M. Tech. (Department of Civil Engineering and Building, Faculty of Engineering and Technology), Vaal University of Technology. / Potable water quality can deteriorate immensely from point of treatment to point of usage. This change in quality along a bulk distribution main may be attributed to numerous factors, such as the ingress of storm water. Furthermore, water utilities experience challenges in terms of the microbiological organisms that are not attributed to operational practices. For example, drinking water bulk distribution mains may be a shelter for these microorganisms that are sustained by organic and inorganic nutrients present within the pipe itself. These microorganisms may be active in the water being transported by the pipe, and can cause a significant drop in the water quality. In order to deal with the problem of deteriorating water quality, sufficient information within the bulk main is required, so that the consumer can be protected from ingesting contaminated water or water of poor quality. Hence, the overall objective of this study was to investigate and model water quality characteristics within the Modimolle reticulation network. Water samples were collected from various points throughout the entire system for quality analysis. Different sampling points were established along the main pipeline as well as within the Modimolle distribution system. Water quality software, EPANET, was then used to model the water quality deterioration for both the bulk line and the reticulation network of Modimolle extension 11. Residual chlorine was the main parameter which was monitored. This study presents results of a research on water quality variation within a long distribution mains conveying water up to 87 km. Results show that raw residual chlorine is constantly depleted along the pipeline, and is therefore unable to be maintained at the required level of 0.2 mg/l, as stipulated by the Department of Water Affairs. This means that if any harmful contaminants should enter the water, the residual chlorine in the water will not be able to protect the consumers from the contaminants.

Worldwide, water reuse is promoted as an alternative for water scarcity, however, wastewater effluents have been reported as possible contaminants to surface water. The failure of some wastewater treatment processes to completely remove organic matter and some pathogenic microorganisms allows them to initiate infections. This manifests more in communities where surface water is used directly for drinking. To assess water quality, bacteria alone cannot be used as it may be absent in virus-contaminated water. This study was carried out to assess the quality of two wastewater treatment plant effluents from the Eastern Cape Province of South Africa. Physicochemical parameters and microbiological parameters like faecal coliforms, adenovirus, rotavirus, hepatitis A virus, norovirus and enterovirus were evaluated over a projected period of one year. Physicochemical parameters were measured on site using multiparameters, faecal coliforms enumerated using culture-based methods and viruses are detected using both conventional and real-time PCR. Physicochemical parameters like electrical conductivity, turbidity, free chlorine and phosphates were incompliant with the standards set by the Department of Water affairs for effluents to be discharged. Faecal coliform counts were nil for one plant (WWTP-R) where they correlated inversely (P < 0.01) with the high free chlorine. For WWTP-K, faecal coliforms were detected in 27% of samples in the range of 9.9 × 101 to 6.4× 104 CFU/100ml. From the five viruses assessed, three viruses were detected with Rotavirus being the most abundant (0-2034176 genome copies/L) followed by Adenovirus (0–275 genome copies/L) then Hepatitis A virus (0–71 genome copies/L) in the WWTP-K while none of the viruses was detected in WWTP-R. Species B, species C and Adv41 serotypes were detected from the May 2013 and June 2013 samples where almost all parameters were incompliant in the plant. The detection of these viruses in supposedly treated effluents is suggestive of these being the sources of contamination to surface water and therefore renders surface waters unsafe for direct use and to aquatic life. Although real-time PCR is more sensitive and reliable in detection of viruses, use of cell-culture techniques in this study would have been more efficient in confirming the infectivity of the viruses detected, hence the recommendation of these techniques in future projects of this nature.

South Africa is a water scarce country. The expansion of the industrial, mining, and agricultural sectors to meet the needs of South Africa’s growing population requires more water. There is therefore an urgent need to develop effective wastewater treatment processes in order to recover and reuse water. This dissertation presents the treatment of an acidic wastewater stream from a platinum refinery which at present is being disposed of by contract with a waste disposal company. The major concern in treating the acid effluent stream is the high concentration of sodium ions (18 200 mg/l) and chloride ions (104 900 mg/l). The precipitation process is used to treat wastewater, but ultimately it generates more secondary waste as a sludge. The other process that is used to treat wastewater is reverse osmosis (RO). RO is usually preferred in the last stage of the treatment because the process is more expensive as membranes need to be replaced regularly. The approach used in this research focuses on evaporating liquid, consequently concentrating the remaining solution until the ions in the solution crystallize. The liquid produced is recycled back into the platinum plant for reuse, and the remaining salt crystals are collected as the useful product. The proposed water treatment process produces dilute hydrochloric acid as the condensate and a crystallized sodium chloride rich residue. The refinery is currently disposing of around 20 000 l/day of wastewater to landfills. The proposed treatment process can recover half of the volume of the wastewater stream to the refinery, helping reduce the fresh water consumption of the process by 10 000 l/day. Furthermore, this will reduce the volume of wastewater going to disposal by a half, namely only 10 000 l/day will need to be disposed of. The amount of Cl that can be recovered is variable and depends on the quantity of chloride in the wastewater. In the two samples processed the recovery was between a 2,5 w% and 10,7 wt% aqueous HCl solution. This corresponds to a saving of between 250 to 1000 kg/day of HCl. As the concentration of the recovered solution is variable, the recycling process would need to monitor the composition of the recycled stream and make up the acid concentration to some fixed value for reuse in the prices. The production of a dilute hydrochloric acid stream should be particularly attractive to the platinum refinery as the operation of the refinery requires hydrochloric acid as a feed. Thus, by recycling the wastewater, the refinery would reduce the volume of wastewater to be disposed of thereby reducing the cost of disposal of the waste while simultaneously reducing the cost of buying fresh hydrochloric acid. The proposed recovery of liquid and recycling it back to the refinery, will also reduce the environmental impact of the refinery, and very importantly in a water scarce country, reduce the freshwater consumption of the process. / Physics / M. Sc. (Physics)

The hydrometallurgical refining of platinum group metals results in large volumes of liquid waste that requires suitable treatment before any disposal can be contemplated. The wastewater streams are characterized by extremes of pH, high inorganic ion content (such as chloride), significant residual metal loads and small amounts of entrained organic compounds. Historically these effluents were housed in evaporation reservoirs, however lack of space and growing water demands have led Anglo Platinum to consider treatment of these effluents. The aim of this study was to investigate whether biological wastewater treatment could produce water suitable for onsite reuse. Bench-scale activated sludge and anaerobic digestion for co-treatment of an acidic refinery waste stream with domestic wastewater were used to give preliminary data. Activated sludge showed better water treatment at lab scale in terms of removal efficiencies of ammonia (approximately 25%, cf. 20% in anaerobic digestion) and COD (70% cf. 43% in digestion) and greater robustness when biomass health was compared. Activated sludge was consequently selected for a pilot plant trial. The pilot plant was operated on-site and performed comparably with the bench-scale system, however challenges in the clarifier design led to losses of biomass and poor effluent quality (suspended solids washout). The pilot plant was unable to alter the pH of the feed, but a two week maturation period resulted in the pH increasing from 5.3 to 7.0. Tests on algal treatment as an alternative or follow-on unit operation to activated sludge showed it not to be a viable process. The activated sludge effluent was assessed for onsite reuse in flotation and it was found that there was no significant difference between its flotation performance and that of the process water currently used, indicating the effluent generated by the biological treatment system can be used successfully for flotation. Flotation is the method whereby minerals refining operations recover minerals of interest from ore through the addition of chemicals and aeration of the ore slurry. Target minerals adhere to the bubbles and can be removed from the process.

MESHWR / Department of Hydrology and Water Resources / This research involves the investigation of the interaction of different sized Nano Gold particles released into municipal drinking water and municipal waste water. Waste water was collected from Malamulele waste water treatment plant and the municipal water was collected at Mintek in Johannesburg, Randburg, South Africa. The waste water was analysed using ICP-MS to detect the metals and anions in it. The results showed the abundance of Sulphur (464 ppm), Calcium (28 ppm), Chloride (27.8 ppm), Iron (20 ppm), Magnesium (8.2 ppm), silicon (6.192 ppm) in descending order and other trace elements, including gold, that were immeasurable (<0.1). The simulated situation was created by adding 20nm gold and 40nm gold nanoparticles into municipal drinking water and waste water and kept at different environmental conditions (light, light and agitation, dark, dark and agitation) under aerobic and anaerobic conditions over a period of two months. Physico-chemical properties (pH and chemical oxygen demand) of the solutions were checked once in a month. The pH fluctuated between the acceptable ranges (5.5 – 9.5) for the two month period. Both municipal water and waste water, with and without gold nanoparticles, under aerobic condition showed an increase in chemical oxygen demand. The gold content in waste water under anaerobic condition showed an increase while under aerobic condition the decline in gold content was evident. The zeta potential of gold nanoparticles in waste water in light and agitation showed (-30 mV) while waste water on other environmental condition (light, dark and dark with agitation) presenting unstable (-18 mV) charge, but the charge shifted positively on the second month rendering them also unstable. Dynamic light scattering and TEM were used to check any possible aggregation or agglomeration of nanoparticles in the waste water. There were some few discrepancies where TEM and DLS contradict, but overall there was no significant probability of any aggregation of gold nanoparticles. The EDX was used to confirm the presence of Au0 in the waste water (with added gold nanoparticles). The research did show that the gold nanoparticles would exist as Au0 in the waste water and thus the discharge of Au-NPs to the sewer system is not recommended, but rather recycle them.

Cape Town, South Africa, falls within a winter rainfall region, making it difficult to assess the feasibility of rain- and stormwater harvesting. The reason for this is because the region’s high water demand period coincides with the low rainfall summer season, thereby limiting the availability of this alternative water resource when most needed. During this study, rainwater harvesting for toilet flushing purposes, collected from roof surfaces, was practically assessed by means of inserted flow meters at a pilot study site in Kommetjie, Cape Town. The combined and single system roof- and land surface runoff yields and savings of commercial buildings within the Kommetjie business area, were also theoretically assessed by making use of a mathematical roof- and land surface runoff model specifically developed during this study. The statistical testing of the hypotheses statements relating to the pre- and post-harvesting savings at the pilot study building, compared against the average actual municipal water usage, were performed. Hypotheses testing were also performed in order to compare the theoretical rain- and stormwater runoff yields for the commercial business area against the average actual municipal water consumption. The conclusions drawn from this study indicated that valuable potable water, as well as related financial savings, can be achieved within a winter rainfall region, thereby making rain- and stormwater harvesting a feasible option for commercial businesses in Cape Town. / Environmental Sciences / M.Sc. (Environmental Management)

Cape Town, South Africa, falls within a winter rainfall region, making it difficult to assess the feasibility of rain- and stormwater harvesting. The reason for this is because the region’s high water demand period coincides with the low rainfall summer season, thereby limiting the availability of this alternative water resource when most needed. During this study, rainwater harvesting for toilet flushing purposes, collected from roof surfaces, was practically assessed by means of inserted flow meters at a pilot study site in Kommetjie, Cape Town. The combined and single system roof- and land surface runoff yields and savings of commercial buildings within the Kommetjie business area, were also theoretically assessed by making use of a mathematical roof- and land surface runoff model specifically developed during this study. The statistical testing of the hypotheses statements relating to the pre- and post-harvesting savings at the pilot study building, compared against the average actual municipal water usage, were performed. Hypotheses testing were also performed in order to compare the theoretical rain- and stormwater runoff yields for the commercial business area against the average actual municipal water consumption. The conclusions drawn from this study indicated that valuable potable water, as well as related financial savings, can be achieved within a winter rainfall region, thereby making rain- and stormwater harvesting a feasible option for commercial businesses in Cape Town. / Environmental Sciences / M.Sc. (Environmental Management)