Wood is a highly versatile renewable material (with carbon sequestering properties), that is light in weight, has good strength properties in both tension and compression while providing good rigidity and toughness, and good insulating properties (relative to typical structural materials). Engineered wood products combine the benefits of wood with engineering knowledge to create optimized structural elements. Cross-laminated timber (CLT), as one such engineered wood product, is an emerging engineering material which provides great opportunities for the building industry. While building with wood has many benefits, there are also some concerns, particularly decay. Should wood be exposed to elevated amounts of moisture, rots and moulds may damage the product or even risk the health of the occupants. As CLT panels are a relatively new engineered wood product, the moisture characteristics have yet to be properly assessed. Consequently, the amount of decay risk for CLT in building applications is unknown, and recommended protective actions during design construction and operation have yet to be determined. The goal of this research was to determine the moisture durability of CLT panels in wall assemblies and address concerns related to built-in construction moisture. The approach used to address the problem was to first determine select moisture properties of CLT panels through experimental approaches, and then use the results to calibrate a hygrothermal model to quantify the risks of wall assemblies. The wall assemblies were simulated in six different cities across Canada, representing a range of climates: Vancouver, B.C., Edmonton, A.B., Winnipeg, M.B., Ottawa, O.N., Québec City, Q.C., and St. John, New-Brunswick. The risks associated with moisture exposure during construction are also considered in the simulations. The experimental phase of the research was limited to moisture uptake tests. These tests were utilized to determine the liquid water absorption coefficient for four different types of full scale panels (2’x2’) and 12 clear wood samples. The panels were either made of 5-ply of Western-SPF, Eastern-SPF, Hemlock-Fir, or 3-ply of a generic softwood provided by a European CLT manufacturer; the clear samples were all cut from the same nominal 2x6 SPF-grade lumber. The panels were installed in a drying rack and gravimetrically tracked to assess the drying rates of the panels. Finite resources precluded more thorough material testing, but a parametric study was conducted to determine the relative impact of the missing material data on the final simulation results. In the hygrothermal simulations, four main wall assembly types were considered- those with either exterior or interior insulation, and those using either vapour permeable or impermeable air-water barriers. Various types of insulation and vapour control were also modelled. The simulations were run for a variety of interior relative humidities. The metric for comparison between the simulations was the water content of a 4mm thin layer on the extreme lamina of a CLT panel system. The results of the simulation suggest that vapour impermeable membranes, when install on dry CLT panels (less than 14% M.C.) do not pose moisture risks in any of the climates considered. However, when high levels of construction moisture is considered, only vapour permeable membranes controlled moisture risks by allowing the CLT panel to dry both to the interior and to the exterior.

This dissertation focuses on a variety of vadose zone processes that impact water table fluctuations. The development of vadose zone process conceptualization has been limited due to both the lack of recognition of the importance of the vadose zone and the absence of suitable field data. Recent studies have, however, shown that vadose zone soil moisture dynamics, especially in shallow water table environments, can have a significant effect on processes such as infiltration, recharge to the water table, and evapotranspiration. This dissertation, hence, attempts to elucidate approaches for modeling vadose zone soil moisture dynamics. The ultimate objective is to predict different vertical and horizontal hydrological fluxes. The first part of the dissertation demonstrates a new methodology using soil moisture and water table data collected along a flow transect. The methodology was found to be successful in the estimation of hydrological fluxes such as evapotranspiration, infiltration, runoff, etc. The observed dataset was also used to verify an exponential model developed to quantify the ground water component of total evapotranspiration. This analysis was followed by a study which analyzed the impact of soil moisture variability in the vadose zone on water table fluctuations. It was found that antecedent soil moisture conditions in the vadose zone greatly affected the specific yield values, causing a broad range of water table fluctuations for similar boundary fluxes. Hence, use of a constant specific yield value can produce inaccurate results. Having gained insight into the process of evapotranspiration and specific yield, a threshold based model to determine evapotranspiration and subsequent water table fluctuation was conceptualized and validated. A discussion of plant root water uptake and its impact on vadose zone soil moisture dynamics is presented in the latter half of this dissertation. A methodology utilizing soil moisture and water table data to determine the root water uptake from different sections of roots is also described. It was found that, unlike traditional empirical root water uptake models, the uptake was not only proportional to the root fraction, but was also dependent on the ambient soil moisture conditions. A modeling framework based on root hydraulic characteristics is provided as well. Lastly, a preliminary analysis of observed data indicated that, under certain field conditions, air entrapment and air pressurization can significantly affect the observed water table values. A modeling technique must be developed to correct such observations.

The feedbacks among aerosols, clouds, and radiation are important components for understanding Earth's climate system and quantifying human-induced climate change, yet the magnitude of these feedbacks remain highly uncertain. Since every cloud droplet in the atmosphere begins with water condensing on a pre-existing aerosol particle, characterizing the ability of aerosols to uptake water vapor and form cloud condensation nuclei (CCN) are key to understanding the microphysics behind cloud formation, as well as assess the impact aerosols have on the Earth system. Through a combination of controlled laboratory experiments and field measurements, this thesis characterizes the ability of atmospheric aerosols to uptake water vapor and become CCN at controlled levels of water vapor supersaturation. The origin of the particle water uptake, termed hygroscopicity, is also explored, being from either the presence of deliquescent soluble material and/or adsorption onto insoluble surfaces. The data collected and presented is comprehensive and includes (1) ground samples of volcanic ash, collected from six recent eruptions re-suspended in the laboratory for analysis, (2) laboratory chamber and flow-tube studies on the oxidation and uptake of surface active organic compounds, and (3) in-situ aircraft measurements of aerosols from the Arctic background, Canadian boreal forests, fresh and aged biomass burning, anthropogenic industrial pollution, and from within tropical cyclones in the Atlantic basin. Having a more thorough understanding of aerosol water uptake will enable more accurate representation of cloud droplet number concentrations in global models, which can have important implications on reducing the uncertainty of aerosol-cloud-climate interactions, as well as additional uncertainties in aerosol transport, atmospheric lifetime, and impact on storm dynamics.

Wood is a highly versatile renewable material (with carbon sequestering properties), that is light in weight, has good strength properties in both tension and compression while providing good rigidity and toughness, and good insulating properties (relative to typical structural materials). Engineered wood products combine the benefits of wood with engineering knowledge to create optimized structural elements. Cross-laminated timber (CLT), as one such engineered wood product, is an emerging engineering material which provides great opportunities for the building industry. While building with wood has many benefits, there are also some concerns, particularly decay. Should wood be exposed to elevated amounts of moisture, rots and moulds may damage the product or even risk the health of the occupants. As CLT panels are a relatively new engineered wood product, the moisture characteristics have yet to be properly assessed. Consequently, the amount of decay risk for CLT in building applications is unknown, and recommended protective actions during design construction and operation have yet to be determined. The goal of this research was to determine the moisture durability of CLT panels in wall assemblies and address concerns related to built-in construction moisture. The approach used to address the problem was to first determine select moisture properties of CLT panels through experimental approaches, and then use the results to calibrate a hygrothermal model to quantify the risks of wall assemblies. The wall assemblies were simulated in six different cities across Canada, representing a range of climates: Vancouver, B.C., Edmonton, A.B., Winnipeg, M.B., Ottawa, O.N., Québec City, Q.C., and St. John, New-Brunswick. The risks associated with moisture exposure during construction are also considered in the simulations. The experimental phase of the research was limited to moisture uptake tests. These tests were utilized to determine the liquid water absorption coefficient for four different types of full scale panels (2’x2’) and 12 clear wood samples. The panels were either made of 5-ply of Western-SPF, Eastern-SPF, Hemlock-Fir, or 3-ply of a generic softwood provided by a European CLT manufacturer; the clear samples were all cut from the same nominal 2x6 SPF-grade lumber. The panels were installed in a drying rack and gravimetrically tracked to assess the drying rates of the panels. Finite resources precluded more thorough material testing, but a parametric study was conducted to determine the relative impact of the missing material data on the final simulation results. In the hygrothermal simulations, four main wall assembly types were considered- those with either exterior or interior insulation, and those using either vapour permeable or impermeable air-water barriers. Various types of insulation and vapour control were also modelled. The simulations were run for a variety of interior relative humidities. The metric for comparison between the simulations was the water content of a 4mm thin layer on the extreme lamina of a CLT panel system. The results of the simulation suggest that vapour impermeable membranes, when install on dry CLT panels (less than 14% M.C.) do not pose moisture risks in any of the climates considered. However, when high levels of construction moisture is considered, only vapour permeable membranes controlled moisture risks by allowing the CLT panel to dry both to the interior and to the exterior.

Diss. (sammanfattning). Umeå : Sveriges lantbruksuniv. / Härtill 4 uppsatser.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2007. / Härtill 4 uppsatser.

No description available.

Aerosols are important atmospheric constituents that impact the Earth's radiative balance and climate. The detailed knowledge of the aerosol optical properties is required for a comprehensive analysis of the impacts of aerosols on climate. Mie theory is often used in satellite and ground-based retrieval algorithms to account for atmospheric mineral dust. However, the approximations used in Mie theory are often not appropriate for mineral dust and can lead to errors in the optical properties modeling. Analytic models based on Rayleigh theory that account for particle shapes can offer significant advantages when used to model infrared (IR) extinction of mineral dust. Here, the IR optical properties of some components of mineral dust, authentic dust samples and minerals processed with organic acids were investigated. Detailed characterization of the particles through online and offline methods of analysis that include IR extinction spectroscopy, micro-Raman spectroscopy and scanning electron microscopy was performed. Analysis of the IR extinction spectra and spectral simulations showed that the positions of the peaks and the shapes of the bands of the IR characteristic features are not well simulated by Mie theory in any of the samples studied. The resonance peaks were consistently shifted relative to the experimental spectrum in the Mie simulation. Rayleigh model solutions derived for different particle shapes better predicted the peak positions and band shapes of experimental spectra. To fill the gaps in the refractive index data for atmospherically relevant organic compounds in the IR region optical properties of atmospherically relevant carboxylic acids and humic-like substances using the IR extinction spectra and size distributions measured in the laboratory were determined. In addition to properties of mineral dust this dissertation focuses on properties of sea spray aerosol. Chemical and elemental composition of individual sea spray aerosol particles were studies using micro-Raman spectroscopy, mass-spectrometry and X-ray spectroscopy to provide insights into the biochemical processes that give rise to classes of organic molecules that make up these aerosol particles. The results suggested that degradation of biota (bacteria and diatoms) present in sea water led to lipopolysaccharides and extracellular polymeric substances that further degraded down to carbohydrates and fatty acids. Solubility of the resulting organic species seemed to play a role in their transfer to the aerosol phase. Furthermore, water uptake and hygroscopic growth of multi-component particles were studied. Understanding the interactions of water with atmospheric aerosols is crucial for determining their size, physical state, reactivity, and therefore for aerosol interactions with electromagnetic radiation and clouds. It was determined that particles composed of ammonium sulfate with succinic acid and of mixture of chlorides typical for marine environment show size dependent hygroscopic behavior. Microscopic analysis of the distribution of components within the aerosol particles showed that the observed size dependence is due to the differences in the mixing state. The composition and water uptake properties of sea spray aerosol particles were also measured during a phytoplankton bloom. The results showed that water uptake properties were directly related to the chemical composition of the particles and hygroscopicity decreased with increase in the fraction of water insoluble organic matter emitted during phytoplankton bloom. Finally, multiple methods of particle size, phase and shape analysis were compared and the results showed that the techniques that operate under ambient conditions provide the most relevant and robust measurement of particle size. Additionally, several storage methods for substrate deposited aerosol particles were evaluated and it was determined that storing samples at low relative humidity led to irreversible changes due to sample dehydration while sample freezing and thawing leads to irreversible changes due to phase changes and water condensation. Therefore it is suggested that samples used for single-particles analysis should be stored at ambient laboratory conditions, or near conditions which they were collected, in order to preserve the sample phase and hydration state. The results presented in this dissertation provide insight into physicochemical properties of atmospheric aerosols and help us better understand the role of aerosol particles in the Earth's atmosphere.

Orientador: Jean-Paul Laclau / Resumo: As mudanças climáticas têm causado alterações na temperatura e também nos regimes de precipitação do planeta, aumentando a probabilidade de ocorrência de secas mais severas, o que, no cenário florestal, pode resultar na mortalidade de florestas ao redor do mundo. Assim, é necessário um conhecimento mais detalhado sobre a dinâmica de absorção de água e nitratos pelas raízes das árvores, que explique o comportamento das árvores sob extrema seca. O objetivo do estudo foi avaliar a distância máxima do tronco e a profundidade máxima de absorção de nutrientes e água pelas raízes das árvores em florestas crescendo sobre Neossolos Quartzarênicos muito profundos, utilizando o 15N como marcador. As consequências do status social das árvores, comparando árvores dominantes e dominadas do mesmo genótipo numa floresta monoclonal foram estudadas em plantios de um clone híbrido de Eucalyptus urophylla x Eucalyptus grandis durante a estação seca. Os efeitos da sazonalidade (comparando as estações seca e chuvosa) foram estudados em três espécies do Cerrado: i) Xylopia aromatica (Lam.) Mart.; ii) Coussarea hydrangeifolia (Benth.) Müll.Arg.; and iii) Miconia albicans (Sw.) Steud. Além disso, foi avaliada a existência de uma complementaridade de nicho no solo entre essas espécies do Cerrado, com uma absorção do marcador em camadas diferentes. O marcador NO3--15N foi aplicado em talhões de eucalipto com 7 meses, 1,2 anos, 2,2 anos e 6,4 anos de idade, a várias profundidades do solo em 60 pontos, s... (Resumo completo, clicar acesso eletrônico abaixo) / Doutor

There are numerous situations where trees are grown together with herbaceous plants. In these situations there will be some degree of competition between their root zones, depending on the water content of the soils and crop and tree root distribution . Two studies were conducted : the first with maple (Acer platanoides) grown in turf grass, and the second with willow (Salix matsudana) grown in more deeply rooted barley . The objectives of this study were to quantify the effect of herbaceous competition of potential tree water stress under irrigation and when the soil is allowed to dry-down . Soil water uptake was measured in both studies to 1.2 m depth and outwards to 1.2-2.10 m away from the tree . In the maple-turf grass study, water content was measured in a single line away from the tree , while four lines covering a quadrant of the surface area were measured in willow . Water relations stomatal conductance and water potential, and tree growth were also monitored in both studies. Water uptake in turf plots was statistically different from mulch plots by depth and distance during three seasons. Water uptake was greatest at 0-60 cm depth in the turf treatments compared with mulch treatments. Soil water in mulched plots decreased slowly during the growing season. There were no statistical differences between bare soil and barley competition water uptake after soil surface water was depleted. There were marked differences in tree root characteristics as a result of competition from turf or barley roots. The root systems of maples in the mulch and willow in bare soil extended laterally and fine roots were evident. Tree roots extended deeper and fine root were reduced under competition from turf and barley. Trees growing with turf and barley had fewer roots in the top 0.3 m soil surface while trees in mulch and bare soil had more and greater diameter roots at the same depth. Early in the season, when water content is high, root competition for water was not evident, and late in the season after turf roots and barley had depleted the soil water, trees exhibited more negative predawn leaf water potential and less stomatal conductance in response to water stress during a soil dry-down period. Tree growth was measured periodically during 1994, 1995, and 1996. Leaf area and stem growth comparisons showed a significant increase in size as a result of the absence of competition in both species, with mulch and bare soil treatments. Leaf area in mulched trees was twice that in turf treatments. In summary, we found that competition resulted in deeper tree root growth and less top growth in the presence of herbaceous competitors.