Materials at the nanoscale show properties uniquely different from the bulk scale which when controlled can be utilized for variety of thermal management applications. Different applications require reduction, increase or directional control of thermal conductivity. This thesis focuses on investigating thermal transport in two such application areas, viz., 1) thermoelectric energy conversion and 2) thermal rectification. Using molecular dynamics simulations, several methods for reducing of thermal conductivity in polyaniline and polyacetylene are investigated. The reduction in thermal conductivity leads to improvement in thermoelectric figure of merit. Thermal diodes allow heat transfer in one direction and prevents in the opposite direction. These materials have potential application in phononics, i.e., for performing logic calculations with phonons. Rectification obtained with existing material systems is either too small or too difficult to implement. In this thesis, a more useful scheme is presented that provides higher rectification using a single wall carbon nanotube (SWCNT) that is covalently functionalized near one end with polyacetylene (PA). Although several thermal diodes are discussed in literature, more complex phononic devices like thermal logic gates and thermal transistors have been sparingly investigated. This thesis presents a first design of a thermal AND gate using asymmetric graphene nanoribbon (GNR) and characterizes its performance. / Ph. D.

Thermoelectric (TE) module integration into a notebook computer is experimentally investigated in this thesis for its energy harvesting opportunities. A detailed Finite Element (FE) model was constructed first for thermal simulations. The model outputs were then correlated with the thermal validation results of the selected system. In parallel, a commercial TE micro-module was experimentally characterized to quantify maximum power generation opportunity from the combined system and component data set. Next, suitable &ldquo / warm spots&rdquo / were identified within the mobile computer to extract TE power with minimum or no notable impact to system performance, as measured by thermal changes in the system, in order to avoid unacceptable performance degradation. The prediction was validated by integrating a TE micro-module to the mobile system under test. Measured TE power generation power density in the carefully selected vicinity of the heat pipe was around 1.26 mW/cm3 with high CPU load. The generated power scales down with lower CPU activity and scales up in proportion to the utilized opportunistic space within the system. The technical feasibility of TE energy harvesting in mobile computers was hence experimentally shown for the first time in this thesis.

Energy harvesting is identified as a promising alternative solution for powering implantable biosensors. It can completely replace the batteries, which are introducing many limitations, and it enables the development of self-powered implantable biosensors. An interface circuit is necessary to correct for differences in the voltage and power levels provided by an energy harvesting device from one side, and required by biosensor circuits from another. This thesis investigates the available energy harvesting sources within the human body, selects the most suitable one and proposes the power management unit (PMU), which serves as an interface between a harvester and biosensor circuits. The PMU targets the efficient power transfer from the selected source to the implantable biosensor circuits. Based on the investigation of potential energy harvesting sources, a thermoelectric energy harvester is selected. It can provide relatively high power density of 100 μW/cm2 at very low temperature difference available in the human body. Additionally, a thermoelectric energy harvester is miniature, biocompatible, and it has an unlimited lifetime. A power management system architecture for thermoelectric energy harvesters is proposed. The input converter, which is the critical block of the PMU, is implemented as a boost converter with an external inductor. A detailed analysis of all potential losses within the boost converter is conducted to estimate their influence on the conversion efficiency. The analysis showed that the inevitable conduction and switching losses can be reduced by the proper sizing of the converter’s switches and that the synchronization losses can be almost completely eliminated by an efficient control circuit. Additionally, usually neglected dead time losses are proved to have a significant impact in implantable applications, in which they can reduce the efficiency with more than 2%. An ultra low power control circuit for the boost converter is proposed. The control is utilizing zero-current switching (ZCS) and zero-voltage switching (ZVS) techniques to eliminate the synchronization losses and enhance the efficiency of the boost converter. The control circuit consumes an average power of only 620 nW. The boost converter driven by the proposed control achieves the peak efficiency higher than 80% and can operate with harvested power below 5 μW. For high voltage conversion ratios, the proposed boost converter/control combination demonstrates significant efficiency improvement compared to state-of-the-art solutions. / <p>QC 20150413</p>