et ont été réticulés sous presse permettant ainsi le maintien de l'orientation des fibres. Ces composites ont été caractérisés à l’aide du rhéomètre à matrice mobile (MDR), par analyse thermique mécanique dynamique (DMTA) et par tests de traction. La morphologie après fracture cryogénique a été observée à l'aide de la microscopie électronique à balayage (MEB). L'effet du NBR dont la teneur varie de 0 à 20 phr par rapport à la teneur totale en caoutchouc, a été également étudié. Le NBR est utilisé afin d’encapsuler totalement les fibres d’ananas (PALF) ; ceci conduisant à un meilleur transfert de contraintes entre la matrice et les fibres. La méthode de mélange a également été étudiée. Plusieurs types de silanes tels que le propylsilane, l'allylsilane et le silane-69 ont été utilisés pour traiter les fibres pré-nettoyées à l’aide d’un traitement alcalin. Les fibres silanisées ont été caractérisées par spectroscopie infrarouge à transformée de Fourier (FTIR), par spectroscopie de photoélectrons aux rayons X (XPS) et par MEB. Le traitement de la fibre par le silane-69 a permis d’augmenter fortement le module du matériau composite à faible déformation. Ce traitement a été plus efficace que l'incorporation de NBR dans les composites NR / PALF. Ceci peut s’expliquer par une possible réticulation chimique entre le caoutchouc et la fibre traitée au silane-69 plutôt qu’une simple interaction physique du NR, du NBR et de la fibre. Cependant, le renforcement par fibre réduit la déformation à la rupture. Par conséquent, du noir de carbone a également été incorporé dans les composites NR/NBR/PALF et NR/ PALF traitée, afin d’améliorer leurs propriétés ultimes. En incorporant du noir de carbone à un taux de 30 phr dans les deux composites, les propriétés mécaniques des composites ont été améliorées et peuvent être contrôlées à la fois à des déformations faibles et hautes. / The effects of nitrile rubber (NBR), fiber surface treatment and carbon black on properties of pineapple leaf fiber-reinforced natural rubber composites (NR/PALF) were studied. The incorporation of NBR and surface treatment of fiber were used to improve the mechanical properties of composites at low deformation, whereas carbon black was used to improve these properties at high deformation. The fiber content was fixed at 10 phr. The composites were prepared using two-roll mill and were cured using compression moulding with keeping the fiber orientation. These composites were characterized using moving die rheometer (MDR), dynamic mechanical thermal analysis (DMTA) and tensile testing. The morphology after cryogenic fracture was observed using scanning electron microscopy (SEM). The effect of NBR from 0 to 20 phr of total rubber content was investigated. NBR is proposed to encase PALF leading to higher stress transfer between matrix and PALF. The method of mixing was also studied. For the fiber surface treatment, propylsilane, allylsilane and silane-69 were treated on the alkali-treated fiber. Treated fibers were characterized using Fourier-Transform infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS) and SEM. Silane-69 treatment of fiber increased the modulus at low deformation more than the incorporation of NBR of NR/PALF composites due to the chemical crosslinking between rubber and fiber from silane-69 treatment rather than the physical interaction of NR, NBR and fiber. However, reinforcement by fiber reduced the deformation at break. Hence, carbon black was also incorporated into NR/NBR/PALF and NR/surface-treated PALF composites to improve the ultimate properties. By incorporation of carbon black 30 phr in both composites, the mechanical properties of composites were improved and can be controlled at both low and high deformations.

Microfibrillated cellulose (MFC) is an alternative material that has been widely studied to enhance the mechanical properties of a polymer matrix due to a number of perceived advantages over traditional plant fibre forms. Mechanical properties of MFC networks were found to depend on parameters such as the modulus of fibrils, bonding strength, porosity, degree of crystallinity, contact area of fibrils and possibly the modulus of the cellulose crystals of the raw materials (cellulose I or II). Even though the longer processing time used to produce MFC was found to yield networks with fewer fibre aggregates, finer fibrils and higher density, some properties, for instance thermal stability and degree of crystallinity, decreased due to the degradation of fibrils caused by the harsh treatment. The aims of this thesis were to assess the mechanical properties and interfaces of composites produced using of a range of MFC materials, prepared using different treatments and from different sources. Raman spectroscopy has been used to detect the molecular orientation of cellulose chains within an MFC network, and to monitor the deformation micromechanics of MFC networks. The Raman band initially located at ~1095 cm-1 obtained from MFC networks was observed to shift towards a lower wavenumber position upon the application of tensile deformation. The intensity of this band as a function of rotation angle of MFC networks was similar, indicating randomly oriented networks of fibrils. From the Raman band shift rate data, the effective moduli of MFC single fibrils produced from pulp were estimated to be in the range of 29-41 GPa. Poly(lactic acid) (PLA) composites reinforced with MFC networks were prepared using compression moulding. Enhanced mechanical properties of MFC reinforced composites were reported, compared to neat PLA films. The mechanical properties of these composites were found to mainly depend on the interaction of the PLA matrix and the reinforcement phase. The mechanical properties of the composites reinforced with dense networks were shown to be dominated by the network properties (fibril-fibril interactions), while matrix-fibril interactions played a major role where more opened networks were used to reinforce a polymer matrix. The penetration of the matrix into the network was found to depend on the pore sizes, fibre width and porosity within the network. It was found that the matrix easily penetrates into the network with a range of mean fibril dimensions, rather than for networks with only fine fibrils present. The stress-transfer process in MFC reinforced PLA composites was monitored using Raman spectroscopy. Greater Raman band shift rates with respect to tensile deformation for the composites were observed compared to pure MFC networks. This indicates that stress is transferred from the PLA matrix to MFC fibrils, supporting the enhancement of the mechanical properties of the composites.

Content: Leather is a fairly durable and flexible material created by tanning animal rawhides and can be found in many household and personal products. However, ensuring that the product endures attack from the environmental elements that contribute to its wear and tear is the key concern of the general consumer. Animal rawhides are soft collagenous connective tissues. The most important function of collagen is a mechanical one - to withstand loads acting on the leather material. The purpose of this paper is to show how findings from recent studies on the mechanics of collagen in connective tissues lend to the goal of structural biologists to establish a complete understanding of the functional significance of collagen in connective tissues. In particular, 28 different types of collagen have been identified - about 90% being type 1 collagen - in the human body. Most types of collagen participate in higher-order assemblies such as networks, filaments, microfibrils, fibrils, fibres/fascicles. These assemblies collectively form a hierarchical architecture in the tissue from the molecular level to the macroscopic level. A complete understanding the functional significance of collagen in connective tissues could direct the development of new technology, e.g. leather design and production. In this paper, I shall discuss findings related to the higher-order assemblies. The conventional understanding of the collagenous fibre-like structures - embedded in a hydrated ground substance - in connective tissue finds an analogy to engineering fibres reinforcing composite materials such as carbon fibre reinforced polymer composites. The macroscopic stress- strain response of the connective tissue to external loads acting on it is consistent with fibre composite behaviour. A structure-mechanical framework, underpinning the hierarchical architecture of the connective tissue, is proposed to explain this mechanical response of the tissue. By integrating models specific to the different levels of the tissue to enable better understanding of the macroscopic nature of the tissue, the framework serves as a representation of reality for guiding further research, especially for the purpose of exploring hypotheses and revealing properties for which only sparse (or no observational data) is available. This paper ends with a discussion on the prospect and challenges for future studies on collagen in connective tissues. Take-Away: A fresh look at the degree of collagen fibril alignment in tissue Rethinking the mechanics of cross-linking between fibrils Interfibrillar mechanics is governed by plastic stress transfer Influence of fibril diameter on interfibrillar stress transfer

One of the most significant issues in nanocomposite performance is improving the dispersion of carbon nanotubes (CNTs) in thermosetting or thermoplastic polymers in order to gain good mechanical properties. Several studies have investigated the fabrication of nanocomposites based on carbon nanotubes and analysed properties, but there is still insufficient data on their structure-property relationships. This thesis has investigated the central importance of stress transfer Raman studies in epoxy composites reinforced with single-walled carbon nanotubes (SWCNTs), double-walled carbon nanotubes (DWCNTs) and multiwall carbon nanotubes (MWCNTs) to elucidate the reinforcing ability of the CNTs in an epoxy matrix. This project was undertaken to synthesise and characterize MWCNTs and determine the effect of different weight fractions of untreated MWCNTs on the stress transfer efficiency at the MWCNTS / epoxy interface and on the stiffness of the thermomechanical properties of the MWCNTS / epoxy composites. It was undertaken to assess the stress transfer efficiency at the CNT / epoxy interface and at the inter-walls of the CNTs with tensile deformation and with cyclic loading.Optimized conditions of the injection chemical vapour deposition method (CVD), such as long injection times were applied to produce MWCNTs with a high yield, high aspect ratio and well-defined G' Raman peak. The morphology and size of CNTs were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) while their thermal stability was examined by Thermogravimetric analysis (TGA). Both Raman spectroscopy and mechanical testing (static and dynamic) were utilized in this study. The Raman spectroscopy research consisted of following the G'-band frequency and linewidth as well as the intensity of radial breathing modes (RBMs) during tensile deformation. The stress-induced Raman shifts in the nanocomposites have been shown to be controlled by the number of carbon nanolayers. A theory has been developed to determine and simulate the stress transfer efficiency parameter, (k_i) for MWCNTs. Tensile tests and dynamic mechanical testing were used to assess the mechanical properties of the nanocomposites.The most obvious finding to be drawn from the present study is that the reinforcement of the epoxy resin with different loadings of MWCNTs is useful, but the best reinforcement was at low loadings of MWCNTs. One of the more significant findings to emerge from this study is that (k_i) between the inner walls of the DWCNTs and MWCNTs are quite similar (~0.7), which suggest that (k_i) may be similar for all CVD MWCNTs and DWCNTs. The second major finding was that there were RBM intensity variations for the SWCNTs and DWCNTs in the hot-cured epoxy composites and that for the DWCNTs both the inner and outer nanotube walls are stressed during deformation

No description available.

Les travaux de cette thèse ont pour objectif d’améliorer la connaissance du comportement desbâtiments en béton armé. Ce comportement est notamment lié à celui de la liaison entre l’acier etle béton, qui permet de transférer les efforts entre les deux matériaux. La connaissance de cetteinterface conduit ainsi à l’amélioration de la conception des structures. Le cas spécifique desenceintes de confinement de réacteurs nucléaires induit une sollicitation particulière de la liaisonpar rapport aux sollicitations habituelles (comme la présence de traction en fibre inférieure d’unepoutre). Afin d’étudier cet état de contraintes, un essai push-in, peu étudié dans la littérature,est mis en place. Une instrumentation par fibres optiques innovante, précise et peu intrusive, estinsérée dans le béton et l’acier, permettant d’accéder aux déformations locales des deux milieux.De nombreuses données sont ainsi obtenues à différents stades du comportement de la liaisonacier-béton. Les essais réalisés font varier la longueur d’interface, menant à l’observation deplusieurs modes de rupture de l’éprouvette qui sont comparés entre eux. Celui correspondant auglissement de l’interface est plus particulièrement étudié. Le comportement précédent la rupture,souvent qualifié de linéaire, est également investigué. L’étude est complétée par la réalisation demesures post-mortem non destructives de perméabilité et par rayons X. Des phénomènes connuset nouveaux sont observés et permettent d’affiner les connaissances sur le comportement de laliaison acier-béton. Ces travaux pourront conduire à améliorer la précision de la modélisation ducomportement des structures en béton armé. De plus, les marges d’incertitude utilisées dans lescodes d’ingénierie sont susceptibles d’être diminuées. / This research aims at improving the knowledge about the behavior of reinforced concretebuildings. This behavior relies in particular on the steel-concrete link one, allowing to transferstresses between the two materials. Knowing the bond behavior leads to optimise the structuredesign. The specific case of confinement vessels of nuclear structures induces a special link sol-licitation compared to the usual sollicitations (such as presence of traction in the beam lowerfiber). In order to study this stress state, a push-in test, less studied according to the litterature,is set up. A new, precise and less-intrusive instrumentation by optic fiber is set up inside theconcrete and the steel, giving access to local strains of both mediums. Much data is obtainedat different steps of the steel-concrete interface behavior. Different interface lengths are used,leading to several rupture modes that are compared one to each other. The interface sliding oneis more particularly studied. The behavior before the rupture, sometimes qualified as linear, isinvestigated as well. Post-mortem non destructive measurements (permeability and X-ray to-mography) are finally performed. Known and new phenomena are observed and allow to refinethe knowledge regarding the steel-concrete link. This reasearch could lead to improve the mo-deling accuracy of reinforced concrete behaviors. Moreover, the uncertainty margins used in theengineering codes are likely to decrease.

Cette thèse s’intéresse à la signature sismique du rôle des fluides dans les mécanismes de déformation des roches fracturées de la croûte supérieure, et plus précisément les failles et les glissements de terrain. S’il est admis que les fluides sont un facteur déclenchant de la rupture dans le cas d’épisodes de forçages climatiques importants ou de glissements très superficiels, leur rôle dans la déstabilisation des grands volumes associée à des forçages faibles est beaucoup moins bien compris. Ainsi, il apparaît nécessaire d’acquérir de nouvelles données synchrones des pressions/débits de fluides, de la déformation et de la sismicité sur le terrain dans des conditions de chargement hydraulique contrôlées pour progresser dans la compréhension des liens entre processus hydromécaniques et sismiques participant à la nucléation de la rupture des roches en partie associée à la réactivation de fractures existantes. Motivé par ce besoin de nouvelles observations, ce travail de thèse concerne l’interprétation de la sismicité produite lors d’expériences originales de stimulation hydraulique (0.3 à 3.5 MPa et 10 à 3000 secondes) de petites zones de faille ou de fractures de taille décamétrique, situées en zones non saturées profonde de versants rocheux. Ces expériences consistaient à produire des déformations menant à l’activation du glissement le long des fractures préexistantes. Le protocole expérimental combine des mesures de déformations/pressions distribuées dans les structures géologiques à des capteurs sismologiques proches (échelle métrique à décamétrique) des zones sources. / This PhD dissertation focuses on the seismic signatures of the role of fluids in the deformation mechanisms of fractured rocks in the upper crust, mainly faults and landslides. While it is generally admitted that fluids are a triggering mechanism for rupture in the cases of episodic and major climate forcing events on shallow landslides, their role in the destabilization of large volumes of rocks, associated to weak forcing, is less understood. Thus, it is primordial to acquire new synchronous data of fluid pressure/flow, deformation and induced seismicity in the field, under controlled conditions of the hydraulic loading, in order to better understand the relationship between seismic and hydromechanical processes involved in the nucleation of rock ruptures, in part associated to the reactivation of existing fractures. Motivated by the need for new observations, this PhD thesis concerns the interpretation of the induced seismicity within unsaturated zones of deep rocky slopes, during original and controlled hydraulic stimulation experiments (0.3 to 3.5 MPa and from 10 to 3000 seconds) of small areas of decameter size. These experiments consisted in triggering rock deformations which lead to the activation of rock sliding along pre-existing fractures where deformation/pressure measurements and seismic sensors were distributed. These experiments were carried out in the Low Noise Underground Laboratory (France), which allows the access to fault zones within a rocky slope (at 250 m depth) and enables accurate geophysical measurements in conditions of very low environmental noise.