Gas migration in saturated argillaceous rock is studied in this work. Dependent on the pressure level the gas transport process is controlled by different mechanisms. Gas injection tests have been carried to investigate the gas transport process in low permeable argillaceous rock. We focus on the Opalinus Clay, which has been widely researched and is important for searching possible host rock of the radioactive waste disposal. Gas injection tests at different scales (laboratory, in-situ borehole and in-situ tunnel test) are intensively investigated in this work. The measurements of the tests are analysed and interpreted with numerical modelling method. A coupled multi-phase flow and mechanical model has been developed and implemented in the scientific computed codes OpenGeoSys (OGS). In the applied numerical model the relationship between capillary pressure and water saturation degree is described with van Genuchten model. The Darcy’s law is used for the phase flux, and the relative permeability of both water and gas phase is considered. The deformation process is calculated with elastic perfect-plastic model. The anisotropic hydraulic and mechanic behaviours of the Opalinus Clay are involved in the numerical model. The hydraulic anisotropy is controlled by the permeability tensor. The elastic deformation process is modelled by generalized Hooke’s law. The plastic behaviour is calculated with return mapping algorithm, and the anisotropy is considered with a so called microstructure tensor method. The permeability change during the gas injection is described using pressure dependent or deformation dependent approach. With considering the permeability evolution the measured data can be in the numerical model quantitatively represented, and test observations can be interpreted. Under laboratory condition it can be determined that the specimen permeability is reduced during compression. The significant permeability increase takes places when the gas injection pressure higher than the confining pressure. By the in-situ tests damage zone can be generated due to the drilling of boreholes and tunnel. The highly permeable areas dominate the hydraulic process. Fluid flows through the damaged zone into the not sealed section, e.g. the seismic observation boreholes by the in-situ borehole tests and the section out of the megapacker by the in-situ tunnel tests. In this work, the two phase flow controlled and pathway dilatancy controlled gas migration mechanisms are successfully simulated. The developed numerical model can be used to investigate the gas injection tests at different scales and conditions.

Gas migration in saturated argillaceous rock is studied in this work. Dependent on the pressure level the gas transport process is controlled by different mechanisms. Gas injection tests have been carried to investigate the gas transport process in low permeable argillaceous rock. We focus on the Opalinus Clay, which has been widely researched and is important for searching possible host rock of the radioactive waste disposal. Gas injection tests at different scales (laboratory, in-situ borehole and in-situ tunnel test) are intensively investigated in this work. The measurements of the tests are analysed and interpreted with numerical modelling method. A coupled multi-phase flow and mechanical model has been developed and implemented in the scientific computed codes OpenGeoSys (OGS). In the applied numerical model the relationship between capillary pressure and water saturation degree is described with van Genuchten model. The Darcy’s law is used for the phase flux, and the relative permeability of both water and gas phase is considered. The deformation process is calculated with elastic perfect-plastic model. The anisotropic hydraulic and mechanic behaviours of the Opalinus Clay are involved in the numerical model. The hydraulic anisotropy is controlled by the permeability tensor. The elastic deformation process is modelled by generalized Hooke’s law. The plastic behaviour is calculated with return mapping algorithm, and the anisotropy is considered with a so called microstructure tensor method. The permeability change during the gas injection is described using pressure dependent or deformation dependent approach. With considering the permeability evolution the measured data can be in the numerical model quantitatively represented, and test observations can be interpreted. Under laboratory condition it can be determined that the specimen permeability is reduced during compression. The significant permeability increase takes places when the gas injection pressure higher than the confining pressure. By the in-situ tests damage zone can be generated due to the drilling of boreholes and tunnel. The highly permeable areas dominate the hydraulic process. Fluid flows through the damaged zone into the not sealed section, e.g. the seismic observation boreholes by the in-situ borehole tests and the section out of the megapacker by the in-situ tunnel tests. In this work, the two phase flow controlled and pathway dilatancy controlled gas migration mechanisms are successfully simulated. The developed numerical model can be used to investigate the gas injection tests at different scales and conditions.

At Zwartbas, about 10 km west of Vioolsdrif, southern Namibia, the Dwyka succession is composed of tillites and distal fossiliferous dropstone-bearing glacio-marine shales. The completely exposed Dwyka succession is interbedded with thin bentonites, altered distal pyroclastic deposits, which were derived from the magmatic arc at the southern rim of Gondwana. Dropstone-bearing and dropstonefree sequences intercalate with four diamictites, of which the two lowest were certainly recognised as tillites. Four events of deglaciation were proven at Zwartbas and thus consist with correlative deposits in southern Africa. Numerous fossilised fishes, trace fossils, and plant fragments appear frequently within the lower half of the Dwyka succession whereas trace fossils were principally found in the complete succession. Although the environmental determination is quite problematic, the fossil assemblage rather implies proximal, shallow water conditions with temporary restricted oxygenation. The hinterland was covered with considerable vegetation, which points to a moderate climate. Water salinity determinations based on shale geochemistry rectify contrary palaeontological results and point to rather brackish or non-marine conditions in comparison to present-day salinites. Geochemical analyses of the bentonites relate the pyroclastic deposits with acid to intermediate source magmas, as they are known from the magmatic arc in present-day Patagonia. Tectono-magmatic comparisons furthermore emphasise a syn-collision or volcanic-arc situation of the magma source. However, significant cyclicity in the production of the pyroclastic deposits was not observed. Radiometric age determinations of two tuff beds clearly date the onset of glacial activity into the Late Carboniferous.

The locality of Zwartbas is situated at the border of Namibia and South Africa about 15 km west of Noordoewer. The mapped area is confined by the Tandjieskoppe Mountains in the north and the Orange River in the south. Outcropping rocks are predominantly sediments of the Nama Group and of the Karoo Supergroup. During the compilation of this paper doubts arose about the correct classification of the Nama rocks as it is found in literature. Since no certain clues were found to revise the classification of the Nama rocks, the original classification remains still valid. Thus the Kuibis and Schwarzrand Subgroup constitute the Nama succession and date it to Vendian age. A glacial unconformity represents a hiatus for about 260 Ma. This is covered by sediments of the Karoo Supergroup. Late Carboniferous and early Permian glacial deposits of diamictitic shale of the Dwyka and shales of the Ecca Group overlie the unconformity. The shales of the Dwyka Group contain fossiliferous units and volcanic ash-layers. A sill of the Jurassic Tandjiesberg Dolerite Complex (also Karoo Supergroup) intruded rocks at the Dwyka-Ecca-boundary. Finally fluvial and aeolian deposits and calcretes of the Cretaceous to Tertiary Kalahari Group and recent depositionary events cover the older rocks occasionally. / Die Lokalität Zwartbas liegt an der namibisch-südafrikanischen Grenze, etwa 15 km westlich von Noordoewer. Das Kartiergebiet wird durch die Tandjiesberge im Norden und den Oranje Fluß im Süden begrenzt. Die anstehenden Gesteine bestehen hauptsächlich aus Sedimenten der Nama Gruppe und der Karoo Supergruppe. Während der Erarbeitung dieser Abhandlung entstanden Zweifel an der Klassifikation der Nama Gesteine, so wie sie in der Literatur zu finden ist. Da keine sicheren Hinweise zur Revision der Klassifikation der Nama Gesteine gefunden wurden, bleibt die ursprünglich Klassifikation jedoch gültig. Die Kuibis und Schwarzrand Untergruppe bilden also die Nama Abfolge und datieren sie ins Vendian. Eine glaziale Diskontinuität repräsentiert einen Hiatus von etwa 260 Mio Jahren. Sie wird überlagert von Sedimenten der Karoo Supergruppe. Spät-karbone und früh-permische glaziale Ablagerungen von diamiktitischen Tonsteinen der Dwyka Gruppe und Tonsteine der Ecca Gruppe liegen über dieser Diskontinuität. Die Sedimente der Dwyka Gruppe sind fossilführend und enthalten Tufflagen. Ein Sill des jurassischen Tandjiesberg Dolerit Komplex (auch Karoo Supergruppe) intrudierte in die Gesteine an der Dwyka-Ecca Grenze. Schließlich bedecken lokal fluviatile und äolische Ablagerungen und Kalkkrusten der kretazischen und tertiären Kalahari Gruppe und jüngerer Ablagerungsereignisse die älteren Gesteine.

Análises mineralógicas, petrográficas e de palinofácies são registradas em um leito de tonstein associado a camadas de carvão na Jazida do Faxinal, Rio Grande do Sul, Brasil. A integração dos dados revestiu-se de grande importância para atribuir uma origem vulcânica para este argilito caolinítico. O tonstein é uma rocha quase monominerálica, composta predominantemente por caolinita antigênica. Dispersos na massa caolinítica ocorrem os minerais piroclásticos: paramorfos de quartzo-ß bipiramidais euédricos, “splinters” de quartzo transparente, zircão idiomórfico, apatita euédrica, alanita e pseudomorfos de sanidina, os quais são considerados como uma suíte restrita de minerais vulcânicos de tonsteins distais que preservaram durante a diagênese. Os minerais primários e suas feições texturais, bem como as relações de campo, indicam uma origem vulcânica de queda para essa camada. O estudo de palinofácies, inédito para este tipo de rocha, evidenciou uma composição diferenciada da matéria orgânica estruturada ao longo do perfil do tonstein. Análises estatísticas do querogênio de diferentes níveis da camada de tonstein indicaram altas percentagens de fitoclastos (xilema e epiderme) associados à menor representatividade de palinomorfos. Análises microestratigráficas destes níveis demonstraram que a saturação e a precipitação dos palinomorfos foram altamente influenciadas pelo intenso processo de queda de cinzas. O nível basal caracteriza-se por densos aglomerados de esporos e polens, enquanto o topo é marcado pela preservação de fragmentos de colônias de algas Botryococcus evidenciando uma deposição subaquosa desta camada. Alguns fragmentos de epiderme (cutículas) evidenciam, por sua coloração, acentuada alteração termal. Esses dados possibilitaram vincular as peculiaridades do mecanismo de deposição e preservação da matéria orgânica com o processo de formação do tonstein relacionado à rápida precipitação de cinzas vulcânicas. O tonstein intercalado em camada de carvão indica um episódio de sedimentação de tefra durante a deposição da seqüência portadora de carvão no Permiano Inferior no sul da Bacia do Paraná. / Mineralogical and palynofacies analyses are reported from a tonstein layer interbedded with coal seams in the Faxinal coalfield, Rio Grande do Sul, Brazil. Integration of data has far reaching significance for attributing a volcanic origin for this kaolinitic claystone bed. The tonstein is almost monomineralic rock, composed mainly by authigenic kaolinite. Scattered in the kaolinitic mass primary pyroclastic minerals occur: euhedral beta-quartz paramorphs and waterclear quartz splinters, idiomorphic zircons, apatite, allanite and sanidine pseudomorphs; considered as a restricted suite of silicic volcanic minerals of the distal tonsteins which preserved during diagenesis. The primary minerals and their textural features, as well as the field relations, indicate a volcanic air-fall origin. Analyses of the kerogens from different levels of tonstein layer indicate high percentages of phytoclasts combined with very low palynomorph percentages. Microstratigraphic analyses of the tonstein profile demonstrated that saturation and precipitation of palynomorphs were highly influenced by the intense ash-fall process. The preservation of Botryococcus colonies at the top of the tonstein evidenced the subaqueous deposition of this bed. The brown color of several cuticle fragments and tracheids was linked to thermal alteration. The tonstein interbedded in a coal seam indicates an episode of tephra sedimentation during the deposition of the coal-bearing sequence of the Lower Permian in the southern Paraná Basin.

Análises mineralógicas, petrográficas e de palinofácies são registradas em um leito de tonstein associado a camadas de carvão na Jazida do Faxinal, Rio Grande do Sul, Brasil. A integração dos dados revestiu-se de grande importância para atribuir uma origem vulcânica para este argilito caolinítico. O tonstein é uma rocha quase monominerálica, composta predominantemente por caolinita antigênica. Dispersos na massa caolinítica ocorrem os minerais piroclásticos: paramorfos de quartzo-ß bipiramidais euédricos, “splinters” de quartzo transparente, zircão idiomórfico, apatita euédrica, alanita e pseudomorfos de sanidina, os quais são considerados como uma suíte restrita de minerais vulcânicos de tonsteins distais que preservaram durante a diagênese. Os minerais primários e suas feições texturais, bem como as relações de campo, indicam uma origem vulcânica de queda para essa camada. O estudo de palinofácies, inédito para este tipo de rocha, evidenciou uma composição diferenciada da matéria orgânica estruturada ao longo do perfil do tonstein. Análises estatísticas do querogênio de diferentes níveis da camada de tonstein indicaram altas percentagens de fitoclastos (xilema e epiderme) associados à menor representatividade de palinomorfos. Análises microestratigráficas destes níveis demonstraram que a saturação e a precipitação dos palinomorfos foram altamente influenciadas pelo intenso processo de queda de cinzas. O nível basal caracteriza-se por densos aglomerados de esporos e polens, enquanto o topo é marcado pela preservação de fragmentos de colônias de algas Botryococcus evidenciando uma deposição subaquosa desta camada. Alguns fragmentos de epiderme (cutículas) evidenciam, por sua coloração, acentuada alteração termal. Esses dados possibilitaram vincular as peculiaridades do mecanismo de deposição e preservação da matéria orgânica com o processo de formação do tonstein relacionado à rápida precipitação de cinzas vulcânicas. O tonstein intercalado em camada de carvão indica um episódio de sedimentação de tefra durante a deposição da seqüência portadora de carvão no Permiano Inferior no sul da Bacia do Paraná. / Mineralogical and palynofacies analyses are reported from a tonstein layer interbedded with coal seams in the Faxinal coalfield, Rio Grande do Sul, Brazil. Integration of data has far reaching significance for attributing a volcanic origin for this kaolinitic claystone bed. The tonstein is almost monomineralic rock, composed mainly by authigenic kaolinite. Scattered in the kaolinitic mass primary pyroclastic minerals occur: euhedral beta-quartz paramorphs and waterclear quartz splinters, idiomorphic zircons, apatite, allanite and sanidine pseudomorphs; considered as a restricted suite of silicic volcanic minerals of the distal tonsteins which preserved during diagenesis. The primary minerals and their textural features, as well as the field relations, indicate a volcanic air-fall origin. Analyses of the kerogens from different levels of tonstein layer indicate high percentages of phytoclasts combined with very low palynomorph percentages. Microstratigraphic analyses of the tonstein profile demonstrated that saturation and precipitation of palynomorphs were highly influenced by the intense ash-fall process. The preservation of Botryococcus colonies at the top of the tonstein evidenced the subaqueous deposition of this bed. The brown color of several cuticle fragments and tracheids was linked to thermal alteration. The tonstein interbedded in a coal seam indicates an episode of tephra sedimentation during the deposition of the coal-bearing sequence of the Lower Permian in the southern Paraná Basin.

Análises mineralógicas, petrográficas e de palinofácies são registradas em um leito de tonstein associado a camadas de carvão na Jazida do Faxinal, Rio Grande do Sul, Brasil. A integração dos dados revestiu-se de grande importância para atribuir uma origem vulcânica para este argilito caolinítico. O tonstein é uma rocha quase monominerálica, composta predominantemente por caolinita antigênica. Dispersos na massa caolinítica ocorrem os minerais piroclásticos: paramorfos de quartzo-ß bipiramidais euédricos, “splinters” de quartzo transparente, zircão idiomórfico, apatita euédrica, alanita e pseudomorfos de sanidina, os quais são considerados como uma suíte restrita de minerais vulcânicos de tonsteins distais que preservaram durante a diagênese. Os minerais primários e suas feições texturais, bem como as relações de campo, indicam uma origem vulcânica de queda para essa camada. O estudo de palinofácies, inédito para este tipo de rocha, evidenciou uma composição diferenciada da matéria orgânica estruturada ao longo do perfil do tonstein. Análises estatísticas do querogênio de diferentes níveis da camada de tonstein indicaram altas percentagens de fitoclastos (xilema e epiderme) associados à menor representatividade de palinomorfos. Análises microestratigráficas destes níveis demonstraram que a saturação e a precipitação dos palinomorfos foram altamente influenciadas pelo intenso processo de queda de cinzas. O nível basal caracteriza-se por densos aglomerados de esporos e polens, enquanto o topo é marcado pela preservação de fragmentos de colônias de algas Botryococcus evidenciando uma deposição subaquosa desta camada. Alguns fragmentos de epiderme (cutículas) evidenciam, por sua coloração, acentuada alteração termal. Esses dados possibilitaram vincular as peculiaridades do mecanismo de deposição e preservação da matéria orgânica com o processo de formação do tonstein relacionado à rápida precipitação de cinzas vulcânicas. O tonstein intercalado em camada de carvão indica um episódio de sedimentação de tefra durante a deposição da seqüência portadora de carvão no Permiano Inferior no sul da Bacia do Paraná. / Mineralogical and palynofacies analyses are reported from a tonstein layer interbedded with coal seams in the Faxinal coalfield, Rio Grande do Sul, Brazil. Integration of data has far reaching significance for attributing a volcanic origin for this kaolinitic claystone bed. The tonstein is almost monomineralic rock, composed mainly by authigenic kaolinite. Scattered in the kaolinitic mass primary pyroclastic minerals occur: euhedral beta-quartz paramorphs and waterclear quartz splinters, idiomorphic zircons, apatite, allanite and sanidine pseudomorphs; considered as a restricted suite of silicic volcanic minerals of the distal tonsteins which preserved during diagenesis. The primary minerals and their textural features, as well as the field relations, indicate a volcanic air-fall origin. Analyses of the kerogens from different levels of tonstein layer indicate high percentages of phytoclasts combined with very low palynomorph percentages. Microstratigraphic analyses of the tonstein profile demonstrated that saturation and precipitation of palynomorphs were highly influenced by the intense ash-fall process. The preservation of Botryococcus colonies at the top of the tonstein evidenced the subaqueous deposition of this bed. The brown color of several cuticle fragments and tracheids was linked to thermal alteration. The tonstein interbedded in a coal seam indicates an episode of tephra sedimentation during the deposition of the coal-bearing sequence of the Lower Permian in the southern Paraná Basin.

This diploma thesis presents first systematic geochemical a petrographical research of clastic bands in the lower-miocene Main Coal of the Most Basin. The main target of the thesis is evaluation of proxy analyses (EDXRF) of clastic bands and ash yield from coal. This method allows for identification of paleogeographic information about provenance of clastics derived from two different sources. The first source area represents weathered Tertiary volcanoclastics and the second is derived from crystalline basement in southwest part of the Bohemian Massif. Different geochemical signal of these two source areas detected in clastic bands allowed to constrain the switching of provenance into the lower part of the middle bench of the Main Coal in the Bílina open-cast mine whereas in the Doly Nástup-Tušimice mine this change occurs below the Main Coal. This result corresponds with idea of gradual changing of provenance across basin. Anomalous geochemical composition characterised by apparently increased content of Sr-Ba-P-Ca elements in one of clastic bands in the lower part of the Main Coal exposed in the Doly Nástup-Tušimice open-cast mine is related to presence of phosphate group minerals florencite and woodhouseite minerals as confirmed by RTG diffraction. This assemblage suggests possible admixture of...

Der Steckbrief informiert über den ˈPodsol aus Sandsteinˈ. Der ˈPodsol aus Sandsteinˈ zählt zur Bodenklasse der ˈBöden der Berg- und Hügelländerˈ. Er stellt eine typische Bodenform in Sachsen dar. Er ist ein nährstoffarmer Boden, der sich typisch in der ˈBodenregion der Berg- und Hügelländer mit hohem Anteil an nichtmetamorphen Sand-, Schluff-, Ton- und Mergelsteinenˈ entwickelt hat. Podsole sind nährstoffarme Böden, die sich durch Verlagerungsprozesse und teilweise Wiederausfällung von Fe, Al, und weiteren Elementen zusammen mit organischen Stoffen auszeichnen und dadurch im oberen Profilteil extrem verarmt sind. Der Steckbrief richtet sich an alle Interessierte, die sich über die Entstehung Verbreitung und das Erscheinungsbild typischer, repräsentativer Böden Sachsens informieren möchten. Redaktionsschluss: 01.03.2017

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