A Building Integrated Photovoltaic/Thermal (BIPV/T) system that consists of a mechanically ventilated, multi-skin facade, a between-the-panes venetian blind layer, and a between-the-panes Photovoltaic (PV) panel is considered. Ambient air is drawn in and forced to flow upward through the system. As air moves through the system, it is heated by the blind layer, the glazing layers, and the PV panel. This BIPV/T system is especially attractive because it can produce electricity and thermal energy in the form of preheated fresh air and allow for adjustable daylighting. There is a need to understand, design, and optimize BIPV/T systems. The velocity and temperature fields around the blind slats were experimentally and numerically studied. Experimental observations and numerical models are essential in understanding the complex fluid dynamical and thermal system and providing design and optimization guidelines. Solar-optical and Computational Fluid Dynamics (CFD) models were developed and validated at various blind slat angles and flow mean speeds. Particle Image Velocimetry (PIV) and temperature measurements were taken inside the ventilated facade. A simple empirical one-dimensional (1–D) model was developed, based on average surface temperatures and heat transfer coefficients, to quickly calculate average surface temperatures and heat flux rates. Between-the-panes convective heat transfer coefficients were obtained from CFD and used in the 1–D model. Despite high vertical temperature stratifications along the glazing, shading, and air layers, the 1–D model can predict the surface temperatures accurately and allow for future optimization and inclusion in building energy simulation software.

The Double Deficit Hypothesis posits that four mutually exclusive subgroups can be identified in a reading disabled (RD) sample. These subgroups are predicted to differ on reading measures, and further evidence suggests they may differ on other academic achievement (AA) and neuropsychological (NP) measures, as well as sex ratios and rate of ADHD diagnosis. Two hundred twenty six college-level adults identified as RD were evaluated, and subgroup comparisons were analyzed. Significant subgroup differences were observed in each domain. No subgroup differences were observed for sex or ADHD diagnosis. Findings suggest that patterns of linguistic ability affect the profiles of reading, AA, and NP performance that characterize adults with RD. These findings have implications for evaluations and academic accommodations.

This study addresses the discrepancy between the range of Beethoven's double bass parts and the instrument or instruments in use in Vienna in his day. Scholars and musicians have complained about Beethoven's apparent disregard for the instrument's capabilities since the middle of the nineteenth century. A systematic examination of Beethoven's orchestral writing for the double bass shows that this reputation is undeserved. In fact Beethoven paid close attention to the lower compass of the double bass throughout his orchestral writing: a clear boundary of F is observed up to op. 55, and thereafter E, though F still obtains in some late works. Beethoven's observance of the F boundary suggests that he was writing for the Viennese five-stringed violone, and not the modern form of the instrument, as has previously been assumed in scholarship. Other evidence pointing to the use of this instrument is presented. Some of Beethoven's bass parts between op. 55 and op. 125 do in fact descend to C (sounding C1); yet there is no evidence supporting the existence of a double bass instrument capable of C1 in Beethoven's day. Possible explanations for these violations of the compass of the double bass are discussed. These focus on the possibility of simple proofreading error, and on evidence for the unwritten practice of reinforcing the double bass with one or more contrabassoons. The contrabassoon in Beethoven's day had a lower compass of C1, and Vienna was an early center for its production and use. Analysis of the bulk of Beethoven's double bass parts for their range is given. Emphasis in this analysis is given to instances where Beethoven demonstrates a clear awareness of the compass of the instrument. Out-of-range pitches are compiled in table form.

Abstract <br /> This thesis deals with the numerical investigation of the upper section of a building-integrated photovoltaic/thermal double-façade. The upper section consists of an airflow window with a between-the-panes roller blind. The purpose of this thesis is to develop and validate a numerical model in order to optimize the design of the system. The lower section, which consists of building-integrated photovoltaics, has already been modelled at Concordia University. The results from the lower section will be used as inputs to the upper section. <br /><br /> The validation of the model was carried out in three stages. In the first stage, the model was validated for forced convection between parallel plates using analytical data as benchmarks. In the second stage, a radiation analysis was performed for single, double and triple-glazed closed system with natural convection only. In the third and final validation stage, experimental data gathered from the Solar Lab at Concordia University was compared to the numerical model. The model included the effects of radiation for an open system with forced convection and a between-the-panes roller blind. For all three stages of validation, the results from the model were in excellent agreement with the benchmarking data. <br /><br /> Once the model was validated, a parametric analysis was used to determine the effects of varying key model parameters. The outlet temperature, the useful energy gain, and the net energy gain of the system were plotted as a function of inlet velocity. It was concluded that as the flow rate through the cavity was increased, the air temperature at the outlet approached that of the outdoor ambient air. By computing the heat generated from advection as well as the total losses from the system, including the heat lost from the indoor environment as well as the power consumed by the fan, the net useful heat gain of the system was calculated as a function of insolation level. Operating points (of the fan) for the upper section were therefore determined as functions of insolation level. A second order polynomial equation provided an excellent fit to the data and could therefore be used to determine the ideal operating point of the upper section for any insolation level.

A Building Integrated Photovoltaic/Thermal (BIPV/T) system that consists of a mechanically ventilated, multi-skin facade, a between-the-panes venetian blind layer, and a between-the-panes Photovoltaic (PV) panel is considered. Ambient air is drawn in and forced to flow upward through the system. As air moves through the system, it is heated by the blind layer, the glazing layers, and the PV panel. This BIPV/T system is especially attractive because it can produce electricity and thermal energy in the form of preheated fresh air and allow for adjustable daylighting. There is a need to understand, design, and optimize BIPV/T systems. The velocity and temperature fields around the blind slats were experimentally and numerically studied. Experimental observations and numerical models are essential in understanding the complex fluid dynamical and thermal system and providing design and optimization guidelines. Solar-optical and Computational Fluid Dynamics (CFD) models were developed and validated at various blind slat angles and flow mean speeds. Particle Image Velocimetry (PIV) and temperature measurements were taken inside the ventilated facade. A simple empirical one-dimensional (1–D) model was developed, based on average surface temperatures and heat transfer coefficients, to quickly calculate average surface temperatures and heat flux rates. Between-the-panes convective heat transfer coefficients were obtained from CFD and used in the 1–D model. Despite high vertical temperature stratifications along the glazing, shading, and air layers, the 1–D model can predict the surface temperatures accurately and allow for future optimization and inclusion in building energy simulation software.

Protected DHA units, known as dioxanones, are interesting compound which can be used as the building blocks for synthesis of polyoxygenated natural products. The direct aldol reaction is employed for converting of those inexpensive starting materials into enantioenriched products of complexed structures. The stereocontrol in the first aldol reaction is achieved by using organocatalysis. Second aldol reaction is conducted by lithium enolate chemistry leading to anticisanti aldols as a major isomer. On the other hand boron chemistry provides antitransanti products. This strategy is used for synthesis of higher sugars.

<p>Liposomes are excellent chemotherapy drug delivery agents, on the cutting edge of cancer treatment technology. Since liposomes are already used to deploy cancer drugs in patients, imaging capacity would make them dual-purpose "theranostic" vesicles. Intermolecular double quantum coherence (iDQC) MRI is uniquely suited to this application, as its contrast does not require any additional chemicals. Adding contrast agents to liposomes can be time-consuming, add to toxicity, interfere with membrane function, or adversely affect drug loading. Furthermore, iDQC contrast measures diffusion and thus directly depends on membrane permeability and related properties. In this set of experiments, it has been shown that iDQC signal from intra-liposomal water can be distinguished from that of bulk water, and that the T2 dynamics of intra-liposomal water are predictable and dependent on the percent of water encapsulated. These techniques to distinguish between water molecules based on their current physical circumstances lead to many novel possibilities in MRI, as nearly all the signal in conventional MRI is from water protons. Based on the signal to noise ratio in the aforementioned iDQC experiments, we predict that iDQC contrast from liposomes will be visible in vivo, and propose to prove this in a murine model. By examining intra-liposomal water, iDQC can be used to improve chemotherapy delivery via real time monitoring of liposome location and drug release.</p> / Thesis

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The hamiltonian number problem is a generalization of hamiltonian cycle problem in graph theory. It is well known that the hamiltonian cycle problem in graph theory is NP-complete [16]. So the hamiltonian number problem is also NP-complete. On the other hand, the hamiltonian number problem is the traveling salesman problem with each edge having weight 1. A hamiltonian walk of a graph G is a closed spanning walk of minimum length. The length of a hamiltonian walk in G is called the hamiltonian number. For graphs, we give some bounds for hamiltonian numbers of graphs. First, we improve some results in [14] and give a necessary and sufficient condition for h(G) < e(G) where e(G) is the minimum length of a closed walk passing through all edges of G. Next, we prove that if two nonadjacent vertices u and v satisfying that deg(u)+deg(v) ≥ |G|, then h(G) = h(G + uv). This result generalizes a theorem of Bondy and Chv¡¬atal for the hamiltonian cycle. Finally, we show that if 0 ≤ k ≤ n − 2 and G is a 2-connected graph of order n satisfying deg(u) + deg(v) + deg(w) ≥ 3n−k−2 for every independent set {u, v,w} of three vertices in G, then h(G) ≤ n+k. It is a generalization of a Bondy¡¦s result. For digraphs, we give some bounds for hamiltonian numbers of digraphs first. We prove that if a digraph D of order n is strongly connected, thenn ≤ h(D) ≤ ⌊(n+1)^2/4 ⌋. Next, we also present some digraphs of order n ≥ 5 which have hamiltonian number k for n ≤ k ≤ ⌊(n+1)^2/4 ⌋. Finally, we study hamiltonian numbers of M¡Lobius double loop networks. We introduce M¡Lobius double loop network and every strongly connected double loop network is isomorphic to some M¡Lobius double loop network. Next, we give an upper bound for the hamiltonian numbers of M¡Lobius double loop networks. Then, we find some necessary and sufficient conditions for M¡Lobius double loop networks MDL(d, m, ℓ) to have hamiltonian numbers dm, dm + 1 or dm + 2.

Traditional transfer function of integrators have warping effect in high frequency, this isn¡¦t good for make filter circuit. In reference[3] they mention a new transfer function to improve this error, but we found that the design of the previous circuit doesn¡¦t conform to the new transfer function. In this thesis, a different structure of integrator is presented, it use the method of double sampling to realize the modified bilinear transfer function, in addition, we also add a grounded-gate amplifier to decrease the input impedance and dummy switch technique what can reduce the charge injection error, then we use the central circuit to make the second order bandpass filter. The proposed circuit employ Hspice to simulate and design the form of the circuit layout, then use TSMC 0.35£gm CMOS process to make chip. The sampling frequency is 10MHz, the central frequency is 1MHz, and the power consumption is 1.78mW.