Fired clay minerals rehydroxylate after firing, a phenomenon that causes the long-term mass gain and expansion seen in archaeological ceramics. During rehydroxylation, fired clay minerals react with H2O to form structural hydroxyl (OH). Recent models propose that rehydroxylation is described by a quartic root (t1/4) time dependence, which has led to a dating method based on the process (RHX, rehydroxylation dating). The time dependence has been interpreted as an indication of a transport process of single-file diffusion of H2O molecules along restricted pathways in clay mineral, as theory predicts that the associated root mean square displacement is proportional to t1/4. However, dating trials have led to alternative models, and the process is still poorly understood. Here we outline currently outstanding problems found in different experimental studies, and propose novel ways of investigating the phenomenon. These include (i) gravimetric analyses using pure clay ceramics which are free of calcite and other minerals, and reducing cooling effects by using thin samples; (ii) highresolution nuclear magnetic resonance (NMR) with aluminum and silicon as well as with protons (hydroxyls, water) for exploring structure and dynamics, and pulsed field gradient (PFG) NMR for exploring water/proton diffusivities; (iii) IR spectroscopy, and micro-IR imaging to explore the spatial-temporal dependence of rehydroxylation of fired clay and (iv) structural investigations by high-resolution electron microscopy and X-ray diffraction.

No description available.

No description available.

No description available.

No description available.

No description available.

No description available.

No description available.

Many efforts have been made to model adsorption and diffusion processes in metalorganic frameworks (MOFs) in the past several years. In most of these studies, the framework has been kept rigid. In this study, we examine the effect of using a flexible framework model on the self-diffusion coefficients and activation energies calculated for several short n-alkanes and benzene in IRMOF-1 from molecular dynamics simulations. We find only minor differences between flexible and rigid framework results. The selfdiffusion coefficients calculated in the flexible framework are 20-50% larger than the ones calculated in the rigid framework, and the activation energies differ by only 10-20%.

No description available.