This dissertation focuses on the effects of heating on superhydrophobic (SHPo) surfaces. The work is divided into two main categories: heat transfer without mass transfer and heat transfer in conjunction with mass transfer. Numerical methods are used to explore the prior while experimental methods are utilized for the latter. The numerical work explores convective heat transfer in SHPo parallel plate microchannels and is separated into two stand-alone chapters that have been published archivally. The first considers surfaces with a rib/cavity structure and the second considers surfaces patterned with a square lattice of square posts. Laminar, fully developed, steady flow with constant fluid properties is considered where the tops of the ribs and posts are maintained at a constant heat flux boundary condition and the gas/liquid interfaces are assumed to be adiabatic. For both surface configurations the overall convective heat transfer is reduced. Results are presented in the form of average Nusselt number as well as apparent temperature jump length (thermal slip length). The heat transfer reduction is magnified by increasing cavity fraction, decreasing Peclet number, and decreasing channel size relative to the micro-structure spacing. Axial fluid conduction is found to be substantial at high Peclet numbers where it is classically neglected. The parameter regimes where prior analytical works found in the literature are valid are delineated. The experimental work is divided into two stand-alone chapters with one considering channel flow and the other a pool scenario. The channel work considers high aspect ratio microchannels with one heated SHPo wall. If water saturated with dissolved air is used, the air-filled cavities of SHPo surfaces act as nucleation sites for mass transfer. As the water heats it becomes supersaturated and air can effervesce onto the SHPo surface forming bubbles that align to the underlying micro-structure if the cavities are comprised of closed cells. The large bubbles increase drag in the channel and reduce heat transfer. Once the bubbles grow large enough, they are expelled from the channel and the nucleation and growth cycle begins again. The pool work considers submerged, heated SHPo surfaces such that the nucleation behavior can be explored in the absence of forced fluid flow. The surface is maintained at a constant temperature and a range of temperatures (40 - 90 °C) are explored. Similar nucleation behavior to that of the microchannels is observed, however, the bubbles are not expelled. Natural convection coefficients are computed. The surfaces with the greatest amount of nucleation show a significant reduction in convection coefficient, relative to a smooth hydrophilic surface, due to the insulating bubble layer.

Magnesium and its alloys have many interesting properties and thanks to them it can be used in many applications (transport industry, medicine etc.). Disadvantage of these materials is their high corrosion rate. For this reason, there is an effort to achieve high corrosion resistance through different modifications of magnesium and its alloys. In recent years the superhydrophobization of the surface seem to be an attractive solution for this question. This type surface modification minimalize contact between the surface and water. In this diploma thesis the superhydrophobic surface was created on the magnesium alloy AZ91. The first step included pretreatment of AZ91 surface by etching in solution of SnCl2 or ZnCl2. Next step was superhydrophobization in the ethanolic solution of stearic acid. The surface morphology and elemental analysis of the superhydrophobic coating were explored by use of scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS). The adhesion properties of the coating on the AZ91 were analysed by means of scratching test. Contact and sliding angles were measured for superhydrophobic coatings. Electrochemical characterization of the coatings was determined using potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS). Finally, the analysis of composition and the functional groups was made using Fourier-transform infrared spectroscopy (FTIR) and the phase composition analysis was performed using X-ray diffraction (XRD). The results show that the coatings prepared by etching did not lead to good corrosion properties, even though the value of contact angle was about 150 °. The reduction of corrosion resistance could be caused by not obtaining required surface morphology or insufficient binding of stearic acid in the form of stearate to the sample surface.

Ice accretion on various surfaces can cause destructive effect of our lives, from cars, aircrafts, to infrastructure, power line, cooling and transportation systems. There are plenty of methods to overcome the icing problems including electrical, thermal and mechanical process to remove already accumulated ice on the surfaces and to reduce the risk of further operation. But all these process required substantial amount of energy and high cost of operation. To save the global energy and to improvement the safety issue in many infrastructure and transportation systems we have to introduce some passive anti-icing coating known as ice-phobic coating to reduce the ice-formation and ice adhesion onto the surface. Ice-phobic coatings mostly devoted to utilizing lotus-leaf-inspired superhydrophobic coatings. These surfaces show promising behavior due to the low contact area between the impacting water droplets and the surface. In this present study we investigate systematically the influence of chemical composition and functionality as well as structure of surfaces on wetting properties and later on icing behavior of surfaces. Robust anti-icing coating has been prepared by using modified silica particles as a particles film. Polymer brushes were synthesized on flat, particle surfaces by using Surface initiated ATRP. We have also investigated the effect of anti-icing behavior on the surfaces by varying surface chemistry and textures by using different sizes of particles. This approach is based on the reducing ice accumulation on the surfaces by reducing contact angle hysteresis. This is achieved by introducing nano to micro structured rough surfaces with varying surface chemistry on different substrates. Freezing and melting dynamics of water has been investigated on different surfaces by water vapour condensation in a high humidity (80%) condition ranging from super hydrophilic to super hydrophobic surfaces below the freezing point of water. Kinetics of frost formation and ice adhesion strength measurements were also performed for all samples. All these experiments were carried out in a custom humidity and temperature controlled chamber. We prepared a superhydrophobic surface by using Poly dimethyl siloxane (PDMS) modified fumed silica which display very low ice-adhesion strength almost 10 times lower than the unmodified surface. Also it has self-cleaning behavior after melting of ice since whole ice layer was folded out from the surface to remove the ice during melting. Systematic investigation of the effect of three parameters as surface energy, surface textures (structure, geometry and roughness) and mechanical properties of polymers (soft and stiff) on icing behavior has also been reported.

No description available.

No description available.

Periodic, micropatterned superhydrophobic surfaces, previously noted for their ability to provide drag reduction in the laminar flow regime, have been demonstrated capable of reducing drag in the turbulent flow regime as well. Superhydrophobic surfaces contain micro or nanoscale hydrophobic features which can support a shear-free air-water interface between peaks in the surface topology. Particle image velocimetry and pressure drop measurements were used to observe significant slip velocities, shear stress, and pressure drop reductions corresponding to skin friction drag reductions approaching 50%. At a given Reynolds number, drag reduction was found to increase with increasing feature size and spacing, as in laminar flows. No observable drag reduction was noted in the laminar regime, consistent with previous experimental results and theoretical predictions for the channel geometry considered. In turbulent flow, viscous sublayer thickness appears to be the relevant length scale as it approaches the scale of the superhydrophobic microfeatures; performance was seen to increase with further reduction of the viscous sublayer. These results indicate superhydrophobic surfaces may provide a significant drag reducing mechanism for marine vessels.

No description available.

In nature, microscopic surface textures impact useful function, such as the drag reduction of shark skin (Dean & Bhushan, 2010) and superhydrophobicity of the lotus leaf(Pan, Kota, Mabry, & Tuteja, 2013). In this study, we explore these phenomena by re-creating microscopic surface textures via the method of interfacial flow instability in drying polyvinylidene fluoride (PVDF) acetone solutions. In general, PVDF films can be made using either spin coating or electrospray deposition with various weight concentrations in acetone. In order to study the morphology of the porous structure of PVDF films, wet deposition samples were fabricated by spin coating or near-field electrospray. Possible theories are discussed and examined to explain the formation of these porous structures resulting in development of a well-controlled method to create porous PVDF films with various pore sizes and pore densities. All samples are characterized and found to exhibit superhydrophobicity and drag reduction. To connect porous PVDF film morphology to the established field of dry particle fabrication, PVDF particle synthesis by far-field electrospray is also reviewed and discussed. An established method to generate polymer particles of different morphologies in other polymers (Almeria-Diez, 2012) by electrospray drying is confirmed using PVDF as well. Due to the ability of scalable and re-configurable electrospray, the microscopic surface textures can be applied to areas of any size to reduce drag or impart water-repelling properties.

No description available.

Many of the flows in nature are turbulent. To modify turbulent flows, nature serves itself with different types of coatings. Sharks have riblets-like structures on their skin, fishes have slime with polymers and the surface of the lotus flower has superhydrophobic properties. However many times these naturally occurring coatings also serve other purposes. Due to millions of years of adaption, there are anyway many reasons to be inspired by these. The present work is an investigation of nature inspired coatings with the aim of passive flow manipulations. The goal of the investigation has not been to achieve drag reduction, but to achieve a better understanding of the effect of these coatings on turbulent flows. Simulations have been performed in a channel flow configuration, where the boundary condition on one wall has been modified. A macroscopic description has been used to simulate superhydrophobic and porous-like surfaces and a microscopic description has been used to simulate suspended fibers, both rigid and flexible, attached to the channel wall. For the macroscopic description, a pseudo-spectral method was used and for the microscopic description a lattice-Boltzmann method was used. The superhydrophobic modification was implemented using a general slip tensor formulation. In agreement with earlier results, drag reduction was achieved with slip in the streamwise direction and slip in the spanwise direction resulted in drag increase. Non-zero off-diagonal terms in the slip tensor resulted in a slight drag increase, but with rather similar flow behaviour. Transpiration, imitating a porous media, gave rise to drag increase and severely modified the turbulent structures, forming two-dimensional structures elongated in the spanwise direction. For the short fibers, neither rigid nor flexible fibers modified the velocity field to a large extent. The fibers gave rise to recirculation regions and these were seen to be stronger below high-speed streaks. Flexible fibers showed similarities to porous media through a coupling of wallnormal velocity and pressure fluctuations, and this was not seen for the rigid fibers. The fiber deflections were seen to correlate well with the pressure fluctuations. / Många naturligt förekommande flöden är turbulenta. Naturen har också gett upphov till flera typer av ytskikt som kan påverka dessa. Hajars skinn har räfflor, fiskar har slem som innehåller polymerer och lotusblommans yta har superhydrofobiska egenskaper, men ofta har dessa naturliga ytskikt också andra egenskaper. På grund av miljoner år av anpassning så finns det ändå många skäl att studera dessa. Detta arbete är en studie av naturinspirerade ytskikt, där målet har varit passiva flödesmanipulationer. Målet har inte varit att åstadkomma en ytfriktionsminskning, utan att få en bättre förståelse om hur dessa ytskikt påverkar turbulenta flöden. Simuleringar har utförts i en kanalliknande geometri, där en kanalväggs randvillkor har modifierats. En makroskopisk beskrivning har använts för att simulera superhydrofobiska och porösa ytor och en mikroskopisk beskriving har använts för att simulera fibrer, både stela och böjbara, fastsatta på en kanalvägg. För flödet med det makroskopiskt beskrivna randvillkoret har en pseudospektral metod använts och för flödet med det mikroskopiskt beskrivna randvillkoret har en lattice-Boltzmannmetod använts. Den superhydrofobiska ytan implementerades genom en generell tensorformulering. Ett randvillkor med nollskild hastighet i kanalens riktning gav upphov till en ytfriktionsminskning och ett randvillkor med nollskild hastighet vinkelrät mot kanalens riktning gav upphov till en ökad ytfriktion, i överensstämmelse med tidigare resultat. Nollskilda icke-diagonala tensorelement gav upphov till en smärre ökning av ytfriktionen, utan att nämnvärt förändra flödet. De porösa ytorna gav upphov till en ytfriktionsökning och hade stor inverkan på de turbulenta strukturerna. Dessa ytor bildade tvådimensionella struturer vinkelrät mot kanalens riktning. Varken de stela eller de böjbara fibrerna gav upphov till stora ändringar i hastighetsfältet. Däremot uppstor cirkulationszoner och dessa var starkare under stråkstrukturer med hög hastighet. De böjbara fibrerna uppvisade likheter med porösa material genom en interaktion mellan det vertikala hastighetsfältet och de turbulenta tryckfluktuationerna. Denna interaktion uppstod inte för de stela fibrerna. Fibrernas böjning korrelerade också i stor utsträckning till tryckfluktuationerna.