O conhecimento da movimentação da água no solo é de grande importância para a agricultura, pois a água é um dos fatores que mais influenciam no rendimento das culturas. Das várias técnicas utilizadas para o monitoramento do conteúdo de água no solo, a reflectometria no domínio do tempo (TDR) vem sendo bastante difundida entre os pesquisadores por apresentar inúmeras vantagens, dentre as quais a mensuração em tempo real e a possibilidade de leituras automatizadas. Com o objetivo de avaliar a movimentação da água num perfil de um Latossolo vermelho-amarelo, conduziu-se um experimento obtendo-se os valores de umidade do solo e condutividade elétrica através das leituras de um equipamento de TDR com sondas instaladas em uma trincheira em diversas profundidades (0,10 m a 0,60 m) e com diferentes taxas de aplicação (2, 4 e 8 L.h-1) de solução em intervalos de 1 hora, via irrigação por gotejamento. A partir dos resultados obtidos, pôde concluir-se que diferentes vazões de aplicação determinam características particulares de formação do bulbo molhado e da movimentação da solução no solo. Para as condições de solo e de acordo com o volume e a frequência utilizada durante este experimento, recomenda-se a aplicação de pequenas quantidades de solução em intervalos mais frequentes para reduzir a perda por percolação de água e solutos. / The knowledge of the water distribution in soil has great importance to the agriculture because of the crop yield the cultures income has a direct influence by the water. There are many techniques used to monity soil moisture, and the time domain reflectometry (TDR), has a satisfactory application among the researches because the advantages, allow the real time measurements can be automatized and the automatized. With the objective to appraise the water distribution and electrical conductivity in a Red-yellow Latosol profile, the experiment was conducted measuring soil moisture through the TDR equipment reading with probes fixed in a trench in various depths (0,10 m to 0,60 m) and with different applications rates of solution (2,4 and 8 L.h-1) , with one hour interval by dripping irrigation. The results allowed us to that the different sewages applications determinate the particular characteristics of the wet bulb arrangement and the water soil distribution. For the soil conditions and according to the volume and frequency used during this experiment, it is recommended to apply of small quantities of a solution at more frequent intervals to reduce the loss by percolation of water and solute.

A citricultura é um setor de grande importância para o país na geração de divisas, formação de renda e capital. Um dos fatores críticos no sucesso de um sistema de irrigação localizada é a definição em projeto da fração de área molhada no solo. Face às dificuldades técnicas encontradas nesse tipo de estudo, até o presente, inexistem na literatura científica trabalhos confiáveis que estabeleçam os valores ótimos de fração de área molhada no solo para as diferentes culturas e condições edafoclimáticas. Esse trabalho teve como objetivo principal avaliar o efeito do molhamento parcial do solo para plantas jovens de laranja Valência sob porta-enxerto de citrumelo Swingle e limão Cravo em dois tipos de solo. Os objetivos secundários foram: a) Avaliar o método da sonda de dissipação térmica na estimativa da transpiração em laranja Valência e b) Estabelecer as relações entre a transpiração das plantas, sem restrição de área de solo, molhado e a demanda atmosférica. O experimento foi conduzido em estufa nas dependências do Departamento de Engenharia de Biossistemas da ESALQ/USP. Foi testado o molhamento de 12,5% da área do solo. Mudas de laranja foram plantadas em caixas de 500 L internamente divididas em compartimentos. Determinou-se simultaneamente a transpiração de todas as plantas através de sondas de dissipação térmica, o conteúdo de água no solo, o crescimento das plantas (área foliar e diâmetro de caule) e o número total de frutos por planta. Inicialmente todas as plantas tiveram 100% do volume de solo ocupado pelas raízes irrigado, sendo determinada a contribuição relativa de cada compartimento da caixa na transpiração. Completada a secagem dos compartimentos não irrigados, foi calculado o percentual da transpiração relativa a 100% de área molhada do solo pela relação entre transpiração de cada planta e a transpiração média das plantas com 100% da área do solo molhado. De acordo com os resultados, conclui-se que ocorre redução da transpiração pela restrição da área de solo molhado, sendo esta redução influenciada não só pelo tipo de solo e porta-enxerto, como também pelo número de dias após início da irrigação parcial, demanda evaporativa da atmosfera e fase fenológica da planta. A adaptação do sistema radicular à redução da área molhada ocorreu em torno de 156 dias. Apesar da redução da taxa transpiratória, não houve diferença significativa entre os tratamentos em relação ao crescimento vegetativo e número de frutos por planta. A transpiração das plantas foi influenciada pelo tipo de porta-enxerto utilizado, do crescimento em área foliar e da fase fenológica, sendo que sua relação com a evapotranspiração de referência não é linear em toda faixa de demanda evaporativa da atmosfera. O método da sonda de dissipação térmica, com calibragem específica e correção dos gradientes térmicos naturais no caule, mostrou-se eficaz na avaliação da transpiração de plantas jovens de laranjeira. / The citrus industry is a great important sector to the Brazilian country to generate foreign currency income and capital formation. The determination of the fractional wetted area in the soil is a critical factor in the success of an irrigation system project. Due to the technical difficulties to find out dates in this kind of study, there are no reliable studies in the scientific literature to establish the optimal values of fractional wetted area for different crops, soil and weather. This study aims to evaluate the effect of partial wetting of the soil for Valencia orange under the rootstock Swingle and Rangpur in two soil types. As secondary objectives: a) To evaluate the method of heat dissipation probe in the transpiration estimative in the Valencia orange plant, b) to establish the relationship between the atmospheric demand and plant transpiration, without restriction wetted area. The experiment was conducted in a greenhouse in the Biosystems Engineering Department of ESALQ/USP, Piracicaba-SP, Brazil. It was tested the wetness of 12.5% of the area of soil. For this, orange seedlings were planted in boxes of 500 L internally divided into compartments. It was simultaneously determined transpiration of all plants using heat dissipation probes (sap flow), measured the soil water content, plant growth (leaf area, stem diameter) and the total number of fruits per plant. Initially, it was irrigated 100% of root system of all plants and it was determined the contribution of each compartment of the box in the plant transpiration by the difference in water storage in the soil and measured plant transpiration. When it was completed the drying of not irrigated compartment, it was calculated the percentage of transpiration on 100% of the wetted soil area by the relationship between transpiration of each plant and the average of plant transpiration with 100% of the wetted area. According to the results can be conclude that occur reduction in the transpiration flow due to the restricting of wet soil area and this reduction is not only influenced by soil type and rootstock, but also due to the number of days after onset of partial irrigation, atmospheric evaporative demand and plant phenological stage. The adaptation of the root system to the reduction of the wet soil volume occurred around 156 days. Despite of the reduction in transpiration rate, it was not observed significant difference between treatments in relation to vegetative growth and fruit number per plant. Plant transpiration was influenced by the type of rootstock used, leaf area growth and phenological stage. However the relationship between the plant transpiration and EToPM is not linear across the range of atmospheric evaporative demand. The method of heat dissipation probe, calibrated specifically for the study and with correction of the thermal natural gradient in the trunk was effective in the evaluation of the seedlings of orange transpiration.

Em função do número reduzido de estudos sobre o movimento da água e de íons no bulbo molhado, foi realizado este trabalho com o objetivo de avaliar a distribuição de água e concentração de nutrientes no bulbo formado pelo sistema de gotejamento enterrado em comparação ao superficial. O ensaio foi conduzido na área experimental do Departamento de Engenharia Rural da Escola Superior de Agricultura "Luiz de Queiroz" - ESALQ/USP, localizada no município de Piracicaba, SP. Para a avaliação foram abertas trincheiras e instaladas sondas de TDR, para o monitoramento da distribuição da solução, dispostas a 0,5; 0,15; 0,25; 0,35 e 0,45 m - profundidade, e a 0,5; 0,15; 0,25; 0,35 m - comprimento, totalizando 17 sondas em malha por trincheira. A solução de KNO3 foi aplicada a partir de gotejadores com diferentes vazões (2 e 4 L/h), sendo aplicado o volume de 1 L em intervalos de 1 hora, totalizando 10 L de solução por repetição, Conjuntamente ao monitoramento da distribuição da solução no solo, medições da área superficial molhada e do disco saturado foram feitas com régua milimetrada, além disso, foi estabelecido um volume de controle onde foram avaliadas a uniformidade de aplicação de água e KNO3. Desta forma, foi possível verificar que: em relação aos sistemas superficiais, os sistemas enterrados apresentaram menor área superficial molhada e atingiram uma maior largura e profundidade; a umidade inicial do solo influencia a formação do bulbo molhado e o movimento do KNO3 no solo; a uniformidade de sais distribuídos no volume de controle é afetada negativamente pelo aumento do volume aplicado e as maiores concentrações de água e concentração de KNO3 foram obtidas próximas ao ponto de emissão. / In function of the reduced number of studies on the water and ions movement in the wet soil volume, this work was conducted with the goal of evaluating the distribution of water and nutrient concentration in the wetted soil volume formed by subsurface drip irrigation (SDI) in comparison to surface system. The rehearsal was concducted in the experimental area of the Rural Engineering Department - ESALQ/USP, located in Piracicaba, SP. Trenches were opened and installed probes of TDR for studying to solution distribution, to facilitate the study a mesh of probes was disposed to 0,5; 0,15; 0,25; 0,35 and 0,45 m - depth, and to 0,5; 0,15; 0,25; 0,35 m - length, with the total of 17 probes. The solution of KNO3 was applied starting from emitters with different flows (2 and 4 L/h), it was applied the volume of 1 L within intervals of 1 hour, with the total of 10 L of solution for repetition. All together to study the solution distribution in the soil, the wet superficial area measurements and of the saturated disc they were done by the ruler, besides, it was established a control volume where the uniformity application of water and KNO3 was analysed. This way, it was possible to verify that: in relation to the superface systems, the SDI presented smaller wet superficial area and they reached a larger width and depth; the initial soil water content influences the formation of the wetted soil volume and the KNO3 movement in the soil; the salt uniformity, distributed in the control volume, is affected negatively by the applied volume increased, and the largest concentrations of water and KNO3 were obtained close to the emission point.

This work is a multi-scale effort to confront the rapidly evolving threat of biological weapons attacks through improved bioaerosol surveillance, detection, and response capabilities. The effects of bioaerosol release characteristics, transport in the atmospheric surface layer, and implications for bioaerosol sampler design and real-time detection were studied to develop risk assessment and modeling tools to enhance our ability to respond to biological weapons attacks. A simple convection-diffusion-sedimentation model was formulated and used to simulate atmospheric bioaerosol dispersion. Model predictions suggest particles smaller than 60 micrometers in aerodynamic diameter (AD) are likely to be transported several kilometers from the source. A five fold increase in effective mass collection rate, a significant bioaerosol detection advantage, is projected for samplers designed to collect particles larger than the traditional limit of 10 micrometers AD when such particles are present in the source distribution. A family of dynamically scaled wetted-wall bioaerosol sampling cyclones (WWC) was studied to provide bioaerosol sampling capability under various threat scenarios. The effects of sampling environment, i.e. air conditions, and air flow rate on liquid recovery rate and response time were systematically studied. The discovery of a critical liquid input rate parameter enabled the description of all data with self-similar relationships. Empirical correlations were then integrated into system control algorithms to maintain microfluidic liquid output rates ideally suited for advanced biological detection technologies. Autonomous ambient air sampling with an output rate of 25 microliters per minute was achieved with open-loop control. This liquid output rate corresponds to a concentration rate on the order of 2,000,000, a substantial increase with respect to other commercially available bioaerosol samplers. Modeling of the WWC was performed to investigate the underlying physics of liquid recovery. The set of conservative equations governing multiphase heat and mass transfer within the WWC were formulated and solved numerically. Approximate solutions were derived for the special cases of adiabatic and isothermal conditions. The heat and mass transfer models were then used to supplement empirical correlations. The resulting semi-empirical models offer enhanced control over liquid concentration factor and further enable the WWC to be deployed as an autonomous bioaerosol sampler. / text

Fossil fuel and advanced industrialization techniques contribute to global warming through emissions of greenhouse gases such as CO2. In order to mitigate climate change, there is a desperate need to reduce CO2 emissions from different sources. CO2 capture and sequestration (CCS) play an important role in these reductions. Naturally occurring enzymes, e.g., carbonic anhydrase (CA), can catalyze these reactions in living systems. Much effort has been focused on complexes of zinc with ligands such as teta, cyclen and tripodal ligands including BIMA and Trispyrazolylborates. These complexes have many interesting CO2 capture properties, but maintain toxic perchlorate ions. We desired to replace them with less hazardous counteranions like BF4- or PF6-. Our research focused mainly on the synthesis and characterization of Zn, Co and Cu cyclen and teta complexes that could mimic CA. We also examined some of these species for catalytic CO2 hydration behavior on wetted-wall column (WWC) at Center for Applied Energy Research (CAER). We successfully synthesized and characterized eight new complexes. These catalysts as CO2 capture systems are more stable have low molecular weights (compared to CA) and more cost effective than enzymes. In terms of catalytic activity significant results were obtained only for few of the catalysts

Em função do número reduzido de estudos sobre o movimento da água e de íons no bulbo molhado, foi realizado este trabalho com o objetivo de avaliar a distribuição de água e concentração de nutrientes no bulbo formado pelo sistema de gotejamento enterrado em comparação ao superficial. O ensaio foi conduzido na área experimental do Departamento de Engenharia Rural da Escola Superior de Agricultura "Luiz de Queiroz" - ESALQ/USP, localizada no município de Piracicaba, SP. Para a avaliação foram abertas trincheiras e instaladas sondas de TDR, para o monitoramento da distribuição da solução, dispostas a 0,5; 0,15; 0,25; 0,35 e 0,45 m - profundidade, e a 0,5; 0,15; 0,25; 0,35 m - comprimento, totalizando 17 sondas em malha por trincheira. A solução de KNO3 foi aplicada a partir de gotejadores com diferentes vazões (2 e 4 L/h), sendo aplicado o volume de 1 L em intervalos de 1 hora, totalizando 10 L de solução por repetição, Conjuntamente ao monitoramento da distribuição da solução no solo, medições da área superficial molhada e do disco saturado foram feitas com régua milimetrada, além disso, foi estabelecido um volume de controle onde foram avaliadas a uniformidade de aplicação de água e KNO3. Desta forma, foi possível verificar que: em relação aos sistemas superficiais, os sistemas enterrados apresentaram menor área superficial molhada e atingiram uma maior largura e profundidade; a umidade inicial do solo influencia a formação do bulbo molhado e o movimento do KNO3 no solo; a uniformidade de sais distribuídos no volume de controle é afetada negativamente pelo aumento do volume aplicado e as maiores concentrações de água e concentração de KNO3 foram obtidas próximas ao ponto de emissão. / In function of the reduced number of studies on the water and ions movement in the wet soil volume, this work was conducted with the goal of evaluating the distribution of water and nutrient concentration in the wetted soil volume formed by subsurface drip irrigation (SDI) in comparison to surface system. The rehearsal was concducted in the experimental area of the Rural Engineering Department - ESALQ/USP, located in Piracicaba, SP. Trenches were opened and installed probes of TDR for studying to solution distribution, to facilitate the study a mesh of probes was disposed to 0,5; 0,15; 0,25; 0,35 and 0,45 m - depth, and to 0,5; 0,15; 0,25; 0,35 m - length, with the total of 17 probes. The solution of KNO3 was applied starting from emitters with different flows (2 and 4 L/h), it was applied the volume of 1 L within intervals of 1 hour, with the total of 10 L of solution for repetition. All together to study the solution distribution in the soil, the wet superficial area measurements and of the saturated disc they were done by the ruler, besides, it was established a control volume where the uniformity application of water and KNO3 was analysed. This way, it was possible to verify that: in relation to the superface systems, the SDI presented smaller wet superficial area and they reached a larger width and depth; the initial soil water content influences the formation of the wetted soil volume and the KNO3 movement in the soil; the salt uniformity, distributed in the control volume, is affected negatively by the applied volume increased, and the largest concentrations of water and KNO3 were obtained close to the emission point.

Melting and melt segregation are key processes in the geochemical evolution of the Earth. However, mechanism and time scale of melt transport from the source to the surface are still not well understood and are dependent on the grain-scale distribution of melt. A related question is the retention of melt in partially molten regions of the Earths upper mantle. Seismic observations from mid-ocean ridges (MOR) and subduction zones are interpreted to show in-situ melt contents up to 3%, while geochemical observations from MOR basalts are inferred to indicate very efficient extraction of melt (porosities of order 0.1%). Earlier theoretical models of the melt distribution were based on the balance of surface tension between melt and uniform crystalline grains, predicting a simple net- work of melt along three-grain edges. Analyses of experimentally produced samples of olivine and basaltic melt show that the melt geometry is much more complex, and includes wetted two-grain boundaries. I reconstructed the melt geometry of two experimentally produced samples by serial sectioning and 3-D rendering of the pore geometry which demonstrates for the first time that melt exists in thin layers on two-grain boundaries. This confirms the inferences from previous 2-D observations and has significant implications for physical properties of partially molten regions, for example seismic velocities and attenuation. The wetted two-grain boundaries are inferred to be a consequence of continuous grain growth. Due to the complexity of the 3-D melt geometry the perme- ability of partially molten rocks can not be predicted from simple models. I therefore investigated the permeability as a function of porosity for both synthetic and ex- perimentally determined pore geometries using a lattice-Boltzmann method. The calculated permeability is not a simple function of porosity, but increases rapidly at a critical fraction of wetted two-grain boundaries. In order to extrapolate the experimentally based findings to grain sizes expected in natural rocks I examined the geometry of secondary phases inferred to represent relict melt in mantle peridotites from the Krivaja massif in Bosnia. These findings corroborate the experimental observations of wetted two-grain boundaries.

Made available in DSpace on 2016-08-31T13:24:10Z (GMT). No. of bitstreams: 1 JeovanizelioFG_DISSERT.pdf: 2944061 bytes, checksum: b719d6cdb79773d0a7ede20c0370bab2 (MD5) Previous issue date: 2009-08-28 / The knowledge of the characteristics and dimensions of wetted bulb is substantially important in the measured of the drip irrigation. Due to the complexity of the physical phenomena involved in the infiltration and redistribution process of water in the soil, develop a mathematical model that simulates the flow of water in the soil is not a very simple task. The objective of this work was developed a mathematical model semi-analytic for predicting dimensions of wetted bulb that it depends on parameters of easy obtaining in the field, just as, the superficial diameter of the wetted bulb. The model allows the simulation of the format and dimensions of the wetted bulb for three different forms: when the diameter of the bulb is given in two depths of easy obtaining in the field, that is, in the surface of the soil and in the depth of 10 cm; starting from the superficial diameter and standards existent for the maximum depth in agreement with the texture of the soil; starting from the surfaces of answers. The mathematical model was obtained by numeric simulation of the equations that govern the flow of water in the soil, originating like this, semi-analytic solution for the formation of the wetted bulb. The model was validate, starting from field data of a soil with medium texture after compared with the simulate data. The accomplished comparisons demonstrate that the proposed model predicting the dimensions of the wetted bulb satisfactorily and it can be used as auxiliary tool in the measurement of the drip irrigation. / O conhecimento das características do bulbo molhado é substancialmente importante para o dimensionamento da irrigação por gotejamento. Devido à complexidade dos fenômenos físicos envolvidos no processo de infiltração e redistribuição de água no solo, desenvolver um modelo matemático que simule o fluxo de água no solo é uma tarefa não muito simples. O objetivo desse trabalho é desenvolver um modelo matemático semi-analítico para estimar as dimensões do bulbo molhado que depende de parâmetros de fácil obtenção no campo, tal como o diâmetro superficial do bulbo molhado. O modelo permite a simulação do formato e as dimensões do bulbo molhado por três formas diferentes: quando é dado o diâmetro do bulbo em duas profundidades de fácil obtenção no campo, isto é, na superfície do solo e na profundidade de 10 cm; a partir do diâmetro superficial e padrões existentes para a profundidade máxima de acordo com a textura do solo; a partir das superfícies de respostas. O modelo matemático foi obtido por simulação numérica das equações que governam o fluxo de água no solo, originando assim, solução semi-analítica para a formação do bulbo molhado. O modelo foi validado, a partir de dados de campo de um solo com textura média e, em seguida comparados com os dados simulados. As comparações realizadas demonstram que o modelo proposto estima satisfatoriamente as dimensões do bulbo molhado e pode ser utilizado como ferramenta auxiliar no dimensionamento da irrigação por gotejamento.

Made available in DSpace on 2016-08-31T13:24:20Z (GMT). No. of bitstreams: 1 LuizAAS_DISSERT.pdf: 2790394 bytes, checksum: 1bac58cbcfc89d893d66e58cfa50081f (MD5) Previous issue date: 2009-03-06 / In this work, a mathematical model was developed for the simulation of soil water movement under surface drip irrigation, being used the method of the finite volumes for the resolution of the partial differential equation of water flow in porous media. The soil water flow was treated three-dimensionally for the determination of your movement in the infiltration and redistribution phases. The model allows the determination dimensions and shape of the wetted bulb, of the partial and final dimension of the saturated disc radius and the determination of the saturated soil volume, when to deal about of isolated bulb. In the case of overlapping bulbs, the model allows the determination of the width and depth of the formed wetted strip, making possible the choice of the drippers spacing that better it is adapted to the conditions of the irrigation project and management. A computational program was developed with base in the model, and the obtained results were validated starting from comparisons with field data and results of simulations of other models. These comparisons demonstrated that the model presents reliable results and it can be used as tool for the designing of drip irrigation installations. The sensibility analysis accomplished starting from the variation of some parameters of the soil and of the emitter (initial moisture, saturated soil hydraulic conductivity and trickle discharge), it demonstrated that, with relationship to the final moisture inside of the bulb, the model is so much relatively sensitive to positive variations as negatives of those parameters. / Neste trabalho, foi desenvolvido um modelo matemático para a simulação do movimento de água no solo sob irrigação por gotejamento superficial, utilizando-se o método dos volumes finitos para a resolução da equação diferencial parcial de escoamento de água em meios porosos. O fluxo de água no solo foi tratado tridimensionalmente para a determinação do seu movimento nas fases de infiltração e redistribuição. O modelo permite a determinação da forma e das dimensões do bulbo molhado, da dimensão parcial e final do raio do disco saturado e a determinação do volume de solo saturado, quando tratar-se de bulbo isolado. No caso de bulbos sobrepostos, o modelo permite a determinação da largura e profundidade da faixa molhada formada, possibilitando a escolha do espaçamento entre gotejadores que melhor se adeque às condições do projeto e manejo da irrigação. Um programa computacional foi desenvolvido com base no modelo, e os resultados obtidos foram validados a partir de comparações com dados de campo e resultados de simulações de outros modelos. Estas comparações demonstraram que o modelo apresenta resultados confiáveis e pode ser utilizado como ferramenta para o dimensionamento de instalações de irrigação por gotejamento. A análise de sensibilidade realizada a partir da variação de alguns parâmetros do solo e do emissor (umidade inicial, condutividade hidráulica do solo saturado e vazão do gotejador), demonstrou que, com relação à umidade final dentro do bulbo, o modelo é relativamente sensível tanto à variações positivas quanto negativas desses parâmetros.

Drag polars for three Micro Air Vehicles (MAVs) were measured at Reynolds numbers of 70,000, 50,000, 30,000, and 10,000 and compared to predictions generated using the classical approach. The MAVs tested had different configurations and aspect ratios varying from 1.2 to 1.6 and ratios of wetted surface area to planform area from 2.6 to 3.9. A force balance was used to measure the lift and drag on the MAVs at angles of attack ranging from -5 degrees (or -10 degrees) to 10 degrees. The force balance allowed the MAVs to rotate in the pitching axis. The MAV angle of attack was set using an elevator installed on the MAV and controlled using a standard radio control used by RC plane enthusiasts. Uncertainty analysis performed on the data showed the uncertainty for high Reynolds numbers was dominated by velocity uncertainty, and uncertainty for the lower Reynolds numbers was dominated by uncertainty in the force measurements. Agreement between measured and predicted drag polars was good with the measured drag never being more than two times the predicted drag. For the majority of the tests, the drag coefficients followed the expected Reynolds number trend: increasing with decreasing Reynolds number.