This research examines environmental dispute resolution as applied to Superfund site cleanup and how the use of collaborative dispute resolution approaches, in particular Alternative Dispute Resolution and Community Involvement, are related to a community's socioeconomic and demographic profile. It examines the sociodemographic characteristics of residents living in census tracts containing Superfund sites in relation to the type of dispute resolution technique used. I hypothesize that collaborative dispute resolution techniques, as opposed to traditional settlement and/or litigation, are less likely to occur in Superfund communities with high poverty levels and high minority populations than in those with low poverty levels and low minority populations. Although minority and lower class communities are less likely to be placed on the National Priorities List (NPL), are slower to be cleaned up once on the NPL, and experience lower quality cleanups (O'Neil 2005; Sigman 2001; Omohundro 2004), the findings of this research indicate that the dispute resolution processes studied here do not contribute to such environmental clean up injustices. Minority status and poverty levels do not impact the likelihood that collaborative dispute resolution will be used in settling Superfund disputes. This analysis does show a significant correlation between education and the use of collaborative dispute resolution. Superfund communities in which residents have low educational attainment are less likely to use collaborative dispute resolution. Low educational levels may be the paramount disadvantage to overcome in the use and successful implementation of collaborative dispute resolution.

The present research examines the impact of not reauthorizing the Superfund taxes on the operations of the program. EPA NPL site status data were obtained from the EPA CERCLIS database for analysis in this study. Data were selected for the fiscal years 1981 to 2009 in four NPL listing status categories: proposal to the NPL, final NPL listing, deletion from the NPL, and achievement of construction completion. Since the Superfund tax expired in 1995, data from the 1981 to 1995 fiscal years and data from the 1996 to 2009 fiscal years were analyzed to determine if there were mean differences in NPL status achievements for those time frames potentially caused by lack of funding. The data in the fifth category (partial NPL deletion) were not analyzed because the EPA did not begin tracking this category as a program goal until 1997. EPA uses the status of sites in these categories to track achievement of program goals and effectiveness. The null hypothesis for this study is that there is no difference between program outcomes (NPL site status data reported by fiscal year) for the time period from 1981 to 1995 and 1996 to 2009 meaning that the failure to re-authorize the Superfund tax has not affected the clean-up of contaminated sites and how they are managed. The alternative hypothesis is that failure to re-authorize the Superfund tax has affected the clean-up of contaminated sites and how they are managed. In support of the alternative hypothesis, there were mean differences (for time frames 1981 to 1995 and 1996 to 2009) for NPL site status achievements for the following milestones: final listing on the NPL, deletion from the NPL, and achieving construction completion status on the NPL. These results suggest that variations in funding may have some impact on NPL status achievements. Annual funding trends from program inception to 2010, achievement of Superfund program goals for the 2009 and 2010 fiscal years, and the impact of the 2009 American Recovery and Reinvestment Act funding on the program were also examined. Although program goals were generally met or exceeded, limited funds will continue to impact the cleanup of existing and future Superfund sites.

No description available.

The following dissertation examines the role of collaborative planning in the redevelopment of National Priorities List Superfund sites and the implementation of Superfund site redevelopment plans. To examine the effect of collaborative planning, two models were constructed: one to predict Superfund site redevelopment and one to predict implementation of Superfund site redevelopment plans. Two test the two models, data was collected primarily from a survey of federal cleanup managers conducted between August 2008 and April 2009. Variables were then constructed and tested using bivariate and multivariate regression analysis. Results from the statistical analysis suggest that use of collaborative planning is positively and significantly associated with Superfund site redevelopment. Collaborative planning’s effect on Superfund site redevelopment plan implementation was inconclusive. To further explore the role of collaborative planning on Superfund site redevelopment and plan implementation, four case studies were developed that describe redevelopment planning at four Superfund sites. Overall, results suggest that collaborative planning is an important tool for the facilitation of Superfund site redevelopment. The effect of collaborative planning on plan implementation is somewhat ambiguous. Additional research is necessary, however, to draw firmer conclusions regarding both phenomena. / text

Wind erosion, transport and deposition of particulate matter can have significant impacts on the environment. It is observed that about 40% of the global land area and 30% of the earth's population lives in semiarid environments which are especially susceptible to wind erosion and airborne transport of contaminants. With the increased desertification caused by land use changes, anthropogenic activities and projected climate change impacts windblown dust will likely become more significant. An important anthropogenic source of windblown dust in this region is associated with mining operations including tailings impoundments. Tailings are especially susceptible to erosion due to their fine grain composition, lack of vegetative coverage and high height compared to the surrounding topography. This study is focused on emissions, dispersion and deposition of windblown dust from the Iron King mine tailings in Dewey-Humboldt, Arizona, a Superfund site. The tailings impoundment is heavily contaminated with lead and arsenic and is located directly adjacent to the town of Dewey-Humboldt. The study includes in situ field measurements, computational fluid dynamic modeling and the development of a windblown dust deposition forecasting model that predicts deposition patterns of dust originating from the tailings impoundment. Two instrumented eddy flux towers were setup on the tailings impoundment to monitor the aeolian and meteorological conditions. The in situ observations were used in conjunction with a computational fluid dynamic (CFD) model to simulate the transport of windblown dust from the mine tailings to the surrounding region. The CFD model simulations include gaseous plume dispersion to simulate the transport of the fine aerosols, while individual particle transport was used to track the trajectories of larger particles and to monitor their deposition locations. The CFD simulations were used to estimate deposition of tailings dust and identify topographic mechanisms that influence deposition. Simulation results indicated that particles preferentially deposit in regions of topographic upslope. In addition, turbulent wind fields enhanced deposition in the wake region downwind of the tailings. This study also describes a deposition forecasting model (DFM) that can be used to forecast the transport and deposition of windblown dust originating from a mine tailings impoundment. The DFM uses in situ observations from the tailings and theoretical simulations of aerosol transport to parameterize the model. The model was verified through the use of inverted-disc deposition samplers. The deposition forecasting model was initialized using data from an operational Weather Research and Forecasting (WRF) model and the forecast deposition patterns were compared to the inverted-disc samples through gravimetric, chemical composition and lead isotopic analysis. The DFM was verified over several month-long observing periods by comparing transects of arsenic and lead tracers measured by the samplers to the DFM PM₂₇ forecast. Results from the sampling periods indicated that the DFM was able to accurately capture the regional deposition patterns of the tailings dust up to 1 km. Lead isotopes were used for source apportionment and showed spatial patterns consistent with the DFM and the observed weather conditions. By providing reasonably accurate estimates of contaminant deposition rates, the DFM can improve the assessment of human health impacts caused by windblown dust from the Iron King tailings impoundment.

The National Electric Coil Company/Cooper Industries, Inc. plant in Harlan County, Kentucky was a mining support operation primarily engaged in the cleaning and repair of mining equipment from 1951 to 1987. Trichloroethylene (TCE) and degradation byproducts, polychlorinated biphenyls (PCBs), and vinyl chloride were released into the areas surrounding the plant periodically for decades. Routine water sampling of area wells by the Kentucky Department of Environmental Protection Division of Water revealed significant levels of TCE, PCBs, and vinyl chloride. The toxicology of these chemicals implicates various systems, including cardiovascular, dermal, endocrine, and neurological. University of Kentucky’s Superfund Basic Research Program’s (UK-SBRP) biomedical research is based on the premise that nutrition can modulate the effects of Superfund contaminants. In this study, the Community Outreach Core developed and delivered nutrition education programs to community members to address three issues: reduce total dietary fat, increase omega-3 fat, and increase dietary fiber. Initial efforts revealed the need for a holistic approach to identify and build trust with community members before programs could be presented. Results from informal discussions, qualitative assessments, and 24-hour dietary recalls using 2007 Nutrient Data System for Research were used to measure specific outcomes; increased knowledge, improved attitudes, and dietary behavior changes.

Biostimulation is the use of in-situ microorganisms and added reagents in order to biosequester, precipitate, or absorb contaminants from contaminated groundwater and sediment. To test the effectiveness of this remediation approach at a particular site, small scale experiments, such as miscible-displacement, batch, or microcosm experiments, should be performed before a large-scale in-situ biosequestration electron donor injection. In this study, electron donor solutions containing contaminated groundwater and ethanol, acetate, benzoate, or glucose were injected into aquifer sediments collected from a UMTRCA Title 1 Site in Monument Valley, AZ. These experiments showed that ethanol, acetate, and glucose were effective electron donors for the stimulation of microbial activity in order to sequester uranium and reduce nitrate and sulfate concentrations. Conversely, benzoate was not effective at sequestering or reducing the contaminants. After electron-donor deficient groundwater was injected into the columns, a rebound of nitrate, sulfate, and uranium concentrations was observed. Due to this rebound, it was inferred that the mechanism of sequestration of uranium and hence reduction of nitrate and sulfate was due to the creation of reducing conditions via microbial activity. The insoluble reduced uranium was hypothesized to have precipitated or adsorbed to surrounding sediments. Incoming groundwater contained dissolved oxygen and therefore oxidized the reduced contaminants, consequently returning them into solution. It was hypothesized that a similar rebound would occur if ethanol, acetate, or glucose were to be injected in-situ due to sustained groundwater flow through the aquifer sediments on site.

Bayview-Hunters Point, a neighborhood in southeastern San Francisco, has long been one of the most impoverished and polluted areas in the city. In an example of environmental racism, much of the African American community in San Francisco was segregated to Bayview-Hunters Point by racist housing policies and practices. This neighborhood was home to the Hunters Point Naval Shipyard (HPNS), which was widely polluted with hazardous wastes from shipyard operation as well as radioactive contamination from the Navy Radiological Defense Laboratory established on this property. The former HPNS was made a federal Superfund site in 1989 and has been in remediation by the Navy since, with the goal of eventual transfer of the land to the city of San Francisco for redevelopment into residential and commercial areas. Throughout the history of the HPNS, government agencies have obscured both radioactive contamination and the nearby disadvantaged community in pursuit of military and economic power. As a result, the forces of redevelopment have outpaced remediation in Hunters Point. In this thesis, I argue that in continuing the environmental racism marginalizes the community in Bayview-Hunters Point and working to hide the contamination at the nearby Superfund site government agencies, primarily the Navy and city government, have fostered the conditions for green gentrification to occur, which could have ill effects on both the longstanding community and new residents.

<p>Polycyclic aromatic hydrocarbons (PAHs) are important contaminants that are found in increasing amounts in aquatic ecosystems. One of the sites that that is contaminated by extremely high levels of PAHs is the Atlantic Wood Industries Superfund Site on the Elizabeth River, VA. The Atlantic killifish (<italic>Fundulus heteroclitus</italic>) from this site exhibit increased levels of antioxidants, increased sensitivity to hypoxia, and increased expression of enzymes involved in glycolytic metabolism, suggesting that exposure to PAHs in the environment may induce changes in mitochondrial function and energy metabolism. Normal mitochondrial activity is crucial to an organism's survival. Therefore, gaining a better understanding of how mitochondria are affected by environmental contaminants such as PAHs is a pressing research objective. As a first step in understanding changes in cellular bioenergetics of aquatic organisms in response to PAHs, this research focused on the effect of benzo[a]pyrene (BaP), a representative PAH, on mitochondria the killifish model and on comparison of the mitochondria of the PAH-adapted killifish from the Elizabeth River Superfund Site to reference site fish. In order to assess the extent of mitochondrial DNA damage in the killifish, a PCR-based assay (LA-QPCR) for nuclear and mitochondrial DNA (nDNA, mtDNA) damage was adapted to this model and validated in with UV exposure and BaP exposure studies, as well as with <italic>ex situ</italic> study examining DNA damage in killifish inhabiting the Elizabeth River Superfund site. With the newly adapted LA-QPCR, mtDNA and nDNA damage in the killifish from the Elizabeth River Superfund site and from a reference site (King's Creek, VA) that were treated with BaP were examined. Similar increases in mitochondrial and nuclear DNA damage were observed in King's Creek fish treated with BaP. Killifish from the Elizabeth River showed high levels of basal nDNA and mtDNA damage compared to fish from the reference site, but the level of damage induced due to BaP treatment was much lower in Elizabeth River killifish. Laboratory-reared offspring from both populations showed increased BaP-induced damage in mtDNA, relative to nDNA. Similar to the adult experiment, the Elizabeth River larvae had higher levels of basal DNA damage than those from the reference site, but were less impacted by BaP exposure. Results suggest that BaP exposure can have important energetic consequences and that multi-generational exposure in the wild may lead to adaptation that dampens DNA damage arising from BaP exposure. Since the toxic effects of many PAHs are the result of bioactivation by cytochrome P4501A (CYP1A), the existence of enzymes that can potentially metabolize PAHs in mitochondria was verified. Using Western blot, protein similar in size to microsomal CYP1A was identified with monoclonal antibody against scup CYP1A in the mitochondrial fraction from adult male killifish livers. The size of the protein in the mitochondria was the similar to that of microsomal CYP1A. Fish dosed with BaP had increased EROD activity in the liver mitochondrial fraction compared to controls. In killifish larvae dosed with BaP and benzo[k]fluoranthene (BkF), CYP1A protein levels as well as enzyme activity were elevated. However, fish from the Elizabeth River Superfund site showed recalcitrant mitochondrial CYP1A protein levels and enzyme activity in a similar manner to microsomal CYP1A. Finally, the hypothesis that energy metabolism of BaP-treated fish may be different from the control group and that killifish from the Elizabeth River Superfund site may also have altered energy metabolism compared to reference site fish was tested. Respiration of killifish embryos treated with BaP from both populations was measured. Compared to the King's Creek control fish, all other treatment groups showed decrease in oxygen consumption, indicating lower respiration rate. However, when activities of key enzymes involved in glycolysis (PK) and anaerobic metabolism (LDH) in adult killifish liver and muscle were measured, no differences in the enzyme activities were observed in BaP-treated group compared to the control group. Moreover, metabolomic analysis on BaP treated King's Creek and Elizabeth River killifish showed no difference in the profile in all four treatment groups. The findings in this thesis contribute to the understanding of how BaP, a common environmental pollutant in the aquatic ecosystem, targets the mitochondria in fish model. Nevertheless, deeper examination of how BaP may impact mitochondrial function in killifish and potentially influence adaptation of killifish at a highly contaminated site is necessary. Further studies will elucidate whether such impacts can potentially affect the energy budget and organism level fitness in populations in the wild.</p> / Dissertation

Thesis (M.S)--University of Tennessee, Knoxville, 2002. / Title from title page screen (viewed on Feb. 26, 2003). Thesis advisor: Eric C. Drumm. Document formatted into pages (viii, 76 p. : ill. (some col.), maps). Vita. Includes bibliographical references.