Graduation date: 2000

Thesis (Ph. D.)--University of Missouri-Columbia, 2001. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 2001. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

The objective of this research was to design a pilot scale continuous supercritical fluid extraction (SFE) system for the treatment of drill cuttings.The design includes: • A Piping and instrumentation diagram (P&ID) • A control philosophy • An operation manual, and • A HAZOP analysis The pilot scale SFE system was designed using a HAZOP-inspired framework, which resulted in the inclusion of risk reducing measures. This design approach was appropriate for the design of a novel technology, as risk reduction was made the inherent priority throughout the process. No major changes were made to the design during the professionally conducted safety analysis (HAZOP), thus the design is considered to be well positioned to operate safely. Recommended, non-critical future design improvements include: • Separation of the process control from the safety control systems • Continuous reduction of “human factors”, and • Review of all changes to the design before implementation / Natural Science and Engineering Research Council of Canada; M-I SWACO, a Schlumberger Company

No description available.

No description available.

No description available.

The technology of supercritical fluid extraction (SFE) offers the opportunity to efficiently extract both relatively non-polar analytes as well as ionic materials (such as metal ions) that can be mobilized with the addition of complexing reagents. The nebulizer of a conventional flame atomic absorption spectrometer (FAAS) was modified to extend the range of metals amenable to on-line detection. The flow injection thermospray-FAAS (FI-TE-FAAS) interface provided efficient detection for a variety of less volatile elements (Co, Cr(III), Cr(VI), Fe, Ni, Mn and Al) present as ions in aqueous media or as complexes in the supercritical fluid (SC-CO2) carrier phase. The range of possible metal analytes that can be monitored has been increased over the nine elements (Ag, As, Cd, Cu, Hg, Mn, Pb, Se and Zn) that could be detected with an all-silica interface. The acetylacetonate complexes offered considerable potential for metal detection in an SC-CO2 carrier phase. Limits of detection (LODs) were used to compare the instrument responses to different metals. (Abstract shortened by UMI.)

Thesis (PhD) -- University of South Australia, 1994

Thesis (Ph.D.)--University of Tulsa, 1991. / Bibliography: leaves 239-249.