In this study, anaerobic treatability of opium alkaloid wastewater and the effect of radiation pretreatment (gamma-rays) on anaerobic treatability were investigated. Biochemical Methane Potential (BMP) assay was performed with alkaloid wastewater having initial COD values of 2400, 6000 and 9600 mg/L with and without basal medium (BM). The highest anaerobic treatment efficiency of 77% was obtained in the BMP reactor containing alkaloid wastewater with initial COD of 9600 mg/L and BM. Co-substrate use was investigated by using BMP assay. Alkaloid wastewater having initial COD concentrations of 9000, 13000 and 18000 mg/L were used with glucose, acetate and glucose-acetate as co-substrates. Results revealed that co-substrate use did not improve alkaloid removal efficiency significantly but it abrogated the acclimation period of anaerobic bacteria to alkaloid wastewater. Continuous reactor experiments were carried out in Upflow Anaerobic Sludge Blanket (UASB) reactors. Highest overall efficiencies (above 80%) were obtained in the reactor fed with co-substrate (R2) for all initial COD concentrations. Up to 78% removal efficiency was obtained in R1 (fed with alkaloid wastewater only) at initial COD concentration of 19 g/L. Effect of radiation was sought by using BMP assay with two initial COD concentrations of 14 and 25 g/L, and two radiation doses 40 and 140 kGy. At 14 g/L COD, there was no effect of radiation on gas production for both doses. However at initial COD of 25 g/L, reactors containing wastewater dosed with 140 and 40 kGy produced gas with higher rates above certain point with respect to raw wastewater.

A macro-homogeneous, nonisothermal, two-phase, and steady state mathematical model is developed to investigate water and thermal management in polymer electrolyte membrane (PEM) fuel cells. An original two-phase energy balance approach is used to catch the thermal transport phenomena in cases when there is a signicant temperature dierence between the fuel cell temperature and the reactants inlet temperatures like during cold start-up. Model considers in depth electrode kinetics for both anode and cathode reactions. External and internal mass transfer resistances on fuel cell performance are accounted by means of a thin-film and agglomerate approach. Developed model accounts for all substantial transport phenomena including diffusion of multi-component gas mixtures in the porous media, electrochemical reactions in the catalytic regions, water and proton transport through the solid polymer electrolyte, transport of electrons within the solid matrix, heat transport in the gas and solid phases, phase change and transport of water through porous diffusion media and catalyst layers. In this study, it is truly shown how significant heat and water transport are to overall fuel cell performance. Model predictions are validated by comparison with experimental data, involving polarization curves, saturation and temperature gradients. For optimal electrode kinetics purposes, an alternative novel hollow core mesoporous shell (HCMS) carbon supported Pt and Pt-Pd electrocatalysts were synthesized by microwave irradiation. HCMS carbon spheres were produced by two different carbon precursors with the template replication of solid core mesoporous shell (SCMS) silica spheres. Compared to Pt/VX and ETEK electrocatalysts, HCMS carbon based Pt and Pt-Pd electrocatalysts showed promising cathode and anode electrodics performance in the fuel cell environment.

This thesis investigates the refrigerant (R-134a) flow in three minichannels having different geometries experimentally. During the last 40 years heat transfer in small scales has been a very attractive research area. Improvements in heat transfer in the refrigeration applications by means of usage of micro/minichannels provide significant developments in this area. Also it is known that experimental studies are very important to constitute a database which is beneficial for new developments and research. During the two-phase flow experiments conducted in the minichannels, low mass flow rates and constant wall temperature approach, which are the conditions in the evaporators of the refrigerator applications were applied because one of the purposes of this study is to determine the most ideal minichannel among the tested minichannels for usage in the evaporator section of the refrigerators. Two-phase flow experiments were made with refrigerant R134a in the three minichannels having hydraulic diameters of 1.69, 3.85 and 1.69 mm respectively. As distinct from the others, the third minichannel has a rough inner surface. Comparison of the experimental results of the three minichannels was made in terms of forced convection heat transfer coefficients and pressure drop at constant quality and mass flux values. As a result of the experiments, the most ideal minichannel among the tested minichannels was determined for the evaporator applications in the refrigerators.

In der vorliegenden Arbeit wird der Einsatz von Positronenemittern zur Bestimmung der Dichte eines zweiphasigen Mediums beschrieben. Zur Messung wird die Dichteabhängigkeit der Positronenreichweite ausgenutzt. Die Realisierbarkeit des Verfahrens wird zunächst in einer Computersimulation geprüft. Danach werden Experimente an einem hochauflösenden PET-Scanner vorgestellt. Bei diesen Experimenten wird die Dichteabhängigkeit der Reichweite von Positronen anhand von Modellmedien aus festen Schaumstoffen untersucht. Dabei werden die in der Computersimulation erzielten Ergebnisse bestätigt. Aus den experimentellen Ergebnissen wird ein Modell zur Beschreibung der Abnahme der Koinzidenzrate in Abhängigkeit von der Entfernung des Detektors von der Positronenquelle und der Mediendichte entwikkelt. Auf der Basis des Modells erfolgt die Konzipierung einer für die Dichtemessung optimierten Detektoranordnung. Die Funktionsweise dieses Detektorsystems wird in Form technischer Unterlagen und experimenteller Ergebnisse beschrieben. Mit dem optimierten Detektorsystem werden die Untersuchungen an den Modellmedien nochmals durchgeführt, wobei die bisherigen Ergebnisse bestätigt werden. Das beschriebene Meßverfahren dient der Bestimmung der mittleren Dichte in einem überwiegend gasförmigen Medium, wobei eine Mittelwertbildung über das Meßvolumen erfolgt. Das Verfahren kombiniert die Vorteile bekannter densitometrischer Meßmethoden auf der Basis einer Schwächung von Strahlung, indem die hohe Dichtesensitivität der Positronenstrahlung mit der relativ geringen Absorption der energiereichen Annihilationsquanten kombiniert wird.

Amusement parks are a huge business. Guest experiences determine the success or failure for an amusement park. This report suggests an approach to improve guest experience by managing guest flow. The guest happiness optimization problem is formulated into a visitor routing management model. The constraints for this model include attraction attributes and guest behavior. To build the attraction constraints, their information is first gathered from internet, field studies and surveys, and then input into simulation software. Constraints on guest behavior are set up with a literature study and a guest survey. A two phase heuristic is developed to solve this problem with constraints. Candidate routes are generated with a route construction algorithm in the first phase. Visitor distribution and selection on these candidate routes are determined in the second phase using a mixed integer programming solver. Visitor routes are then recommended to the park’s operator side, for them to distribute to guests visiting on their vacations. Data from Disney Epcot are collected and applied in the case study to implement the methodology in this report. Attraction operations capability is maintained at the current level with no additional cost for the project, while guest satisfaction is improved by ensuring the number and type of attractions they visit. In addition, average waiting time for visitors is reduced by at least 70% in the recommended operation strategy. / text

On the first part, we consider nonlinear operators I depending on a family of nonlocal linear operators [mathematical equations]. We study the solutions of the Dirichlet initial and boundary value problems [mathematical equations]. We do not assume even symmetry for the kernels. The odd part bring some sort of nonlocal drift term, which in principle competes against the regularization of the solution. Existence and uniqueness is established for viscosity solutions. Several Hölder estimates are established for u and its derivatives under special assumptions. Moreover, the estimates remain uniform as the order of the equation approaches the second order case. This allows to consider our results as an extension of the classical theory of second order fully nonlinear equations. On the second part, we study two phase problems posed over a two dimensional cone generated by a smooth curve [mathematical symbol] on the unit sphere. We show that when [mathematical equation] the free boundary avoids the vertex of the cone. When [mathematical equation]we provide examples of minimizers such that the vertex belongs to the free boundary. / text

We use Darcy's law and conservation of mass to model the flow of a fluid through a porous medium. It is a second order elliptic system with a heterogeneous coefficient. We consider the equations written in mixed form. In the heterogeneous case, we define a new multiscale mortar space that incorporates purely local information from homogenization theory to better approximate the solution along the interfaces with just a few degrees of freedom. In the case of a locally periodic heterogeneous coefficient of period epsilon, we prove that the new method achieves both optimal order error estimates in the discretization parameters and good approximation when epsilon is small. Moreover, we present numerical examples to assess its performance when the coefficient is not obviously locally periodic. We show that the new mortar method works well, and better than polynomial mortar spaces. On the other hand, we also propose to use multiscale mortars as a coarse component to construct a two-level preconditioner for the saddle point linear system arising from the fine scale discretization of the mixed finite element system. The two-level preconditioners are constructed based on the interfaces. We propose a framework to define the interpolation operators for the face based two-level preconditioners for different combination of coarse and fine scale mortar spaces for matching and nonmatching grids. In this dissertation, we show that for quasi-homogeneous problems and matching grids, the condition number of the preconditioned interface operator is bounded by (log(H/h))², which is the same as the traditional two-level preconditioners, for quasi-homogeneous problems. We show several numerical examples to demonstrate that for the strongly heterogeneous porous media, it is often desirable and even necessary to use a higher dimensional coarse mortar space to construct the coarse preconditioner to achieve convergence. We apply our ideas to study slightly compressible single phase and two-phase flow in a porous medium. We find that for the nonlinear single phase problem, the two-level preconditioners could be successfully applied to the symmetrized linear system. For the two-phase problem, using the fine scale, instead of multiscale, velocity solutions from the flow problem can greatly benefit the transport problem. / text

A significant percentage of computational time in compositional simulations is spent performing flash calculations to determine the equilibrium compositions of hydrocarbon phases in situ. Flash calculations must be done at each time step for each grid block; thus billions of such calculations are possible. It would be very important to reduce the computational time of flash calculations significantly so that more grid blocks or components may be used. In this dissertation, three different methods are developed that yield fast, robust and accurate phase behavior calculations useful for compositional simulation and other applications. The first approach is to express the mixing rule in equations-of-state (EOS) so that a flash calculation is at most a function of six variables, often referred to as reduced parameters, regardless of the number of pseudocomponents. This is done without sacrificing accuracy and with improved robustness compared with the conventional method. This approach is extended for flash calculations with three or more phases. The reduced method is also derived for use in stability analysis, yielding significant speedup. The second approach improves flash calculations when K-values are assumed constant. We developed a new continuous objective function with improved linearity and specified a small window in which the equilibrium compositions must lie. The calculation speed and robustness of the constant K-value flash are significantly improved. This new approach replaces the Rachford-Rice procedure that is embedded in the conventional flash calculations. In the last approach, a limited compositional model for ternary systems is developed using a novel transformation method. In this method, all tie lines in ternary systems are first transformed to a new compositional space where all tie lines are made parallel. The binodal curves in the transformed space are regressed with any accurate function. Equilibrium phase behavior calculations are then done in this transformed space non-iteratively. The compositions in the transformed space are translated back to the actual compositional space. The new method is very fast and robust because no iteration is required and thus always converges even at the critical point because it is a direct method. The implementation of some of these approaches into compositional simulators, for example UTCOMP or GPAS, shows that they are faster than conventional flash calculations, without sacrificing simulation accuracy. For example, the implementation of the transformation method into UTCOMP shows that the new method is more than ten times faster than conventional flash calculations.

This thesis examined the biological treatment of gas streams containing benzene, toluene, ethylbenzene and o-xylene (BTEX) using solid-liquid two-phase partitioning bioscrubbers (SL-TPPBs). SL-TPPBs consist of a cell containing aqueous phase and a polymeric solid phase that sequesters poorly water soluble and/or toxic substrates, mitigating substrate toxicity in the aqueous phase and improving the gas mass transfer during treatment of VOC contaminated gases. An initial investigation of oxygen transport determined that the polymers in a stirred-tank SL-TPPB enhance gas-liquid mass transfer. In addition, a study on biodegradation kinetics of BTEX by a bacterial consortium identified and quantified substrate interactions such as inhibition, enhancement and cometabolism. The stirred-tank SL-TPPB was then experimentally investigated for treatment of BTEX gas streams during steady-state and dynamic step-change operation to determine performance of the system relative to other biotreatment methods. A mathematical model was developed to predict system performance, which included the microbial kinetic model structure and parameters estimated during kinetic and oxygen mass transfer studies. As a less energy intensive alternative, an airlift SL-TPPB was operated and characterized. The airlift SL-TPPB was compared to an airlift liquid-liquid TPPB (silicone oil as sequestering phase) and a single phase airlift over dynamic step-change loadings, which showed that the airlift SL-TPPB outperformed the single phase airlift by >30% and had similar performance to the liquid-liquid airlift. However, the airlift SL-TPPB performance was lower relative to the stirred-tank SL-TPPB by >15%. Steady-state operation of the airlift SL-TPPB identified a range of operating conditions that provided maximum performance and conditions that were not oxygen limited. This prompted a study of oxygen mass transfer and hydrodynamics in the airlift system, which identified that the addition of polymers to an airlift does not cause physical enhancement of the gas-liquid mass transfer coefficient, but improves aqueous phase mixing and enhances overall oxygen transfer rate. A tanks-in-series mathematical model was formulated to predict performance of the airlift SL-TPPB, wherein the number of tanks-in-series to describe mixing in the airlift was obtained from a residence time distribution analysis of the airlift system completed during the hydrodynamic investigation. This thesis contributes a low-energy solution for the effective treatment of gases contaminated with BTEX. / Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2009-08-18 16:16:22.598

If air is entrained in a bottom outlet of a dam in an uncontrolled way, the resulting air pockets may cause problems such as blowback, blowout and loss of discharge capacity. In order to provide guidance for bottom outlet design and operation, this study examines how governing parameters affect air entrainment, air-pocket transport and de-aeration and the surrounding flow structure in pipe flows. Both experimental and numerical approaches are used. Air can be entrained into the bottom outlet conduit due to vortex formation at the intake if the intake submergence is not sufficient. The influent of the intake entrance profiles and channel width on the critical submergence were studied in the experiment. The experimental study was performed to investigate the incipient motion of air pockets in pipes with rectangular and circular cross sections. The critical velocity is dependent on pipe slope, pipe diameter, pipe roughness and air-pocket volume. If the pipe is horizontal, air removal is generally easier in a rectangular pipe than in a circular pipe. However, if the pipe is downward-inclined, air removal is easier in a circular pipe. When a bottom outlet gate opens, air can become entrained into the conduit in the gate shaft downstream of the gate. Using FLUENT software, the transient process of air entrainment into a prototype bottom outlet during gate opening is simulated in three dimensions. The simulations show in the flow-pattern changes in the conduit and the amount of air entrainment in the gate shaft. The initial conduit water level affects the degree of air entrainment. A de-aeration chamber is effective in reducing water surface fluctuations at blowout. High-speed particle image velocimetry (HSPIV) were applied to investigate the characteristics of the flow field around a stationary air pocket in a fully developed horizontal pipe flow. The air pocket generates a horseshoe vortex upstream and a reverse flow downstream. A shear layer forms from the separation point. Flow reattachment is observed for large air pockets. The air―water interface moves with the adjacent flow. A similarity profile is obtained for the mean streamwise velocity in the shear layer beneath the air pocket. / <p>QC 20140211</p>